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1
Vaskovic, Nada. "Petrology and P-T condition of white mica-chlorite schists from Vlasina series - Surdulica, SE Serbia." Annales g?ologiques de la Peninsule balkanique, no. 64 (2002): 199–220. http://dx.doi.org/10.2298/gabp0264199v.
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This paper reports structural, textural, petrological and metamorphic data from Vlasina Series of greenschists rocks (as part of the Upper Complex of the Serbo-Macedonian Massif) within which group of white mica-chlorite schist are extensively developed. This group of rocks made the ground of series in which various types of green rocks appear as a lenses and small irregular mass, rarely as dykes. Other features, that characterize these rocks, are the common occurrence of albite and garnet (subordinate) porphyroblasts, as well as development of quartz segregation. Group of white mica-chlorite schist makes about 75 vol. % of Series. Among them, according to mode and mineral composition, the following schist varieties are distinguished: albite-white mica-chlorite (?garnet), white mica-chlorite (?garnet), albite-white mica, sericite-chlorite (?albite), graphite-sericite as well as phyllites and calcshists. Their metamorphic evolution is characterized by the development of a metamorphic episode during Carboniferous - c. 350-330 Ma (Milovanovic et al., 1988) of low to medium P and T. The mineral assemblages of first phase (low PT) is preserved as a very thin Si=S1 foliation included in albite porphyroblast or as small polygonal arcs of S1 in S2 foliation. Textural, mineralogical and petrological data indicate that original volcanoclastic-sedimentary series was transformed during three phase of deformation and metamorphism in the temperature range from 320-415?C, locally 450-500?C and pressures 3 to 5 kbar.
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Sadegh, Hadiseh Rahimi, Hesam Moeinzadeh, and Kazu Nakashima. "Geochemistry, mineral chemistry and P-T evaluation of metasediments of Bahram-Gur complex, ES Sanandaj-Sirjan zone, Iran." Mineralogia 50, no. 1-4 (December 1, 2019): 34–68. http://dx.doi.org/10.2478/mipo-2019-0003.
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AbstractThe Bahram-Gur area in the southeastern part of the Sanandaj – Sirjan metamorphic zone, contains metabasites and metasediments. The metasedimentary rocks are mainly garnet schists and garnet-staurolite schists that were metamorphosed under amphibolite facies conditions. The rocks consist of garnet ± staurolite, biotite, muscovite, chlorite and quartz. The geochemistry of the Bahram-Gur metasediments classifies them as quartziferous sedimentary rocks. The protoliths of the metasedimentary rocks were close to greywackes from an ensialic arc basin depositional setting, with a source comprising mostly mixture of acid and intermediate magmatic rocks in the upper continental crust. The metamorphic conditions of formation of the Bahram-Gur metasedimentary are investigated by geothermobarometric methods. The results show that the metasedimentary rocks formed at temperatures of 600-750°C and pressures of 5-7.5 kbar.
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Næraa, Tomas, Jens Konnerup-Madsen, Bjørn Hageskov, and Lalu Prasad Paudel. "Structure and petrology of the Dadeldhura Group, far western Nepal, Himalaya." Journal of Nepal Geological Society 35 (December 31, 2007): 21–28. http://dx.doi.org/10.3126/jngs.v35i0.23631.
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The granites, phyllites, schists, and gneisses of the Dadeldhura Group exhibit a significant Himalayan metamorphic imprint. The rocks of the group constitute a synform and the group is delimited by thrusts. The North Dadeldhura Thrust (NDT) zone is dominated by granitic mylonite with subordinate quartzite, quartz-chlorite schist, and amphibolite. In the quartz-chlorite schist from the NDT zone, relict kyanite is observed, which together with recrystallisation textures in the granitic mylonite indicate that low-temperature syn-tectonic retrogression has affected the thrust zone. Prograde garnets with spiral structures from a zone 2–4 km structurally above the base of the NDT are associated with mylonite-like rocks, and indicate distinct prograde shear zones in this area. This suggested that prograde thrust stacking has affected about 4 km wide north belt of the Dadeldhura Group. Rim thermobarometry from the garnet holding rocks shows that the minerals were re-equilibrated at 440–550 °C and 6.5–9.5 kbar. In the southern part of the Dadeldhura Group, textures in quartz and feldspar from the Saukhark Granite-Gneiss indicate that temperatures during recrystallisation were around 450–550 °C. These P–T estimates suggest that most of the now exposed rocks in the Dadeldhura Group experienced prograde epidoteamphibolite facies metamorphism during early orogenic build up and thrusting of the Dadeldhura Nappe. A subsequent syntectonic retrograde phase is observed in the NDT zone as low temperature recrystallisation of quartz and feldspar in mylonitic rocks, and chlorite and quartz in chlorite-grade rocks holding relict kyanite. Retrograde trusting was also focused along a distinct “back thrusting” zone within the northern part of the group.
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Beyarslan, Melahat, and A. Feyzi Bingöl. "Petrology of a supra-subduction zone ophiolite (Elaz1g, Turkey)." Canadian Journal of Earth Sciences 37, no. 10 (October 1, 2000): 1411–24. http://dx.doi.org/10.1139/e00-041.
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The Elaz1g region in eastern Taurus, Turkey, exposes Paleozoic-Tertiary metamorphic, magmatic, and sedimentary units. Contacts between the different units are mostly tectonic, but there are also primary sedimentary, and intrusive contacts. The metamorphic rocks of the Elaz1g region are the Bitlis-Pütürge and Keban-Malatya massifs, which are a single tectonostratigraphic unit that has been tectonically disrupted and fragmented during the Upper Cretaceous. Magmatic rocks in the region are represented by ophiolitic units, magmatic arc products, and young volcanic rocks. The sedimentary units are represented by Upper Cretaceous - Tertiary marine and lacustrine sedimentary rocks. In the study area, the metamorphic units are represented by the Paleozoic Pütürge metamorphic rocks composed of phyllite, slate, mica schist, quartz-muscovite schist, calc-schist, and low-grade metamorphite. The ophiolite that is described in this paper is composed of wehrlite-pyroxenite, gabbro, diabase dykes, and dykes cutting gabbro. These units are cut by the granitic rocks of the Upper Cretaceous Elaz1g magmatic suite. The lithological and geochemical data on the rocks of Kömürhan ophiolite indicate that these rocks were derived from crystallization of an enriched mid-ocean ridge basalt (MORB)-type magma. The Kömürhan ophiolite formed in a supra-subduction spreading zone during the Cretaceous; related to this event is the north-dipping subduction of the southern branch of Neo-Tethys ocean, which began spreading in the Late Triassic. The crust was thickened by the development of an island arc and by the thrusting of the Pütürge metamorphic rocks onto this island arc in response to north-south compression during the Late Cretaceous. The magma formed by partial melting of the subducted slab giving rise to granitic rocks that cut the upper parts of the ophiolite. The ophiolite and the Elaz1g magmatic suite attained their present position after the Middle Eocene.
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White, S. H., J. M. Huggett, and H. F. Shaw. "Electron-optical studies of phyllosilicate intergrowths in sedimentary and metamorphic rocks." Mineralogical Magazine 49, no. 352 (June 1985): 413–23. http://dx.doi.org/10.1180/minmag.1985.049.352.12.
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AbstractThe results of a microstructural study by backscattered scanning electron microscopy and a microchemical study using X-ray microprobe analysis of phyllosilicate intergrowths from sandstones, shales, metagreywackes, and low-grade schists are presented. The microstructural study revealed that the intergrowths thicken and become more coherent with metamorphic grade; the intergrowths change from incoherent to coherent in the anchizone. The increasing coherency is mirrored by an increase in the crystallinity indices of the illites/phengites. Chemical analysis of the individual intergrowth phases was difficult in the sediments and no systematic compositional variations were recorded. However, clear compositional trends with increasing metamorphic grade emerged in the phengites from the metagreywackes and schists, but in the chlorites only slight compositional changes were recorded.
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Serra-Varela, Samanta, Pablo D. González, Raúl E. Giacosa, Nemesio Heredia, David Pedreira, Fidel Martín-González, and Ana María Sato. "Evolution of the Palaeozoic basement of the North Patagonian Andes in the San Martín de los Andes area (Neuquén, Argentina): petrology, age and correlations." Andean Geology 46, no. 1 (September 28, 2018): 102. http://dx.doi.org/10.5027/andgeov46n1-3124.
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In San Martín de los Andes area (Argentinian Patagonia) the Palaeozoic basement consists of metamorphic and plutonic rocks. The metamorphic rocks include strongly deformed schists, gneisses and migmatites. Their geochemical and petrographic characteristics suggest that the protholith could have been a sequence of pelites and greywackes. Detrital zircon analysis (U-Pb Q-ICP-LA-MS) yielded a maximum depositional age of 501±14 Ma (Series 3 Cambrian) for this sedimentary protolith. Metasedimentary rocks are affected by a regional foliation defined by the minerals of the metamorphic peak. This is a S2 foliation, since relics of a former foliation are present in some samples. This regional foliation is locally affected by open folds that develop an incipient crenulation cleavage (S3). The high-grade metamorphism includes partial melting processes, where the incipient segregates intrude parallel to the regional foliation and also cut it in presence of abundant melt. Zircons from anatectic granites formed during this partial melting process yielded a U-Pb Concordia age of 434.1±4.5 Ma (Llandovery-Wenlock, Silurian). The age of maximum sedimentation and the anatectic age constrain the metamorphic evolution of the basement into the lower Palaeozoic (between upper Cambrian and lower Silurian). The igneous rocks of the basement are granodiorites, tonalities, and some gabbros that cut the metamorphic basement and contain xenoliths and roof pendants from the country rocks. These plutonic rocks are affected by low-grade metamorphism, with the development of discrete, centimetric to hectometric, brittle-ductile shear zones. The age of these igneous rocks has been constrained through U-Pb zircons analysis, carried out by several authors between ca. 370 and 400 Ma (Devonian). The maximum sedimentation age for the protolith and its metamorphic evolution seems to be related to an early Palaeozoic orogenic event, probably the Patagonian Famatinian orogeny. In contrast, the Devonian igneous rocks of San Martín de los Andes could represent a Devonian magmatic arc, related to subduction processes developed at the beginning of the Gondwanan orogenic cycle, which culminates with the Gondwanan orogeny.
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Ilnicki, S. "Variscan progradeP-Tevolution and contact metamorphism in metabasites from the Sowia Dolina, Karkonosze-Izera massif, SW Poland." Mineralogical Magazine 75, no. 1 (February 2011): 185–212. http://dx.doi.org/10.1180/minmag.2011.075.1.185.
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AbstractSeveral bodies of moderately foliated and porphyroblastic metabasites crop out on the SE side of the metamorphic cover of the Karkonosze granite within metapelites of the Sowia Dolina area (West Sudetes, Saxothuringian zone). Depending on the microstructural setting of the Ca-amphiboles in the rocks, different mineral-chemical trends have been determined for Si,XMg, AlVI,A[Na+K] which serve as semi-quantitative indicators of temperature and pressure changes. Porphyroblasts and prisms oblique to the main foliation in schistose metabasites show zoning from Mg-hornblende and actinolite to tschermakite, and then to Mg-hornblende (or actinolite). Matrix amphiboles and those in pressure shadows around some porphyroblasts have tschermakitic cores and actinolitic rims. Rarely, Ca-amphibole is accompanied in schists by late- to post-tectonic cummingtonite. Thermobarometric calculations involving empirically calibrated amphibole equilibria enable a reconstruction ofP-Tpaths for individual rocks and the unravelling of the metamorphic evolution of the metabasites. Peak metamorphic temperatures of 615–640°C and pressures of 7.3–8.2 kbar were preceded by a variably preserved earlier stage (T = 370–550°C, P = 2.8–6.2 kbar). The final metamorphic episode took place at 450–550°C and 2.5–4.8 kbar and is recorded particularly in rocks close to the Karkonosze pluton. The metabasites shed new light on the history of metamorphism in the Sowia Dolina area. The first two stages ofMP-MTmetamorphism, coeval with Variscan deformation events (continental collision, burial and subsequent exhumation), took place under epidote-amphibolite then amphibolite facies conditions. The last stage partly concurred with the final stages of Variscan deformation and overlapped the onset of thermal activity associated with the Karkonosze granite. This metamorphic event is documented by metabasites (occasionally cummingtonite-bearing) outcropping close to the granite. Finally, a prehnitebearing assemblage reflects retrograde re-equilibration under greenschist/sub-greenschist facies conditions (T<300–350°C,P<2.5–3 kbar), which might also be partly due to hydrothermal activity around the pluton.
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Och, D. J., E. C. Leitch, G. Caprarelli, and T. Watanabe. "Blueschist and eclogite in tectonic melange, Port Macquarie, New South Wales, Australia." Mineralogical Magazine 67, no. 4 (August 2003): 609–24. http://dx.doi.org/10.1180/0026461036740121.
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Abstract The Rocky Beach Metamorphic Melange contains metre-scale phacoids of high-P low-T metamorphic rocks embedded in chlorite-actinolite schist. The phacoids include eclogite, glaucophane schist and omphacitite and provide evidence for four episodes of metamorphism with mineral assemblages: M1 = actinolite-glaucophane-titanite-apaite, M2 = almandine-omphacite-lawsonite ±quartz, M3 = phengite- glaucophane-K-feldspar-quartz, and M4 = chlorite-actinolite-calcite-quartz-titanite-white mica ± albite ± talc. M1-M3 occurred at a Neoproterozoic-Early Palaeozoic convergent plate boundary close to the eastern margin of Gondwana. Peak metamorphic conditions were attained during the static phase M2, with temperatures of ~560°C and pressures in excess of 1.8 GPa, equivalent to a depth of burial of at least 54 km.
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Catlos, Elizabeth, Courteney Baker, Ibrahim Çemen, and Cenk Ozerdem. "Whole rock major element influences on monazite growth: examples from igneous and metamorphic rocks in the Menderes Massif, western Turkey." Mineralogia 39, no. 1-2 (January 1, 2008): 7–30. http://dx.doi.org/10.2478/v10002-008-0002-8.
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Whole rock major element influences on monazite growth: examples from igneous and metamorphic rocks in the Menderes Massif, western TurkeyMonazite (LREEPO4) is a radiogenic, rare-earth bearing mineral commonly used for geochronology. Here we examine the control of major element chemistry in influencing the crystallization of monazite in granites (Salihli and Turgutlu bodies) and garnet-bearing metamorphic assemblages (Bozdag and Bayindir nappes) from the Menderes Massif, western Turkey. In S-type granites from the massif, the presence of monazite correlates to the CaO and Al2O3content of the whole rock. Granites with monazite only are low Ca (0.6-1.8 wt% CaO). As CaO increases (from 2.1-4.6 wt%), allanite [(Ce, Ca, Y)2(Al, Fe3+)3(SiO4)3(OH)] is present. Higher Al2O3(>15 wt%) rocks contain allanite and/or monazite, whereas those with lower Al2O3contain monazite only. However, examining data reported elsewhere for A-type granites, the correlation between major element chemistry and presence of monazite is likely restricted to S-type lithologies. Pelitic schists of the Menderes Massif show no correlation between major element chemistry and presence of monazite. One Bayindir nappe sample contains both prograde garnets and those affected significantly by diffusion. These rocks have likely experienced a complicated multi-stage tectonic history, which influenced their current mineral assemblages. The presence of monazite in a metamorphic rock can be influenced by the number, duration, and nature of events that were experienced and the degree to which fluids were involved. The source of monazite in the Bayindir and Bozdag samples was likely reactions that involved allanite. These reactions may not have significantly changed the bulk composition of the rock.
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Cook, Nigel J., Christopher Halls, and Alan P. Boyle. "Deformation and metamorphism of massive sulphides at Sulitjelma, Norway." Mineralogical Magazine 57, no. 386 (March 1993): 67–81. http://dx.doi.org/10.1180/minmag.1993.057.386.07.
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AbstractThe copper-bearing stratabound pyritic massive sulphide bodies contained in metamorphosed basic eruptives of Ordovician age at Sulitjelma in Nordland County, Norway, form one of the important fields of sulphide mineralisation within the Köli Nappe Complex. The sulphide bodies and their enclosing rocks were subject to successive stages of penetrative deformation and recrystallisation during the cycle of metamorphism and tectonic transport caused by the Scandian Orogeny. Textures within the ores and the immediate envelope of schists show that strain was focused along the mineralised horizons. The marked contrast in competence between the massive pyritic sulphides and their envelopes of alteration composed dominantly of phyllosilicates, and the metasediments of the overlying Furulund Group, led to the formation of macroscale fold and shear structures. On the mesoto microscale, a variety of textures have been formed within the pyrite-pyrrhotite-chalcopyrite-sphalerite sulphide rocks as a result of strain and recrystallisation. Variations in pyrite:pyrrhotite ratios and in the texture and proportions of associated gangue minerals evidently governed the strength and ductility of the sulphide rocks so that the same sulphide mineral can behave differently, displaying different textures in different matrices. In massive pyritic samples there is evidence of evolution towards textural equilibrium by recrystallisation, grain growth and annealment during the prograde part of the metamorphic cycle. Later, brittle deformation was superimposed on these early fabrics and the textural evidence is clearly preserved. By comparing published data on the brittle-ductile transformation boundaries of sulphide minerals with the conditions governing metamorphism at Sulitjelma, it is concluded that most of the brittle deformation in the sulphides took place during or after D3under retrograde greenschist conditions. Grain growth of pyrite in matrices of more ductile sulphides during the prograde and early retrograde stages of metamorphism produced the coarse metablastic textures for which Sulitjelma is well-known. In some zones of high resolved shear stress, pyrite shows ductile behaviour which could be explained by a dislocation flow mechanism operating at conditions close to the metamorphic peak. In those horizons in which pyrrhotite is the dominant iron sulphide, the contrast in ductility between silicates, pyrite and pyrrhotite has led to the development of spectacular tectonoclastic textures in which fragments of wall rock have been broken, deformed, rolled and rotated within the ductile pyrrhotite matrix.
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Grapes, Rodney H. "Barian mica and distribution of barium in metacherts and quartzofeldspathic schists, Southern Alps, New Zealand." Mineralogical Magazine 57, no. 387 (June 1993): 265–72. http://dx.doi.org/10.1180/minmag.1993.057.387.09.
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AbstractZoned barian muscovite (2.52-5.66% BaO) and unzoned biotite (0.99-1.77% BaO) occur in two amphibolite grade metacherts of the Alpine schists, Southern Alps, New Zealand. The Ba-micas are associated with quartz-chlorite-Mn-garnet-tourmaline-apatite-sulphide ± oligoclase ± rutile ± magnetite ± ankerite. Increasing Ba (core to rim) in the muscovite is accompanied by a decrease in Si, Ti, Fe + Mg, and K and an increase in [4]Al, [6]Al, and Na. The main substitution that accounts for entry of Ba into both micas is [A]Ba2+ + [4]Al3+ ⇋ [A]K+ + [4]Si4+ and possibly [A]Ba2+ ⇋ [A]K+ + □. Compositional variation of the muscovite is also governed by the substitutions, [6]Al3+ + [4]Al3+ ⇋ [6](Mg,Fe)2+ + [4]si4+, and [A]Na+ ⇋ [A]K+. The presence or absence of oligoclase, rutile, magnetite and Mg/(Mg + Fe) ratio of coexisting biotite control the Na, Ti, Fe and Mg contents of muscovite in the respective metacherts. Important variables controlling the occurrence of Ba-mica is the Ba-rich composition of the metacherts (1387 and 2741 ppm Ba) and metamorphic grade. In metacherts, siliceous and quartzofeldspathic schists with <1000 ppm Ba barium increases with increasing K2O content indicating that in K-feldspar-absent rocks barium is mainly contained in micas (<0.70% BaO). In greenschist facies metacherts and siliceous schists with high Ba (>1000 ppm) and low K2O, barian micas are not present and most of the Ba occurs in baryte ± barian carbonate with implication of a significant original hydrothermal-hydrogenous input. Although low grade illite/sericite/smectites containing Ba are the most likely precursor of the barian micas in the metacherts, strong marginal Ba enrichment in the muscovite indicates a later Ba-metasomatism resulting from the breakdown of baryte under reducing conditions during amphibolite facies metamorphism.
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Ömeroğlu Sayit, Işil, Asuman Günal Türkmenoğlu, Ş. Ali Sayin, and Cengiz Demirci. "Hydrothermal alteration products in the vicinity of the Ahırözü kaolin deposits, Mihalıççık-Eskişehir,Turkey." Clay Minerals 53, no. 2 (June 2018): 289–303. http://dx.doi.org/10.1180/clm.2018.19.
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ABSTRACTThe mineralogy, texture and composition of rocks associated with the kaolin deposits in the Ahırözü-Hamidiye-Üçbaşlı area, SE of Mihalıççık, Eskişehir, Turkey, were investigated. In the study area, Triassic, blue-green schists and serpentinized ultramafic rocks are exposed. Kaolinization occurs at the contact between a Triassic granitic intrusion and metamorphic rocks. Textural and mineralogical characteristics were identified by X-ray diffraction (XRD) and scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDX) analyses. The effects of hydrothermal alteration on the whole-rock chemical composition were determined by inductively coupled plasma mass spectrometry (ICP-MS) analysis. Homogenization temperature (Th, °C), salinity, (wt.% NaCl) and melting temperature (Tm, °C) were detected by fluid-inclusion analyses.The argillic alteration zone (Zone A) includes kaolinite, smectite, natroalunite and accessory pyrite, hematite and goethite. This paragenesis corresponds to a low–intermediate argillic alteration caused by fluids having neutral to acidic pH, at a temperature of <200°C. The propylitic alteration zone (Zone B) is characterized by epidote, chlorite, illite and pyrite and was caused by fluids with a neutral pH and a temperature of >250°C. The rocks in Zone C are mainly silicified and represent sinter formation in the study area. The rocks in the kaolin deposit are depleted in Rb, Pb and Y and enriched in Cs, U and Sr, and represent the products of epithermal hydrothermal alteration of granitic intrusions emplaced in a volcanic arc.
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Massonne, H. J., F. Hervé, O. Medenbach, V. Muñoz, and A. P. Willner. "Zussmanite in ferruginous metasediments from Southern Central Chile." Mineralogical Magazine 62, no. 6 (December 1998): 869–76. http://dx.doi.org/10.1180/002646198548098.
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AbstractZussmanite KFe13[AlSi17O42](OH)14, a modulated 2:1 layer silicate, has so far been found only in iron-rich metasediments from Laytonville, California (Agrellet al.), 1965). A new occurrence is reported here from Punta Nihue north of Valdivia, Chile, in banded stilpnomelane-schists. These are intercalated in the ‘Western Series’, a complex of low-grade metamorphic rocks with local high-pressure, low-temperature overprint (e.g. blueschists).The rock contains conspicuous porphyroblasts of zussmanite of mm size and is composed of chemically distinct bands with the subsequent assemblages: (1) zussmanite-stilpnomelane-quartz, (2) siderite-quartz±stilpnomelane (3) apatite-stilpnomelane-quartz±siderite. The chemical composition of zussmanite, (K0.80Na0.05Ba0.01)(Fe11.292+Mg1.11Mn0.25Fe0.143+Cr0.01Al0.19Ti0.01)[Al1.23Si16.77O42](OH)14, its optical properties and X-ray data correlate well with the Californian occurrence. Additionally, we present new IR data. In type (2) bands of fine-grained crystals of a K,Al poor mineral formed from siderite and quartz. Its chemical composition is close to that of zussmanite. A similar phase was also reported from Laytonville, California (Muir Wood, 1980).The rarity of rock-forming zussmanite can be explained by its occurrence in strongly Fe-rich and reduced rocks, as well as, by a possibly narrowP-Tstability field.
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Schulz, Bernhard. "Mineral chemistry, geothermobarometry and pre-Alpine high-pressure metamorphism of eclogitic amphibolites and mica schists from the Schobergruppe, Austroalpine basement, Eastern Alps." Mineralogical Magazine 57, no. 387 (June 1993): 189–202. http://dx.doi.org/10.1180/minmag.1993.057.387.01.
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AbstractAlternating eclogitic amphibolites, mica schists and orthogneisses in the Schobergruppe to the south of the Tauern Window suffered a post-Upper-Ordovician progressive deformation D1-D2which produced parallel planar-linear structures in all the rocks. Zoned garnets, preferentially oriented zoned clinopyroxenes (Jd 35-42%) and albite (An 7-9%) give evidence of high-pressure metamorphism (550-650°C 14-16 kbar) of the metabasites. Ca-amphiboles crystallized during subsequent decompression. In a kyanite-staurolite-garnet mica schist 300 metres below the metabasites, garnetbearing assemblages grew synchronous with the development of foliations S1and S2. Garnets are zoned with increasing XMgand decreasing-increasing-rcdecreasing Xcafrom cores to rims. Albitic plagioclase (An 1-3%) and micas are enclosed in garnet cores and rims, are in contact with garnet, and occur with garnet in microlithons. When these minerals are used for geothermobarometry, a prograde P-T evolution (460 to 680°C with coeval pressure variations which reach high-pressure conditions can be estimated. This suggests that garnet-plagioclase geobarometry with albitic plagioclase works in the relevant P-T field. Similar garnet zonation trends and a similarly shaped P-T path from mica schists of an adjacent region with late-Variscan cooling ages, points to an eady-Variscan age of the syn-D1-D2high-pressure and subsequent amphibolite-facies metamorphism.
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Downes, P. J., and A. W. R. Bevan. "Chrysoberyl, beryl and zincian spinel mineralization in granulite-facies Archaean rocks at Dowerin, Western Australia." Mineralogical Magazine 66, no. 6 (December 2002): 985–1002. http://dx.doi.org/10.1180/0026461026660072.
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Abstract A deposit of chrysoberyl (BeAl2O4), including the variety alexandrite, occurs near Dowerin, in the southwestern region of the Archaean Yilgarn Craton, Western Australia. The deposit is situated in the northern part of the Lake Grace Terrain, a crustal component of the southwestern Yilgarn Craton, in granulite-facies gneisses (2640–2649 Ma; T = 700°C, P <6 kbar) adjacent to the margin of the Kellerberrin Batholith (2587±25 Ma). Beryllium mineralization at Dowerin occurs in plagioclase-quartz-biotite-garnet gneiss and cross-cutting tourmaline-plagioclase veins situated adjacent to lenses of actinolite-cummingtonite-phlogopite schist. Crystals of chrysoberyl (0.15–1.74 wt.% Cr2O3; 2.25–3.23 wt.% FeO; trace–0.13 wt.% ZnO; SiO2 <0.05 wt.%) are found embedded in almandine or plagioclase, and closely intergrown with biotite and/or zincian hercynite in the host-rock gneiss. Minor Cr and Fe in the alexandrite variety of chrysoberyl were possibly derived from associated zincian hercynite and/or almandine. Trace beryl (0.04–0.20 wt.% Cr2O3; 0.54–0.71 wt.% FeO; trace– 0.22 wt.% Na2O; 0.1–0.71 wt.% MgO) occurs as anhedral interstital grains between crystals of chrysoberyl, plagioclase and biotite, and as rare inclusions in chrysoberyl. Textural and mineral chemical evidence suggests that chrysoberyl and zincian spinels (chromite to hercynite containing from 2–8 wt.% ZnO) formed during granulite-facies regional metamorphism and probably pre-dated the formation of metamorphic tourmaline-plagioclase veins during the same metamorphic episode. The Be, B and Zn required to form chrysoberyl, beryl, tourmaline and zincian spinels may have been released by metamorphic reactions in host-rock metapelites during prograde granulite-facies metamorphism.
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Ríos, Carlos Alberto, and Óscar Mauricio Castellanos. "Petrologic significance of Fe-rich staurolite in pelitic schists of the Silgará Formation, Santander Massif." Earth Sciences Research Journal 20, no. 1 (April 30, 2016): 1–7. http://dx.doi.org/10.15446/esrj.v20n1.40847.
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<p>Medium grade metapelites of the Silgará Formation at the Santander Massif (Colombian Andes) have been affected by a medium-pressure/high-temperature Barrovian type of metamorphism, developing a sequence of metamorphic zones (biotite, garnet, staurolite and sillimanite). These rocks record a complex tectonometamorphic evolution and reaction history. Metapelitic rocks from the staurolite zone are typically foliated, medium- to coarse-grained, pelitic to semipelitic schists that contain the mineral assemblage biotite + garnet + staurolite ± kyanite; all contain muscovite + quartz + plagioclase with minor K-feldspar, tourmaline, apatite, zircon, epidote, calcite, and Fe–Ti oxides. Field and microscopic evidences reveal that Fe-rich staurolite in pelitic schists is involved in several chemical reactions, which explains its formation and transformation to other minerals, which are very important to elucidate the reaction history of the Silgará Formation metapelites.</p><p> </p><p><strong>Significado Petrológico de Estaurolita Rica en Fe en Esquistos Pelíticos de la Formación Silgará, Macizo de Santander</strong></p><p> </p><p><strong>Resumen</strong></p><p>Medium grade metapelites of the Silgará Formation en el Macizo de Santander (Andes Colombianos) han sido afectadas por un metamorfismo de tipo Barroviense, el cual se ha producido en condiciones de media presión y alta temperatura, desarrollando una secuencia de zonas metamórficas (biotita, granate, estaurolita y silimanita). Estas rocas registran una evolución tectono-metamórfico e historia reacción compleja. Las metapelitas de la zona de la estaurolita están representadas por esquistos pelíticos a semipelíticos de grano medio a grueso típicamente foliados que contienen la paragénesis mineral biotita + granate + estaurolita ± cianita; todos contienen moscovita + cuarzo + plagioclasa con menor feldespato potásico, turmalina, apatito, zircón, epidota, calcita, y óxidos de Fe-Ti. Evidencias de campo y microscópicas revelan que la estaurolita rica en Fe en esquistos pelíticos se involucró en varias reacciones químicas a partir de las cuales esta se formó o transformó a otra fase mineral, lo cual es muy importante para dilucidar la historia de reacción de los metapelitas de la Formación Silgará.</p>
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Sarifakioglu, E., Y. Dilek, and M. Sevin. "Jurassic–Paleogene intraoceanic magmatic evolution of the Ankara Mélange, north-central Anatolia, Turkey." Solid Earth 5, no. 1 (February 19, 2014): 77–108. http://dx.doi.org/10.5194/se-5-77-2014.
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Abstract. Oceanic rocks in the Ankara Mélange along the Izmir–Ankara–Erzincan suture zone (IAESZ) in north-central Anatolia include locally coherent ophiolite complexes (~ 179 Ma and ~ 80 Ma), seamount or oceanic plateau volcanic units with pelagic and reefal limestones (96.6 ± 1.8 Ma), metamorphic rocks with ages of 256.9 ± 8.0 Ma, 187.4 ± 3.7 Ma, 158.4 ± 4.2 Ma, and 83.5 ± 1.2 Ma indicating northern Tethys during the late Paleozoic through Cretaceous, and subalkaline to alkaline volcanic and plutonic rocks of an island arc origin (~ 67–63 Ma). All but the arc rocks occur in a shale–graywacke and/or serpentinite matrix, and are deformed by south-vergent thrust faults and folds that developed in the middle to late Eocene due to continental collisions in the region. Ophiolitic volcanic rocks have mid-ocean ridge (MORB) and island arc tholeiite (IAT) affinities showing moderate to significant large ion lithophile elements (LILE) enrichment and depletion in Nb, Hf, Ti, Y and Yb, which indicate the influence of subduction-derived fluids in their melt evolution. Seamount/oceanic plateau basalts show ocean island basalt (OIB) affinities. The arc-related volcanic rocks, lamprophyric dikes and syenodioritic plutons exhibit high-K shoshonitic to medium- to high-K calc-alkaline compositions with strong enrichment in LILE, rare earth elements (REE) and Pb, and initial εNd values between +1.3 and +1.7. Subalkaline arc volcanic units occur in the northern part of the mélange, whereas the younger alkaline volcanic rocks and intrusions (lamprophyre dikes and syenodioritic plutons) in the southern part. The late Permian, Early to Late Jurassic, and Late Cretaceous amphibole-epidote schist, epidote-actinolite, epidote-chlorite and epidote-glaucophane schists represent the metamorphic units formed in a subduction channel in the northern Neotethys. The Middle to Upper Triassic neritic limestones spatially associated with the seamount volcanic rocks indicate that the northern Neotethys was an open ocean with its MORB-type oceanic lithosphere by the early Triassic (or earlier). The latest Cretaceous–early Paleocene island arc volcanic, dike and plutonic rocks with subalkaline to alkaline geochemical affinities represent intraoceanic magmatism that developed on and across the subduction–accretion complex above a N-dipping, southward-rolling subducted lithospheric slab within the northern Neotethys. The Ankara Mélange thus exhibits the record of ~ 120–130 million years of oceanic magmatism in geological history of the northern Neotethys.
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Zeh, Armin, Allan H. Wilson, Dominik Gudelius, and Axel Gerdes. "Hafnium Isotopic Composition of the Bushveld Complex Requires Mantle Melt–Upper Crust Mixing: New Evidence from Zirconology of Mafic, Felsic and Metasedimentary Rocks." Journal of Petrology 60, no. 11 (November 1, 2019): 2169–200. http://dx.doi.org/10.1093/petrology/egaa004.
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Abstract The origin of magmas that formed the Bushveld Complex remains highly debated in spite of many decades of intense research. Previous geochemical–petrological studies have shown a strong mantle derivation resulting ultimately in highly economic ore bodies of platinum group elements and chromium. However, geochemistry also points to the contribution of a significant crustal component, which may have been derived singly or in combination from a number of different sources. These include subcontinental lithospheric mantle that was enriched prior to Bushveld magma formation, possibly by subduction, assimilation of lower and upper crust during magma ascent, and contamination during magma chamber accretion within sedimentary rocks of the enclosing Transvaal Supergroup. In this study, the contributions of these various reservoirs will be evaluated by employing Hf isotopic data of well-characterized zircon grains in mafic, felsic and metasedimentary rocks, together with Zr–Hf bulk-rock compositions. The results reveal that magmatic zircon grains in mafic cumulate rocks from the floor to the roof of the c. 9 km thick Rustenburg Layered Suite (RLS) show essentially the same variations in εHf2·055 Ga from −7·5 to −10·2 as those of metamorphic zircon grains and overgrowths in the immediate surrounding quartzite and metapelitic rocks, as well as in granitic melt batches, granophyres, and the upper Rooiberg volcanics. The same values are also obtained by estimating the average Hf isotopic compositions of detrital zircon grains in many quartzite and metapelitic rocks from the surrounding Magaliesberg (εHf2·055 Ga = −6·2 to −10·8, six samples, maximum deposition age at 2080 Ma) and Houtenbeck formations (εHf2·055 Ga = −7·1 to −8·9, three samples, maximum deposition age at 2070 Ma), and by a six-point isochron of a garnet-schist from the Silverton Formation (εHft = −6·6 ± 0·7; age = 2059·4 ± 2·7 Ma). Zircon morphologies, zoning patterns, Hf isotopic data and petrological constraints furthermore reveal that metamorphic zircon was precipitated from aqueous fluids and/or felsic melts at temperatures between 550 and 900 °C, and that the Hf isotopic composition became homogenized during fluid transport in the contact aureole. However, results of numerical modelling indicate that fluid infiltration had only a minor effect on the Zr–Hf budget and Hf isotopic composition of the RLS, and that these parameters were mainly controlled by the mixing of melts derived from three major sources: (1) the asthenospheric mantle (>20 %); (2) enriched subcontinental lithospheric mantle (<80 %); (3) assimilation of significant amounts of crust (up to 40 %). The modelling furthermore suggests that assimilation of lower Kaapvaal Craton crust was minor (<15 %) during B1 (high-Mg andesite) magma formation, but up to 40 % during B3 (tholeiite) magma formation. The minor variation in εHft of zircon throughout the entire stratigraphy of the RLS resulted from the interplay of three dominant contributing factors: (1) intrusion of hot (>1200 °C) mantle-derived magmas with relatively low Zr–Hf concentrations having a similar εHf2·055 Ga of −8·5 ± 1·9 to that of upper crust rocks surrounding the RLS; (2) significant assimilation of volcanic and metasedimentary rocks with high Zr–Hf concentration; (3) mingling, mixing and/or diffusive exchange of Zr and Hf between crust and mantle-derived melts and aqueous fluids prior to late-magmatic crystallization of zircon at temperatures between 700 and 900 °C. This study shows that the combination of Zr–Hf bulk-rock data with Hf isotopic data of well-characterized zircon grains provides a powerful tool to quantify various mantle and crustal reservoirs of mafic layered intrusions, and allows new insights into magma chamber and related contact metamorphic processes.
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Holdaway, M. J. "Optimization of some key geothermobarometers for pelitic metamorphic rocks." Mineralogical Magazine 68, no. 1 (February 2004): 1–14. http://dx.doi.org/10.1180/0026461046810167.
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AbstractI will consider mainly geothermobarometry in medium-grade pelitic rocks, including the garnet-biotite (GB) geothermometer, the Grossular-Al silicate-plagioclase (GASP) geobarometer, and the muscovite-almandine-biotite-sillimanite (MABS) geobarometer. For GB (Holdaway, 2000) experimental data and estimated biotite ΔWTi were used to optimize two exchange parameters and four biotite Margules parameters. Using stepwise linear regression, experimental vs. calculated T were constrained to lie on a line with slope of one and intercept of zero, maximizing r2. The best model involves experiments by Ferry and Spear (1978) and Perchuk and Lavrent’eva (1983), suggesting minimal viAl in the Ferry and Spear product biotite. For GASP (Holdaway, 2001), end-member experimental data do not adequately constrain the equilibrium. I used the GB model above, and allowed the end-member curve to rotate about the best-constrained part of the GASP end-member data. The end-member curve was further constrained with the kyanite-sillimanite (K-S) boundary using published chemical data on 76 pelitic schist samples from 11 localities, rejecting Low-Grs and low-An samples. The Fuhrman and Lindsley (1988) plagioclase model gives the best results. For MABS, work in progress involves 61 samples from the 11 localities which have muscovite analyses. Biotite Margules parameters were based on the GB model and McMullin et al. (1991). The MABS end-member curve was calibrated by comparison of P values determined using trial MABS data and GASP results. The P values for the 61 samples agree well with the K-S boundary, and sillimanite-bearing rocks of west-central Maine all fall in the sillimanite field. Preliminary biotite values are: GAnn = –5149198 – 412.05 T, WAlFe = –14023 + 28.14 T, WAlMg = –259582 + 308.44 T, WTiFe = 124842 – 98.67 T, WTiMg = –186148 + 271.72 T. For geobarometry, the Berman (1988, revised 1992) database was used with adjustable H and S of grossular for GASP and H and S of annite for MABS. The accuracy of currently available databases, activity models and mole fraction models is not adequate for good geothermobarometry, without further refinement. Adjustable parameters tend to compensate for error in activity models, mole fraction models and databases.
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Xia, Qiong-Xia, Peng Gao, Guang Yang, Yong-Fei Zheng, Zi-Fu Zhao, Wan-Cai Li, and Xu Luo. "The Origin of Garnets in Anatectic Rocks from the Eastern Himalayan Syntaxis, Southeastern Tibet: Constraints from Major and Trace Element Zoning and Phase Equilibrium Relationships." Journal of Petrology 60, no. 11 (November 1, 2019): 2241–80. http://dx.doi.org/10.1093/petrology/egaa009.
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Abstract Amphibolite- and granulite-facies metamorphic rocks are common in the eastern Himalayan syntaxis of southeastern Tibet. These rocks are composed mainly of gneiss, amphibolite and schist that underwent various degrees of migmatization to produce leucogranites, pegmatites and felsic veins. Zircon U–Pb dating of biotite gneiss, leucocratic vein and vein granite from the syntaxis yields consistent ages of ∼49 Ma, indicating crustal anatexis during continental collision between India and Asia. Garnets in these rocks are categorized into peritecitc and anatectic varieties based on their mode of occurrence, mineral inclusions and major- and trace-element zoning. The peritectic garnets mainly occur in the biotite gneiss (mesosome layer) and leucocratic veins. They are anhedral and contain abundant mineral inclusions such as high-Ti biotites and quartz, and show almost homogeneous major-element compositions (except Ca) and decreasing HREE contents from core to rim, indicating growth during the P- and T-increasing anatexis. Peak anatectic conditions at 760–800°C and 9–10·5 kbar are well constrained by phase equilibrium calculations, mineral assemblages, and garnet isopleths. In contrast, anatectic garnets only occur in the vein granite. They are round or subhedral, contain quartz inclusions, and exhibit increasing spessartine and trace-element contents from core to rim. The garnet–biotite geothermometry and the garnet–biotite–plagioclase–quartz geobarometry suggest that the anatectic garnets crystallized at ∼620–650°C and 4–5 kbar. Some garnet grains show two-stage zoning in major and trace elements, with the core similar to the peritectic garnet but the rim similar to the anatectic garnet. Mineralogy, whole-rock major- and trace-element compositions and zircon O isotopes indicate that the two types of leucosomes were produced by hydration (water-present) melting and dehydration (water-absent) melting, respectively. The leucocratic veins contain peritectic garnet but no K-feldspar, have lower whole-rock K2O contents and Rb/Sr ratios, higher whole-rock CaO contents and Sr/Ba ratios, and show homogeneous δ18O values that are lower than those of relict zircons, indicating that such veins were produced by the hydration melting. In contrast, the vein granite contains peritectic garnet and K-feldspar, has higher whole-rock K2O contents and Rb/Sr ratios, lower whole-rock CaO contents and Sr/Ba ratios, and shows comparable δ18O values with those of relict zircons, suggesting that this granite were generated by the dehydration melting. Accordingly, both hydration and dehydration melting mechanisms have occurred in the eastern Himalayan syntaxis.
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Marger, Katharina, Cindy Luisier, Lukas P. Baumgartner, Benita Putlitz, Barbara L. Dutrow, Anne-Sophie Bouvier, and Andrea Dini. "Origin of Monte Rosa whiteschist from in-situ tourmaline and quartz oxygen isotope analysis by SIMS using new tourmaline reference materials." American Mineralogist 104, no. 10 (October 1, 2019): 1503–20. http://dx.doi.org/10.2138/am-2019-7012.
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Abstract A series of tourmaline reference materials are developed for in situ oxygen isotope analysis by secondary ion mass spectrometry (SIMS), which allow study of the tourmaline compositions found in most igneous and metamorphic rocks. The new reference material was applied to measure oxygen isotope composition of tourmaline from metagranite, meta-leucogranite, and whiteschist from the Monte Rosa nappe (Western Alps). The protolith and genesis of whiteschist are highly debated in the literature. Whiteschists occur as 10 to 50 m tube-like bodies within the Permian Monte Rosa granite. They consist of chloritoid, talc, phengite, and quartz, with local kyanite, garnet, tourmaline, and carbonates. Whiteschist tourmaline is characterized by an igneous core and a dravitic overgrowth (XMg > 0.9). The core reveals similar chemical composition and zonation as meta-leucogranitic tourmaline (XMg = 0.25, δ18O = 11.3–11.5‰), proving their common origin. Dravitic overgrowths in whiteschists have lower oxygen isotope compositions (8.9–9.5‰). Tourmaline in metagranite is an intermediate schorl-dravite with XMg of 0.50. Oxygen isotope data reveal homogeneous composition for metagranite and meta-leucogranite tourmalines of 10.4–11.3‰ and 11.0–11.9‰, respectively. Quartz inclusions in both meta-igneous rocks show the same oxygen isotopic composition as the quartz in the matrix (13.6–13.9‰). In whiteschist the oxygen isotope composition of quartz included in tourmaline cores lost their igneous signature, having the same values as quartz in the matrix (11.4–11.7‰). A network of small fractures filled with dravitic tourmaline can be observed in the igneous core and suggested to serve as a connection between included quartz and matrix, and lead to recrystallization of the inclusion. In contrast, the igneous core of the whiteschist tourmaline fully retained its magmatic oxygen isotope signature, indicating oxygen diffusion is extremely slow in tourmaline. Tourmaline included in high-pressure chloritoid shows the characteristic dravitic overgrowth, demonstrating that chloritoid grew after the metasomatism responsible for the whiteschist formation, but continued to grow during the Alpine metamorphism. Our data on tourmaline and quartz show that tourmaline-bearing white-schists originated from the related meta-leucogranites, which were locally altered by late magmatic hydrothermal fluids prior to Alpine high-pressure metamorphism.
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Korikovsky, S. P., and S. Karamata. "Metamorphism of glaucophane-schist rocks at Fruška Gora complex, northern Vardar zone, Serbia: Glaucophane-riebeckite-pumpellyite-actinolite-epidote-chlorite schists with zonal Na-amphiboles." Petrology 19, no. 1 (January 2011): 1–12. http://dx.doi.org/10.1134/s0869591111010048.
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Kondor, Henrietta, and Tivadar M Tóth. "Contrasting metamorphic and post-metamorphic evolutions within the Algyő basement high (Tisza Mega-unit, SE Hungary). Consequences for structural history." Central European Geology 64, no. 2 (May 29, 2021): 91–112. http://dx.doi.org/10.1556/24.2021.00004.
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AbstractThe Algyő High (AH) is an elevated crystalline block in southeastern Hungary covered by thick Neogene sediments. Although productive hydrocarbon reservoirs are found in these Neogene sequences, numerous fractured reservoirs also occur in the pre-Neogene basement of the Pannonian Basin. Based on these analogies, the rock body of the AH might also play a key role in fluid storage and migration; however, its structure and therefore the reservoir potential is little known. Based on a comprehensive petrologic study in conjunction with analysis of the spatial position of the major lithologies, the AH is considered to have been assembled from blocks with different petrographic features and metamorphic history. The most common lithologies of garnet-kyanite gneiss and mica schist associated with garnetiferous amphibolite are dominant in the northwestern and southeastern parts of the AH. The first regional amphibolite facies metamorphism of the gneiss and mica schist was overprinted by a contact metamorphic (metasomatic) event during decompression in the stability field of kyanite. Garnet-bearing amphibolite experienced amphibolite facies peak conditions comparable with the host gneiss. Regarding the similarities in petrologic features, the northwestern and southeastern parts of the area represent disaggregated blocks of the same rock body. The central part of the AH area is characterized by an epidote gneiss-dominated block metamorphosed along with a greenschist-facies retrograde pathway as well as a chlorite schist-dominated block formed by greenschist-facies progressive metamorphism. The independent evolution of these two blocks is further confirmed by the presence of a propylitic overprint in the chlorite schists. The different metamorphic blocks of the northwestern, southeastern and central parts of the AH probably became juxtaposed along post-metamorphic normal faults developed due to extensional processes. The supposed brittle structural boundaries between the blocks could have provided hydrocarbon migration pathways from the adjacent over-pressured sub-basins, or could even represent suitable reservoirs.
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Al- Zubaidi, Aqeel A., Varoujan Sissakian, and Hassan K. Jassim. "PETROLOGY AND PROVENANCE OF THE NATURAL STONE TOOLS FROM Al-DALMAJ ARCHAEOLOGICAL SITE, MESOPOTAMIAN PLAIN, IRAQ." Bulletin of the Iraq Natural History Museum 16, no. 3 (June 20, 2021): 231–51. http://dx.doi.org/10.26842/binhm.7.2021.16.3.0231.
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Many stone tools were found on a hill south of the Hor Al-Dalmaj which is located in the central part of the alluvial plain of Mesopotamia, between the Tigris and Euphrates Rivers. The types of rocks from which the studied stone tools were made are not found in the alluvial plain, because it consists of friable sand, silt, and clay. All existing sediments were precipitated in riverine environments such as point bar, over bank, and floodplain sediments. The collected stone tools were described with a magnifying glass (10 x) and a polarized microscope after they were thin sectioned. Microscopic analysis showed that these stone tools are made of sedimentary, volcanic igneous and metamorphic rocks, such as: sandstones, limestones, chert, conglomerate, rhyolite, basalt, mica schist, and quartzite. The current studied stone tools were used by ancient humans as pestles, querns, scrapers, and knives. The present study showed that these tools were transported from outside the alluvial plain of Mesopotamia. A stone tool at the archaeological site of Al-Dalmaj indicates that there were some trade routes that connected this site with its surrounding; in addition to the economic, and that might occurred cultural exchanges during the Neolithic Period.
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Bebout, Gray E., and Marilyn L. Fogel. "Nitrogen-isotope compositions of metasedimentary rocks in the Catalina Schist, California: Implications for metamorphic devolatilization history." Geochimica et Cosmochimica Acta 56, no. 7 (July 1992): 2839–49. http://dx.doi.org/10.1016/0016-7037(92)90363-n.
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Torres-Ruiz, J., A. Pesquera, and V. López Sánchez-Vizcaíno. "Chromian tourmaline and associated Cr-bearing minerals from the Nevado-Fildbride Complex (Betic Cordilleras, SE Spain)." Mineralogical Magazine 67, no. 3 (June 2003): 517–33. http://dx.doi.org/10.1180/0026461036730114.
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AbstractChromian tourmaline, in association with other Cr-bearing minerals (amphibole, mica, epidote, chlorite, titanite, rutile and chromian spinel), occurs in fine calc-schist levels within metacarbonate rocks from the Nevado-Filabride Complex, SE Spain. Electron microprobe analyses of tourmaline and coexisting minerals document both chemical differences dependent on the host-rock type and an irregular distribution of Cr at grain scale. Tourmaline is Na-rich dravite, with average Mg/(Mg+Fe) ratios of 0.83 and 0.63 a.p.f.u. and Cr contents of 0.32 and 0.18 a.p.f.u., in dolomitic and ankeritic marbles, respectively. Tourmaline contains small but significant concentrations of Zn (av. 0.01 a.p.f.u.) and in ankeritic marble it also contains Ni (av. 0.04 a.p.f.u.). Zn-rich chromian spinel appears as small relict inclusions in silicates, with average Cr, Fe, Al and Zn contents of 1.201, 1.241, 0.411 and 0.107 a.p.f.u., respectively. Amphibole, epidote, mica and chlorite show average Cr contents of 0.088, 0.138, 0.115 and 0.267 a.p.f.u., respectively, in dolomitic marbles, and 0.103, 0.078, 0.065 and 0.185 a.p.f.u., respectively, in ankeritic marbles. Cr-silicates formed through metamorphic reactions involving detrital Cr-rich spinel, in addition to clay minerals and carbonates. The B necessary to form tourmaline was probably derived from the leaching of underlying evaporitic rocks.
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Melcher, Frank. "Genesis of chemical sediments in Birimian greenstone belts: evidence from gondites and related manganese-bearing rocks from Northern Ghana." Mineralogical Magazine 59, no. 395 (June 1995): 229–51. http://dx.doi.org/10.1180/minmag.1995.059.395.08.
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AbstractEarly Proterozoic chemical sediments of the Birimian Supergroup in northern Ghana host several types of metamorphosed manganese-bearing rocks. Differences in the mineralogy and geochemistry can be attributed to facies changes in a mixed volcanic-volcaniclastic depositional environment. Manganese oxide-bearing phyllite, which is enriched in transition metals (Cu, Ni, Co, Zn), formed on the flanks of submarine volcanic edifices above an oxidation boundary. Towards the deeper basin, manganese silicate-rich gondites occur. These consist either of spessartine + quartz + ilmenite, or of spessartine + quartz + Mn amphiboles ± rhodonite ± hyalophane ± Mn stilpnomelane ± ilmenite. The Mn amphiboles are identified as manganoan actinolite, tirodite, and dannemorite. Sulphides are widespread as premetamorphic inclusions in Mn garnet grains. In the basin centre, chlorite schist containing garnet with 50–60 mol.% spessartine represents the most distal manganese-bearing rock which is highly diluted by volcanogenic background sedimentation. The origin of Mn-rich rocks is explained by heat-driven seawater convection systems active in submarine volcanic centres that provided hydrothermal solutions. Precipitation of different minerals depended on the geochemical conditions prevailing on the seafloor. During the Eburnean event (around 2000 Ma), the chemical sediments were metamorphosed to upper greenschist or lower amphibolite facies. Mineral assemblages in the gondites point to metamorphic conditions in the range of 450–500°C at 2–3 kbar.
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NAKAMURA, C., and M. ENAMI. "Prograde amphiboles in hematite-bearing basic and quartz schists in the Sanbagawa belt, central Shikoku: relationship between metamorphic field gradient and P-T paths of individual rocks." Journal of Metamorphic Geology 12, no. 6 (November 1994): 841–52. http://dx.doi.org/10.1111/j.1525-1314.1994.tb00063.x.
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Eugster, Hans P. "Granites and hydrothermal ore deposits: a geochemical framework." Mineralogical Magazine 49, no. 350 (March 1985): 7–23. http://dx.doi.org/10.1180/minmag.1985.049.350.02.
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AbstractThe geochemical evolution of tin-tungsten deposits and their associated sulphides can be discussed in terms of four sequential processes: acquisition of the ore-forming elements (OFEs) by the granitic magma, emplacement of these elements in minerals and residual melt of the crystallizing granite, release of the OFEs to the circulating hydrothermal fluids and transport to the depositional sites, and finally, deposition of ore minerals through interaction of these fluids with the wall rock. Based on their crystallographic behaviour, it is useful to distinguish three principal classes of OFEs, here identified as BOC, LHC, and ALC elements. BOC (bivalent octahedral cation) elements are similar to ferrous iron and here are represented mainly by Zn, Mn, and perhaps Cu. Li also belongs to this class, although it is monovalent. LHC (large highly charged cations) elements encompass As, Nb, Mo, Sn, Sb, Ta, and W and they are similar to ferric iron or titanium in their crystallographic role. ALC (alkali-like cations) are capable of occupying alkali positions and are represented mainly by Pb, Ag, and Hg.LHCs are rejected from the polymerized silicate liquid network and become enriched in the roof of the acid magma chamber, where more non-bridging oxygens are available. Transport to the roof may be enhanced by the formation of hydrous complexes, as is the pronounced enrichment of Na and Li. BOCs, along with Cl, F, and B, fractionate strongly into the vapour phase during vesiculation. HCl in the ore fluid is crucial for the alteration process and can be produced during boiling by a hydrolysis reaction of the NaCl dissolved or immiscibly present in the silicate magma.Considerable laboratory information is available concerning release mechanisms of the OFEs to hydrothermal fluids. We can distinguish congruent and incongruent dissolution, both in response to acid buildup, as well as congruent and incongruent exchange not involving HCl. Melt-fluid fractionation is also thought to be important, though the physical mechanisms are not well understood. Any of these release mechanisms may be coupled with reduction or oxidation reactions. LHC, BOC, and ALC elements respond differently to each of these mechanisms, and these differences may in part be responsible for the observed separation of ore minerals in space and time. It is suggested that LHC elements are released preferentially during acid, non-oxidizing conditions typical of early stages, while BOC elements respond more readily to later acid-oxidizing environments, as well as exchange reactions with or without oxidation.Depositional reactions have been formulated with respect to two contrasting types of country rocks: carbonates and schists. Differences are related to the process of neutralization of the HCl produced by ore deposition: carbonate dissolution on one hand and feldspar-muscovite or biotite-muscovite conversion on the other. In carbonate rocks, evaporite-related sulphates may provide the H2S necessary for sulphide precipitation, while in schists disseminated sulphides and organic matter may be important sulphur reservoirs in addition to the sulphur liberated from the granite. A variety of situations can be envisaged with respect to the sources of the OFEs and the sulphur species required for ore deposition, including granite and wall rocks. Chloride is recognized as the crucial anion for OFE release, transport, and deposition, although F and B play a role yet to be evaluated. Final HCl neutralization is an essential step in the reactions responsible for the deposition of ore minerals.The ultimate sources of the OFEs must be related to the continental material involved in the process of melt production by partial melting. Oxidized sediments provide sources for LHC and ALC elements in the form of heavy minerals and clastic feldspars and micas. Organic-rich reduced sediments are hosts to BOC and LHC elements as sulphides and ALC elements in organic matter. Remelting of igneous and metamorphic rocks can enrich LHC, BOC, and ALC elements in the melt by extraction from opaques, Fe-Mg silicates, feldspars, and micas.
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Bramwell, M. G. "Metamorphic differentiation; a mechanism indicated by zoned kyanite crystals in some rocks from the Lukmanier region, Switzerland." Mineralogical Magazine 49, no. 350 (March 1985): 59–64. http://dx.doi.org/10.1180/minmag.1985.049.350.07.
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AbstractTwo samples of garnet-kyanite-staurolite schist from Lukmanier, Switzerland, each contain two chemical varieties of kyanite which occur in texturally distinct areas of the rock. Type 1 form large idiomorphic crystals within an open crenulation cleavage S3. They exhibit a systematic zonation of F2O3, with core values of 0.8% decreasing to 0.3% at the crystal margin. Type 2 form small, much less abundant crystals in areas between S3 cleavage zones, and have a homogeneous distribution of 0.3% Fe2O3 throughout the crystal.It is suggested that the first-nucleated crystals contain the highest core concentration of Fe2O3 and are the largest. A positive correlation between core Fe2O3 values and crystal size is interpreted as a nucleation and growth sequence. This indicates that the first crystals formed preferentially in S3 (Type 1), with Type 2 crystals growing later outside the S3 zones.Concentration of kyanite in S3 zones produces a distinct mineral banding in the rock. A mechanism for the development of metamorphic differentiation by preferred nucleation of kyanite in S3 is proposed.
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Kästner, Felix, Simona Pierdominici, Judith Elger, Alba Zappone, Jochem Kück, and Christian Berndt. "Correlation of core and downhole seismic velocities in high-pressure metamorphic rocks: a case study for the COSC-1 borehole, Sweden." Solid Earth 11, no. 2 (April 23, 2020): 607–26. http://dx.doi.org/10.5194/se-11-607-2020.
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Abstract. Deeply rooted thrust zones are key features of tectonic processes and the evolution of mountain belts. Exhumed and deeply eroded orogens like the Scandinavian Caledonides allow us to study such systems from the surface. Previous seismic investigations of the Seve Nappe Complex have shown indications of a strong but discontinuous reflectivity of this thrust zone, which is only poorly understood. The correlation of seismic properties measured on borehole cores with surface seismic data can constrain the origin of this reflectivity. To this end, we compare seismic velocities measured on cores to in situ velocities measured in the borehole. For some intervals of the COSC-1 borehole, the core and downhole velocities deviate by up to 2 km s−1. These differences in the core and downhole velocities are most likely the result of microcracks mainly due to depressurization. However, the core and downhole velocities of the intervals with mafic rocks are generally in close agreement. Seismic anisotropy measured in laboratory samples increases from about 5 % to 26 % at depth, correlating with a transition from gneissic to schistose foliation. Thus, metamorphic foliation has a clear expression in seismic anisotropy. These results will aid in the evaluation of core-derived seismic properties of high-grade metamorphic rocks at the COSC-1 borehole and elsewhere.
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Skrzypek, Etienne, Shuhei Sakata, and Dominik Sorger. "Alteration of magmatic monazite in granitoids from the Ryoke belt (SW Japan): Processes and consequences." American Mineralogist 105, no. 4 (April 1, 2020): 538–54. http://dx.doi.org/10.2138/am-2020-7025.
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Abstract The alteration of magmatic monazite and its consequences for monazite geochronology are explored in granitoids from the western part of the Ryoke belt (Iwakuni-Yanai area, SW Japan). Biotite-granite samples were collected in two plutons emplaced slightly before the main tectono-metamorphic event: the first one, a massive granite (Shimokuhara) adjoins schistose rocks affected by greenschist facies metamorphism; and the second, a gneissose granite (Namera) adjoins migmatitic gneiss that experienced upper-amphibolite facies conditions. Despite contrasting textures, the granite samples have similar mineral modes and compositions. Monazite in the massive granite is dominated by primary domains with limited secondary recrystallization along cracks and veinlets. It is variably replaced by allanite+apatite±xenotime±Th-U-rich phases. The outermost rims of primary domains yield a weighted average 206Pb/238U date of 102 ± 2 Ma while the Th-U phases show Th-U-Pb dates of 58 ± 5 and 15 to 14 ± 2–3 Ma. Monazite in the gneissose granite preserves sector- or oscillatory-zoned primary domains cross-cut by secondary domains enriched in Ca, Y, U, P, and containing numerous inclusions. The secondary domains preserve concordant 206Pb/238U dates spreading from 102 ± 3 to 91 ± 2 Ma while primary domain analyses are commonly discordant and range from 116 to 101 Ma. Monazite alteration textures in the two granites chiefly reflect differences in their post-magmatic histories. In the massive granite, monazite replacement occurred via a nearly stoichiometrically balanced reaction reflecting interaction with an aqueous fluid enriched in Ca+Al+Si±F during hydrothermal alteration of the granitic assemblage, likely below 500 °C. In the gneissose granite, a small amount of anatectic melt, probably derived from the neighboring metasedimentary rocks, was responsible for pseudomorphic recrystallization of monazite by dissolution-reprecipitation above 600 °C. Regardless of whether monazite underwent replacement or recrystallization, primary monazite domains preserve the age of magmatic crystallization for both plutons (102 ± 2 and 106 ± 5 Ma). Conversely, the age of monazite alteration is not easily resolved. Monazite replacement in the massive granite might be constrained using the Th-U-rich alteration products; with due caution and despite probable radiogenic Pb loss, the oldest date of 58 ± 5 Ma could be ascribed to chloritization during final exhumation of the granite. The spread in apparently concordant 206Pb/238U dates for secondary domains in the gneissose granite is attributed to incomplete isotopic resetting during dissolution-reprecipitation, and the youngest date of 91 ± 2 Ma is considered as the age of monazite recrystallization during a suprasolidus metamorphic event. These results reveal a diachronous, ca. 10 Ma-long high-temperature (HT) history and an overall duration of about 15 Ma for the metamorphic evolution of the western part of the Ryoke belt.
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SORENSEN, S. S. "Petrology of amphibolite-facies mafic and ultramafic rocks from the Catalina Schist, southern California: metasomatism and migmatization in a subduction zone metamorphic setting." Journal of Metamorphic Geology 6, no. 4 (July 1988): 405–35. http://dx.doi.org/10.1111/j.1525-1314.1988.tb00431.x.
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Jacobson, Carl E., and M. Robert Dawson. "Structural and metamorphic evolution of the Orocopia Schist and related rocks, southern California: Evidence for late movement on the Orocopia fault." Tectonics 14, no. 4 (August 1995): 933–44. http://dx.doi.org/10.1029/95tc01446.
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Lanzirotti, A., and Gilbert N. Hanson. "Geochronology and geochemistry of multiple generations of monazite from the Wepawaug Schist, Connecticut, USA: implications for monazite stability in metamorphic rocks." Contributions to Mineralogy and Petrology 125, no. 4 (November 26, 1996): 332–40. http://dx.doi.org/10.1007/s004100050226.
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FAGERENG, Å., and A. F. COOPER. "The metamorphic history of rocks buried, accreted and exhumed in an accretionary prism: an example from the Otago Schist, New Zealand." Journal of Metamorphic Geology 28, no. 9 (October 1, 2010): 935–54. http://dx.doi.org/10.1111/j.1525-1314.2010.00900.x.
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Schreyer, Werner. "Experimental Studies on Metamorphism of Crustal Rocks Under Mantle Pressures." Mineralogical Magazine 52, no. 364 (March 1988): 1–26. http://dx.doi.org/10.1180/minmag.1988.052.364.01.
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AbstractMetamorphic rocks of undoubted crustal origin have been described in recent years, principally from Mediterranean collision zones that have been subjected to PT conditions along very low geothermal gradients (∼ 7°C/km) and have reached pressures up to 30 kbar. MgAl-rich metapelites develop particularly diagnostic high-pressure minerals and mineral assemblages that have been and are being studied experimentally in model systems involving the components K2O, MgO, Al2O3, TiO2, SiO2, P2O5, and H2O up to pressures of 50 kbar and temperatures of 1000°C.In the present review the following synthetic phases and phase assemblages are discussed, emphasizing their water-pressure-temperature stability fields (approximated in parentheses here), their reaction relationships, and their known or potential occurrences in metamorphic rocks. Sudoite (0 to ∼ 12 kbar, 150? to 380°C) occurs in very low-grade metapelites. Mg-carpholite (∼ 7 to ∼ 45 kbar, ∼ 200 to 600°C) is found in subducted metabauxites, metapelites, and related quartz veins. Mg-chloritoid (18 to 45 kbar?; 400 to 760°C) has not been found in nature as pure or nearly pure end-member; it requires silica-deficient environments. Yoderite, known in nature only from a single talc-kyanite schist occurrence, has only a small stability field (9 to 18 kbar?, 700 to 870°C?), cannot coexist with quartz, but may be stabilized by Fe3+. Pyrope (∼ 15 to at least 50 kbar, ∼ 700°C to melting), with or without relic coesite inclusions, occurs spectacularly in quartzites. Mg-staurolite (∼ 14 to some 90 kbar?, 700 to 1000°C), recently discovered as inclusions in pyrope, requires silica-deficiency. MgMgAl-pumpellyite is a new synthetic phase in which Mg totally replaces Ca of normal pumpellyite; because of its very high-pressure, low-temperature stability (∼ 37 to at least 55 kbar, < 400 to 780°C) it may not form within our globe. Ellenbergerite, the new high-pressure mineral forming inclusions in pyrope, apparently exhibits a rather composition-dependent stability with Ti-ellenbergerite, requiring higher pressures (> 20 kbar) than P-bearing, Ti-free members; a pure hydrous Mg-phosphate with ellenbergerite structure was synthesized at 10 kbar. Phengites, the widespread MgSi-substituted muscovites, require increasingly high water pressures (up to ∼ 20 kbar) for higher degrees of substitution, but the Al-celadonite end-member is not stable under any conditions; the compositions of phengites coexisting with limiting assemblages such as phlogopite, K-feldspar, and an SiO2 phase are useful geobarometers. The common assemblage Mg-chlorite + Al2SiO5 (mainly kyanite) has an extensive stability field ranging from near zero to 31 kbar at temperatures varying from some 320 to ∼ 760°C depending on pressure. The whiteschist assemblage talc + kyanite (6 to ∼ 45 kbar, 550 to 810°C) plays an important role in collision zone metamorphism as it forms from the greenschist assemblage chlorite + quartz at low grades but is also known to break down into pyrope + coesite at the highest grade observed thus far. The assemblage talc-phengite (11 to at least 35 kbar, 300? to 820°C depending on pressure), on the other hand, is well known from subducted metapelites. At pressures of 15–20 kbar and temperatures of 400–650°C a very K,Mg-rich, siliceous fluid forms as a consequence of the mutual reaction of the minerals K-feldspar and phlogopite (biotite) which are very common in crustal rocks including granites. Such fluids are bound to cause metasomatism in neighbouring mantle rocks which, upon subsequent increase of temperature, produce post-collisional ultrapotassic, lamproitic melts.
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Whitney, D. L., M. Hirschmann, and M. G. Miller. "Zincian ilmenite-ecandrewsite from a pelitic schist, Death Valley, California, and the paragenesis of (Zn,Fe)TiO 3 solid solution in metamorphic rocks." Canadian Mineralogist 31, no. 2 (June 1, 1993): 425–36. http://dx.doi.org/10.3749/1499-1276-31.2.425.
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Mokhtar, T. A., R. B. Herrmann, and D. R. Russell. "Seismic velocity and Q model for the shallow structure of the Arabian shield from short‐period Rayleigh waves." GEOPHYSICS 53, no. 11 (November 1988): 1379–87. http://dx.doi.org/10.1190/1.1442417.
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The shear velocity and [Formula: see text] structure for the upper 1 km in different tectonic regions of the Arabian shield have been investigated using high‐frequency vertical component records of Rayleigh waves (1–20 Hz), which were recorded at source‐to‐receiver separations 55–80 km during a deep seismic refraction survey. Group and phase velocities of the fundamental and first higher modes were inverted for the shear‐wave velocity structure; Rayleigh‐wave attenuation coefficients were determined from the decay of the amplitude spectrum of the fundamental mode and used to invert for the [Formula: see text] structure. Models derived from the data were tested by calculating synthetic seismograms for the fundamental and the first higher modes from surface‐wave theory with a center of compression used to represent the source; both band‐pass filtered step and Dirac delta source time functions were tested. Modeling indicates that the shear‐wave velocity of the shield increases from 2.6 km/s to 3.4 km/s in the upper 400 m of the crust. [Formula: see text] increases from 30 in the upper 50 m to 150 at 500 m depth. The underlying material has a [Formula: see text] of 400–500 for the out‐cropping igneous rocks such as granite and may reach values higher than 700 for the metamorphic green schist rock. A band‐pass filtered Dirac delta source time function produces the synthetic that is the best fit with observations.
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Diener, Johann F. A., Åke Fagereng, and Sukey A. J. Thomas. "Mid-crustal shear zone development under retrograde conditions: pressure–temperature–fluid constraints from the Kuckaus Mylonite Zone, Namibia." Solid Earth 7, no. 5 (September 16, 2016): 1331–47. http://dx.doi.org/10.5194/se-7-1331-2016.
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Abstract. The Kuckaus Mylonite Zone (KMZ) forms part of the larger Marshall Rocks–Pofadder shear zone system, a 550 km-long, crustal-scale strike-slip shear zone system that is localized in high-grade granitoid gneisses and migmatites of the Namaqua Metamorphic Complex. Shearing along the KMZ occurred ca. 40 Ma after peak granulite-facies metamorphism during a discrete tectonic event and affected the granulites that had remained at depth since peak metamorphism. Isolated lenses of metamafic rocks within the shear zone allow the P–T–fluid conditions under which shearing occurred to be quantified. These lenses consist of an unsheared core that preserves relict granulite-facies textures and is mantled by a schistose collar and mylonitic envelope that formed during shearing. All three metamafic textural varieties contain the same amphibolite-facies mineral assemblage, from which calculated pseudosections constrain the P–T conditions of deformation at 2.7–4.2 kbar and 450–480 °C, indicating that deformation occurred at mid-crustal depths through predominantly viscous flow. Calculated T–MH2O diagrams show that the mineral assemblages were fluid saturated and that lithologies within the KMZ must have been rehydrated from an external source and retrogressed during shearing. Given that the KMZ is localized in strongly dehydrated granulites, the fluid must have been derived from an external source, with fluid flow allowed by local dilation and increased permeability within the shear zone. The absence of pervasive hydrothermal fractures or precipitates indicates that, even though the KMZ was fluid bearing, the fluid/rock ratio and fluid pressure remained low. In addition, the fluid could not have contributed to shear zone initiation, as an existing zone of enhanced permeability is required for fluid infiltration. We propose that, following initiation, fluid infiltration caused a positive feedback that allowed weakening and continued strain localization. Therefore, the main contribution of the fluid was to produce retrograde mineral phases and facilitate grain-size reduction. Features such as tectonic tremor, which are observed on active faults under similar conditions as described here, may not require high fluid pressure, but could be explained by reaction weakening under hydrostatic fluid pressure conditions.
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Imrecke, Daniel B., Alexander C. Robinson, Lewis A. Owen, Jie Chen, Lindsay M. Schoenbohm, Kathryn A. Hedrick, Thomas J. Lapen, Wenqiao Li, and Zhaode Yuan. "Mesozoic evolution of the eastern Pamir." Lithosphere 11, no. 4 (May 16, 2019): 560–80. http://dx.doi.org/10.1130/l1017.1.
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Abstract We present field and analytical results from the Tashkurgan and Waqia valleys in the southeastern Pamir that shed new light on the tectonic evolution and terrane architecture of the region. Field mapping of metasedimentary and igneous units along the Tashkurgan and Waqia valleys in the Southeast Pamir, integrated with metamorphic petrology, garnet-biotite thermometry, and zircon U/Pb isotopic analysis, help identify major structures and terrane boundaries in the region, as well as compare structural units across the Miocene Muztaghata gneiss dome. South of the Muztaghata dome, the gently northwest-plunging synformal Torbashi thrust klippe juxtaposes amphibolite facies Triassic Karakul-Mazar terrane schist and gneiss structurally above (1) greenschist facies Triassic Karakul-Mazar terrane metasedimentary rock in the north, and (2) lower-amphibolite facies schist in the south that are interpreted to be Gondwanan-derived crust (Central or South Pamir terrane). Farther south, the Rouluke thrust fault imbricates the Gondwanan crust, placing early Paleozoic schists over Permian marble and slate. Exposure of the Torbashi thrust sheet terminates in the southeast, and with it the surface exposure of the Triassic Karakul-Mazar terrane, leaving the Paleozoic Kunlun terrane juxtaposed directly against Gondwanan terrane crust. Based on lithologic and isotopic similarities of units north and south of the Muztaghata gneiss dome, we document the existence of a regionally extensive thrust nappe that stretched across the northern and eastern Pamir, prior to being cut by Miocene exhumation of the Muztaghata dome. The thrust nappe links the Torbashi thrust in the southeast Pamir with the Tanymas thrust in the northern Pamir, and documents regionally extensive exposure of lithologically continuous units across the northeast Pamir. While timing of emplacement of the Torbashi thrust klippe and displacement on the Rouluke fault to the south is not well constrained, we interpret shortening to be Cretaceous in age based on previously published cooling ages. However, a component of Cenozoic shortening cannot be ruled out. A key observation from our mapping results is that the surface exposures of the Karakul–Mazar–Songpan Ganzi terrane are not continuous between western Tibet and the Pamir, which indicates tectonic and/or erosional removal, likely sometime in the Mesozoic. Furthermore, our documentation of the Jinsha suture in the southeast Pamir on the eastern side of the Karakoram fault shows deflections of terranes across the Himalayan-Tibetan orogen were not primarily accommodated along discrete, large displacement faults (>400 km) faults. Instead, oroclinal bending of the northern Pamir, and dextral shear along the Pamir margins, may be largely responsible for the northward deflection of terranes.
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Carter, Matthew J., and Sharon Mosher. "Alleghanian deformation of Cambrian metasedimentary rocks on Avalonia in south-central Rhode Island, USA." Atlantic Geology 49 (June 16, 2013): 70. http://dx.doi.org/10.4138/atlgeol.2013.003.
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Lower greenschist-facies metasedimentary rocks of the Middle Cambrian Conanicut Group occur in and around Beavertail State Park, Rhode Island. Detailed structural mapping (1:1000-scale) and petrology of these rocks indicate an early fold generation (F1) and axial planar metamorphic foliation (S1). F1 is folded by a more prominent, E-verging, NNE- to NNW-trending, non-coaxial fold generation (F2) and an associated pressure solution-enhanced crenulation cleavage (S2). A third map-scale fold generation is inferred from NNE-trending broad folding of F2 and S2. N-S extension resulted in boudins that deformed S2 on a scale of 1–10 m, whereas late planar quartz veins indicate NW-SE extension. All structures are cross cut by faults striking N- to NE- and ENE-to ESE that show dominantly normal motion with minor sinistral or dextral components. Kink bands associated with faulting trend NNE to ENE with WNW to NNW side up. The vertical Beaverhead shear zone juxtaposes the Cambrian rocks with Pennsylvanian rocks of the Narragansett Basin, and deflects S2 in a dextral sense, consistent with motion recorded elsewhere.The Cambrian rocks record the same deformation and metamorphism as the adjacent Narragansett Basin rocks. No evidence was found for pre-Alleghanian deformation or for northwest- or north-directed thrusting and accretion of a Meguma-like terrane during the Alleghanian orogeny. If the Beaverhead shear zone was a preexisting terrane boundary within Avalonia, both the Cambrian and Pennsylvanian Narragansett Basin sediments were deposited aſter terrane accretion.RÉSUMÉDes roches profondes métasédimentaires du faciès des schistes verts, que l’on retrouve dans le groupe Conanicut du Cambrien moyen, sont présentes dans le Beavertail State Park, au Rhode Island, et dans les environs. Une cartographie structurale détaillée (à l’échelle 1:1 000) et la pétrologie de ces roches indiquent la formation précoce d’un pli (F1) et une foliation métamorphique (S1) de plan axial. Le F1 est causé par la formation d’un pli (F2) non coaxial plus dominant, à vergence est et d’orientation NNE-NNO ainsi que par une schistosité de crénulation (S2) amplifiée en raison d’une dissolution par pression connexe. La formation d’un troisième pli à l’échelle cartographique est provoquée par un vaste plissement du F2 et de la S2 d’orientation NNE. Une extension N-S a produit des boudins qui déforment la S2 sur l’échelle de 1 à 10 m, tandis que des veines de quartz planes formées ultérieurement indiquent une extension NO-SE. Toutes les structures sont traversées par des failles orientées N-NE et ENE-ESE montrant un mouvement normal dominant accompagné de composantes senestres et dextres peu importantes. Les bandes froissées associées à ces failles sont orientées NNE-ENE et présentent une tangente verticale ONO-NNO. Dans la zone de cisaillement verticale de Beaverhead, les roches du Cambrien sont juxtaposées aux roches de la Pennsylvanie du bassin Narragansett, et la S2 dévie en un mouvement dextre, ce qui concorde avec le mouvement enregistré ailleurs.Les roches du Cambrien montrent la même déformation et le même métamorphisme que les roches du bassin Narragansett adjacent. On n’a trouvé aucune donnée appuyant la création d’une déformation avant l’orogenèse alléghanienne ni celle d’un chevauchement et d’une accrétion orientés vers le nord ou le nordouest d’un terrane semblable à la zone de Meguma lors de l’orogenèse alléghanienne. Si la zone de cisaillement verticale de Beaverhead constituait une limite de terrane qui existait avant l’orogenèse de l’Avalonien, les sédiments cambriens et pennsylvaniens du bassin Narragansett se sont déposés après l’accrétion du terrane.[Traduit par la redaction]
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Geiger, Charles A., and George R. Rossman. "Micro- and nano-size hydrogarnet clusters in calcium silicate garnet: Part II. Mineralogical, petrological, and geochemical aspects." American Mineralogist 105, no. 4 (April 1, 2020): 468–78. http://dx.doi.org/10.2138/am-2020-7257.
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Abstract The nominally anhydrous, calcium-silicate garnets, grossular (Ca3Al2Si3O12), andradite (Ca3Fe23+Si3O12), schorlomite (Ca3Ti24+[Si,Fe23+]O12), and their solid solutions can incorporate structural OH-, often termed “water.” The IR single-crystal spectra of several calcium silicate garnets were recorded between 3000 and 4000 cm–1. Spectroscopic results are also taken from the literature. All spectra show various OH- stretching modes between 3500 and 3700 cm–1 and they are analyzed. Following the conclusions of Part I of this study, the garnets appear to contain local microscopic- and nano-size Ca3Al2H12O12- and Ca3Fe23+H12O12-like domains and/or clusters dispersed throughout an anhydrous “matrix.” The substitution mechanism is the hydrogarnet one, where (H4O4)4– ↔ (SiO4)4–, and various local configurations containing different numbers of (H4O4)4– groups define the cluster type. A single (H4O4) group is roughly 3 Å across and most (H4O4)-clusters are between this and 15 Å in size. This model can explain the IR spectra and also other experimental results. Various hypothetical “defect” and cation substitutional mechanisms are not needed to account for OH- incorporation and behavior in garnet. New understanding at the atomic level into published dehydration and H-species diffusion results, as well as H2O-concentration and IR absorption-coefficient determinations, is now possible for the first time. End-member synthetic and natural grossular crystals can show similar OH- “band patterns,” as can different natural garnets, indicating that chemical equilibrium could have operated during their crystallization. Under this assumption, the hydrogarnet-cluster types and their concentrations can potentially be used to decipher petrologic (i.e., P-T-X) conditions under which a garnet crystal, and the rock in which it occurs, formed. Schorlomites from phonolites contain no or very minor amounts of H2O (0.0 to 0.02 wt%), whereas Ti-bearing andradites from chlorite schists can contain more H2O (∼0.3 wt%). Different hydrogarnet clusters and concentrations can occur in metamorphic grossulars from Asbestos, Quebec, Canada. IR absorption coefficients for H2O held in hydrogrossularand hydroandradite-like clusters should be different in magnitude and this work lays out how they can be best determined. Hydrogen diffusion behavior in garnet crystals at high temperatures is primarily governed by the thermal stability of the different local hydrogarnet clusters at 1 atm.
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Narantsetseg, Tserendash, Yuan Chao, Wang Tao, Ren Zhongyuan, Li Pengfei, Zhang Le, Guo Lei, et al. "Metamorphic rocks from the north-eastern part of the Ereendavaa terrane (Eastern Mongolia) :." Mongolian Geoscientist 26, no. 52 (June 23, 2021): 16–45. http://dx.doi.org/10.5564/mgs.v26i52.1079.
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In this paper, we have conducted geochronological and geochemical studies on the metamorphic rocks of the Khaychingol and Ereendavaa Formations in the Mogoitiin Gol, Khaychin Gol and Emgentiin Bulag areas from the Ereendavaa terrane and these rocks have been considered to be Precambrian in age. However, new LA–ICP–MS zircon U–Pb dating results indicate that the protolith of the studied metamorphic rocks was formed in two stages: 1) during ~ 296 - 285 Ma, the protolith of mafic, felsic and black schists formed; 2) during ~276 - 271 Ma, the protolith of gneiss and psammitic schists began to deposit. The Early Permian bimodal association composed of low-K basalt and comagmatic high-Na, low-K dacite with high-K calc-alkaline rhyolite, represent protolith of the mafic and felsic schists which were formed in back-arc basin environment. The Middle Permian gneiss, and psammitic schists with sedimentary protolith have geochemical signatures of island arc rocks, such as enrichment of LILE relative to HFSE, and markedly negative Nb, Ta and Ti anomalies, suggesting that they were formed in a continental arc environment. Considering a close spatial relationship of the Ereendavaa terrane with the Mongol-Okhotsk Belt in the north-west, we propose that accompanied with the emplacement of arc magmatic rocks, the arc rifting occurred and formed the Early Permian bimodal volcanic rocks. In the Late Permian, after the formation of the back-arc basin, deposition of the immature deposits as wacke, arkose and litharenite dominated sediments in a continental arc environment started.
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Vďačný, Marek, and Peter Bačík. "Provenance of the Permian Malužiná Formation sandstones (Malé Karpaty Mountains, Western Carpathians): evidence of garnet and tourmaline mineral chemistry." Geologica Carpathica 66, no. 2 (April 1, 2015): 83–97. http://dx.doi.org/10.1515/geoca-2015-0012.
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Abstract The chemistry of detrital garnets (almandine; spessartine-, grossular-, and pyrope-rich almandine; andradite) and mostly dravitic tourmalines from three sandstone samples of the Permian Malužiná Formation in the northern part of the Malé Karpaty Mts (Western Carpathians, SW Slovakia) reveals a great variability of potential source rocks. They comprise (1) low-grade regionally metamorphosed rocks (metacherts, blue schists, metapelites and metapsammites), (2) contact-thermal metamorphic calcareous rocks (skarns or rodingites), (3) garnet-bearing mica schists and gneisses resulting from the regional metamorphism of argillaceous sediments, (4) amphibolites and metabasic sub-ophiolitic rocks, (5) granulites, (6) Li-poor granites and their associated pegmatites and aplites as well as (7) rhyolites. Consequently, the post-Variscan, rift-related sedimentary basin of the Malužiná Formation originated in the vicinity of a low- to high-grade crystalline basement with granitic rocks. Such lithological types of metamorphic and magmatic rocks are characteristic for the Variscan terranes of the Central Western Carpathians (Tatricum and Veporicum Superunits).
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Dixon, H. Roberta. "Petrology of metamorphic rocks." Chemical Geology 49, no. 4 (June 1985): 459–60. http://dx.doi.org/10.1016/0009-2541(85)90010-5.
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Erokhin, Yuriy V., Kirill S. Ivanov, Anatoliy V. Zakharov, and Vera V. Khiller. "Accessory and Ore Mineralization of Schists from the Basement of the Yamal Peninsula (Zapadno-Yarotinsky Area, Western Siberia)." UNIVERSITY NEWS. NORTH-CAUCASIAN REGION. NATURAL SCIENCES SERIES, no. 2 (210) (June 28, 2021): 49–55. http://dx.doi.org/10.18522/1026-2237-2021-2-49-55.
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The results of studying the mineralogy of metamorphic schists from the Pre-Jurassic base of the Arctic part of the West Siberian plate are presented. The accessory and ore mineralization of schists from the Zapadno-Yarotinsky license area located in the southern part of the Yamal Peninsula is studied. The schists was uncovered by the Zapadno-Yarotinskaya No. 300 well at a depth of 2762 m. Above the section, the metamorphic rocks are overlain by a young Meso-Cenozoic cover. The schists are mainly composed of quartz, plagioclase (albite), carbonates (dolomite and siderite), mica (muscovite) and chlorite (donbassite). The discovered accessory and ore minerals in the metamorphic schists of the Zapadno-Yarotinsky area can be divided into two groups. The first group includes minerals that were formed during the metamorphism of schists, or were preserved as detrital matter. These minerals include zircon, fluorapatite, and rutile as the most stable compounds. The remaining mineralization (pyrite, sphalerite, chalcopyrite, cubanite, galena, cobaltite, barite, xenotime-(Y), goyazite, synchysite-(Nd), native silver and copper) is clearly secondary and was formed as a result of superimposed metasomatic processes. Judging from the described mineralogy, the schists underwent changes as a result of superimposed propyllitization. The temperature range of this process is determined by the formation of cubanite in association with chalcopyrite at a temperature of 200-210 оС.
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Barnes, Jaime D., Sarah C. Penniston-Dorland, Gray E. Bebout, William Hoover, Grace M. Beaudoin, and Philippe Agard. "Chlorine and lithium behavior in metasedimentary rocks during prograde metamorphism: A comparative study of exhumed subduction complexes (Catalina Schist and Schistes Lustrés)." Lithos 336-337 (July 2019): 40–53. http://dx.doi.org/10.1016/j.lithos.2019.03.028.
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Miranda, Daniel Cândido, and Norberto Olmiro Horn Filho. "geossítio monólito bico do papagaio, município de Itajaí, SC, Brasil." Terrae Didatica 16 (September 25, 2020): e020038. http://dx.doi.org/10.20396/td.v16i0.8660450.
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The geosite Monolith Bico do Papagaio (MBP) is a geomonument of great scenic beauty, whose outcrop, of approximately 65 m2 area, resembles the “head or beak of a parrot”. The rare and prominent geological “piece” stimulates tourist activity at the Itajaí municipality. This paper describes the petrology and analyses the vulnerability to human depredation. The monolith is composed by gray to silvery schist, belonging to the Neoproterozoic Brusque Metamorphic Complex. The main rock minerals are muscovite, chlorite, quartz, andalusite and zircon, with lepidoblastic, granoblastic and subordinate porphyroblastic textures. For studying the vulnerability and valuation of the geosite, it was used the methodology proposed by Dr. José Brilha in 2005 which is based on three important aspects, namely: (A) intrinsic value; (B) potential use; (C) need of geosite protection. The focus is to quantify intrinsic values, to guarantee sustainability and promote geoconservation of the geosite, which has high geotouristic potential.
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SAKI, ADEL, MOHSSEN MOAZZEN, and ROLAND OBERHÄNSLI. "Mineral chemistry and thermobarometry of the staurolite-chloritoid schists from Poshtuk, NW Iran." Geological Magazine 149, no. 6 (May 17, 2012): 1077–88. http://dx.doi.org/10.1017/s0016756812000209.
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AbstractThe Poshtuk metapelitic rocks in northwestern Iran underwent two main phases of regional and contact metamorphism. Microstructures, textural features and field relations indicate that these rocks underwent a polymetamorphic history. The dominant metamorphic assemblage of the metapelites is garnet, staurolite, chloritoid, chlorite, muscovite and quartz, which grew mainly syntectonically during the later contact metamorphic event. Peak metamorphic conditions of this event took place at 580 °C and ~3–4 kbar, indicating that this event occurred under high-temperature and low-pressure conditions (HT/LP metamorphism), which reflects the high heat flow in this part of the crust. This event is mainly controlled by advective heat input through magmatic intrusions into all levels of the crust. These extensive Eocene metamorphic and magmatic activities can be associated with the early Alpine Orogeny, which resulted in this area from the convergence between the Arabian and Eurasian plates, and the Cenozoic closure of the Tethys oceanic tract(s).