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Dissertations / Theses on the topic 'Ruthenium Metal Complexes'

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Published: 6 September 2023
Last updated: 31 July 2025

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1

Barthram, Anita Marie. "Metal-metal interactions in polynuclear complexes of ruthenium and osmium." Thesis, University of Bristol, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.326683.

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2

Greguric, Ivan. "Molecular recognition of DNA by metal co-ordination complexes /." [Campbelltown, N.S.W.] : University of Western Sydney, Macarthur, Faculty of Informatics, Science and Technology, 1999. http://library.uws.edu.au/adt-NUWS/public/adt-NUWS20030624.114833/index.html.

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3

Morewood, Catherine Alexandra. "π-complexes of osmium and ruthenium organometallic clusters". Thesis, University of Cambridge, 1995. https://www.repository.cam.ac.uk/handle/1810/272792.

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4

Luther, Thomas Alan. "Dicationic dihydrogen complexes of osmium and ruthenium /." Thesis, Connect to this title online; UW restricted, 1997. http://hdl.handle.net/1773/11540.

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5

Wong, Chun-yuen. "Ruthenium-carbon bonding interaction synthesis and spectroscopic studies of ruthenium-acetylide, -carbene, -vinylidene and -allenylidene complexes." Click to view the E-thesis via HKUTO, 2004. http://sunzi.lib.hku.hk/hkuto/record/B31040858.

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6

Stuart, Clare Anne. "Reactions of ruthenium(II) diphosphine complexes with silver(I) salts." Thesis, University of Liverpool, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.366948.

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7

Humphrey, Paul Andrew. "A study of transition metal complexes /." Title page, contents and summary only, 1990. http://web4.library.adelaide.edu.au/theses/09PH/09phh9262.pdf.

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8

Wong, Chun-yuen, and 黃駿弦. "Ruthenium-carbon bonding interaction synthesis and spectroscopic studies of ruthenium-acetylide, -carbene, -vinylidene and -allenylidene complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2004. http://hub.hku.hk/bib/B31040858.

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9

Vanover, Eric. "Photochemical Oxidation Studies of Porphyrin Ruthenium Complexes." TopSCHOLAR®, 2012. http://digitalcommons.wku.edu/theses/1201.

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In nature, transition metal containing enzymes display many biologically important, attractive and efficient catalytic oxidation reactions. Many transition metal catalysts have been designed to mimic the predominant oxidation catalysts in nature, namely, the cytochrome P450 enzymes. Ruthenium porphyrin complexes have been the center of this research and have successfully been utilized, as catalysts, in major oxidation reactions, such as the hydroxylation of alkanes. The present work focuses on photocatalytic studies of aerobic oxidation reactions with well characterized ruthenium porphyrin com
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10

Guest, Ruth Winifred. "Synthesis and reactions of iron and rutheniuim dinitrogen complexes." Connect to full text, 2008. http://ses.library.usyd.edu.au/handle/2123/3533.

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Thesis (Ph. D.)--University of Sydney, 2008.<br>Includes tables. Includes list of publications: leaves i-ii. Title from title screen (viewed October 30, 2008). Submitted in fulfilment of the requirements for the degree of Doctor of Philosophy to the School of Chemistry, Faculty of Science. Includes bibliographical references. Also available in print form.
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11

Lugan, Noël. "Clusters du ruthenium a ligands assembleurs : stabilite, reactivite." Toulouse 3, 1987. http://www.theses.fr/1987TOU30156.

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Etude de la reactivite d'agregats derives de ru::(3)(co)::(12) stabilises par des coordinats polydentes phosphores et/ou azotes, en vue d'application en catalyse homogene. Les coordinats assembleurs sont appm et diphenylpyridylphosphine. On etudie egalement la reactivite des complexes a coordinats acyle ru::(3)(co)::(9)(c(o) (c::(6)h::(5))) (p(c::(6)h::(5)) (c::(5)h::(4)n))
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12

Chan, Ka-ho, and 陳嘉豪. "Ruthenium-N-heterocyclic carbene and ruthenium acetylide complexes supported by macrocyclic porphyrin or tetradentate schiff base ligands : synthesis, structure and catalytic applications." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2015. http://hdl.handle.net/10722/211130.

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13

Xie, Jin. "Synthesis, structures and spectroscopic properties of primary and secondary phosphine complexes of iron, ruthenium and osmium porphyrins." Click to view the E-thesis via HKUTO, 2007. http://sunzi.lib.hku.hk/HKUTO/record/B39556876.

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14

Page, Simon Matthew. "Ruthenium anticancer complexes : a targeted approach to enzyme inhibition." Thesis, University of Cambridge, 2013. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.608027.

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15

Ono, Takashi. "Second-Row Transition-Metal Complexes Relevant to CO2." Doctoral thesis, Universitat Rovira i Virgili, 2014. http://hdl.handle.net/10803/276964.

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dinucleares de rutenio que contienen ligandospolypyridyl. Estos complejos se han aplicado para las reacciones catalíticas, tales como la reducción de CO2 y la oxidación del agua y sustrato orgánico. En la primera, las actividades catalíticas hacia la reducción de CO2 se han investigado desde el punto de vista de las propiedades electrónicas y estéricas de los catalizadores, así como su nuclearidad. En el segundo, la aplicación de mono-y dinucleares complejos de Ru-aqua que contienen ligando tridentadoaniónico hacia reacción de oxidación se ha estudiado. Además, una reactividad potencial de dia
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16

Walters, Stephen John. "Acyl(oxy) carbene and vinylidene chemistry of iron and ruthenium half-sandwich complexes." Thesis, University of Sheffield, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.245691.

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17

Xie, Jin, and 解錦. "Synthesis, structures and spectroscopic properties of primary and secondary phosphine complexes of iron, ruthenium and osmiumporphyrins." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2007. http://hub.hku.hk/bib/B39556876.

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18

Chambron, Jean-Claude. "Synthese et etude de complexes du cuivre (i) et du ruthenium (ii) en vue de la separation intramoleculaire des charges photoinduites." Université Louis Pasteur (Strasbourg) (1971-2008), 1986. http://www.theses.fr/1986STR13092.

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Preparation de 2 macrocycles contenant a la fois des sites chelatants diphenyl-2,9 phenanthroline-1,10 et dialkyl-4,4' ou diaryl-4,4' bipyridine-2,2'. Dans le complexe heterodinucleaire il existe une interaction a l'etat excite entre les 2 metaux
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19

Chen, Jun. "Transition Metal Complexes of Nucleosides for Cancer Chemotherapy." University of Dayton / OhioLINK, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=dayton1461516224.

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20

何毅雯 and Ngai-man Emmie Ho. "The chemistry of ruthenium carbonyl clusters containing nitrene and nitrido ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2000. http://hub.hku.hk/bib/B3124029X.

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21

Ho, Ngai-man Emmie. "The chemistry of ruthenium carbonyl clusters containing nitrene and nitrido ligands /." Hong Kong : University of Hong Kong, 2000. http://sunzi.lib.hku.hk/hkuto/record.jsp?B21982351.

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22

Ke, Mingzhe. "Synthesis, characterization and reactivity of ruthenium porphyrin complexes containing metal-carbon bonds." Thesis, University of British Columbia, 1988. http://hdl.handle.net/2429/29126.

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The thesis describes developments in the organometallic chemistry of ruthenium porphyrin complexes, particularly their preparation, characterization and reactivity. Treatment of paramagnetic Ru(rV)(porp)Br₂ species, prepared via the interaction of [Ru(porp)]₂ with HBr in CH₂CI₂, with organolithiums or Grignard reagents yields the corresponding diamagnetic Ru(IV) complexes Ru(porp)R₂, where porp = the 2,3,7,8,12,13,17,18-octaethylporphyrinato dianion(OEP): R = Ph, m-MeC₆H₄, p-MeC₆H₄, p-MeOC₆H₄, p-FC₆H₄, Me, Et; and porp = the 5,10,15,20-tetraphenylporphyrinato dianion(TPP): R = Ph. The spectra
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23

Johnson, David. "A computational study of ruthenium metal vinylidene complexes : novel mechanisms and catalysis." Thesis, University of York, 2013. http://etheses.whiterose.ac.uk/6170/.

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A theoretical investigation into several reactions is reported, centred around the chemistry, formation, and reactivity of ruthenium vinylidene complexes. The first reaction discussed involves the formation of a vinylidene ligand through non-innocent ligand-mediated alkyne-vinylidene tautomerization (via the LAPS mechanism), where the coordinated acetate group acts as a proton shuttle allowing rapid formation of vinylidene under mild conditions. The reaction of hydroxy-vinylidene complexes is also studied, where formation of a carbonyl complex and free ethene was shown to involve nucleophilic
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24

Faulkner, Charlotte Waveney. "A study of some ruthenium(II) and manganese(I) acetylide and vinylidene complexes." Thesis, University of Cambridge, 1994. https://www.repository.cam.ac.uk/handle/1810/272793.

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25

Simpson, Naomi Rosalind Mary. "The supramolecular photochemistry of precious metal #alpha#,#alpha#'-diimine complexes." Thesis, University of Bristol, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.368205.

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26

Greguric, Ivan. "Molecular recognition of DNA by metal co-ordination complexes." Thesis, [Campbelltown, N.S.W.] : University of Western Sydney, Macarthur, Faculty of Informatics, Science and Technology, 1999. http://handle.uws.edu.au:8081/1959.7/328.

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This thesis reports the design, synthesis, optical resolution of polypyridyl metal complexes and their molecular recognition of DNA. These metal complexes have been synthesised to bind DNA intercalation in a sequence selective manner. Modifications have manipulated the intercalative segments to bind to DNA in a rigid fashion by appending chemical groups directly to the aromatic extensions of the fragment. Also the ancillary non-intercalative ligands comprised of either bidentates or tetradentates, have been specifically chosen to deliver appended groups along the DNA sugar phosphate backbone,
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27

Zapiter, Joan Marie Diangson. "Transition Metal Complexes Anchored on Europium Oxide Nanoparticles." Thesis, Virginia Tech, 2014. http://hdl.handle.net/10919/24786.

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Polypyridyl transition metal complexes containing ruthenium, rhodium and iridium centers are mainly studied due to their light absorbing and emitting properties. Lanthanide oxides such as europium oxide absorb light as well and exhibit strong luminescence and long lifetimes. The optical properties of these materials were significant especially in solar energy utilization schemes and optical applications. Energy transfer across a surface is important in several applications including phosphors and biomedical applications. Excited states of metal complexes with a carboxylate-containing ligand su
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28

Huang, Xin. "Theoretical studies on transition metal mediated reactions /." View abstract or full-text, 2004. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202004%20HUANG.

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29

Hung, Wai Yiu. "Syntheses and reactivities of osmium and ruthenium complexes with metal-carbon triple bonds /." View abstract or full-text, 2006. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202006%20HUNG.

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30

Norman, Julia. "Investigating Peptide Conjugation for the Selective Activation of Metal Complexes in Tumours." Thesis, The University of Sydney, 2013. http://hdl.handle.net/2123/9506.

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There are various strategies in the treatment of cancer including surgical excision, radiotherapy, chemotherapy and immunotherapy. Chemotherapy offers the distinct advantage of systemic distribution, with the potential to reach primary tumours as well as metastases. A significant drawback of the vast majority of chemotherapeutic agents is their lack of specificity for cancer cells as well as poor tumour penetration, meaning that cells distal to blood vessels receive an inadequate dose and remain viable. There is an imperative need for the development of anti-tumour drugs which exhibit good tum
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31

Zhu, Jun. "Theoretical studies on bonding in platinum boryl and metallabenzene complexes and mechanisms of ruthenium/osmium mediated allene insertion reactions and molybdenum/tungsten catalyzed alkyne metathesis /." View abstract or full-text, 2007. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202007%20ZHU.

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32

Bryant, Jasmine R. "Mechanistic studies of the oxidations of hydrocarbons by manganese and ruthenium transition metal complexes /." Thesis, Connect to this title online; UW restricted, 2002. http://hdl.handle.net/1773/8586.

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33

Ko, Chi-chiu. "Design, synthesis and studies of novel classes of photochromic spirooxazine and diarylethene ligands and their metal-to-ligand charge transfer complexes." Click to view the E-thesis via HKUTO, 2003. http://sunzi.lib.hku.hk/hkuto/record/B43895311.

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34

Wang, Haitao. "Synthesis and bio-applications of luminescent iridium (III) and ruthenium (II) bipyridine complexes." HKBU Institutional Repository, 2020. https://repository.hkbu.edu.hk/etd_oa/831.

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This thesis is based on the past three years of research work including synthesis, characterization of three series of iridium(III) complexes and one series of ruthenium(II) complexes, and their comparative bio-applications of DNA-binding, cell morphology, cytotoxicity, mitochondrial membrane potential, cellular uptake and distribution. Chapter 1 introduces the background and recent studies of transition-metal complexes as biosensors and anti-tumor medicines. Their structure related properties of cytotoxicities, cellular uptake and distributions were also discussed. In chapter 2, five iridium(
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35

鄧煒堂 and Wai-tong Tang. "Homogeneous oxidation of organic substrates by ruthenium, iron and manganese tertiary amine complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1989. http://hub.hku.hk/bib/B31231706.

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36

Tang, Wai-tong. "Homogeneous oxidation of organic substrates by ruthenium, iron and manganese tertiary amine complexes /." [Hong Kong : University of Hong Kong], 1989. http://sunzi.lib.hku.hk/hkuto/record.jsp?B12355203.

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37

Greguric, Antun, University of Western Sydney, of Science Technology and Environment College, and of Science Food and Horticulture School. "The DNA binding interactions of Ru(II) polypyridyl complexes." THESIS_CSTE_SFH_Greguric_A.xml, 2002. http://handle.uws.edu.au:8081/1959.7/620.

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This thesis reports on the synthesis, characterisation, enantiomeric resolution, 1H NMR structural study and physical evaluation of a series of certain bidentate ligand metal complexes, where ‘L-L’ denotes the ancillary bidentate ligand and ‘intercalator’ indicates the intercalating bidentate ligand. The L-L series varies in size and shape. Results of many tests and projects conducted are explained in detail.<br>Master of Science (Hons)
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38

Leung, Hoi-Yan. "Catalytic properties of transition metal complexes with [beta]-cyclodextrin-functionalized phosphine ligands and oligomerization of alkynes with ruthenium complexes /." View abstract or full-text, 2004. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202004%20LEUNG.

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39

Ruan, Zhixiong. "C−H Alkylations and Alkynylations Using Ruthenium, Nickel and Manganese Complexes." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2017. http://hdl.handle.net/11858/00-1735-0000-0023-3F33-6.

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40

張碧玉 and Pik-yuk Christine Cheung. "Crystal structure analysis of imido, nitrido and oxo complexes of rhenium (V), osmium (VI) and ruthenium (III) and some complexes oftrinuclear gold (I)." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1991. http://hub.hku.hk/bib/B31210211.

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41

Mellows, Heather. "Synthesis and properties of two fold symmetric ruthenium and rhodium dihydrogen-hydride complexes /." Thesis, Connect to this title online; UW restricted, 2000. http://hdl.handle.net/1773/8598.

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42

Cheung, Pik-yuk Christine. "Crystal structure analysis of imido, nitrido and oxo complexes of rhenium (V), osmium (VI) and ruthenium (III) and some complexes of trinuclear gold (I) /." [Hong Kong : University of Hong Kong], 1991. http://sunzi.lib.hku.hk/hkuto/record.jsp?B13138327.

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43

Wang, Haitao. "Synthesis and bio-applications of luminescent iridium (III) and rutherium (II) bipyridine complexes." HKBU Institutional Repository, 2020. https://repository.hkbu.edu.hk/etd_oa/774.

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This thesis is based on the past three years of research work including synthesis, characterization of three series of iridium(III) complexes and one series of ruthenium(II) complexes, and their comparative bio-applications of DNA-binding, cell morphology, cytotoxicity, mitochondrial membrane potential, cellular uptake and distribution. Chapter 1 introduces the background and recent studies of transition-metal complexes as biosensors and anti-tumor medicines. Their structure related properties of cytotoxicities, cellular uptake and distributions were also discussed. In chapter 2, five iridium
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44

Huang, Yan. "Synthesis, Kinetic and Photocatalytic Studies of Porphyrin-Ruthenium-Oxo Complexes." TopSCHOLAR®, 2010. http://digitalcommons.wku.edu/theses/182.

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Macrocyclic ligand-complexed transition metal-oxo intermediates are the active oxidizing species in a variety of important biological and catalytic oxidation reactions. Many transition metal catalysts have been designed to mimic the predominant oxidation catalysts in Nature, namely the cytochrome P450 enzymes. Ruthenium porphyrin complexes have been the center of the research and have successfully been utilized, as catalysts, in major oxidation reactions such as the hydroxylation of alkanes. This study focuses on kinetic and photocatalytic studies of oxidation reactions with wellcharacterized
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45

Polapally, Mamatha. "Synthesis,Structure and Properties of Ruthenium Polypyridyl Metalloligand Based Metal-Organic Frameworks." TopSCHOLAR®, 2017. https://digitalcommons.wku.edu/theses/2035.

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Metal-organic frameworks (MOFs) have been extensively studied because of their amazing applications in gas storage, purification, photocatalysis, chemical sensing, and imaging techniques. Ruthenium polypyridyl complexes have been broadly considered as photosensitizers for the conversion of solar energy and photoelectronic materials. With this aspect, we have synthesized three new ruthenium polypyridyl based MOFs ([Ru(H2bpc)Cu(bpc)(Hbpc)2(H2O)]·5H2O (1), [Ru(H2bpc)(Fe(bpc)(Hbpc)2(H2O)2]·6H2O (2) and [Ru(H2bpc)Ni(bpc)(Hbpc)2(H2O)2]·6H2O (3)) from ruthenium(III) chloride, bpc (2,2’- bipyridine-4,
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46

Greguric, Ivan, University of Western Sydney, and of Informatics Science and Technology Faculty. "Molecular recognition of DNA by metal co-ordination complexes." THESIS_FIST_XXX_Greguric_I.xml, 1999. http://handle.uws.edu.au:8081/1959.7/328.

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This thesis reports the design, synthesis, optical resolution of polypyridyl metal complexes and their molecular recognition of DNA. These metal complexes have been synthesised to bind DNA intercalation in a sequence selective manner. Modifications have manipulated the intercalative segments to bind to DNA in a rigid fashion by appending chemical groups directly to the aromatic extensions of the fragment. Also the ancillary non-intercalative ligands comprised of either bidentates or tetradentates, have been specifically chosen to deliver appended groups along the DNA sugar phosphate backbone,
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47

Greguric, Antun. "The DNA binding interactions of Ru(II) polypyridyl complexes." Thesis, View thesis View thesis, 2002. http://handle.uws.edu.au:8081/1959.7/620.

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This thesis reports on the synthesis, characterisation, enantiomeric resolution, 1H NMR structural study and physical evaluation of a series of certain bidentate ligand metal complexes, where ‘L-L’ denotes the ancillary bidentate ligand and ‘intercalator’ indicates the intercalating bidentate ligand. The L-L series varies in size and shape. Results of many tests and projects conducted are explained in detail.
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48

Bidal, Yannick D. "Transition-metal complexes bearing normal, abnormal and remote carbenes : synthetic access and catalytic applications." Thesis, University of St Andrews, 2015. http://hdl.handle.net/10023/6125.

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The study of normal N-heterocyclic carbenes (NHCs), which probably represent one of the most important families of ligands in organometallic chemistry and homogeneous catalysis, has indubitably led to the usage of other related ligands beyond di-amino carbenes. So far, such species are only marginally used as ligands due to their relative novelty and stability. The following chapters describe the exciting journey into the development of new synthetic accesses of various abnormal, remote N-heterocyclic, mesoionic and carbocyclic carbene transition metal complexes. The uses of a number of these
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49

Arliguie, Thérèse. "Complexes du ruthenium hydrures et derives de l'hydrogene moleculaire : reactions de deshydrogenation inter et intramoleculaires." Toulouse 3, 1988. http://www.theses.fr/1988TOU30111.

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On etudie la reactivite chimique de complexes polyhudrures de ruthenium apres activation thermique ou photochimique. Certains complexes pentamethylcyclopentadienyl sont egalement prepares et etudies en spectroscopie rmn du proton
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50

Delavaux, Béatrice. "Complexes heterobimetalliques hydrures (ru-m) (m=rh,ir,cu) a ligands bisdiphenylphosphinomethane : synthese et reactivite." Toulouse 3, 1986. http://www.theses.fr/1986TOU30078.

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Synthese de complexes hydruro a coordinat dppm : ph::(2) pch::(2) pph::(2). L'etude de la reactivite de certains complexes comme rurhh::(2)cl(cod) (dppm)::(2), conduit a la preparation de nouveaux hydrures dont on etudie les structures
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