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Journal articles on the topic 'Ruthenium clusters'

Author: Grafiati

Published: 4 June 2021

Last updated: 26 July 2025

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1

Adachi, Kenji, Sadahiro lida, and Kazuhide Hayashi. "Ruthenium clusters in lead-borosilicate glass in thick film resistors." Journal of Materials Research 9, no. 7 (1994): 1866–78. http://dx.doi.org/10.1557/jmr.1994.1866.

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An interparticle glass matrix in ruthenium dioxide-based thick film resistors has been studied intensively by means of analytical and high resolution transmission electron microscopy. The ruthenium dioxide phase interacts with lead-borosilicate glass at high temperature by dissolving ruthenium ions and incorporating a small number of lead and aluminum ions on the surface. Ruthenium ions diffuse through the glass network at least over a distance of 1 μm during firing, but are accommodated in the glass structure by an amount only less than 7 at. % at room temperature. High resolution electron mi

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2

Zhu, Bao Hua, Guo Hua Xu, and Zhi Wei Xia. "Ruthenium and Iron Carbonyl Clusters Catalyzed Reduction of N,N-dimethylbenzamide and N,N-diethyl-(3-methyl)benzamide." Advanced Materials Research 396-398 (November 2011): 2485–88. http://dx.doi.org/10.4028/www.scientific.net/amr.396-398.2485.

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One new Ruthenium and one known Iron bimetallic carbonyl clusters containing triphos (1,1,1-tris(diphenylphosphinomethyl)ethane) ligand have been prepared as catalyst to study the reduction of amide to amine. All clusters were characterized by elemental analysis, 1HNMR, 31PNMR and IR spectroscopy. The reduction of N,N-dimethylbenzamide and N,N-diethyl-(3-methyl) benzamide catalyzed by Ru and Fe carbonyl clusters were investigated at 100 ~ 110 °C for 24 ~ 28h, polymethylhydrogensiloxane (PMHS) as reduction agent. The products were analysized using GC-MS, IR and UV-vis spectroscopy and an excell

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3

Zhizhin, Gennadiy Vladimirovich. "The Geometry of Higher-Dimensional Multi-Shell Clusters With Common Center and Different Centers." International Journal of Applied Nanotechnology Research 4, no. 2 (2019): 45–65. http://dx.doi.org/10.4018/ijanr.2019070103.

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In this article, it is shown that the dimension of a metal skeleton of giant palladium cluster, containing 561 atoms in five shells, is 8. The claims of some authors that the palladium cluster in this case is an E8 lattice are groundless. The internal geometry of multi-shell metal clusters with ligands and core was investigated. It is proved that the multi-shell clusters with common center and different centers have a higher dimension. Clusters with ligands and a structural unit octahedron exist with different metals in the core. A spatial image of the cobalt tetra-anion cluster is presented.

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4

Boncheff, Alexander G., and Mario A. Monteiro. "The detection of ruthenium chloride clusters by laser desorption ionization-mass spectrometry of RuCl3·3H2O." Canadian Journal of Chemistry 89, no. 4 (2011): 511–16. http://dx.doi.org/10.1139/v11-005.

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The production of gas-phase singly charged ruthenium chloride anionic complexes by laser desorption ionization of RuCl3·3H2O is reported. The [RuxCly]− clusters could only be detected in the absence of the matrix component in the negative mode. The cluster compositions observed were [RuCl4]−, [RuCl5]−, [Ru2Cl6]−, [Ru2Cl7]−, [Ru3Cl9]−, [Ru4Cl11]−, and [Ru5Cl12]−. With the aid of density functional theory calculations, we proposed feasible structures for each ruthenium chloride cluster, in which Ru–Ru bonds and Cl bridges were a common characteristic.

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5

Toma, Henrique E., and Carlos J. Cunha. "Spectroelectrochemical behaviour of the trinuclear [Ru3O(O2CCH3)6(isonicotinamide)3] cluster." Canadian Journal of Chemistry 67, no. 10 (1989): 1632–35. http://dx.doi.org/10.1139/v89-250.

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The [Ru3O(OOCCH3)6(isonicotinamide)3] cluster exhibits reversible electrochemical and spectroelectrochemical behaviour in acetonitrile solutions, associated with a series of successive μ-oxo RuIVRuIVRuIII/RuIVRu1IIRuIII/…/RuIIRuIIRuII redox couples with E0 = 2.16, 1.21, 0.19, −0.98, and −1.4 V versus SHE. The metal-isonicotinamide and metal–metal charge–transfer transitions shift to lower energies as the oxidation states of the ruthenium ions decrease. In alkaline aqueous solution, the μ-oxo RuIIIRuIIIRuII cluster can be reversibly reduced to the μ-oxo RuIIIRuIIRuII product (E0 = −0.85 V); how

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6

Chen, Hong, Zi-Chao Tang, Rong-Bin Huang, and Lan-Sun Zheng. "Photodissociation Mass Spectrometry of Trinuclear Carbonyl Clusters M3(CO)12 (M = Fe, Ru, Os)." European Journal of Mass Spectrometry 6, no. 1 (2000): 19–22. http://dx.doi.org/10.1255/ejms.301.

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Photodissociation of trinuclear carbonyl cluster compounds of Fe, Ru and Os was studied by recording the mass spectra produced from laser ablation of the cluster compounds. Under the experimental conditions, dissociation of the cluster compounds is very extensive, but the dissociation pathway of the osmium cluster is different from those of the iron and ruthenium clusters. The iron and ruthenium clusters not only lost their carbonyl ligands, but their cluster cores were also fragmented. As the osmium cluster dissociated, it ejected three pairs of oxygen atoms, in sequence, before losing the ca

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7

Tabet-Zatla, Chaima Z., Sumeya Bedrane, José Juan Calvino, et al. "Single-Atom and Sub-Nano Ruthenium Cluster Catalysts—Application to Biomass Upgrading into Biofuel Additive." Catalysts 15, no. 5 (2025): 449. https://doi.org/10.3390/catal15050449.

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Sub-nano metal clusters have important physicochemical features that lead to a wide range of applications. Herein, we point out an unfailing reproducible protocol to synthesize ruthenium single-atom catalysts and ultra-small clusters supported on various silica–alumina mixed oxides. The catalysts were synthesized via a dendrimer-free, sonication-assisted route, with ruthenium loadings up to 2 wt%. Raman spectroscopy mapping revealed a wide coverage of the materials’ surfaces by ruthenium, while HAADF-STEM evidenced that 100% of the ruthenium was at the sub-nano scale, with up to 74% of the sin

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8

Geetharani, K., Shubhankar Kumar Bose, and Sundargopal Ghosh. "Heterometallic cubane-type clusters containing group 13 and 16 elements." Pure and Applied Chemistry 84, no. 11 (2012): 2233–41. http://dx.doi.org/10.1351/pac-con-11-10-17.

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Heterometallic cubane-type clusters were synthesized from the reaction of group 6 and 8 metallaboranes using transition-metal carbonyl compounds. Structural and spectroscopic study revealed the existence of novel “capped-cubane” geometry. In addition, the crystal structure of these clusters distinctly confirms the presence of boride unit as one of the vertices. These clusters possess 60 cluster valence electrons (cve) and six metal–metal bonds. A plausible pathway for the formation of ruthenium-capped cubane has been described.

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9

Pomogailo, A. D. "Polymer-Immobilised Clusters of the Platinum Group Metals." Platinum Metals Review 38, no. 2 (1994): 60–70. http://dx.doi.org/10.1595/003214094x3826070.

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In this review major developments associated with the synthesis, properties, structure and applications of polymer-immobilised clusters of platinum, palladium, ridium, rhodium, osmium and ruthenium, are presented. Special attention is paid to polymer analogous reactions with metal clusters and new directions involving the polymerisation and copolymerisation of cluster-containing monomers. Some specific features of fixing heterometallic clusters on polymers are examined and the more interesting application of PCNM in catalysis, and future developments in this direction, are discussed.

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10

Deng, Bang Chao, and Ai Qing Zhang. "Size Control of Ruthenium Nano-Cluster by Seed-Mediated Method." Journal of Nano Research 49 (September 2017): 66–74. http://dx.doi.org/10.4028/www.scientific.net/jnanor.49.66.

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A series of well dispersed ruthenium nano-clusters using Polyvinylpyrrolidone (PVP) as stabilizer were synthesized by seed-mediated method. In this method, polymer-stabilized PVP-Ru nano-cluster with a diameter of about 3.14 nm was prepared by the reduction of RuCl3 in ethylene glycol and used as a seed solution (S), which was then added to the EG solution of ruthenium (Ⅲ) salts (E) to control the size of the Ru nano-cluster synthesized in this seed-mediated method. The influences of the amount of S solution that was added to E solution and the existence of PVP in ruthenium salts solution on t

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11

Dyson, Paul J., Brian F. G. Johnson, David Reed, Dario Braga, Fabrizia Grepioni, and Emilio Parisini. "Hexanuclear arene clusters of ruthenium." Journal of the Chemical Society, Dalton Transactions, no. 18 (1993): 2817. http://dx.doi.org/10.1039/dt9930002817.

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12

Willeit, Nicole S., Viktor Hlukhyy, and Thomas F. Fässler. "Ruthenium Decorated Tris-Silylated Germanium Zintl Clusters Featuring an Unexpected Ligand Arrangement." Molecules 30, no. 6 (2025): 1247. https://doi.org/10.3390/molecules30061247.

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The incorporation of transition metal atoms into [Ge9] clusters is a widely studied area of Zintl-cluster chemistry. Recently, it was shown that clusters comprising single transition metal atoms in the cluster surface show catalytic properties. Here, we present a synthetic approach to four new compounds comprising silylated Ge9 clusters with organometallic ruthenium complexes. [η5-Ge9Hyp3]RuCp* (1), [η1-Ge9(SitBu2H)3]RuCp(PPh3)2 (2), and [Hyp3Ge9][RuCp(PPh3)2(MeCN)] (3b) (Cp = cyclopentadienyl, Cp* = pentamethylcyclopentadienyl, Hyp = Si(SiMe3)3, Ph = C6H5, tBu = tert-butyl) were characterized

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13

Ruzicka, Jan-Yves, David P. Anderson, Sally Gaw, and Vladimir B. Golovko. "Platinum-Ruthenium Nanoparticles: Active and Selective Catalysts for Hydrogenation of Phenylacetylene." Australian Journal of Chemistry 65, no. 10 (2012): 1420. http://dx.doi.org/10.1071/ch12219.

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Bimetallic metal nanoparticles are often more catalytically active than their monometallic counterparts, due to a so-called ‘synergistic effect’. Atomically precise ruthenium-platinum clusters have been shown to be active in the hydrogenation of phenylacetylene to styrene (a reaction of importance to the polymer industry). However, the synthesis of these clusters is generally complex, and cannot be modified to produce clusters with differing metal compositions or ratios. Hence, any truly systematic study of compositional effects using such clusters is hindered by the inaccessibility of certain

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14

Bhaduri, S., K. R. Sharma, and H. I. Khwaja. "Homogeneous catalysis by ruthenium carbonyl clusters." Proceedings / Indian Academy of Sciences 101, no. 3 (1989): 195–209. http://dx.doi.org/10.1007/bf02840635.

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15

Albinati, Alberto, Luigi M. Venanzi, and Guozhi Wang. "Ruthenium tri- and digold hydride clusters." Inorganic Chemistry 32, no. 17 (1993): 3660–69. http://dx.doi.org/10.1021/ic00069a020.

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16

Tschan, Mathieu, Bruno Therrien, Frédéric Chérioux, and Georg Süss-Fink. "Sulfur-containing trinuclear arene ruthenium clusters." Journal of Molecular Structure 743, no. 1-3 (2005): 177–81. http://dx.doi.org/10.1016/j.molstruc.2005.03.006.

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17

Bruce, Michael I., Marie P. Cifuentes, and Mark G. Humphrey. "Ruthenium clusters containing N-donor ligands." Polyhedron 10, no. 3 (1991): 277–322. http://dx.doi.org/10.1016/s0277-5387(00)80150-3.

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18

Kerpal, Christian, Dan J. Harding, Jonathan T. Lyon, Gerard Meijer, and André Fielicke. "N2 Activation by Neutral Ruthenium Clusters." Journal of Physical Chemistry C 117, no. 23 (2013): 12153–58. http://dx.doi.org/10.1021/jp401876b.

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19

Basu, Amitabha, Sumit Bhaduri, and Hanif Khwaja. "Carbonylation of nitrobenzene with ruthenium clusters." Journal of Organometallic Chemistry 319, no. 2 (1987): C28—C30. http://dx.doi.org/10.1016/0022-328x(87)83037-1.

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20

Bag, Ranjit, Bijan Mondal, K. Bakthavachalam, Thierry Roisnel, and Sundargopal Ghosh. "Heterometallic boride clusters: synthesis and characterization of butterfly and square pyramidal boride clusters*." Pure and Applied Chemistry 90, no. 4 (2018): 665–75. http://dx.doi.org/10.1515/pac-2017-1001.

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AbstractA number of heterometallic boride clusters have been synthesized and structurally characterized using various spectroscopic and crystallographic analyses. Thermolysis of [Ru3(CO)12] with [Cp*WH3(B4H8)] (1) yielded [{Cp*W(CO)2}2(μ4-B){Ru(CO)3}2(μ-H)] (2), [{Cp*W(CO)2}2(μ5-B){Ru(CO)3}2{Ru(CO)2}(μ-H)] (3), [{Cp*W(CO)2}(μ5-B){Ru(CO)3}4] (4) and a ditungstaborane cluster [(Cp*W)2B4H8Ru(CO)3] (5) (Cp*=η5-C5Me5). Compound2contains 62 cluster valence-electrons, in which the boron atom occupies the semi-interstitial position of a M4-butterfly core, composed of two tungsten and two ruthenium ato

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21

Soini, Thomas M., Xiufang Ma, Olcay Üzengi Aktürk, Suwit Suthirakun, Alexander Genest, and Notker Rösch. "Extending the cluster scaling technique to ruthenium clusters with hcp structures." Surface Science 643 (January 2016): 156–63. http://dx.doi.org/10.1016/j.susc.2015.06.020.

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22

Reinholdt, Anders, Konrad Herbst, and Jesper Bendix. "Delivering carbide ligands to sulfide-rich clusters." Chemical Communications 52, no. 10 (2016): 2015–18. http://dx.doi.org/10.1039/c5cc08918b.

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The propensity of the terminal ruthenium carbide Ru(C)Cl<sub>2</sub>(PCy<sub>3</sub>)<sub>2</sub> (RuC) to form carbide bridges to electron-rich transition metals enables synthetic routes to metal clusters with coexisting carbide and sulfide ligands.

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23

Zhang, Wenqin, Haitao Zhao, and Lichang Wang. "The Simple Cubic Structure of Ruthenium Clusters." Journal of Physical Chemistry B 108, no. 7 (2004): 2140–47. http://dx.doi.org/10.1021/jp035995x.

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24

Sappa, Enrico. "Reactions of ruthenium carbonyl clusters with alkynes." Journal of Cluster Science 5, no. 2 (1994): 211–63. http://dx.doi.org/10.1007/bf01170711.

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25

Braga, Dario, Fabrizia Grepioni, Brian F. G. Johnson, et al. "Trinuclear benzene clusters of ruthenium and osmium." Journal of the Chemical Society, Dalton Transactions, no. 5 (1992): 807. http://dx.doi.org/10.1039/dt9920000807.

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26

Kaiming, Deng, Yang Jinlong, Xiao Chuanyun, and Wang Kelin. "Electronic properties and magnetism of ruthenium clusters." Physical Review B 54, no. 3 (1996): 2191–97. http://dx.doi.org/10.1103/physrevb.54.2191.

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27

Bates, Richard S., and Anthony H. Wright. "Ruthenium–arene complexes and clusters via ultrasound." J. Chem. Soc., Chem. Commun., no. 16 (1990): 1129–31. http://dx.doi.org/10.1039/c39900001129.

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28

Bruce, Michael I., Paul A. Humphrey, Brian W. Skelton, and Allan H. White. "Acetylenic Phosphines Bridging Two Cluster Units: Molecular Structure of {Ru3(µ-H)(µ3-C2But )(CO)8}2(µ-dppa)[dppa =C2(PPh2)2]." Australian Journal of Chemistry 50, no. 6 (1997): 535. http://dx.doi.org/10.1071/c97008.

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The syntheses of two complexes consisting of two Ru3(µ-H)(µ3-C2But)(CO)8 clusters bridged by acetylenic ditertiary phosphines, C2(PR2)2 [R = Ph (3), Bun (4)], are described. The molecular structure of (3) confirms that substitution of the cluster at the ruthenium which is σ bonded to the acetylide has occurred. The structural parameters closely resemble those of Ru3(µ−H)(µ3-C2But)(CO)8(L) [L = CO, PPh2(OEt)].

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29

Konoplev, Vitalii E., Maxim V. Tachev, and Elena A. Ulyukina. ""POLYHEDRAL CONTRACTION" OF TETRAMETHYLAMMONIUM CLOSO-CARBOUNDECABORATE UNDER ACTION OF TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM DICHLORIDE." IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA KHIMICHESKAYA TEKHNOLOGIYA 63, no. 5 (2020): 26–32. http://dx.doi.org/10.6060/ivkkt.20206305.6146.

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In this paper the objectives were not only to investigate new promising methods leading to a deep structural rearrangement of carboranes and metallacarboranes but also to try to fix, to isolate and to characterize the intermediates. At the same time considerable attention is paid to the so-called "anti-wade" clusters formed during the reactions, the electronic structure of which does not correspond to their actually observed geometry. It is shown that the interaction of 11-vertex monocarbon closo-carboundecaborane with tris(triphenylphosphine)ruthenium dichloride leads to a series of new metal

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30

Kameo, Hajime, Yutaka Ito, Ryuichi Shimogawa, et al. "Synthesis and characterisation of tetranuclear ruthenium polyhydrido clusters with pseudo-tetrahedral geometry." Dalton Transactions 46, no. 17 (2017): 5631–43. http://dx.doi.org/10.1039/c6dt04523e.

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31

Lang, Sandra M., Thorsten M. Bernhardt, Marjan Krstić, and Vlasta Bonačić-Koutecký. "Water activation by small free ruthenium oxide clusters." Phys. Chem. Chem. Phys. 16, no. 48 (2014): 26578–83. http://dx.doi.org/10.1039/c4cp02366h.

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32

Li, Ying-Zhou, and Weng Kee Leong. "Raft-like osmium- and ruthenium-antimony carbonyl clusters." Journal of Organometallic Chemistry 812 (June 2016): 217–25. http://dx.doi.org/10.1016/j.jorganchem.2015.06.007.

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33

Das, Birinchi K., and Mercouri G. Kanatzidis. "Methanothermal synthesis of polynuclear ruthenium telluride carbonyl clusters." Polyhedron 16, no. 17 (1997): 3061–66. http://dx.doi.org/10.1016/s0277-5387(97)00018-1.

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34

Rosenberg, Edward, David Ryckman, I. Nan Hsu, and Robert W. Gellert. "Reactivity of trinuclear ruthenium clusters with mercury halides." Inorganic Chemistry 25, no. 2 (1986): 194–99. http://dx.doi.org/10.1021/ic00222a021.

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35

Fontal, Bernardo, Marisela Reyes, Trino Suárez, Fernando Bellandi, and Juan Carlos Dı́az. "Catalytic studies with ruthenium clusters substituted with diphosphines." Journal of Molecular Catalysis A: Chemical 149, no. 1-2 (1999): 75–85. http://dx.doi.org/10.1016/s1381-1169(99)00195-8.

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36

Fontal, Bernardo, Marisela Reyes, Trino Suárez, Fernando Bellandi, and Nestor Ruiz. "Catalytic studies with ruthenium clusters substituted with diphosphines." Journal of Molecular Catalysis A: Chemical 149, no. 1-2 (1999): 87–97. http://dx.doi.org/10.1016/s1381-1169(99)00196-x.

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37

Bruce, Michael I. "Pentanuclear ruthenium clusters containing C2 and related ligands." Journal of Cluster Science 8, no. 3 (1997): 293–327. http://dx.doi.org/10.1007/bf02764111.

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38

Galsworthy, Jane R., Catherine E. Housecroft, Dorn M. Nixon та Arnold L. Rheingold. "Ruthenium butterfly boride clusters with (η6-arene) ligands". Journal of Organometallic Chemistry 531, № 1-2 (1997): 165–70. http://dx.doi.org/10.1016/s0022-328x(96)06706-x.

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39

Räsänen, Tiina M., Sirpa Jääskeläinen, and Tapani A. Pakkanen. "Heteroligand substitution in clusters of ruthenium and cobalt." Journal of Organometallic Chemistry 553, no. 1-2 (1998): 453–61. http://dx.doi.org/10.1016/s0022-328x(97)00594-9.

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40

Arce, Alejandro J., Pilar Arrojo, Antony J. Deeming, and Ysaura De Sanctis. "Dalton communications. Desulfurization of thiophenes with ruthenium clusters." Journal of the Chemical Society, Dalton Transactions, no. 15 (1992): 2423. http://dx.doi.org/10.1039/dt9920002423.

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41

Ge, Gui-Xian, Hong-Xia Yan, Qun Jing, and You-Hua Luo. "Theoretical Study of Hydrogen Adsorption on Ruthenium Clusters." Journal of Cluster Science 22, no. 3 (2011): 473–89. http://dx.doi.org/10.1007/s10876-011-0395-1.

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42

BRUCE, M. I., M. P. CIFUENTES, and M. G. HUMPHREY. "ChemInform Abstract: Ruthenium Clusters Containing N-Donor Ligands." ChemInform 22, no. 23 (2010): no. http://dx.doi.org/10.1002/chin.199123280.

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43

Adams, Richard D., and Miklos Tasi. "Synthesis and reactivity of sulfido ruthenium carbonyl clusters." Journal of Cluster Science 1, no. 3 (1990): 249–67. http://dx.doi.org/10.1007/bf00702744.

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44

S�ss-Fink, Georg, Ulf Bodensieck, Lisa Hoferkamp, Gerd Rheinwald, and Helen Stoeckli-Evans. "Multicenter ligand transformations of thioureas on ruthenium clusters." Journal of Cluster Science 3, no. 4 (1992): 469–78. http://dx.doi.org/10.1007/bf00702752.

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45

IZUMI, Y., and Y. IWASAWA. "ChemInform Abstract: CO-Breathing Ruthenium and Rhodium Clusters." ChemInform 25, no. 49 (2010): no. http://dx.doi.org/10.1002/chin.199449295.

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46

Li, Ying-Zhou, Rakesh Ganguly, Weng Kee Leong, and Yang Liu. "Synthesis and Reactivity of Ruthenium-Antimony Carbonyl Clusters." European Journal of Inorganic Chemistry 2015, no. 23 (2015): 3861–72. http://dx.doi.org/10.1002/ejic.201500522.

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47

VRIEZE, K., and C. J. ELSEVIER. "ChemInform Abstract: Reactions and Dynamics of Ruthenium Clusters." ChemInform 27, no. 20 (2010): no. http://dx.doi.org/10.1002/chin.199620237.

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48

ARCE, A. J., P. ARROJO, A. J. DEEMING, and Y. DE SANCTIS. "ChemInform Abstract: Desulfurization of Thiophenes with Ruthenium Clusters." ChemInform 23, no. 47 (2010): no. http://dx.doi.org/10.1002/chin.199247120.

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49

Randles, Michael D., Marie P. Cifuentes, Graeme J. Moxey, Achim Zahl, Rudi van Eldik, and Mark G. Humphrey. "High-nuclearity ruthenium carbonyl cluster chemistry. 9. Ligand substitution at decaruthenium carbonyl clusters." Journal of Organometallic Chemistry 849-850 (November 2017): 63–70. http://dx.doi.org/10.1016/j.jorganchem.2017.05.026.

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50

Dyson, Paul J., Brian F. G. Johnson, and Caroline M. Martin. "Ruthenium clusters containing the [2.2] paracyclophane ligand: Recent developments in arene-cluster chemistry." Journal of Cluster Science 6, no. 1 (1995): 21–37. http://dx.doi.org/10.1007/bf01175834.

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