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Dissertations / Theses on the topic 'Ring systems'

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1

Slater, Rachel. "Polyfunctional heteroaromatic fused ring systems." Thesis, Durham University, 2005. http://etheses.dur.ac.uk/2755/.

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Many current therapeutic agents are based on a core structure consisting of a fused ring heteroaromatic polycyclic system. Methodology for the synthesis of a range of these structurally diverse heteroaromatic derivatives is therefore highly desirable and short, high yielding, regioselective and flexible routes to such systems is very important. Our methodology utilises nucleophilic substitution reactions between pentafluoropyridine (PFP) and its derivatives, and various binucleophiles, e.g. The methodology has also been extended to 4-substituted tetrafluoropyridine derivativesand different bin
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2

Sutradhar, Nitai Chandra. "The study of ring-spinning with particular reference to rotating rings." Thesis, University of Leeds, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.329210.

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3

Lingard, Hannah. "Cascade approaches to decahydroquinoline ring systems." Thesis, University of Oxford, 2010. http://ora.ox.ac.uk/objects/uuid:e0ff1123-eae7-47aa-b377-1a12346d2538.

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The aims of this project were to develop a cascade approach towards decahydroquinoline frameworks (Scheme I) and apply this to the synthesis of decahydroquinoline-containing natural products such as lycopodine, cermizine B and lepadin D (Scheme I). Scheme I. Several linear precursors were synthesized via a modular strategy. For example, lycopodine linear precursor i was synthesized in a total of 12 steps (Scheme II). Scheme II. Conditions for cyclization and hydrogenation were tested, with the diastereoselectivity examined in each system. For example, the lepadin linear precursor ii produced t
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4

Kiss, Emily. "Diasterodivergent synthesis of fused ring systems." Thesis, University of Oxford, 2015. https://ora.ox.ac.uk/objects/uuid:37545702-38f9-4bb5-a233-69a296387792.

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Introduction: We envisioned using phase transfer catalysis (PTC) to develop asymmetric carba-6p- electrocyclisations. We believed that the configurational lability of 6p systems could be reduced by constraining them within a ring system. Results and Discussion: En route to the synthesis of a starting material for the transannular electrocyclisation reaction, we noticed that a 5-5-3 fused ring system had formed, in one step, from a linear precursor and as a single diastereomer. We synthesised both geometric isomers of the starting materials, and unexpectedly, the E or Z isomers cyclised to form
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5

Lu, Yingzi. "Polycyclic and oligocyclic phosphorus-nitrogen ring systems." [S.l.] : [s.n.], 2006. http://www.digibib.tu-bs.de/?docid=00005216.

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6

Robertson, G. M. "Synthesis of ring systems via radical reactions." Thesis, University of Nottingham, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.353927.

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7

Longthorne, Darren Stuart. "Thieno-extended purines and related ring systems." Thesis, University of Salford, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.261839.

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8

Rodger, Robert. "Fused ring systems in natural product synthesis." Thesis, The University of Sydney, 2022. https://hdl.handle.net/2123/27645.

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On the instigation of A/Prof C. S. P. McErlean I investigated the rapid synthesis of fused ring compounds by a key polyene cyclisation. Chapter 1 sets the scene by highlighting deficiencies in literature syntheses of selected fused-ring compounds, where synthetic strategies are often suboptimal. In particular, the scarcity of reported syntheses involving a direct cyclisation method is noted. Chapter 2 discusses the taiwaniaquinoids and previous synthetic approaches including McErlean group efforts which delivered the non-natural stereochemistry. A method to produce the desired trans stereo
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9

Dincoflaz, Yasemin. "The Synthesis Of 6- And 7- Membered Heterocyclic Ring Systems Fused To Pyridine Ring." Master's thesis, METU, 2013. http://etd.lib.metu.edu.tr/upload/12615579/index.pdf.

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The synthesis of the nitrogen containing heterocyclic compounds is one of the leading research areas throughout the organic chemistry due to their significant activities in biological systems. Among the various biologically active molecules, pyridine-fused ring systems are of prime importance on the grounds of their proven clinical roles. The coupling reactions with 6-membered heterocyclic compounds and diazepines gave rise to new pharmalogical compounds in recent years. Therefore, our object was the synthesis of pyridine-fused 6- and 7-membered heterocycles. Starting from bromopyridine, two d
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10

Bean, David Edward. "Aromaticity in molecular systems with multiple ring currents." Thesis, University of Sheffield, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.531195.

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11

O'Sullivan, Paul Thomas. "Natural product systems from eight-membered ring lactones." Thesis, University of Cambridge, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.621632.

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12

McMillan, Fiona M. "New pyrolytic routes to ortho-condensed ring systems." Thesis, University of Edinburgh, 2007. http://hdl.handle.net/1842/11148.

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A variety of methyl biphenyl-2-acrylate precursors, substituted in the 2’-, 3’- or 4’-positions, were synthesised using a Suzuki coupling reaction between 2-formylphenylboronic acid and the appropriate aryl halide, followed by Wittig olefination. These precursors were then pyrolysed to produce 3-cyano, 3-methyl and 3-chloro substituted phenanthrenes. The synthesis of 1-cyanophenanthrene was also successful. This route was also successful in producing naphthothiophenes and naphthofurans from appropriate heteroaryl-substituted precursors. This methodology was expanded into the synthesis of sever
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13

Oakley, D. Bruce (Douglas Bruce) Carleton University Dissertation Engineering Electrical. "Image filtering on slotted ring multiple DSP systems." Ottawa, 1992.

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14

Xu, Tianyuan. "On the Subregular J-ring of Coxeter Systems." Thesis, University of Oregon, 2017. http://hdl.handle.net/1794/22741.

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Let (W, S) be an arbitrary Coxeter system, and let J be the asymptotic Hecke algebra associated to (W, S) via Kazhdan-Lusztig polynomials by Lusztig. We study a subalgebra J_C of J corresponding to the subregular cell C of W . We prove a factorization theorem that allows us to compute products in J_C without inputs from Kazhdan-Lusztig theory, then discuss two applications of this result. First, we describe J_C in terms of the Coxeter diagram of (W, S) in the case (W, S) is simply- laced, and deduce more connections between the diagram and J_C in some other cases. Second, we prove that
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15

VanWiggeren, Gregory D. "Chaotic communication with erbium-doped fiber ring lasers." Diss., Georgia Institute of Technology, 2000. http://hdl.handle.net/1853/30299.

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16

Marino, S., L. Matrà, C. Stark, et al. "Exocometary gas in the HD 181327 debris ring." OXFORD UNIV PRESS, 2016. http://hdl.handle.net/10150/621723.

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An increasing number of observations have shown that gaseous debris discs are not an exception. However, until now, we only knew of cases around A stars. Here we present the first detection of (CO)-C-12 (2-1) disc emission around an F star, HD 181327, obtained with the Atacama Large Millimeter/submillimeter Array (ALMA) observations at 1.3 mm. The continuum and CO emission are resolved into an axisymmetric disc with ring-like morphology. Using a Markov chain Monte Carlo method coupled with radiative transfer calculations, we study the dust and CO mass distribution. We find the dust is distribu
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17

Hill, K. E. "The utility of ring springs in seismic isolation systems." Thesis, University of Canterbury. Mechanical Engineering, 1995. http://hdl.handle.net/10092/7923.

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Ring springs are frictional devices consisting of inner and outer ring elements assembled to form a spring stack. External load applied to the spring produces sliding action across mating ring interfaces. Large amounts of energy, as much as 60-70% of the total cycle energy, may be absorbed in overcoming frictional forces. This thesis details the characteristics and dynamic behaviour of ring spring systems and describes the design and testing of a seismic isolation system that uses ring springs. Initially the characteristics and fundamental dynamic behaviour of single-degree-of-freedom mass/r
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18

McAuley, Barry Joseph. "Asymmetric chemoenzymatic synthesis of densely functionalised small ring systems." Thesis, Queen's University Belfast, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.314015.

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19

Cameron, Donald King. "Some reactions of unsaturated ring systems containing sulphonyl groups." Thesis, University of Edinburgh, 1987. http://hdl.handle.net/1842/10859.

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20

Dong, Zhiming (Eric). "New Adventures in the Chemistry of Polycarboncyclic Ring Systems." Thesis, University of North Texas, 1997. https://digital.library.unt.edu/ark:/67531/metadc278356/.

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I. Diels-Alder reactions of 1,2,3,4,9,9-hexachloro-1,4,4a,8a-tetrahydro-1,4-metha- nonaphthalene (16) and 1,2,3,4,9,9-hexachloro-1,4,6,7-tetrahydro-1,4-methanonaphthalene (17) toward dienophiles N-methyl-1,2,4-triazoline-3,5-dione (MTAD), N-phenyl-1,2,4-triazoline-3,5-dione (PTAD) and/or N-methylmaleimide (NMM) have been examined. II. Epoxides derived from functionalized 1,4,4a,9a-tetrahydro-9,10-dioxo-1,4-methanoanthracenes (1a and 1b) undergo acid- and base-promoted intramolecular nucleophilic ring-opening to form new polycyclic alcohols. III. The title cycloalkylidenecarbene has been
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21

Pugh, David. "Novel methods for the synthesis of small ring systems." Thesis, University of York, 2011. http://etheses.whiterose.ac.uk/1959/.

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Chapter 1 briefly reviews telescoped reactions, in particular tandem oxidation processes, detailing the background to the development of the methodology presented here, and sets out the aims for the Thesis. Chapter 2 reviews cyclopropanation methods and examines the preparation and use of triisopropylsulfoxonium tetrafluoroborate II for the preparation of gemdimethylcyclopropanes for a range of α,β-unsaturated compounds including ketones, esters, amides, nitriles and nitro-compounds (Scheme I). Chapter 2 also examines potential applications for the methodology, outlining a route towards the sy
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22

Batchelor, John. "Annular ring microstrip patch antennas for mobile communications." Thesis, University of Kent, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.282579.

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23

Thompson, David Francis. "Iron (III) mediated ring expansion / cyclisation reactions." Thesis, University of East Anglia, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.297007.

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24

Bowden, M. C. "Synthesis with citreoviridinoids." Thesis, University of Nottingham, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.379011.

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25

Hill, David Ronald. "The cycloadditions of 2-(N-Acylamino)-1-thia-1,3-dienes." Thesis, University of Leeds, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.277566.

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26

Williams, David Alan John. "Radical approaches toward polycyclic alkaloids." Thesis, University of York, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.323499.

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27

Woodward, Gary. "Synthetic, chemical and structural studies of some new linear, cyclic and bicyclic phosphazane oxides." Thesis, University of Bristol, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.352909.

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28

Oliveira, Neto Vivaldo Lopes. "Structural properties of nanoscopic ring systems and their optical response." Universidade Federal de São Carlos, 2016. https://repositorio.ufscar.br/handle/ufscar/8131.

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Submitted by Alison Vanceto (alison-vanceto@hotmail.com) on 2016-10-14T12:48:52Z No. of bitstreams: 1 TeseVLON.pdf: 12327358 bytes, checksum: 6fe55d85e4aff3ba5318f9671501f27c (MD5)<br>Approved for entry into archive by Marina Freitas (marinapf@ufscar.br) on 2016-10-21T13:10:16Z (GMT) No. of bitstreams: 1 TeseVLON.pdf: 12327358 bytes, checksum: 6fe55d85e4aff3ba5318f9671501f27c (MD5)<br>Approved for entry into archive by Marina Freitas (marinapf@ufscar.br) on 2016-10-21T13:10:23Z (GMT) No. of bitstreams: 1 TeseVLON.pdf: 12327358 bytes, checksum: 6fe55d85e4aff3ba5318f9671501f27c (MD5)<br>Made
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29

Jaseemuddin, Muhammad. "Bidirectional ring, an interconnection network for shared-memory multiprocessor systems." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape11/PQDD_0004/NQ41554.pdf.

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30

Gillman, Kevin W. "Hydroboration of strained cyclopropane ring systems promoted by Wilkinson's catalyst /." Online version of thesis, 1991. http://hdl.handle.net/1850/10947.

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31

Li, Yunchu. "Silicon Micro-ring Resonator Device Design for Optical Interconnect Systems." Thesis, University of Southern California, 2013. http://pqdtopen.proquest.com/#viewpdf?dispub=3563933.

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<p> Optical interconnect systems is one of the most promising solutions to surpass the speed bottleneck of CPU from the electrical interconnects. To realize this idea, one of the key topics is to design compact photonic devices suitable for building the optical interconnects. </p><p> The use of silicon microring resonators is an attractive technology for the integrated photonics pursuing optical interconnect applications, highly exciting due to the high integration density, low power consumption, and versatile functionalities. The platform technologies available for silicon microring resona
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32

Tierney, Christopher John. "Non-linear dynamics of couple SQUID ring : tank circuit systems." Thesis, University of Sussex, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.360589.

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33

Justice, David E. "A synthetic study of the tropane and homotropane ring systems." Thesis, University of Leicester, 1995. http://hdl.handle.net/2381/33769.

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1,4-Functionalisation of cyclohepta-l,3-diene using a nitroso-cycloaddition strategy provided precursors which were converted into the N-methyl-8-azabicyclo- [3.2.1]octane (tropane) ring system. Cycloocta-1,3-diene was used as the starting material to prepare precursors to the N-methyl-9-azabicyclo[4.2.1]nonane (homo-tropane) ring system. Homotropane has been constructed, either with or without a bridgehead substituent, using mercury-mediated cyclisation of nitrogen onto an sp2 carbon centre. The versatile N-alkoxycarbonyl protecting group was employed to synthesise the corresponding norhomotr
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34

Houseknecht, Justin B. "Conformational Analysis of Furanose Ring Systems: Experimental and Theoretical Studies." Connect to this title online, 2003. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1040404808.

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Thesis (Ph. D.)--Ohio State University, 2003.<br>Title from first page of PDF file. Document formatted into pages; contains xxiv, 529 p.; also includes graphics Includes bibliographical references (p. 510-529). Available online via OhioLINK's ETD Center
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35

Duffy, Liam John. "Novel synthetic routes towards polycyclic alkaloids and tetracycline ring systems." Thesis, Loughborough University, 2008. https://dspace.lboro.ac.uk/2134/34617.

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Novel and complementary routes for the selective preparation of either the 2,11 b-cis (B) or trans (C) series of functionalised benzo[α]quinolizidines have been developed and reported in close collaboration with the Bosch group. The common aromatic core, chiral p-aminoalcohol (A), allows access to either (B) or (C) via judicious choice of substrate sub-structure for lactamisation. The key cyclisation step in both instances involves the attack of a pendent aromatic nucleophile onto an N-acyliminium intermediate. [Illustration omitted.] Also described in this thesis is the first asymmetric synth
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36

Podder, Ranjan Kumar. "Formation and cleavage of cyclopropane ring systems and related studies." Thesis, University of North Bengal, 1986. http://hdl.handle.net/123456789/848.

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37

Bell, Brian Robert. "Synthesis of novel materials using ring-opening metathesis polymerisation." Thesis, Queen's University Belfast, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.295364.

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38

Washington, Kyle. "A wireless token ring approach for contention resolution in a wimax environment." Diss., Online access via UMI:, 2006.

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39

Alcaçoas, Dellainey. "Anomaly detection in ring rolling process : Using Tree Ensemble Methods." Thesis, Högskolan i Skövde, Institutionen för informationsteknologi, 2019. http://urn.kb.se/resolve?urn=urn:nbn:se:his:diva-18400.

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Anomaly detection has been studied for many years and has been implemented successfully in many domains. There are various approaches one could adopt to achieve this goal. The core idea behind these is to build a model that is trained in detecting patterns of anomalies. For this thesis, the objective was to detect anomalies and identify the causes for the same given the data about the process in a manufacturing setup. The scenario chosen was of a ring rolling process followed at Ovako steel company in Hofors, Sweden. An approach involving tree ensemble method coupled with manual feature engine
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40

Yao, Li-Jun. "Real-time communications in token ring networks." Title page, abstract and contents only, 1994. http://web4.library.adelaide.edu.au/theses/09PH/09phy248.pdf.

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41

Boyd, Joseph W. "A novel photochemical route towards the aphidicolane and stemodane ring systems." Thesis, University of Reading, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.408321.

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42

Liu, Yifan. "Synthesis of the CDE & EFG ring systems of pectenotoxin-4." Thesis, University of Oxford, 2016. https://ora.ox.ac.uk/objects/uuid:c531f0b3-4961-43e6-b7aa-c273df89a16f.

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This thesis explores new synthetic routes for the formation of CDE & EFG fragments of pectenotoxin-4. Chapter 1: Introduction and Previous Work: This chapter reviews the discovery and biological activities of members of the pectenotoxin family. Two previous total syntheses are discussed, and previous work regarding the synthesis of ABC, E and FG fragments within the group is introduced. Chapter 2: Synthesis of the E Ring Fragment of Pectenotoxin-4: The synthesis of the E ring fragment is discussed. Key reactions include Negishi coupling and osmium mediated oxidative cyclisation. Chapter 3: Fir
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43

Allen, Jamie. "Instrumentation for HARMONI and the mass ratios of ring galaxy systems." Thesis, University of Oxford, 2017. http://ora.ox.ac.uk/objects/uuid:3df69b43-eb71-4931-b3cf-722c2612f422.

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HARMONI is the visible and near-infrared integral field spectrograph due to be one of the first light instruments on the European Extremely Large Telescope. The prototype HARMONI lens mounts were cryogenically tested, to measure the radial decentre of the lens as it was cooled to 130 K. Initial problems of the epoxy cracking the lens were solved by switching to a silicone RTV adhesive. The lens in the baseline mount design was found to move radially by 18 μm: just below the tightest radial positioning tolerance. The Oxford SWIFT Spectrograph spare camera was rebuilt using lens mounts based on
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44

Robertson-Ralph, Michael J. "Photochemical synthesis and electrocyclic ring opening of cyclobutene-fused bicyclic systems." Thesis, University of Bristol, 2015. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.690756.

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This thesis has two main themes both with synthetic organic photochemistry at the centre of their research aims. The first deals with the synthesis of [2.0.n] cyclobutenes via the photo [2+2] cycloaddition of propargyl alcohol with an appropriate unsaturated anhydride followed by their thermal electrocyc1ic ring opening. According to molecular orbital theory this must occur via a conrotatory operation. However, this would lead to cis,trans dienes but only cis,cis dienes have, to date, been observed.
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45

Angrish, Parul. "Syntheses of meso-substituted porphodimethenes and porphyrins with exocyclic ring systems." [Gainesville, Fla.] : University of Florida, 2003. http://purl.fcla.edu/fcla/etd/UFE0001940.

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46

Nwogwugwu, Dennis C. S. "The synthesis and characterization of random copolyesters containing biphenylene ring systems." DigitalCommons@Robert W. Woodruff Library, Atlanta University Center, 1986. http://digitalcommons.auctr.edu/dissertations/3874.

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47

Bagola, Katrin. "Aktivität Ubiquitin-konjugierender Enzyme an den RING-Ligasen des ERAD-Systems." Doctoral thesis, Humboldt-Universität zu Berlin, Mathematisch-Naturwissenschaftliche Fakultät I, 2012. http://dx.doi.org/10.18452/16522.

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Fehlerhafte sekretorische Proteine werden über einen speziellen Abbauweg, die ER-assoziierte Proteindegradation (ERAD), mit Lysin48-verknüpften Ubiquitinketten polyubiquitiniert und dem proteolytischen Abbau am 26S Proteasom zugeführt. In der Hefe Saccharomyces cerevisiae bilden die beiden ER-membranständigen RING-Ubiquitinligasen Hrd1 und Doa10 zentrale Komponenten im Ubiquitinierungsprozess. Das lösliche zytosolische Ubiquitin-konjugierende Enzym Ubc7, welches mit beiden Ligasen bei der Polyubiquitinierung von Substratproteinen zusammenwirkt, wird über den membranverankerten Co-Faktor Cue1
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48

Booth, Mark, William R. F. Dent, Andrés Jordán та ін. "The Northern arc of ε Eridani’s Debris Ring as seen by ALMA". OXFORD UNIV PRESS, 2017. http://hdl.handle.net/10150/625481.

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We present the first Atacama Large Millimeter/submillimeter Array (ALMA) observations of the closest known extrasolar debris disc. This disc orbits the star is an element of Eri, a K-type star just 3.2 pc away. Due to the proximity of the star, the entire disc cannot fit within the ALMA field of view. Therefore, the observations have been centred 18" North of the star, providing us with a clear detection of the Northern arc of the ring, at a wavelength of 1.3 mm. The observed disc emission is found to be narrow with a width of just 11-13 AU. The fractional disc width we find is comparable to t
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49

Grah, Adrian. "Active and passive coupling in WDM photonic ring and bus networks." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp02/NQ30088.pdf.

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50

Banh, Dennis V. "A ring model for local mobile radio communications with variable packet length." Thesis, Monterey, California: Naval Postgraduate School, 1990. http://hdl.handle.net/10945/27549.

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Approved for public release; distribution unlimited.<br>This thesis presents an analysis of the performance of a local mobile radio communications system utilizing the Aloha random access protocol with variable length packets. The capture phenomenon due to the nearfar effect that enhances the performance of the system is investigated. A tagged packet will capture the base station if its signal-to-interference ratio exceeds a threshold gamma sub zero. Because of the nearfar effect, users near the base station typically have a stronger signal than those farther away. A multiple ring model is use
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