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Relevant bibliographies by topics / Ruthenium-based catalysts

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Academic literature on the topic 'Ruthenium-based catalysts'

Author: Grafiati

Published: 7 September 2024

Last updated: 31 July 2025

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Journal articles on the topic "Ruthenium-based catalysts"

1

Singh, Keisham. "Recent Advances in C–H Bond Functionalization with Ruthenium-Based Catalysts." Catalysts 9, no. 2 (2019): 173. http://dx.doi.org/10.3390/catal9020173.

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The past decades have witnessed rapid development in organic synthesis via catalysis, particularly the reactions through C–H bond functionalization. Transition metals such as Pd, Rh and Ru constitute a crucial catalyst in these C–H bond functionalization reactions. This process is highly attractive not only because it saves reaction time and reduces waste,but also, more importantly, it allows the reaction to be performed in a highly region specific manner. Indeed, several organic compounds could be readily accessed via C–H bond functionalization with transition metals. In the recent past, trem

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Nahra, Fady, and Catherine S. J. Cazin. "Sustainability in Ru- and Pd-based catalytic systems using N-heterocyclic carbenes as ligands." Chemical Society Reviews 50, no. 5 (2021): 3094–142. http://dx.doi.org/10.1039/c8cs00836a.

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This review is a critical presentation of catalysts based on palladium and ruthenium bearing N-heterocyclic carbene ligands that have enabled a more sustainable approach to catalysis and to catalyst uses.

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Weissenberger, Tobias, Ralf Zapf, Helmut Pennemann, and Gunther Kolb. "Catalyst Coatings for Ammonia Decomposition in Microchannels at High Temperature and Elevated Pressure for Use in Decentralized and Mobile Hydrogen Generation." Catalysts 14, no. 2 (2024): 104. http://dx.doi.org/10.3390/catal14020104.

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We report an investigation of catalyst performance for the decomposition of ammonia under industrially relevant conditions (high temperatures of up to 800 °C and an elevated pressure of 5 bar) with further emphasis on their stability at high reaction temperatures. The catalysts were applied and tested as coatings in 500 µm wide channels of microreactors. Nickel-based catalysts were studied and compared to a ruthenium-based catalyst supported on SiO2. The effect of the support on the catalytic performance was investigated, and CeO2-supported nickel catalysts were found to exhibit the highest ac

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Reany, Ofer, and N. Gabriel Lemcoff. "Light guided chemoselective olefin metathesis reactions." Pure and Applied Chemistry 89, no. 6 (2017): 829–40. http://dx.doi.org/10.1515/pac-2016-1221.

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AbstractAn appealing concept in synthetic chemistry is photo-induced catalysis; where dormant complexes become catalytically active upon activation with light. The ruthenium-based olefin metathesis complexes founded on the original Grubbs catalyst have probably been one of the most widely studied families of catalysts for the past 25 years. Greater stability and versatility of these olefin-metathesis catalysts has been achieved by careful design of the ligand sphere, including latent catalysts which are activated by external stimuli. This article describes our recent developments towards light

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Podolean, Iunia, Mara Dogaru, Nicolae Cristian Guzo, et al. "Highly Efficient Ru-Based Catalysts for Lactic Acid Conversion to Alanine." Nanomaterials 14, no. 3 (2024): 277. http://dx.doi.org/10.3390/nano14030277.

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The primary objective of this research was to develop efficient solid catalysts that can directly convert the lactic acid (LA) obtained from lignocellulosic biomass into alanine (AL) through a reductive amination process. To achieve this, various catalysts based on ruthenium were synthesized using different carriers such as multi-walled carbon nanotubes (MWCNTs), beta-zeolite, and magnetic nanoparticles (MNPs). Among these catalysts, Ru/MNP demonstrated a remarkable yield of 74.0% for alanine at a temperature of 200 °C. This yield was found to be superior not only to the Ru/CNT (55.7%) and Ru/

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Chen, Hui, Runxu Deng, Shixin Gao, and Feng Liu. "Preparation of porous iridium-ruthenium-based acidic water oxidation catalyst by ascorbic acid reduction and evaporation." Journal of Physics: Conference Series 2566, no. 1 (2023): 012017. http://dx.doi.org/10.1088/1742-6596/2566/1/012017.

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Abstract Green hydrogen is the ultimate direction for energy development technology. Hereon, the porous materials of promoted iridium-ruthenium-based catalyst were prepared by ascorbic acid reduction and evaporation drying methods. The unsupported iridium ruthenium-based catalysts were porous structures, characterized by scanning electron microscopes (SEM). In 0.5 mol·L−1 H2SO4, the electrochemical oxygen precipitation reaction overpotential was only 251 mV at 10 mA·cm2, compared to commercial 303 mV. The polarization overpotential was not significantly reduced, after 20 000 cycles of accelera

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Abubakar, Oluwafemi David, and Thomas Hamann. "Ligand Design for Enhanced Ruthenium-Based Electrocatalytic Ammonia Oxidation." ECS Meeting Abstracts MA2025-01, no. 52 (2025): 2589. https://doi.org/10.1149/ma2025-01522589mtgabs.

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The electrocatalytic oxidation of ammonia remains a critical challenge in energy and environmental technologies, with current molecular catalysts struggling with high overpotentials, limited stability, and low turnover frequencies. Since the first molecular catalyst, [Ru(tpy)(dmabpy)NH3)]2+, was reported in 2019, there has been progress in investigating alternative ligand frameworks and transition metal centers to better understand and control the reaction. This presentation will highlight a novel strategy for improving the electrocatalytic performance by systematically optimizing ligand bite

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Truszkiewicz, Elżbieta, Wioletta Raróg-Pilecka, Magdalena Zybert, Malwina Wasilewska-Stefańska, Ewa Topolska, and Kamila Michalska. "Effect of the ruthenium loading and barium addition on the activity of ruthenium/carbon catalysts in carbon monoxide methanation." Polish Journal of Chemical Technology 16, no. 4 (2014): 106–10. http://dx.doi.org/10.2478/pjct-2014-0079.

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Abstract A group of supported ruthenium catalysts was prepared and tested in methanation of small CO amounts (7000 ppm) in hydrogen-rich streams. High surface area graphitized carbon (484 m2/g) was used as a support for ruthenium and RuCl3 was used as a Ru precursor. Some of the Ru/C systems were additionally doped with barium (Ba(NO3)2 was barium precursor). The catalysts were characterized by the chemisorption technique using CO as an adsorbate. To determine the resistance of the catalysts to undesired carbon support methanation, the TG-MS experiments were performed. They revealed that the b

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Zhong, He Xiang, Hua Min Zhang, and Mei Ri Wang. "Oxygen Reduction Reaction on Carbon Supported Ruthenium-Based Electrocatalysts in PEMFC." Materials Science Forum 675-677 (February 2011): 97–100. http://dx.doi.org/10.4028/www.scientific.net/msf.675-677.97.

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The ruthenium-based electrocatalysts supported on carbon black were prepared by the decarbonylation of the transition metal carbonyl with the 1,6-hexanediol as the solvent. The catalysts were characterized via X-ray diffraction (XRD), transmission electron microscopy (TEM) and high resolution TEM (HRTEM). The electrochemical behaviours of the catalysts were investigated by cyclic voltammetry (CV) and rotating disk electrode (RDE) measurements in 0.5 M H2SO4 solution. The catalysts demonstrate attractive catalytic activity towards the ORR. The catalyst is expected to be promising alternative no

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Ma, Peng, Jiaren Zhang, Xiaqian Wu, and Jianhui Wang. "Ruthenium Metathesis Catalysts with Imidazole Ligands." Catalysts 13, no. 2 (2023): 276. http://dx.doi.org/10.3390/catal13020276.

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Phosphine-free ruthenium benzylidene complexes containing imidazole ligands are reported. These catalysts are effective for ring-closing metathesis (RCM) and cross-metathesis (CM) reactions at high temperatures, where the more widely used phosphine-containing N-heterocyclic carbene-based ruthenium catalysts show side reactions. This discovery opens up a pathway to develop more selective ruthenium metathesis catalysts for reactions requiring harsh conditions.

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Dissertations / Theses on the topic "Ruthenium-based catalysts"

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Robinson, Alan. "Novel catalysts and additives for ruthenium-based metathesis systems." Thesis, University of Bristol, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.508098.

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MOTOKI, YOSHIDA. "Synthesis of Ruthenium-based Water Oxidation Catalysts and Mechanistic Study." Thesis, KTH, Skolan för kemivetenskap (CHE), 2015. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-173843.

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Two series of new mononuclear ruthenium complexes with hydrophobic or hydrophilic ligands [Ru(bda)L2] and [Ru(pdc)L3] (H2bda = 2,2'-bipyridine-6,6'-dicarboxylic acid; H2pdc = 2,6-pyridinedicarboxylic acid; L = pyridyl ligands) were synthesized and their electrochemical properties and catalytic activity toward water oxidation were examined. It was revealed that the hydrophobic ligands introduced to [Ru(bda)L2 ] improved the catalytic performance, ahnost twofold TON and TOF values were achieved compared to the [Ru(bda)] catalyst with hydrophilic ligands. The cyclic voltammogram of [Ru(bda)L2] ex

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Urbina-Blanco, César A. "Design and synthesis of ruthenium indenylidene-based catalysts for olefin metathesis." Thesis, University of St Andrews, 2013. http://hdl.handle.net/10023/3737.

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As part of a European wide effort to develop metathesis catalysts for use in fine chemical and pharmaceutical compound synthesis, this study focuses on the design and synthesis of ruthenium based catalysts for olefin metathesis. The aim, of this work was simple: to develop new, more active, more stable, easy to synthesise and commercially viable Ruthenium based catalysts, as well trying to rationalize the effect of structural changes on reactivity. Two different approaches were explored in order to develop more active catalysts bearing N-heterocyclic carbene (NHC) ligands: changing the leaving

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Gowda, Anitha Shankaralinge. "HYDROGENATION AND HYDROGENOLYSIS OF FURAN DERIVATIVES USING BIPYRIDINE-BASED ELECTROPHILIC RUTHENIUM(II) CATALYSTS." UKnowledge, 2013. http://uknowledge.uky.edu/chemistry_etds/29.

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The catalytic activity of ruthenium(II) bis(diimine) complexes cis-[Ru(6,6′-Cl2bpy)2(OH2)2](Z)2 (2, Z = CF3SO3; 3, Z = (3,5-(CF3)2C6H3)4B ,i.e. BArF), cis-[Ru(4,4′-Cl2bpy)2(OH2)2](Z)2 (4, Z = CF3SO3; 5, Z = BArF) and cis-[Ru(bpy)2(PR3)(OH2)](CF3SO3)2 (7, bpy = 2,2’-bipyridine, PR3 = P(C6H4F)3; 8, bpy = 2,2-bipyridine, PR3 = PPh3; 9, bpy = 4,4’-dichloro-2,2’-bipyridine, PR3 = PPh3; 10, bpy = 4,4’-dimethyl-2,2’-bipyridine, PR3 = P(C6H4F)3) for the hydrogenation and hydrogenolysis of furfural (FFR), furfuryl alcohol (FFA) and 5-hydroxymethylfurfural (HMF) was investigated. The compounds 2-5 are a

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Bashal, Ali Habib. "Aqueous phase hydrogenation of succinic acid using mono-and bi-metallic ruthenium-based catalysts." Thesis, University of Liverpool, 2018. http://livrepository.liverpool.ac.uk/3021601/.

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Morgan, John Philip Stoltz Brian M. Grubbs Robert H. "Ruthenium-based olefin metathesis catalysts coordinated with n-heterocyclic carbene ligands : synthesis and applications /." Diss., Pasadena, Calif. : California Institute of Technology, 2003. http://resolver.caltech.edu/CaltechETD:etd-10222002-204928.

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Fraser, Ian. "The feasibility of high synthesis gas conversion over ruthenium promoted iron-based Fischer Tropsch catalyst." Thesis, Cape Peninsula University of Technology, 2017. http://hdl.handle.net/20.500.11838/2588.

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Thesis (MTech (Chemical Engineering))--Cape Peninsula University of Technology, 2017.<br>One of the very promising synthetic fuel production strategies is the Fischer-Tropsch process, founded on the Fischer-Tropsch Synthesis, which owes its discovery to the namesake researchers Franz Fischer and Hans Tropsch. The Fischer-Tropsch Synthesis (FTS) converts via complex polymerisation reaction a mixture of CO and H2 over transition metal catalysts to a complex mixture of hydrocarbons and oxygen containing compounds with water as major by-product. The mixture of CO and H2 (termed syngas) may b

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Zhang, Hui-Jun. "Novel syntheses from building blocks based on 1,3-butadienyl skeleton and new polysubstitued ruthenium based catalysts for regioselective allylation." Rennes 1, 2010. http://www.theses.fr/2010REN1S011.

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In this thesis the author concentrates on the preparation of several novel building blocks based on butadienyl skeleton and their synthetic application for organic synthesis. Stereo-defined 1,1,4,4-tetrahalo-1,3-butadienes could be readily synthesized. The reactions of these butadienes with butyllithium and its Suzuki coupling reactions with aryl boronic acid are unprecedented. Moreover, bis(pinacolato)diboron could react with 1,4,4-trihalo-1-lithiodienes which were obtained in situ by lithiation of our new bis(gem-dihalo)dienes, to afford corresponding novel gem-diboryldienes which serve as g

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Delgado, Jaime Mario Ulises. "Electronic structure studies of ruthenium-based catalysts for olefin metathesis : an x-ray absoprtion spectroscopy perspective." Thesis, University of British Columbia, 2009. http://hdl.handle.net/2429/17434.

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Interest in olefin metathesis has increased over the years with the development of ruthenium-based catalysts. Their unique properties have allowed their use in numerous industrial and laboratory processes in relatively mild conditions and in combination with a wide range of solvents. Several studies have provided insights into how these catalysts work, but very little has been done in order to understand why they work that way; an important aspect that has the potential of benefiting chemists while designing new catalysts. The research introduced here has focused on the fundamental understandi

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Bernardi, Andrea. "Synthesis, characterization and catalytic performances of ruthenium-based catalysts for the acceptorless dehydrogenative coupling of butanol." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2015. http://amslaurea.unibo.it/8521/.

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A growing interest towards new sources of energy has led in recent years to the development of a new generation of catalysts for alcohol dehydrogenative coupling (ADC). This green, atom-efficient reaction is capable of turning alcohol derivatives into higher value and chemically more attractive ester molecules, and it finds interesting applications in the transformation of the large variety of products deriving from biomass. In the present work, a new series of ruthenium-PNP pincer complexes are investigated for the transformation of 1-butanol, one of the most challenging substrates for this

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Book chapters on the topic "Ruthenium-based catalysts"

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Grubbs, R. H., and M. Sanford. "Mechanism of Ruthenium Based Olefin Metathesis Catalysts." In Ring Opening Metathesis Polymerisation and Related Chemistry. Springer Netherlands, 2002. http://dx.doi.org/10.1007/978-94-010-0373-5_2.

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Ilker, M. Firat, Habib Skaff, Todd Emrick, and E. Bryan Coughlin. "Metathesis and Polyolefin Growth on Cadmium Selenide Surfaces Using Ruthenium-Based Catalysts." In Novel Metathesis Chemistry: Well-Defined Initiator Systems for Specialty Chemical Synthesis, Tailored Polymers and Advanced Material Applications. Springer Netherlands, 2003. http://dx.doi.org/10.1007/978-94-010-0066-6_22.

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Quigley, Brendan L., and Robert H. Grubbs. "Catalyst Structure andCis-TransSelectivity in Ruthenium-based Olefin Metathesis." In Ligand Design in Metal Chemistry. John Wiley & Sons, Ltd, 2016. http://dx.doi.org/10.1002/9781118839621.ch2.

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Pettinari, Claudio, Riccardo Pettinari, Corrado Di Nicola, and Fabio Marchetti. "Half-Sandwich Rhodium(III), Iridium(III), and Ruthenium(II) Complexes with Ancillary Pyrazole-Based Ligands." In Advances in Organometallic Chemistry and Catalysis. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118742952.ch21.

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Noels, A. F., and A. Demonceau. "Metathesis of Low-Strain Olefins and Functionalized Olefins with New Ruthenium-Based Catalyst Systems." In Metathesis Polymerization of Olefins and Polymerization of Alkynes. Springer Netherlands, 1998. http://dx.doi.org/10.1007/978-94-011-5188-7_2.

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Karabulut, Solmaz, and Francis Verpoort. "Ring-Opening Metathesis Activity of Ruthenium-Based Olefin Metathesis Catalyst Coordinated with 1,3-Bis(2,6-Diisopropylphenyl)-4,5-Dihydroimidazoline." In Metathesis Chemistry. Springer Netherlands, 2007. http://dx.doi.org/10.1007/978-1-4020-6091-5_11.

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Ernst Müller, Thomas. "Catalysis with Ruthenium for Sustainable Carbon Cycles." In Ruthenium - Materials Properties, Device Characterizations, and Advanced Applications [Working Title]. IntechOpen, 2023. http://dx.doi.org/10.5772/intechopen.112101.

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Nestled between the noble and non-noble metals in the periodic table, ruthenium, one of the transition metals, offers a combination of intriguing properties. Due to its variable oxidation states and its ability to form complexes with various Lewis base compounds, ruthenium, has been widely used in the field of catalysis. Its application has led to groundbreaking breakthroughs in a variety of chemical transformations and has attracted considerable attention in both academic research and industrial applications. Ruthenium catalysis is a dynamic and rapidly evolving field, with ongoing efforts to

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"Ruthenium Sulfide Based Catalysts." In Hydrotreating Technology for Pollution Control. CRC Press, 1996. http://dx.doi.org/10.1201/9781482273540-13.

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von Angerer, S. "With Ruthenium-Based Catalysts." In Ketones. Georg Thieme Verlag KG, 2005. http://dx.doi.org/10.1055/sos-sd-026-00033.

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"Ruthenium Based Ammonia Synthesis Catalysts." In Ammonia Synthesis Catalysts. WORLD SCIENTIFIC / CHEMICAL INDUSTRY PRESS, CHINA, 2013. http://dx.doi.org/10.1142/9789814355780_0006.

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Conference papers on the topic "Ruthenium-based catalysts"

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Sudiyarmanto, Sudiyarmanto, Fauzan Aulia, Fauzul Adzim, Hendri Setiyanto, and Adid Adep Dwiatmoko. "Catalytic conversion of furfural to furfuryl alcohol over ruthenium based catalysts." In SolarPACES 2017: International Conference on Concentrating Solar Power and Chemical Energy Systems. Author(s), 2018. http://dx.doi.org/10.1063/1.5064313.

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Bartley, Gordon J., Zachary Tonzetich, and Ryan Hartley. "Ruthenium-Based Catalyst in EGR Leg of a D-EGR Engine Offers Combustion Improvements Through Selective NOX Removal." In SAE 2016 World Congress and Exhibition. SAE International, 2016. http://dx.doi.org/10.4271/2016-01-0952.

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Yang, Lijun, and Wallace Woon-Fong Leung. "Improvement of Dye Sensitized Solar Cells With Nanofiber-Based Anode." In ASME 2011 International Mechanical Engineering Congress and Exposition. ASMEDC, 2011. http://dx.doi.org/10.1115/imece2011-64710.

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Dye Sensitized Solar Cell (DSSC) has great advantages over conventional silicon-based photovoltaics as it is inexpensive, flexible, and transparent. Sun energy is used to excite the electron of the organic (ruthenium-polypyridine) dye from which the electron from the dye is injected into the anode made of titanium dioxide (TiO2). The excited electron enters the conduction band of the TiO2 and gets transmitted across the TiO2 nanoparticles (anode) to the FTO (Fluorine-doped tin-oxide) glass/electrode, which in turn go to the external circuit powering the electrical load. The electron returns to

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Rabie, A. H., Y. F. Alwahedi, B. G. Ciotti, J. A. Anguiano, and D. L. Merryfield. "Novel Blue Hydrogen and Transportation Process Supporting Global Carbon Footprint Reduction." In ADIPEC. SPE, 2024. http://dx.doi.org/10.2118/222807-ms.

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Abstract With the imminent threat of global warming, the international energy industry has sought out alternative fuels to reduce greenhouse emissions. Hydrogen, a clean fuel, has been identified as a promising alternative to carbon-based fuels. When utilized, hydrogen produces no harmful exhaust emissions. Blue hydrogen, also known as low carbon intensity hydrogen, is generated via the reaction of hydrocarbons and steam under heat and pressure [steam methane reforming (SMR)] to create hydrogen-enriched syngas. The hydrogen is then purified via a Pressure Swing Adsorption (PSA) unit. The blue

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Basu, Sumit, Yuan Zheng, and Jay P. Gore. "Chemical Kinetics Parameter Estimation for Ammonia Borane Hydrolysis." In ASME 2008 Heat Transfer Summer Conference collocated with the Fluids Engineering, Energy Sustainability, and 3rd Energy Nanotechnology Conferences. ASMEDC, 2008. http://dx.doi.org/10.1115/ht2008-56139.

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Onboard hydrogen storage is an enabling factor in the development of fuel cell powered passenger cars. Ammonia borane (AB) hydrolysis is one of the potential technologies for onboard hydrogen storage. In this study, kinetics of catalyzed ammonia borane hydrolysis using ruthenium-supported-on-carbon has been measured. For reacting flows, chemical kinetics determines the rates of heat generation and species production or consumption in the overall energy and mass balances respectively. Kinetic measurements under isothermal conditions provide critical data for the design of hydrolysis reactors. I

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