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Dissertations / Theses on the topic 'Ruthenium compounds'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 July 2025

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1

Almodares, Zahra. "Ruthenium compounds as anti-tumour agents." Thesis, University of Leeds, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.531426.

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2

Orenha, Renato Pereira. "Computational study of ruthenium-nitrosyl compounds." Universidade de São Paulo, 2017. http://www.teses.usp.br/teses/disponiveis/59/59138/tde-08062017-141410/.

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The discovery of the chemical properties related to the physiological and pathophysiological processes of the nitric oxide molecule has advanced scientific research concerning the control of NO availability in the biological environment. Complexes involving ruthenium and other ligands, such as amine and tetraazomacrocycles, have been used as models because they display properties like stability to air oxidation, solubility in water, and low cytotoxicity against host cells. Given the peculiar properties of nitric oxide, we first conducted a computational experiment based on the molecular orbita

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3

Haire, Geoffrey Robert. "Ruthenium catalysed oxidation of organic compounds." Thesis, University of Cambridge, 1994. https://www.repository.cam.ac.uk/handle/1810/272775.

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4

Liang, Jianglin, and 梁江林. "Ruthenium-catalyzed carbon-nitrogen bond formations." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2003. http://hub.hku.hk/bib/B31245729.

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5

劉純晶 and Chunjing Liu. "Nonplanar and sterically encumbered ruthenium porphyrins and catalyticreactivity of ruthenium and manganese porphyrin complexes supported onMCM-41." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1998. http://hub.hku.hk/bib/B31237423.

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6

楊志雄 and Chi-hung Yeung. "Organic oxidation catalysed by ruthenium and manganese macrocycles." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1993. http://hub.hku.hk/bib/B31233971.

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7

Yeung, Chi-hung. "Organic oxidation catalysed by ruthenium and manganese macrocycles /." [Hong Kong : University of Hong Kong], 1993. http://sunzi.lib.hku.hk/hkuto/record.jsp?B13883896.

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8

Wong, Kwok-ming, and 黃國明. "Ruthenium-nitrogen and ruthenium-phosphorus multiple bonds supported by phthalocyanines: syntheses, spectroscopicproperties, and reactivities." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2010. http://hub.hku.hk/bib/B45545893.

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9

Park, Sunghan. "Planar chiral arene ruthenium complexes." Thesis, Canberra, ACT : The Australian National University, 1993. http://hdl.handle.net/1885/140056.

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10

Liu, Chunjing. "Nonplanar and sterically encumbered ruthenium porphyrins and catalytic reactivity of ruthenium and manganese porphyrin complexes supported on MCM-41 /." Hong Kong : University of Hong Kong, 1998. http://sunzi.lib.hku.hk/hkuto/record.jsp?B19737518.

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11

Luther, Thomas Alan. "Dicationic dihydrogen complexes of osmium and ruthenium /." Thesis, Connect to this title online; UW restricted, 1997. http://hdl.handle.net/1773/11540.

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12

Choi, Kwok-wai Matthew, and 蔡國偉. "Carbenoid transfer reactions catalyzed by arene ruthenium complexes and polymer supported ruthenium catalysts." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2008. http://hub.hku.hk/bib/B4088773X.

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13

Choi, Kwok-wai Matthew. "Carbenoid transfer reactions catalyzed by arene ruthenium complexes and polymer supported ruthenium catalysts." Click to view the E-thesis via HKUTO, 2008. http://sunzi.lib.hku.hk/hkuto/record/B4088773X.

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14

Van, Aswegen Werner. "The kinetics and associated reactions of ruthenium(VIII)." Thesis, Nelson Mandela Metropolitan University, 2009. http://hdl.handle.net/10948/1130.

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This study investigated the reduction reaction of ruthenium tetroxide by various aliphatic alcohols in acidic medium. UV-Vis spectroscopy still plays an essential role in the analysis and study of volatile ruthenium tetroxide and was used in this study to collect kinetic data. This data was analyzed using graphical and computational methods, such as Mauser diagrams and kinetic simulation software. From the results obtained it is proposed that the reaction occurs by the following two-step reaction model: Ru(VIII) k1 Ru(VI) Ru(VI) k2 k-2 Ru(III) Molar extinction coefficients and conditional rate

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15

Moritz, Paul Stuart. "Substitution and redox chemistry of ruthenium complexes /." Title page, contents and summary only, 1987. http://web4.library.adelaide.edu.au/theses/09PH/09phm862.pdf.

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16

Lam, Ngai Man. "Synthesis, crystal structures, and reactivity of ruthenium and osmium nitrido complexes /." View abstract or full-text, 2006. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202006%20LAMN.

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17

Cheung, Ka Man. "Syntheses and reactivity of cyclometalated iridium and ruthenium complexes /." View abstract or full-text, 2005. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202005%20CHEUNG.

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18

Yau, Benita Chui Kam. "Organometallic chemistry of phosphine complexes of iron and ruthenium." Thesis, The University of Sydney, 1992. https://hdl.handle.net/2123/26717.

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This thesis describes two projects involving the organometallic chemistry of iron and ruthenium complexes with DMPE ligands [DMPE = 1,2-bis(dimethylphosphino)ethane]. The first study involves an investigation into the kinetics and mechanisms of OH bond activation reactions of [Fe(DMPE)2]. The second project involves an investigation into the synthesis of RuH2(DMPE)2, the formation and properties of trans-[RuH(n2-H2)(DMPE)2]*, and the reactions of RuH2(DMPE)2 with alkyl and aryl thiols. In Part I of this work, the kinetics of the cis/trans isomerization of FeH(C6H5)(DMPE)2 and FeD(C6D5)(DMPE

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19

Jessop, Philip Gregory. "The syntheses and reactions of carbonyl(phosphine)(thiolator)ruthenium(II) complexes." Thesis, University of British Columbia, 1991. http://hdl.handle.net/2429/30928.

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The chemistry of homogeneous transition metal systems offer parallels to the reactions on the surfaces of industrial hydrodesulphurization catalysts. The reactions of several ruthenium complexes with sulphur-containing reagents are described, with an emphasis on the kinetics and mechanisms thereof. The complex Ru(CO)₂(PPh₃)₃ (2), for example, reacts quickly with thiols and disulphides, producing cct-RuH(SR)(CO)₂(PPh₃)₂ (9) and cct-Ru(SR)₂(CO)₂(PPh₃)₂ (14), respectively, although 2 fails to react with unstrained thioethers. Reactions of the related complex Ru(CO)₂(PPh₃)(dpm) (dpm=Ph₂PCH₂PPh₂) a

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20

Sishta, Chand. "The coordination chemistry of ruthenium porphyrin complexes." Thesis, University of British Columbia, 1990. http://hdl.handle.net/2429/30790.

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This thesis work reports developments in the coordination chemistry of ruthenium porphyrin complexes, both in terms of the synthesis and chemistry of new compounds, as well as the study of the solution chemistry of some previously reported complexes. The synthesis, characterization and chemistry of ten new Ru(porp) coordination complexes in the oxidation states Ru[superscript]Ⅲ and Ru[superscript]Ⅳ containing halide (Br, CI) and other axial ligands (pyridine, CH₃CN, NH₃ and SbF₆) are described in this thesis. Some additional ten Ru(porp) complexes have been studied in situ. Measurement of the

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21

Lai, Chui Ying. "Ruthenium complexes with thiolate and sulfoxide ligands /." View Abstract or Full-Text, 2002. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202002%20LAI.

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Thesis (M. Phil.)--Hong Kong University of Science and Technology, 2002.<br>Includes bibliographical references (leaves 135-146). Also available in electronic version. Access restricted to campus users.

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22

Hampton, Cashman Roger Stirling Mason. "Hydrogen and methanol activation by some tertiary phosphine ruthenium complexes." Thesis, University of British Columbia, 1989. http://hdl.handle.net/2429/29763.

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The previously known complexes, RU₂H₄Cl₂(PR₃)₄, have now been correctly reformulated as the η²-H₂ species (η²-H₂)(PR₃)₂Ru(μ-Cl)₂(μ-H)RuH(PR₃)₂ (R = Ph, p-tol), 1a and 1b, and it is confirmed that in solution they are dimeric and undergo no ligand dissociation. Also, a new analogue of complexes of type 1 is reported: the complex (η²-H₂)(isoPFA)Ru(μ-Cl)₂(μ-H)RuH(PPh₃)₂,4, is formed from the reaction of RuCl₂(PPh₃)(isoPFA), 3b, with H₂ in methanol/benzene, and a crystal structure of 4 shows the η²-H₂ ligand; isoPFA and PPFA (see below) are ferrocene based, chelating P-N ligands, with the structu

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23

Zheng, Sipeng. "The reactions of ruthenium (ii) polypyridyl complexes." Thesis, Nelson Mandela Metropolitan University, 2009. http://hdl.handle.net/10948/1089.

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Ruthenium (II) polypyridine complexes in general have been extensively studied because of their unique redox and photochemical properties. A typical example of such complexes is tris(2,2’-bipyridyl) ruthenium (II). In this study, this complex was synthesized and then characterized using electronic spectroscopy and cyclic voltammetry. It was also shown that the ruthenium concentration could be accurately determined using ICP-MS. It was found that the complex is very stable in various chemical environments. It was observed from spectrophotometric investigations that persulphate and lead dioxide

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24

Li, Yan, and 李艷. "Synthesis and reactivity of carbene complexes of iron, ruthenium and osmium porphyrins." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2004. http://hub.hku.hk/bib/B31245730.

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25

Lau, Sze-wai Cindy. "The chemistry of polynuclear ruthenium carbonyl clusters containing functionalised alkyne ligands /." Hong Kong : University of Hong Kong, 1999. http://sunzi.lib.hku.hk/hkuto/record.jsp?B21021442.

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26

Cheng, Kar-wai Anita. "Preparation, reactivities and oxidative catalytic activities of ruthenium(II) polypyridines, rhenium(I) carbonyl complexes and ruthenium-encapsulated meso- and micro-porous molecular sieves /." Hong Kong : University of Hong Kong, 1998. http://sunzi.lib.hku.hk/hkuto/record.jsp?B1973816X.

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27

Billah, Syed Abul Muzaddad Mustafij. "Half-sandwich indenyl and related compounds of ruthenium(II)." Thesis, University of Salford, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.262619.

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28

Delsorbo, Carter A., Annie B. McCullough, Pau Peiro'Vila, et al. "Ruthenium Compounds for Photodynamic Chemotherapeutics and Solar Fuel Generation." Digital Commons @ East Tennessee State University, 2019. https://dc.etsu.edu/asrf/2019/schedule/156.

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Ruthenium polypyridyl complexes have long been studied due to their unique photophysical characteristics and their synthetic accessibility. We report here the use of new ruthenium polypyridyl’s in photodynamic chemotherapeutic and solar fuel applications. Nearly half of all chemotherapeutics administered today are derived from platinum-based drugs (platins) which lack specificity and can cause sever side-effects. Photodynamic chemotherapeutics (PDT) circumvent these issues utilizing light activation at the site of cancerous cells to generate a cytotoxic Ru(II) center and eventually trigger cel

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29

Gamble, Aimee J. "Ruthenium(II) cis-triaminocyclohexane complexes as anti-cancer compounds." Thesis, University of York, 2012. http://etheses.whiterose.ac.uk/2909/.

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Ruthenium complexes are promising candidates for the treatment of cancers. Two ruthenium(III) complexes have previously completed phase I clinical trials and half-sandwich ruthenium(II) η6-arene complexes are receiving much interest as anti-cancer agents. A range of new ruthenium(II) complexes have been prepared with a κ3-N fac-coordinating six electron donor, cis-1,3,5-triaminocyclohexane (cis-tach), replacing the η6-arene ligand. It is hypothesised that the cis-tach ligand will allow highly active complexes with good water solubility. Initial access to ruthenium(II) cis-tach complexes was es

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30

Torabi, Ali Asghar. "X-ray studies on Pt/Re and other compounds." Thesis, University of Glasgow, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.307196.

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31

陳沛明 and Pui-ming Chan. "Reactivities of nitrido- and oxo-ruthenium(VI) and nitridoosmium(VI) complexes containing chelating multianionic ligands and 1,4,7-trimethyl-1,4,7-triazacyclonoane." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1999. http://hub.hku.hk/bib/B31238208.

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32

羅錦榮 and Kam-wing Kenneth Lo. "Luminescent copper (I) and rhenium (I) diimines, and coinage metal chalcogenides." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1996. http://hub.hku.hk/bib/B42128468.

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33

Lo, Kam-wing Kenneth. "Luminescent copper (I) and rhenium (I) diimines, and coinage metal chalcogenides." Click to view the E-thesis via HKUTO, 1996. http://sunzi.lib.hku.hk/hkuto/record/B42128468.

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34

Chan, Pui-ming. "Reactivities of nitrido- and oxo-ruthenium(VI) and nitridoosmium(VI) complexes containing chelating multianionic ligands and 1,4,7-trimethyl-1,4,7-triazacyclonoane /." Hong Kong : University of Hong Kong, 1999. http://sunzi.lib.hku.hk/hkuto/record.jsp?B21021405.

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35

Au, Sze-man Vanessa. "Synthesis, characterization and reactivities of bis(imido)-ruthenium(vi) and -osmium(vi) porphyrins /." Hong Kong : University of Hong Kong, 1999. http://sunzi.lib.hku.hk/hkuto/record.jsp?B21021478.

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36

Bryant, Jasmine R. "Mechanistic studies of the oxidations of hydrocarbons by manganese and ruthenium transition metal complexes /." Thesis, Connect to this title online; UW restricted, 2002. http://hdl.handle.net/1773/8586.

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37

Joshi, Ajey Madhav. "Activation of dihydrogen by ruthenium complexes containing chelating phosphines." Thesis, University of British Columbia, 1990. http://hdl.handle.net/2429/30822.

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The previously reported synthesis of dinuclear mixed-valence ruthenium complexes of general formula Ru₂Cl₅(P-P)₂, P-P = DPPP, DPPB, 5,5-CHIRAPHOS, or R.R-DIOP, has been extended to include other diphosphines: P-P = DPPN, DPPH, rac-DPPCP, rac-DPCYCP, S,S-BDPP, R- and S-BINAP, or S-PHENOP. The complexes are prepared by the reaction of RuCl₃P₂(DMA)-DMA, P = PPh₃ or P(p-tolyl)₃, with one equivalent of the appropriate diphosphine. The H₂-reduction of Ru₂Cl₅(P-P)₂ complexes in DMA, or in toluene in the presence of an added base, affords the corresponding dimeric Ru(II) complexes [RuCl(P-P)(µ-Cl)]₂,

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38

Hung, Wai Yiu. "Syntheses and reactivities of osmium and ruthenium complexes with metal-carbon triple bonds /." View abstract or full-text, 2006. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202006%20HUNG.

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39

劉思慧 and Sze-wai Cindy Lau. "The chemistry of polynuclear ruthenium carbonyl clusters containing functionalised alkyne ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1999. http://hub.hku.hk/bib/B31238786.

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40

梁嘉茵 and Ka-yan Sarana Leung. "Complexes of iminato, nitrido, imido, and hydrazido ruthenium of osmium porphyrins." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2002. http://hub.hku.hk/bib/B31243307.

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41

鄭永志 and Wing-chi Cheng. "Oxidation chemistry of mono-oxoruthenium (IV) and cis-dioxoruthenium (VI) complexes of 1,4,7 - trimethyl - 1,4,7 - triazacyclononane." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1995. http://hub.hku.hk/bib/B31234136.

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42

黃國賢 and Kwok-yin Wong. "Syntheses, reactivities and electrochemical studies of some high valent oxo complexes of ruthenium." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1986. http://hub.hku.hk/bib/B31230763.

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43

Chiu, Wing-hong. "Syntheses, reactivities and electrochemistry of high-valent amido, imido and nitrido complexes of ruthenium /." Hong Kong : University of Hong Kong, 1995. http://sunzi.lib.hku.hk/hkuto/record.jsp?B17538397.

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44

Cheng, Wing-chi. "Oxidation chemistry of mono-oxoruthenium (IV) and cis-dioxoruthenium (VI) complexes of 1,4,7 - trimethyl - 1,4,7 - triazacyclononane /." Hong Kong : University of Hong Kong, 1995. http://sunzi.lib.hku.hk/hkuto/record.jsp?B16504409.

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45

Wong, Kwok-yin. "Syntheses, reactivities and electrochemical studies of some high valent oxo complexes of ruthenium /." [Hong Kong : University of Hong Kong], 1986. http://sunzi.lib.hku.hk/hkuto/record.jsp?B12322623.

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46

Steiger, George Edward. "Synthesis and thermal decomposition of alkyl-olefin chelate complexes of iron and ruthenium." Diss., Georgia Institute of Technology, 1992. http://hdl.handle.net/1853/28052.

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47

Voelker, Dirk. "Interactions of Ruthenium Red with Phospholipid Vesicles." PDXScholar, 1994. https://pdxscholar.library.pdx.edu/open_access_etds/4881.

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We have studied the electrostatic and other interactions of the inorganic, hexavalent dye Ruthenium Red (RR) with phospholipid vesicles composed of phosphatidylcholine (PC) and phosphatidylserine (PS) or phosphatidylinositol (Pl) in various mixtures and concentrations. Experiments were based on spectrophotometric absorption measurements which compared RR concentrations in the presence and in the absence of liposomes at different dye concentrations. Multilamellar liposomes were obtained by handshaken preparations. Five freeze-and-thaw cycles of the lipid-RR suspension produced an ion equilibriu

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48

Ng, Fei-yeung. "Structure and properties of self-assembled coordination compounds : homoleptic d10-metal aryl/alkylacetylides, ruthenium n-heterocycles and picolinates." View the Table of Contents & Abstract, 2006. http://sunzi.lib.hku.hk/hkuto/record/B36587126.

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49

高寶鴻 and Po-hung Ko. "Syntheses, structures and reactivities of some ruthenium, manganese and osmium complexes of non-porphyrin chelating multi-anionic ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1997. http://hub.hku.hk/bib/B31235906.

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50

Ng, Fei-yeung, and 吳飛洋. "Structure and properties of self-assembled coordination compounds: homoleptic d10-metal aryl/alkylacetylides, ruthenium n-heterocyclesand picolinates." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2006. http://hub.hku.hk/bib/B37878566.

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