Relevant bibliographies by topics / Ru(p-cym)

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Academic literature on the topic 'Ru(p-cym)'

Author: Grafiati
Published: 2 June 2025
Last updated: 31 July 2025

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Journal articles on the topic "Ru(p-cym)"

1

Matveevskaya, Vladislava V., Dmitry I. Pavlov, Denis G. Samsonenko, et al. "Synthesis and Structural Characterization of Half-Sandwich Arene–Ruthenium(II) Complexes with Bis(imidazol-1-yl)methane, Imidazole and Benzimidazole." Inorganics 9, no. 5 (2021): 34. http://dx.doi.org/10.3390/inorganics9050034.

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Mono- and binuclear arene–ruthenium(II) complexes with imidazole-containing ligands were prepared by the reaction of the ligands (L1 = bis(imidazole-1-yl)methane; ImH = 1H-Imidazole; BImH = 1H-Benzimidazole) with [(p-cym)Ru(µ-Cl)2]2 dimers. When bis(imidazole-1-yl)methane reacted with [(p-cym)Ru(µ-Cl)2]2 in methanol, a binuclear complex of the type [Ru2(L1)2(p-cym)2Cl2]Cl2 (2) with cyclic structure was synthesized, whereas by using acetonitrile as a solvent under the same reaction conditions, an unexpected C–N bond cleavage was observed, and a complex of formula [Ru(ImH)2(p-cym)Cl]Cl (1) with
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2

Nolla-Saltiel, Roberto, Ana M. Geer, Helen R. Sharpe, et al. "Organoruthenium Complexes Containing Phosphinodicarboxamide Ligands." Inorganics 11, no. 9 (2023): 372. http://dx.doi.org/10.3390/inorganics11090372.

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Ruthenium complexes of phosphinocarboxamide ligands, and their use to form metallacycles using halide abstraction/deprotonation reactions are reported. Thus, [Ru(p-cym){PPh2C(=O)NHR}Cl2; R = iPr (1), Ph (2), p-tol (3)] and [Ru(p-cym){PPh2C(=O)N(R)C(=O)N(H)R}Cl2; R = Ph (4), p-tol (5)] were synthesized from [(p-cym)RuCl2]2 (p-cym = para-cymene) and phosphinocarboxamides or phosphinodicarboxamides, respectively. Single-crystal X-ray diffraction measurements on 1–5 reveal coordination to ruthenium through the phosphorus donor, with an intramolecular hydrogen bond between the amine-bound proton an
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3

Tran, Tan Ba, Éva Sipos, Attila Csaba Bényei, Sándor Nagy, István Lekli, and Péter Buglyó. "Synthesis and Characterization of Novel Co(III)/Ru(II) Heterobimetallic Complexes as Hypoxia-Activated Iron-Sequestering Anticancer Prodrugs." Molecules 29, no. 24 (2024): 5967. https://doi.org/10.3390/molecules29245967.

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Heterobimetallic complexes of an ambidentate deferiprone derivative, 3-hydroxy-2-methyl-1-(3-((pyridin-2-ylmethyl)amino)propyl)pyridin-4(1H)-one (PyPropHpH), incorporating an octahedral [Co(4N)]3+ (4N = tris(2-aminoethyl)amine (tren) or tris(2-pyridylmethyl)amine (tpa)) and a half-sandwich type [(η6-p-cym)Ru]2+ (p-cym = p-cymene) entity have been synthesized and characterized by various analytical techniques. The reaction between PyPropHpH and [Co(4N)Cl]Cl2 resulted in the exclusive (O,O) coordination of the ligand to Co(III) yielding [Co(tren)PyPropHp](PF6)2 (1) and [Co(tpa)PyPropHp](PF6)2 (2
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4

Tripathy, Suman Kumar, Margarethe van der Meer, Anupam Sahoo та ін. "A dinuclear [{(p-cym)RuIICl}2(μ-bpytz˙−)]+ complex bridged by a radical anion: synthesis, spectroelectrochemical, EPR and theoretical investigation (bpytz = 3,6-bis(3,5-dimethylpyrazolyl)1,2,4,5-tetrazine; p-cym = p-cymene)". Dalton Transactions 45, № 31 (2016): 12532–38. http://dx.doi.org/10.1039/c6dt01995a.

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5

Volkov, Oleg, Nigam P. Rath, and Lawrence Barton. "Chemistry on the Rhodacarborane Cluster [9,9-(PPh3)-nido-9,7,8-RhC2B8H11]: Formation of Bidentate Phosphine and Bimetallic Derivatives." Collection of Czechoslovak Chemical Communications 67, no. 6 (2002): 769–82. http://dx.doi.org/10.1135/cccc20020769.

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The electronically unsaturated rhodacarborane [9,9-(PPh3)2-nido-9,7,8-RhC2B8H11] (1), reacts with Ph2PCH2PPh2 (dppm) to afford [9,9-(dppm-κ2P)-9-(dppm-κP)-nido-9,7,8-RhC2B8H11] (3), in which the Rh-bonded PPh3 ligands have been replaced by two dppm ligands, one in a bidentate mode and the second in a unidentate mode with a free PPh2 end. The structure of 3 is similar to the related, and isoelectronic, species [8,8-(dppm-κ2P)-8-(dppm-κP)-nido-8,7-RhSB9H10] (4), but with a difference in the orientation of the ligands. Reaction of 1 with Ph2P(CH2)2PPh2 (dppe) affords a species tentatively identif
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6

Purkait, Kallol, Subhendu Karmakar, Sudipta Bhattacharyya, Saptarshi Chatterjee, Suman Kr Dey, and Arindam Mukherjee. "A hypoxia efficient imidazole-based Ru(ii) arene anticancer agent resistant to deactivation by glutathione." Dalton Transactions 44, no. 13 (2015): 5969–73. http://dx.doi.org/10.1039/c4dt03983a.

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7

Tripathy, Suman Kumar, Ashoka Chary Taviti, Niranjan Dehury, et al. "Synthesis, characterisation and antibacterial activity of [(p-cym)RuX(L)]+/2+ (X = Cl, H2O; L = bpmo, bpms) complexes." Dalton Transactions 44, no. 11 (2015): 5114–24. http://dx.doi.org/10.1039/c4dt03647f.

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8

Mansour, Ahmed M., and Krzysztof Radacki. "Experimental and DFT studies of sulfadiazine ‘piano-stool’ Ru(ii) and Rh(iii) complexes." RSC Advances 10, no. 18 (2020): 10673–80. http://dx.doi.org/10.1039/d0ra01085e.

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Binding of certain metal complexes to proteins may cause cytotoxicity. While [(η<sup>6</sup>-p-Cym)Ru(L<sup>SZ</sup>)<sub>2</sub>] decomposed during the reaction with hen white egg lysozyme, a Rh(iii) analogue was covalently bio-conjugated via the elimination of a sulfadiazine.
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9

Tripathy, Suman Kumar, Umasankar De, Niranjan Dehury, Satyanarayan Pal, Hyung Sik Kim та Srikanta Patra. "Dinuclear [{(p-cym)RuCl}2(μ-phpy)](PF6)2 and heterodinuclear [(ppy)2Ir(μ-phpy)Ru(p-cym)Cl](PF6)2 complexes: synthesis, structure and anticancer activity". Dalton Trans. 43, № 39 (2014): 14546–49. http://dx.doi.org/10.1039/c4dt01033g.

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10

Ywaya, David O., Halliru Ibrahim, Holger B. Friedrich та ін. "Chemotherapeutic Activities of New η6-p-Cymene Ruthenium(II) and Osmium(II) Complexes with Chelating SS and Tridentate SNS Ligands". Molecules 29, № 5 (2024): 944. http://dx.doi.org/10.3390/molecules29050944.

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A series of new chelating bidentate (SS) alkylimidazole-2-thione-Ru(II)/Os(II) complexes (3ai, 3aii, 3aiii, 3bii/4aiii, 4bi, 4bii), and the tridentate (SNS) pyridine-2,6-diylimidazole-2-thione-Ru(II)/Os(II) complexes (5bi, 5civ/6bi, 6ci, 6civ) in the forms [MII(cym)(L)Cl]PF6 and [MII(cym)(L)]PF6 (M = Ru or Os, cym = η6-p-cymene, and L = heterocyclic derivatives of thiourea) respectively, were successfully synthesized. Spectroscopic and analytical methods were used to characterize the complexes and their ligands. Solid-state single-crystal X-ray diffraction analyses revealed a “piano-stool” geo
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