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Journal articles on the topic 'Rhodium (II) dimers'

Author: Grafiati

Published: 4 June 2021

Last updated: 11 February 2022

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1

Zhu, Di, Arzoo Z. Sharma, Christopher R. Wiebe, and Peter H. M. Budzelaar. "Rhodium(ii) dimers without metal–metal bonds." Dalton Transactions 44, no. 30 (2015): 13460–63. http://dx.doi.org/10.1039/c5dt02218e.

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Oxidation of (^MeBDI)Rh(cyclooctene) (^MeBDI = [2,6-Me₂C₆H₃NCMe]₂CH) with Br₂ or I₂ produces paramagnetic halide-bridged Rh^II dimers [(^MeBDI)Rh]₂(μ-X)₂ without a direct Rh–Rh bond.

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2

Cooke, Michael W., Garry S. Hanan, Frédérique Loiseau, Sebastiano Campagna, Masashi Watanabe, and Yasutaka Tanaka. "The Structural and Functional Roles of Rhodium(II)-Rhodium(II) Dimers in Multinuclear Ruthenium(II) Complexes." Angewandte Chemie International Edition 44, no. 31 (August 5, 2005): 4881–84. http://dx.doi.org/10.1002/anie.200500392.

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3

Cooke, Michael W., Garry S. Hanan, Frédérique Loiseau, Sebastiano Campagna, Masashi Watanabe, and Yasutaka Tanaka. "The Structural and Functional Roles of Rhodium(II)-Rhodium(II) Dimers in Multinuclear Ruthenium(II) Complexes." Angewandte Chemie 117, no. 31 (August 5, 2005): 4959–62. http://dx.doi.org/10.1002/ange.200500392.

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4

Pruchnik, Florian, Brian R. James, and Pál Kvintovics. "Dimeric rhodium(II) complexes containing bridging mandelate ligands." Canadian Journal of Chemistry 64, no. 5 (May 1, 1986): 936–39. http://dx.doi.org/10.1139/v86-155.

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The syntheses and characterization of some dimeric rhodium(II) complexes containing bridging mandelato ligands and a metal–metal bond are described. The compounds isolated are Rh2(O2CR)4(H2O)2, previously described by Shchelokov and coworkers, and derivatives of the type Rh2(O2CR)2(N—N)2X2•nH2O (R = (R)—CH(OH)Ph, N—N = o-phenanthroline or 2,2′-dipyridyl, X = Cl, Br, I, and n is 4, 2, or 1). A mixture of species containing both bridged acetate and mandelate was isolated also. Infrared and electronic spectral data are reported. The chloride ligands of the dimers are displaced readily by alcohols, phosphines, phosphites, and amines; the metal centre also may be reduced by alcohols, P(OEt)3, and nBu2NH. Preliminary studies point to the conditions necessary for the rhodium(II) mandelate and derivatives (phosphine or (N—N) substituted) to activate H2 for catalytic hydrogenation of olefins and ketones, including prochiral substrates.

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5

Liang, Jiang-Lin, Shi-Xue Yuan, Philip Wai Hong Chan, and Chi-Ming Che. "Chiral rhodium(II,II) dimers catalyzed enantioselective intramolecular aziridination of sulfonamides and carbamates." Tetrahedron Letters 44, no. 31 (July 2003): 5917–20. http://dx.doi.org/10.1016/s0040-4039(03)01409-6.

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6

Del Rossi, Kenneth J., Xiao-Xiang Zhang, and Bradford B. Wayland. "Reactions of CH bonds in organica oxygenates with octaethylporphyrinato rhodium(II) and iridium(II) dimers." Journal of Organometallic Chemistry 504, no. 1-2 (November 1995): 47–56. http://dx.doi.org/10.1016/0022-328x(95)05569-b.

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7

Vasil'ev, Victor V., Sergey M. Borisov, Andrea Maldotti, and Alessandra Molinari. "Spectral properties of cationic water-soluble metallo-porphyrins immobilized in a perfluorosulfonated ion-exchange membrane." Journal of Porphyrins and Phthalocyanines 07, no. 12 (December 2003): 780–86. http://dx.doi.org/10.1142/s1088424603000963.

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The behavior of palladium(II), platinum(II) and rhodium(III) complexes with two cationic water-soluble porphyrins: meso-tetrakis(4-N-methylpyridyl)porphyrin and meso-tetrakis(4-N,N,N-trimethylaminophenyl)porphyrin in Nafion® membrane and in Nafion® solution have been studied by UV-visible absorption and emission spectroscopy. All metalloporphyrins are localized in the interfacial region of Nafion®. The six-coordinate Rh(III) complexes are monomeric inside Nafion®, but immobilized four-coordinate Pd(II) and Pt(II) complexes form face-to-face dimers with a characteristic blue shifted Soret band. All immobilized complexes exhibit a strong red phosphorescence at room temperature in the absence of oxygen. Phosphorescence decays for all metalloporphyrins were found to be a single exponential but phosphorescence lifetimes noticeably increased in the Nafion® membrane as compared to lifetimes in aqueous solution.

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8

Natkaniec, Leszek, and Florian P. Pruchnik. "Electronic structure of rhodium(II) dimers of formula [Rh2X2(µ-O2CH)2(HNCHCHNH)2](X = halide)." J. Chem. Soc., Dalton Trans., no. 22 (1994): 3261–66. http://dx.doi.org/10.1039/dt9940003261.

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9

Handa, Makoto, Mayumi Watanabe, Daisuke Yoshioka, Seiichiro Kawabata, Ryoji Nukada, Masahiro Mikuriya, Hiroshi Azuma, and Kuninobu Kasuga. "Adduct Polymers and Dimers of Rhodium(II) Pivalate with Pyrazine, 4,4′-Bipyridine, 1,4-Diazabicyclo[2.2.2]octane, Triethylamine, and Pyridine." Bulletin of the Chemical Society of Japan 72, no. 12 (December 1999): 2681–86. http://dx.doi.org/10.1246/bcsj.72.2681.

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10

Bailey, James A., Stephen L. Grundy, and Stephen R. Stobart. "Pyrazolyl-bridged iridium dimers 15. Synthesis of binuclear cyclopentadienyl Ir(III) complexes and the rhodium analogues: reductive access to the bimetal (II) state." Inorganica Chimica Acta 243, no. 1-2 (February 1996): 47–56. http://dx.doi.org/10.1016/0020-1693(96)04891-8.

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11

Begum, I., G. Schnakenburg, and R. Streubel. "Synthesis and reactions of C-phosphanylated thiazol-2-thiones." Dalton Transactions 45, no. 7 (2016): 2955–62. http://dx.doi.org/10.1039/c5dt03662c.

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Regioselective synthesis of the P(iii) substituted thiazole-2-thione I is presented. Oxidation of I resulted in P(V) chalcogenide thiazole-2-thiones (E = O, S, Se). Desulfurization of I (E = O) using hydrogenperoxide led to the first C-phosphanoyl thiazolium salt II. Deprotonation of II and reaction with cyclooctadiene rhodium(i) chloride dimer yielded thiazole-2-ylidene rhodium(i) complex III.

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12

Muthusamy, Sengodagounder, and Thangaraju Karikalan. "Rhodium(ii) catalyzed synthesis of macrocycles incorporating oxindole via O–H/N–H insertion reactions." Org. Biomol. Chem. 12, no. 45 (2014): 9243–56. http://dx.doi.org/10.1039/c4ob01671h.

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Synthesis of 10- to 29-membered oxaza-macrocyclesviaintramolecular O–H/N–H insertion reactions catalyzed by a rhodium(ii) acetate dimer is demonstrated. Synthesis of symmetric macrocyclesviahead to tail dimerization reactions is also delineated.

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13

Handa, Makoto, Tadahiro Nakao, Masahiro Mikuriya, Takanori Kotera, Ryoji Nukada, and Kuninobu Kasuga. "Chain Complexes of Rhodium(II) Pivalate Dimers Formed by Ligation of CC Double Bond and Carbonyl Oxygen ofp-Quinone [{Rh2(O2CCMe3)4(p-Q)2}{Rh2(O2CCMe3)4}]n,p-Q = 1,4-Benzoquinone and 1,4-Naphthoquinone." Inorganic Chemistry 37, no. 1 (January 1998): 149–52. http://dx.doi.org/10.1021/ic970246d.

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14

Lee, Sin, Mario Mediati, and Bradford Wayland. "Octaethylporphyrinato rhodium cation dimer, [(OEP)Rh]2+2: strong dimer bonding resulting from both rhodium(II)–rhodium(II) and interporphyrin cation radical interactions." J. Chem. Soc., Chem. Commun., no. 19 (1994): 2299–300. http://dx.doi.org/10.1039/c39940002299.

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15

Honey, Mark A., and Christopher J. Moody. "Synthesis of Indoxylic Acid Esters by Rhodium-catalyzed Carbene N–H Insertion and Thermal Cyclization." Australian Journal of Chemistry 67, no. 9 (2014): 1211. http://dx.doi.org/10.1071/ch14116.

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Reaction between diethyl diazomalonate and a range of N-alkylanilines in the presence of a catalytic amount of rhodium(ii) acetate dimer afforded carbene N–H insertion to produce anilinomalonates in modest-to-good yields. Upon heating to a high temperature for a short time, the anilinomalonates underwent thermal cyclization to indoxylic acid esters.

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16

Aghabali, Amineh, Sharon Jun, Marilyn M. Olmstead, and Alan L. Balch. "The directional character of the piperazine double addition product, e{N(CH2CH2)2N}2C60, as a building block for forming crystalline fullerene polymers." CrystEngComm 20, no. 7 (2018): 924–29. http://dx.doi.org/10.1039/c7ce02117h.

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The piperazine double addition product, ^e{N(CH₂CH₂)₂N}₂C₆₀, has its donor atoms positioned to bind Lewis acids in two orthogonal directions. It has been used to construct crystalline, 1-d and 2-d polymers through reactions with diiodine and the rhodium(ii) acetate dimer.

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17

Wang, Kun, Thomas J. Emge, and Alan S. Goldman. "Crystal and molecular structure of a novel coordinatively unsaturated rhodium(II) dimer." Inorganica Chimica Acta 255, no. 2 (February 1997): 395–98. http://dx.doi.org/10.1016/s0020-1693(96)05388-1.

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18

HANDA, Makoto, Motoi YASUDA, Daisuke YOSHIOKA, Takahisa IKEUE, and Masahiro MIKURIYA. "Crystal Structure of Rhodium(II) Formamidinate Dimer with an Axial Acetonitrile Molecule." X-ray Structure Analysis Online 27 (2011): 15–16. http://dx.doi.org/10.2116/xraystruct.27.15.

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19

Liang, Jiang-Lin, Shi-Xue Yuan, Philip Wai Hong Chan, and Chi-Ming Che. "Rhodium(II,II) Dimer as an Efficient Catalyst for Aziridination of Sulfonamides and Amidation of Steroids." Organic Letters 4, no. 25 (December 2002): 4507–10. http://dx.doi.org/10.1021/ol0270475.

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20

HANDA, Makoto, Yoshiyuki ISHITOBI, Kazutaka MORIYAMA, Takahisa IKEUE, Daisuke YOSHIOKA, and Masahiro MIKURIYA. "Synthesis and Crystal Structure of Rhodium(II) Pentafluorobenzoate Dimer with Axial Methanol Molecules." X-ray Structure Analysis Online 27 (2011): 49–50. http://dx.doi.org/10.2116/xraystruct.27.49.

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21

Tocher, Derek A., and Joanne H. Tocher. "Synthesis and spectroelectrochemical characterisation of a novel rhodium(II) dimer, Rh2(PhNpy)4." Inorganica Chimica Acta 104, no. 2 (October 1985): L15—L17. http://dx.doi.org/10.1016/s0020-1693(00)86415-4.

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22

Handa, Makoto, Akihiro Takata, Tadahiro Nakao, Kuninobu Kasuga, Masahiro Mikuriya, and Takanori Kotera. "A Novel Chain Compound Composed of Rhodium(II) Pivalate Dimer and 1,4-Benzoquinone." Chemistry Letters 21, no. 10 (October 1992): 2085–88. http://dx.doi.org/10.1246/cl.1992.2085.

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23

Taber, Douglass F., Scott C. Malcolm, Klaus Bieger, Pascual Lahuerta, Mercedes Sanaú, Salah-Eddine Stiriba, Julia Pérez-Prieto, and M. Angeles Monge. "Synthesis, Structure, and Reactivity of the First Enantiomerically Pure Ortho-Metalated Rhodium(II) Dimer." Journal of the American Chemical Society 121, no. 4 (February 1999): 860–61. http://dx.doi.org/10.1021/ja9819559.

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24

HANDA, Makoto, Ryoko INOUE, Asami INOUE, Takayuki NAKAI, Takahisa IKEUE, Daisuke YOSHIOKA, and Masahiro MIKURIYA. "Synthesis and Crystal Structure of a Rhodium(II) Formamidinate Dimer with Axial Water and Methanol Molecules." X-ray Structure Analysis Online 28 (2012): 53–54. http://dx.doi.org/10.2116/xraystruct.28.53.

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25

Cogne, Andre, Andre Grand, Paul Rey, and Robert Subra. "Coordination chemistry of the nitronyl and imino nitroxides. Linear chain adducts with rhodium(II) trifluoroacetate dimer." Journal of the American Chemical Society 111, no. 9 (April 1989): 3230–38. http://dx.doi.org/10.1021/ja00191a020.

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26

Aghabali, Amineh, Marilyn M. Olmstead, and Alan L. Balch. "Zipping up fullerenes into polymers using rhodium(ii) acetate dimer and N(CH2CH2)2NC60as building blocks." Chem. Commun. 50, no. 96 (October 16, 2014): 15152–55. http://dx.doi.org/10.1039/c4cc06995a.

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27

HANDA, Makoto, Ayako SANAKA, Yuka SUGIKAWA, Takahisa IKEUE, Hidekazu TANAKA, Daisuke YOSHIOKA, and Masahiro MIKURIYA. "Polymer Complex of Rhodium(II) Formamidinate Dimer Linked by 1,4-Diisocyanobenzene with Toluene as Solvent of Crystallization." X-ray Structure Analysis Online 27 (2011): 73–74. http://dx.doi.org/10.2116/xraystruct.27.73.

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28

Best, Stephen P., Andrew J. Nightingale, and Derek A. Tocher. "The destructive oxidation of a rhodium(II) dimer: crystal and molecular structure of [Rh(Ph)(SbPh3)2Cl2(CH3CN)]." Inorganica Chimica Acta 181, no. 1 (March 1991): 7–9. http://dx.doi.org/10.1016/s0020-1693(00)85252-4.

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29

Wayland, Bradford B., Virginia L. Coffin, and Maria D. Farnos. "Estimation of the Rh-Rh bond dissociation energy in the (octaethylporphyrinato)rhodium(II) dimer by proton NMR line broadening." Inorganic Chemistry 27, no. 15 (July 1988): 2745–47. http://dx.doi.org/10.1021/ic00288a035.

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30

Cooper, Mervyn K., Gregory J. Organ, Paul A. Duckworth, Kim Henrick, and Mary McPartlin. "Synthesis and oxidation reactions of mono- and di-nuclear rhodium carbonyl complexes of (o-diphenylphosphinophenyl)amine, H2L; X-ray structure analysis of a rhodium(II) amido-bridged dimer, [{Rh(µ-HL)(CO)Cl}2]·EtOH." J. Chem. Soc., Dalton Trans., no. 9 (1988): 2287–92. http://dx.doi.org/10.1039/dt9880002287.

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31

Dowerah, Dulal, Lewis J. Radonovich, Neil F. Woolsey, and Mary Jane Heeg. "Reaction of 2-((.alpha.-R-benzylidene)amino)pyridines [R = CH3, 4-(CH3O)C6H4] with RhCl(L)3 or Rh2Cl2(CO)4: formation and structure of a rhodium(II) dimer." Organometallics 9, no. 3 (March 1990): 614–20. http://dx.doi.org/10.1021/om00117a014.

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32

Selent, Detlef, and Matthias Ramm. "Molekül- und kristallstruktur von μ-hydroxy-cyclooctadien(1,5)-rhodium(I)-dimer bei 173 K. Zur reaktion von [μ-OH)R(COD-1,5)]2mit [η5-C5(CH3)5]2Ti(VI)(CH)3)2 und (η5-C5H5)2Ti(II)[P(CH)3)3]2." Journal of Organometallic Chemistry 485, no. 1-2 (January 1995): 135–40. http://dx.doi.org/10.1016/0022-328x(94)24749-9.

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33

Liang, Jiang-Lin, Shi-Xue Yuan, Philip Wai Hong Chan, and Chi-Ming Che. "Chiral Rhodium(II,II) Dimers Catalyzed Enantioselective Intramolecular Aziridination of Sulfonamides and Carbamates." ChemInform 34, no. 47 (November 25, 2003). http://dx.doi.org/10.1002/chin.200347117.

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34

Liang, Jiang-Lin, Shi-Xue Yuan, Philip Wai Hong Chan, and Chi-Ming Che. "Rhodium(II,II) Dimer as an Efficient Catalyst for Aziridination of Sulfonamides and Amidation of Steroids." ChemInform 34, no. 16 (April 22, 2003). http://dx.doi.org/10.1002/chin.200316104.

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35

TOCHER, D. A., and J. H. TOCHER. "ChemInform Abstract: Synthesis and Spectroelectrochemical Characterisation of a Novel Rhodium(II) Dimer, Rh2(PhNpy)4." Chemischer Informationsdienst 17, no. 4 (January 28, 1986). http://dx.doi.org/10.1002/chin.198604299.

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36

COGNE, A., A. GRAND, P. REY, and R. SUBRA. "ChemInform Abstract: Coordination Chemistry of the Nitronyl and Imino Nitroxides. Linear Chain Adducts with Rhodium(II) Trifluoroacetate Dimer." ChemInform 20, no. 32 (August 8, 1989). http://dx.doi.org/10.1002/chin.198932272.

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37

WAYLAND, B. B., V. L. COFFIN, and M. D. FARNOS. "ChemInform Abstract: Estimation of the Rh-Rh Bond Dissociation Energy in the (Octaethylporphyrinato)rhodium(II) Dimer by 1H NMR Line Broadening." ChemInform 19, no. 47 (November 22, 1988). http://dx.doi.org/10.1002/chin.198847288.

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38

COOPER, M. K., G. J. ORGAN, P. A. DUCKWORTH, K. HENRICK, and M. MCPARTLIN. "ChemInform Abstract: Synthesis and Oxidation Reactions of Mono- and Dinuclear Rhodium Carbonyl Complexes of (o-Diphenylphosphinophenyl)amine, H2L; X-Ray Structure Analysis of a Rhodium(II) Amido-Bridged Dimer, ((Rh(μ-HL)(CO)Cl)2)·EtOH." ChemInform 19, no. 52 (December 27, 1988). http://dx.doi.org/10.1002/chin.198852269.

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