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1

Liu, Wen, Hong Li, Jing-Ying Xie, and Zheng-Wen Fu. "Rechargeable Room-Temperature CFx-Sodium Battery." ACS Applied Materials & Interfaces 6, no. 4 (2014): 2209–12. http://dx.doi.org/10.1021/am4051348.

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2

Park, Cheol-Wan, Jou-Hyeon Ahn, Ho-Suk Ryu, Ki-Won Kim, and Hyo-Jun Ahn. "Room-Temperature Solid-State Sodium∕Sulfur Battery." Electrochemical and Solid-State Letters 9, no. 3 (2006): A123. http://dx.doi.org/10.1149/1.2164607.

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3

Hartmann, Pascal, Conrad L. Bender, Miloš Vračar, et al. "A rechargeable room-temperature sodium superoxide (NaO2) battery." Nature Materials 12, no. 3 (2012): 228–32. http://dx.doi.org/10.1038/nmat3486.

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4

Xin, Sen, Ya-Xia Yin, Yu-Guo Guo, and Li-Jun Wan. "A High-Energy Room-Temperature Sodium-Sulfur Battery." Advanced Materials 26, no. 8 (2013): 1261–65. http://dx.doi.org/10.1002/adma.201304126.

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5

McCormick, Colin. "Energy Focus: Rechargeable room-temperature sodium-air battery involves sodium superoxide." MRS Bulletin 38, no. 2 (2013): 119. http://dx.doi.org/10.1557/mrs.2013.30.

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6

Kim, T. B., J. W. Choi, H. S. Ryu, et al. "Electrochemical properties of sodium/pyrite battery at room temperature." Journal of Power Sources 174, no. 2 (2007): 1275–78. http://dx.doi.org/10.1016/j.jpowsour.2007.06.093.

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7

Feng, Jinkui, Zhen Zhang, Lifei Li, Jian Yang, Shenglin Xiong, and Yitai Qian. "Ether-based nonflammable electrolyte for room temperature sodium battery." Journal of Power Sources 284 (June 2015): 222–26. http://dx.doi.org/10.1016/j.jpowsour.2015.03.038.

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8

Brutti, S., M. A. Navarra, G. Maresca, et al. "Ionic liquid electrolytes for room temperature sodium battery systems." Electrochimica Acta 306 (May 2019): 317–26. http://dx.doi.org/10.1016/j.electacta.2019.03.139.

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9

Wang, Yanjie, Yingjie Zhang, Hongyu Cheng, et al. "Research Progress toward Room Temperature Sodium Sulfur Batteries: A Review." Molecules 26, no. 6 (2021): 1535. http://dx.doi.org/10.3390/molecules26061535.

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Lithium metal batteries have achieved large-scale application, but still have limitations such as poor safety performance and high cost, and limited lithium resources limit the production of lithium batteries. The construction of these devices is also hampered by limited lithium supplies. Therefore, it is particularly important to find alternative metals for lithium replacement. Sodium has the properties of rich in content, low cost and ability to provide high voltage, which makes it an ideal substitute for lithium. Sulfur-based materials have attributes of high energy density, high theoretica
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10

Kim, Icpyo, Chang Hyeon Kim, Sun hwa Choi, et al. "A singular flexible cathode for room temperature sodium/sulfur battery." Journal of Power Sources 307 (March 2016): 31–37. http://dx.doi.org/10.1016/j.jpowsour.2015.12.035.

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11

Xia, Chuan, Fan Zhang, Hanfeng Liang, and Husam N. Alshareef. "Layered SnS sodium ion battery anodes synthesized near room temperature." Nano Research 10, no. 12 (2017): 4368–77. http://dx.doi.org/10.1007/s12274-017-1722-0.

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12

Xiao, Xiang, Wei Li, and Jianbing Jiang. "Sulfur-Biological Carbon for Long-Life Room-Temperature Sodium-Sulfur Battery." Journal of Biobased Materials and Bioenergy 14, no. 4 (2020): 487–91. http://dx.doi.org/10.1166/jbmb.2020.1982.

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Room-temperature sodium-sulfur (RT-Na/S) batteries are gaining much attention particularly in large-scale energy storage due to high theoretical energy density and low cost. However, low conductivity and volume expansion of sulfur, as well as severe shuttle effect of soluble sodium polysulfides largely hamper their practical applications. Herein, we report an architecture of sulfur embedded in biological carbon (SBC) as cathode for RT-Na/S batteries. The SBC with N, P co-doping biological carbon and hierarchically porous structure afford fast electron and ion transportation, as well as good me
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13

Wang, Nana, Yunxiao Wang, Zhongchao Bai, et al. "High-performance room-temperature sodium–sulfur battery enabled by electrocatalytic sodium polysulfides full conversion." Energy & Environmental Science 13, no. 2 (2020): 562–70. http://dx.doi.org/10.1039/c9ee03251g.

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Developing novel gold nanoclusters as an electrocatalyst can facilitate a completely reversible reaction between S and Na, achieving advanced high-energy-density room-temperature sodium–sulfur batteries.
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14

Adelhelm, Philipp, Pascal Hartmann, Conrad L. Bender, Martin Busche, Christine Eufinger, and Juergen Janek. "From lithium to sodium: cell chemistry of room temperature sodium–air and sodium–sulfur batteries." Beilstein Journal of Nanotechnology 6 (April 23, 2015): 1016–55. http://dx.doi.org/10.3762/bjnano.6.105.

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Research devoted to room temperature lithium–sulfur (Li/S8) and lithium–oxygen (Li/O2) batteries has significantly increased over the past ten years. The race to develop such cell systems is mainly motivated by the very high theoretical energy density and the abundance of sulfur and oxygen. The cell chemistry, however, is complex, and progress toward practical device development remains hampered by some fundamental key issues, which are currently being tackled by numerous approaches. Quite surprisingly, not much is known about the analogous sodium-based battery systems, although the already co
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15

Han, Man Huon, Elena Gonzalo, Gurpreet Singh, and Teófilo Rojo. "A comprehensive review of sodium layered oxides: powerful cathodes for Na-ion batteries." Energy & Environmental Science 8, no. 1 (2015): 81–102. http://dx.doi.org/10.1039/c4ee03192j.

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16

Rao, R. Prasada, Xin Zhang, Kia Chai Phuah, and Stefan Adams. "Mechanochemical synthesis of fast sodium ion conductor Na11Sn2PSe12 enables first sodium–selenium all-solid-state battery." Journal of Materials Chemistry A 7, no. 36 (2019): 20790–98. http://dx.doi.org/10.1039/c9ta06279c.

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Fast-ion conducting Na<sub>11</sub>Sn<sub>2</sub>PS<sub>12</sub> prepared by ball-milling allowed us to realize the first all-solid-state Na–Se battery, which can reach 500 charge–discharge cycles at room temperature.
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17

Wang, Chueh-Han, Cheng-Hsien Yang, and Jeng-Kuei Chang. "Suitability of ionic liquid electrolytes for room-temperature sodium-ion battery applications." Chemical Communications 52, no. 72 (2016): 10890–93. http://dx.doi.org/10.1039/c6cc04625h.

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18

Zhou, Jiahui, Yue Yang, Yingchao Zhang, et al. "Sulfur in Amorphous Silica for an Advanced Room‐Temperature Sodium–Sulfur Battery." Angewandte Chemie International Edition 60, no. 18 (2021): 10129–36. http://dx.doi.org/10.1002/anie.202015932.

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19

Zhou, Jiahui, Yue Yang, Yingchao Zhang, et al. "Sulfur in Amorphous Silica for an Advanced Room‐Temperature Sodium–Sulfur Battery." Angewandte Chemie 133, no. 18 (2021): 10217–24. http://dx.doi.org/10.1002/ange.202015932.

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20

Oh, Jin An Sam, Yumei Wang, Qibin Zeng, et al. "Intrinsic low sodium/NASICON interfacial resistance paving the way for room temperature sodium-metal battery." Journal of Colloid and Interface Science 601 (November 2021): 418–26. http://dx.doi.org/10.1016/j.jcis.2021.05.123.

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21

Liu, Xizheng, Xi Wang, Akira Iyo, Haijun Yu, De Li, and Haoshen Zhou. "High stable post-spinel NaMn2O4 cathode of sodium ion battery." J. Mater. Chem. A 2, no. 36 (2014): 14822–26. http://dx.doi.org/10.1039/c4ta03349c.

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A CaFe<sub>2</sub>O<sub>4</sub>-type NaMn<sub>2</sub>O<sub>4</sub> has been synthesized at a pressure of 4.5 Gpa, as the cathode of SIBs. It exhibits a smooth voltage profile, limited polarization and good capacity retention both at room temperature and at a higher temperature. The stable battery performance is due to the high barrier of structure rearrangement and suppressed Jahn–Teller distortions in this post-spinel structure.
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22

Carter, Rachel, Landon Oakes, Anna Douglas, Nitin Muralidharan, Adam P. Cohn, and Cary L. Pint. "A Sugar-Derived Room-Temperature Sodium Sulfur Battery with Long Term Cycling Stability." Nano Letters 17, no. 3 (2017): 1863–69. http://dx.doi.org/10.1021/acs.nanolett.6b05172.

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23

Xin, Sen, Ya-Xia Yin, Yu-Guo Guo, and Li-Jun Wan. "Batteries: A High-Energy Room-Temperature Sodium-Sulfur Battery (Adv. Mater. 8/2014)." Advanced Materials 26, no. 8 (2014): 1308. http://dx.doi.org/10.1002/adma.201470053.

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24

Gaddam, Rohit Ranganathan, Amir H. Farokh Niaei, Marlies Hankel, Debra J. Searles, Nanjundan Ashok Kumar, and X. S. Zhao. "Capacitance-enhanced sodium-ion storage in nitrogen-rich hard carbon." J. Mater. Chem. A 5, no. 42 (2017): 22186–92. http://dx.doi.org/10.1039/c7ta06754b.

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Nitrogen-rich hard carbon with enhanced capacitive storage for room temperature sodium-ion battery is investigated. The presence of nitrogen allows stronger sodium ion interaction to realize high-performance batteries with a specific capacity of ∼204 mA h g<sup>−1</sup> after 1000 cycles at 1 A g<sup>−1</sup> current density.
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25

Zhao, Hongyang, Jianwei Wang, Yuheng Zheng, et al. "Organic Thiocarboxylate Electrodes for a Room-Temperature Sodium-Ion Battery Delivering an Ultrahigh Capacity." Angewandte Chemie International Edition 56, no. 48 (2017): 15334–38. http://dx.doi.org/10.1002/anie.201708960.

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26

Yang, Tingting, Bingshu Guo, Wenyan Du, et al. "Design and Construction of Sodium Polysulfides Defense System for Room‐Temperature Na–S Battery." Advanced Science 6, no. 23 (2019): 1901557. http://dx.doi.org/10.1002/advs.201901557.

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27

Zhao, Hongyang, Jianwei Wang, Yuheng Zheng, et al. "Organic Thiocarboxylate Electrodes for a Room-Temperature Sodium-Ion Battery Delivering an Ultrahigh Capacity." Angewandte Chemie 129, no. 48 (2017): 15536–40. http://dx.doi.org/10.1002/ange.201708960.

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28

Kim, Tae-Bum, Cheol Wan Park, Ho Suk Ryu, and Hyo Jun Ahn. "Ionic Conductivity of Sodium Ion with NaCF3SO3 Salts in Electrolyte for Sodium Batteries." Materials Science Forum 486-487 (June 2005): 638–41. http://dx.doi.org/10.4028/www.scientific.net/msf.486-487.638.

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To find out the proper sodium ion conducting electrolyte at room temperature, we investigated the ac impedance measurement of PVdF gel polymer electrolyte and liquid tetraglyme(TEGDME) with various concentrations of sodium trifluoromethane sulfonate(NaCF3SO3). The concentration of NaCF3SO3 did not severely affect the ionic conductivity. The sodium ionic conductivity using TEGDME with NaCF3SO3 was about 3.3×10-4 S㎝-1 which was lower than that of the PVdF gel polymer electrolyte, 5.0×10-4 S㎝-1. From the viewpoint of ionic conductivity, PVdF gel polymer electrolyte was proper electrolyte for sodi
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29

Li, Shuping, Ziqi Zeng, Jiaqiang Yang, et al. "High Performance Room Temperature Sodium–Sulfur Battery by Eutectic Acceleration in Tellurium-Doped Sulfurized Polyacrylonitrile." ACS Applied Energy Materials 2, no. 4 (2019): 2956–64. http://dx.doi.org/10.1021/acsaem.9b00343.

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30

Liu, Yihang, Qingzhou Liu, Anyi Zhang, et al. "Room-Temperature Pressure Synthesis of Layered Black Phosphorus–Graphene Composite for Sodium-Ion Battery Anodes." ACS Nano 12, no. 8 (2018): 8323–29. http://dx.doi.org/10.1021/acsnano.8b03615.

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31

Kim, Icpyo, Jin-Young Park, ChangHyeon Kim, et al. "Sodium Polysulfides during Charge/Discharge of the Room-Temperature Na/S Battery Using TEGDME Electrolyte." Journal of The Electrochemical Society 163, no. 5 (2016): A611—A616. http://dx.doi.org/10.1149/2.0201605jes.

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32

Bellusci, Mariangela, Elisabetta Simonetti, Massimo De Francesco, and Giovanni Battista Appetecchi. "Ionic Liquid Electrolytes for Safer and More Reliable Sodium Battery Systems." Applied Sciences 10, no. 18 (2020): 6323. http://dx.doi.org/10.3390/app10186323.

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Na+-conducting, binary electrolytic mixtures, based on 1-ethyl-3-methyl-imidazolium, trimethyl-butyl-ammonium, and N-alkyl-N-methyl-piperidinium ionic liquid (IL) families, were designed and investigated. The anions were selected among the per(fluoroalkylsulfonyl)imide families. Sodium bis(trifluoromethylsulfonyl)imide, NaTFSI, was selected as the salt. The NaTFSI-IL electrolytes, addressed to safer sodium battery systems, were studied and compared in terms of ionic conductivity and thermal stability as a function of the temperature, the nature of the anion and the cation aliphatic side chain
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33

Yang, Ming Shan, Jian Wei Liu, Jin Yu, Xu Zhang, Jing Wei, and Lin Kai Li. "The Synthesis and Properties of a Novel Solid Polyphosphazene Electrolyte for Lithium Ion Battery." Advanced Materials Research 148-149 (October 2010): 749–52. http://dx.doi.org/10.4028/www.scientific.net/amr.148-149.749.

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Polydichlorophosphazene was synthesized from hexachlorocyclotriphosphazene by high-temperature ring-opening polymerization, and poly(2-(2-methoxyethoxy) ethanol phosphazene)(MEEP) was synthesized by reacting polydichlorophosphazene with alcohol sodium. The optimal synthesis parameters were obtained and the structure of MEEP was analyzed by NMR. Then polyphosphazene electrolyte was prepared by mixing MEEP with LiCF3SO3. The results indicated that the electrolyte prepared in this paper has high decomposition temperature, and its room-temperature conductivity is up to 1.187×10-4 S/cm.
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34

Zhu, Jianhui, Amr Abdelkader, Denisa Demko, et al. "Electrocatalytic Assisted Performance Enhancement for the Na-S Battery in Nitrogen-Doped Carbon Nanospheres Loaded with Fe." Molecules 25, no. 7 (2020): 1585. http://dx.doi.org/10.3390/molecules25071585.

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Room temperature sodium-sulfur batteries have been considered to be potential candidates for future energy storage devices because of their low cost, abundance, and high performance. The sluggish sulfur reaction and the “shuttle effect” are among the main problems that hinder the commercial utilization of room temperature sodium-sulfur batteries. In this study, the performance of a hybrid that was based on nitrogen (N)-doped carbon nanospheres loaded with a meagre amount of Fe ions (0.14 at.%) was investigated in the sodium-sulfur battery. The Fe ions accelerated the conversion of polysulfides
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35

R, Arunkumar, Ajay Piriya Vijaya Kumar Saroja, and Ramaprabhu Sundara. "Barium Titanate-Based Porous Ceramic Flexible Membrane as a Separator for Room-Temperature Sodium-Ion Battery." ACS Applied Materials & Interfaces 11, no. 4 (2019): 3889–96. http://dx.doi.org/10.1021/acsami.8b17887.

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36

Wan, Hongli, Wei Weng, Fudong Han, Liangting Cai, Chunsheng Wang, and Xiayin Yao. "Bio-inspired Nanoscaled Electronic/Ionic Conduction Networks for Room-Temperature All-Solid-State Sodium-Sulfur Battery." Nano Today 33 (August 2020): 100860. http://dx.doi.org/10.1016/j.nantod.2020.100860.

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37

Zhao, Liang, Junmei Zhao, Yong-Sheng Hu, et al. "Disodium Terephthalate (Na2C8H4O4) as High Performance Anode Material for Low-Cost Room-Temperature Sodium-Ion Battery." Advanced Energy Materials 2, no. 8 (2012): 962–65. http://dx.doi.org/10.1002/aenm.201200166.

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38

Ye, Xin, Jiafeng Ruan, Yuepeng Pang, et al. "Enabling a Stable Room-Temperature Sodium–Sulfur Battery Cathode by Building Heterostructures in Multichannel Carbon Fibers." ACS Nano 15, no. 3 (2021): 5639–48. http://dx.doi.org/10.1021/acsnano.1c00804.

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39

Zhang, Xueqian, Zhiguo Hou, Xiaona Li, Jianwen Liang, Yongchun Zhu, and Yitai Qian. "Na-birnessite with high capacity and long cycle life for rechargeable aqueous sodium-ion battery cathode electrodes." Journal of Materials Chemistry A 4, no. 3 (2016): 856–60. http://dx.doi.org/10.1039/c5ta08857g.

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Na-birnessite has been synthesized using a simple precipitation reaction at room temperature and exhibits a high capacity of 39 mA h g<sup>−1</sup> and long cycle life at 10C in Na-Bir/NaTi<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub> full cells.
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40

Ryu, Hosuk, Taebum Kim, Kiwon Kim, et al. "Discharge reaction mechanism of room-temperature sodium–sulfur battery with tetra ethylene glycol dimethyl ether liquid electrolyte." Journal of Power Sources 196, no. 11 (2011): 5186–90. http://dx.doi.org/10.1016/j.jpowsour.2011.01.109.

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41

Asakura, Ryo, David Reber, Léo Duchêne, et al. "4 V room-temperature all-solid-state sodium battery enabled by a passivating cathode/hydroborate solid electrolyte interface." Energy & Environmental Science 13, no. 12 (2020): 5048–58. http://dx.doi.org/10.1039/d0ee01569e.

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A self-passivating cathode/electrolyte interface achieves stable, room-temperature long-term cycling of 4 V-class Na<sub>3</sub>(VOPO<sub>4</sub>)<sub>2</sub>F|Na<sub>4</sub>(CB<sub>11</sub>H<sub>12</sub>)<sub>2</sub>(B<sub>12</sub>H<sub>12</sub>)|Na all-solid-state sodium batteries with the highest reported discharge cell voltage and cathode-based specific energy.
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42

Tabuyo-Martínez, Marina, Bernd Wicklein, and Pilar Aranda. "Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteries." Beilstein Journal of Nanotechnology 12 (September 9, 2021): 995–1020. http://dx.doi.org/10.3762/bjnano.12.75.

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Rechargeable batteries are a major element in the transition to renewable energie systems, but the current lithium-ion battery technology may face limitations in the future concerning the availability of raw materials and socio-economic insecurities. Sodium–sulfur (Na–S) batteries are a promising alternative energy storage device for small- to large-scale applications driven by more favorable environmental and economic perspectives. However, scientific and technological problems are still hindering a commercial breakthrough of these batteries. This review discusses strategies to remedy some of
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43

Kumar, Ajit, Arnab Ghosh, Amlan Roy, et al. "High-energy density room temperature sodium-sulfur battery enabled by sodium polysulfide catholyte and carbon cloth current collector decorated with MnO2 nanoarrays." Energy Storage Materials 20 (July 2019): 196–202. http://dx.doi.org/10.1016/j.ensm.2018.11.031.

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44

Vijaya Kumar Saroja, Ajay Piriya, Kamaraj Muthusamy, and Ramaprabhu Sundara. "Strong Surface Bonding of Polysulfides by Teflonized Carbon Matrix for Enhanced Performance in Room Temperature Sodium‐Sulfur Battery." Advanced Materials Interfaces 6, no. 7 (2019): 1801873. http://dx.doi.org/10.1002/admi.201801873.

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45

Ponnaiah, Arjunan, Subadevi Rengapillai, Diwakar Karuppiah, Sivakumar Marimuthu, Wei-Ren Liu, and Chia-Hung Huang. "High Capacity Prismatic Type Layered Electrode with Anionic Redox Activity as an Efficient Cathode Material and PVdF/SiO2 Composite Membrane for a Sodium Ion Battery." Polymers 12, no. 3 (2020): 662. http://dx.doi.org/10.3390/polym12030662.

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A prismatic type layered Na2/3Ni1/3Mn2/3O2 cathode material for a sodium ion battery is prepared via two different methods viz., the solid state and sol–gel method with dissimilar surface morphology and a single phase crystal structure. It shows tremendous electrochemical chattels when studied as a cathode for a sodium-ion battery of an initial specific discharge capacity of 244 mAh g−1 with decent columbic efficiency of 98% up to 250 cycles, between the voltage range from 1.8 to 4.5 V (Na+/Na) at 0.1 C under room temperature. It is much higher than its theoretical value of 173 mAh g−1 and als
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46

Arjunan, Ponnaiah, Mathiyalagan Kouthaman, Rengapillai Subadevi, et al. "Superior Ionic Transferring Polymer with Silicon Dioxide Composite Membrane via Phase Inversion Method Designed for High Performance Sodium-Ion Battery." Polymers 12, no. 2 (2020): 405. http://dx.doi.org/10.3390/polym12020405.

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Superior sodium-ion-conducting polymer poly(vinyledene fluoride)–silicon dioxide (PVdF-SiO2) composite separator membrane was prepared via simple phase inversion method, which is a suitable alternative conventional polypropylene membrane. Basically, PVdF is the promising for use as high porous polymer electrolyte membrane due to its high dielectric constant (ε = 8.4). In this work, we prepared a composite membrane using PVdF-SiO2 via phase inversion method. This work was systematically studied towards the morphology, porosity, and electrochemical properties of as prepared membrane. The electro
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47

Hassan, N., A. Sanusi, and Azizah Hanom Ahmad. "Evaluation of Binary System (NaI-Na3PO4) Solid Electrolyte and Performance of Sodium Battery." Applied Mechanics and Materials 703 (December 2014): 33–40. http://dx.doi.org/10.4028/www.scientific.net/amm.703.33.

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A Na–ion conducting solid electrolyte system was prepared by using ball milling and sintering method. The electrical conductivity study was carried out as a function of NaI concentration by Electrical Impedance Spectroscopy technique and the maximum conductivity of (1.02±0.19)×10-4S cm−1at room temperature was obtained for the composition 0.50 NaI:0.50 Na3PO4. Further characterization was performed by using and Infrared (FTIR) technique. From FTIR spectra, the variation in the peak intensity and shifting is observed due to the presence of P–O and PO43−bands that had been shifted indicating cha
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48

Zhao, Liang, Hui-Lin Pan, Yong-Sheng Hu, Hong Li, and Li-Quan Chen. "Spinel lithium titanate (Li 4 Ti 5 O 12 ) as novel anode material for room-temperature sodium-ion battery." Chinese Physics B 21, no. 2 (2012): 028201. http://dx.doi.org/10.1088/1674-1056/21/2/028201.

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49

Nagata, Hiroshi, and Yasuo Chikusa. "An All-solid-state Sodium–Sulfur Battery Operating at Room Temperature Using a High-sulfur-content Positive Composite Electrode." Chemistry Letters 43, no. 8 (2014): 1333–34. http://dx.doi.org/10.1246/cl.140353.

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50

Benchakar, Mohamed, Régine Naéjus, Christine Damas, and Jesús Santos-Peña. "Exploring the use of EMImFSI ionic liquid as additive or co-solvent for room temperature sodium ion battery electrolytes." Electrochimica Acta 330 (January 2020): 135193. http://dx.doi.org/10.1016/j.electacta.2019.135193.

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