Academic literature on the topic 'Ring closing olefin metathesis'

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Journal articles on the topic "Ring closing olefin metathesis"

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Groso, Emilia, and Corinna Schindler. "Recent Advances in the Application of Ring-Closing Metathesis for the Synthesis of Unsaturated Nitrogen Heterocycles." Synthesis 51, no. 05 (2019): 1100–1114. http://dx.doi.org/10.1055/s-0037-1611651.

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This short review summarizes recent advances relating to the application of ring-closing olefin-olefin and carbonyl-olefin metathesis reactions towards the synthesis of unsaturated five- and six-membered nitrogen heterocycles. These developments include catalyst modifications and reaction designs that will enable access to more complex nitrogen heterocycles.1 Introduction2 Expansion of Ring-Closing Metathesis Methods3 Evaluation of Catalyst Design4 Indenylidene Catalysts5 Unsymmetrical N-Heterocyclic Carbene Ligands6 Carbonyl-Olefin Metathesis7 Conclusions
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Bruneau, Christian, Cédric Fischmeister, Dalmo Mandelli, et al. "Transformations of terpenes and terpenoids via carbon–carbon double bond metathesis." Catalysis Science & Technology 8, no. 16 (2018): 3989–4004. http://dx.doi.org/10.1039/c8cy01152d.

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The review reports on transformations of unsaturated terpenes and terpenoids via olefin metathesis processes including ring closing metathesis of dienes, cross metathesis with functional olefins and ethenolysis, and ring opening metathesis as well as ring opening/cross metathesis.
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Chatterjee, A. K., F. D. Toste, S. D. Goldberg, and Robert H. Grubbs. "Synthesis of coumarins by ring-closing metathesis." Pure and Applied Chemistry 75, no. 4 (2003): 421–25. http://dx.doi.org/10.1351/pac200375040421.

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Investigations into olefin ring-closing metathesis (RCM) have led to a general method for the synthesis of coumarins. Catalysts with higher activity, such as the second-generation ruthenium catalyst, promote the intramolecular reaction between two-electron deficient olefins. This method allows for convenient access to a variety of coumarins substituted at both the 3- and 4-positions, as well as a tetrasubstituted example.
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Kinderman, Sape S., Jan H. van Maarseveen, Hans E. Schoemaker, Henk Hiemstra, and Floris P. J. T. Rutjes. "Enamide−Olefin Ring-Closing Metathesis." Organic Letters 3, no. 13 (2001): 2045–48. http://dx.doi.org/10.1021/ol016013e.

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Riehl, Paul S., Daniel J. Nasrallah, and Corinna S. Schindler. "Catalytic, transannular carbonyl-olefin metathesis reactions." Chemical Science 10, no. 44 (2019): 10267–74. http://dx.doi.org/10.1039/c9sc03716k.

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Transannular carbonyl-olefin metathesis reactions complement existing procedures for related ring-closing, ring-opening, and intermolecular carbonyl-olefin metathesis. This enables molecular editing of steroid-derived frameworks.
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Fogg, Deryn E. "Inside the black box — Perspectives on transformations in catalysis." Canadian Journal of Chemistry 86, no. 10 (2008): 931–41. http://dx.doi.org/10.1139/v08-103.

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Tandem catalysis and olefin metathesis are powerful tools in the development of sustainable synthetic practices. This Award Lecture describes our advances in designing new tandem metathesis-hydrogenation methodologies for the synthesis of “designer materials” and Ru-pseudohalide metathesis catalysts that amplify opportunities for tuning catalyst activity, selectivity, and lifetime. Also discussed is the operation of a previously unrecognized oligomerization-backbiting pathway in ring-closing metathesis of conformationally flexible α,ω-dienes, which has important implications for the sustainabl
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Ni, Shengjun, and Johan Franzén. "Carbocation catalysed ring closing aldehyde–olefin metathesis." Chemical Communications 54, no. 92 (2018): 12982–85. http://dx.doi.org/10.1039/c8cc06734a.

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Vidavsky, Yuval, and N. Gabriel Lemcoff. "Light-induced olefin metathesis." Beilstein Journal of Organic Chemistry 6 (November 23, 2010): 1106–19. http://dx.doi.org/10.3762/bjoc.6.127.

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Light activation is a most desirable property for catalysis control. Among the many catalytic processes that may be activated by light, olefin metathesis stands out as both academically motivating and practically useful. Starting from early tungsten heterogeneous photoinitiated metathesis, up to modern ruthenium methods based on complex photoisomerisation or indirect photoactivation, this survey of the relevant literature summarises past and present developments in the use of light to expedite olefin ring-closing, ring-opening polymerisation and cross-metathesis reactions.
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Karle, Michael, and Ulrich Koert. "ChemInform Abstract: Ring-Closing Olefin Metathesis." ChemInform 33, no. 18 (2010): no. http://dx.doi.org/10.1002/chin.200218260.

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Wappel, Julia, César A. Urbina-Blanco, Mudassar Abbas, et al. "Halide exchanged Hoveyda-type complexes in olefin metathesis." Beilstein Journal of Organic Chemistry 6 (November 23, 2010): 1091–98. http://dx.doi.org/10.3762/bjoc.6.125.

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The aims of this contribution are to present a straightforward synthesis of 2nd generation Hoveyda-type olefin metathesis catalysts bearing bromo and iodo ligands, and to disclose the subtle influence of the different anionic co-ligands on the catalytic performance of the complexes in ring opening metathesis polymerisation, ring closing metathesis, enyne cycloisomerisation and cross metathesis reactions.
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Dissertations / Theses on the topic "Ring closing olefin metathesis"

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Courtney, Anne Kathleen. "Studies of substituted olefins in ring closing olefin metathesis and approaches toward a synthesis of manzamine A /." Digital version accessible at:, 2000. http://wwwlib.umi.com/cr/utexas/main.

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Nam, Youn Hee. "Development of Ru-Catalyzed Tandem Sequences Involving Ring-Closing Metathesis." Thesis, Boston College, 2013. http://hdl.handle.net/2345/3036.

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Thesis advisor: Marc L. Snapper<br>Tandem processes can have several advantages over multiple single step processes. Non-metathesis transformations of ruthenium alkylidenes were studied and applied to tandem processes. Ruthenium catalyzed tandem RCM/hydroacylation that allows access to tricyclic ring systems from readily available substrates was developed. Mechanistic investigations indicated that this reaction may proceed through a mechanism involving [Ru]-H species. A Ru-catalyzed tandem RCM/olefin isomerization/C-H activation sequence that provides significant advantages in terms of rapid e
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Xu, Chaofan. "New Ru-Based Catalysts and Strategies for Kinetically Controlled Stereoselective Olefin Metathesis:." Thesis, Boston College, 2020. http://hdl.handle.net/2345/bc-ir:109015.

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Thesis advisor: Amir H. Hoveyda<br>Chapter 1. In Situ Methylene Capping: A Key Strategy in Catalytic Stereoretentive Olefin MetathesisA general approach for in situ methylene capping that significantly expands the scope of catalyst-controlled stereoselective olefin metathesis is presented. By incorporation of stereodefined 2-butene as the capping reagent, the catechothiolate Ru complex is enabled to catalyze olefin metathesis reactions of terminal alkenes. Substrates bearing a carboxylic acid, an aldehyde, an aryl substituent, an α substituent were thus converted to the desired products in 47–
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Mann, Tyler J. "Stereoselective Olefin Metathesis Reactions Catalyzed by Molybdenum Monoaryloxide Monopyrrolide Complexes." Thesis, Boston College, 2016. http://hdl.handle.net/2345/bc-ir:104995.

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Thesis advisor: Amir H. Hoveyda<br>Chapter 1: Efficient Z-Selective Cross-Metathesis of Secondary Allylic Ethers Efficient Z-selective cross-metathesis of secondary allylic ethers were catalyzed by monoaryloxide monopyrrolide molybdenum complexes. Reactions involving both silyl and benzyl protected ethers were demonstrated, as well as ethers containing alkyl, aryl and alkynyl substituents. Mechanistic studies were performed, and the reactions were applied to the total synthesis of several ene-diyne natural products. Chapter 2. Stereoselective Total Synthesis of Disorazole C1 The stereoselectiv
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Yu, Miao. "Stereoselective Olefin Metathesis Reactions for Natural Product Synthesis." Thesis, Boston College, 2014. http://hdl.handle.net/2345/3861.

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Thesis advisor: Amir H. Hoveyda<br>Chapter 1. The first examples of highly Z- and enantioselective ring-opening/cross-metathesis reactions are disclosed. Transformations involve meso cyclic olefin substrate and styrenes or enol ethers as olefin cross partners. A stereogenic-at-Mo monoaryloxide monopyrrolide (MAP) complex, prepared and used in situ, is discovered for the efficient formation of Z olefins. Such complex, bearing a relatively smaller adamantylimido and a larger chiral aryloxide ligand, leads to kinetic Z-selectivity due to the size differential. In most cases, the resulting disubst
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Méndez-Andino, José Luis. "New fields in organic chemistry : developments in aqueous organoindium chemistry and ring closing olefin metathesis /." The Ohio State University, 2001. http://rave.ohiolink.edu/etdc/view?acc_num=osu1488204276534782.

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Chen, Zhong-Ren Kornfield Julia A. Grubbs Robert H. "I. Dynamics of block copolymer nanostructures. : II. Polymerizability of cyclic olefins and ring-closing metathesis /." Diss., Pasadena, Calif. : California Institute of Technology, 1998. http://resolver.caltech.edu/CaltechETD:etd-01242008-095827.

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Metaferia, Belhu B. "Synthesis of Taxol™ Analogs as Conformational Probes." Diss., Virginia Tech, 2002. http://hdl.handle.net/10919/28428.

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Taxol™, isolated from the bark of Taxus brevifolia in the late 1960s, and the semisynthetic analog Taxotere™ have proven clinical importance for the treatment of ovarian and breast cancer. Taxol™ exerts its biological effect by binding to polymerized tubulin and stabilizing the resulting microtubules. Studies aimed at understanding the biologically active conformation of taxol and its binding environment on β-tubulin are described. This knowledge is important because it could lead to the design of structurally less complicated drugs with better efficacy and better bioavailability. Moreover
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Coe, Samuel. "Phyllostictine A ring assembly via ring closing metathesis." Thesis, University of Warwick, 2014. http://wrap.warwick.ac.uk/67101/.

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This thesis describes work focused on the chemical synthesis and herbicidal activity of the natural product phyllostictine A, a molecule of unique structure and unknown mode of action. Chapter 1 serves to introduce the natural product and describe the known activity of the natural product. Furthermore, it discusses literature methods for the construction of a-methylene-b-lactams, a key component of phyllostictine A. Chapter 2 describes work towards the construction of the macrocyclic rings found in phyllostictine A. As a result a-methylene-b-lactams have been shown, for the first time, to part
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Salim, Sofia Saima. "Synthesis of sulfamides using ring closing diene metathesis and enyne metathesis." Thesis, University of Southampton, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.417402.

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Books on the topic "Ring closing olefin metathesis"

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T, Balaban Alexandru, and Dimonie M, eds. Olefin metathesis and ring-opening polymerization of cyclo-olefins. 2nd ed. Editura Academiei, 1985.

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Drăguțan, Valerian. Olefin metathesis and ring-opening polymerization of cyclo-olefins. 2nd ed. Editura Academiei, 1985.

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Jaecques, Ryan Patrick. Studies toward the synthesis of indolizidine alkaloids and analogues using ring-closing metathesis. National Library of Canada, 2003.

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Zunic, Valentin B. Diastereoselective ring closing metathesis as an approach to cycloalkenes and symmetrical bicyclodienes and their functionalization through desymmetrization reactions. 2001.

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Book chapters on the topic "Ring closing olefin metathesis"

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van Lierop, Bianca J., Justin A. M. Lummiss, and Deryn E. Fogg. "Ring-Closing Metathesis." In Olefin Metathesis. John Wiley & Sons, Inc., 2014. http://dx.doi.org/10.1002/9781118711613.ch3.

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Fiedler, Tobias, and John A. Gladysz. "Multifold Ring-Closing Olefin Metatheses in Syntheses of Organometallic Molecules with Unusual Connectivities." In Olefin Metathesis. John Wiley & Sons, Inc., 2014. http://dx.doi.org/10.1002/9781118711613.ch9.

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Fandrick, Keith R., Jolaine Savoie, Nathan Yee, Jinhua J. Song, and Chris H. Senanayake. "Challenges and Opportunities for Scaling the Ring-Closing Metathesis Reaction in the Pharmaceutical Industry." In Olefin Metathesis. John Wiley & Sons, Inc., 2014. http://dx.doi.org/10.1002/9781118711613.ch12.

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van Maarseveen, Jan H. "Linkers Releasing Olefins or Cycloolefins by Ring Closing Metathesis." In Linker Strategies in Solid-Phase Organic Synthesis. John Wiley & Sons, Ltd, 2009. http://dx.doi.org/10.1002/9780470749043.ch20.

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de Koning, Charles B., and Willem A. L. van Otterlo. "Ring-Closing Metathesis." In Arene Chemistry. John Wiley & Sons, Inc, 2015. http://dx.doi.org/10.1002/9781118754887.ch17.

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Hanson, Paul R., Soma Maitra, Rambabu Chegondi, and Jana L. Markley. "General Ring-Closing Metathesis." In Handbook of Metathesis. Wiley-VCH Verlag GmbH & Co. KGaA, 2015. http://dx.doi.org/10.1002/9783527674107.ch15.

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Li, Jie Jack. "Ring-closing metathesis (RCM)." In Name Reactions. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-01053-8_217.

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Li, Jie Jack. "Ring-closing metathesis (RCM)." In Name Reactions. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-03979-4_232.

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Düz, B., Ç. Bozkurt, and Y. İmamoğlu. "Photocatalytic Ring-Opening Polymerization of Norbornene, Norbornadiene and Cylopentene." In Olefin Metathesis and Polymerization Catalysts. Springer Netherlands, 1990. http://dx.doi.org/10.1007/978-94-011-3328-9_32.

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McGrath, Dominic V., Bruce M. Novak, and Robert H. Grubbs. "Aqueous Ring-Opening Metathesis Polymerizations of 7-Oxanorbornene Derivatives Using Ruthenium Catalysts." In Olefin Metathesis and Polymerization Catalysts. Springer Netherlands, 1990. http://dx.doi.org/10.1007/978-94-011-3328-9_22.

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Conference papers on the topic "Ring closing olefin metathesis"

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Gisemba, Solomon A., and Jane V. Aldrich. "Peptide Ring Closing Metathesis: Minimizing Side Reactions in Arodyn Analogs." In The 24th American Peptide Symposium. Prompt Scientific Publishing, 2015. http://dx.doi.org/10.17952/24aps.2015.177.

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Etheve-Quelquejeu, Melanie, Jean-Marc Valery, and Juan Xie. "A NEW APPROACH TOWARDS THE BICYCLIC MOIETY OF THE MIHARAMYCINS BY RING CLOSING METATHESIS." In XXIst International Carbohydrate Symposium 2002. TheScientificWorld Ltd, 2002. http://dx.doi.org/10.1100/tsw.2002.583.

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Gumus, Aysegul, Selcuk Gumus, Nalan Büyükadalı, and Nezir Aslan. "Synthesis of Chiral Heteroaryl-Substituted Dihydropyran Derivatives via Ring Closing Enyne Metathesis Reaction." In The 21st International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2017. http://dx.doi.org/10.3390/ecsoc-21-04790.

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Bruder, Marjorie, and Ronaldo Aloise Pilli. "A tandem ring-closing/cross-coupling metathesis reaction toward the short synthesis of goniothalamin analogs." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0372-1.

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Lamaty, Frédéric, Stéphane Varray, Bérengère Sauvagnat, Christine Gauzy, René Lazaro, and Jean Martinez. "Poly(ethylene glycol) Supported Synthesis of Aminoacid Derivatives via Ring Closing Metathesis or Microwave-assisted Alkylation." In The 4th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2000. http://dx.doi.org/10.3390/ecsoc-4-01890.

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De Kimpe, Norbert, Tuyen Nguyen Van, Matthias D’Hooghe, and Siegfried Pattyn. "Application of Ring Closing Metathesis Towards Functionalized 1,4-dihydro-9,10-anthraquinones and Anthraquinones Using Grubbs’ Catalyst." In The 8th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2004. http://dx.doi.org/10.3390/ecsoc-8-01951.

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Al-Abed, Yousef, and Mohindra Seepersaud. "CONVERSION OF MONOSACCHARIDES INTO POLYHYDROXYCYCLOPENTENES VIA RING CLOSING METATHESIS, AN EXPEDITIOUS ROUTE TO PENTENOMYCIN, TREHAZOLIN, AND CARBA-D-FRUCTOFURANOSE." In XXIst International Carbohydrate Symposium 2002. TheScientificWorld Ltd, 2002. http://dx.doi.org/10.1100/tsw.2002.574.

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Reports on the topic "Ring closing olefin metathesis"

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Low, Tammy K., and Eric Enholm. Ring-Closing Metathesis of Macrocyclic Compounds and Cross-Metathesis of Allyl Esters of Amino Acids Leading to Peptidominetics. Defense Technical Information Center, 2005. http://dx.doi.org/10.21236/ada431183.

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