Academic literature on the topic 'Ruthenium nitrosyle complexe'

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Journal articles on the topic "Ruthenium nitrosyle complexe"

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Ford, Peter C. "Photochemical reactions of metal nitrosyl complexes. Mechanisms of NO reactions with biologically relevant metal centers." International Journal of Photoenergy 3, no. 3 (2001): 161–69. http://dx.doi.org/10.1155/s1110662x01000204.

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The discoveries that nitric oxide (a.k.a. nitrogen monoxide) serves important roles in mammalian bioregulation and immunology have stimulated intense interest in the chemistry and biochemistry of NO and derivatives such as metal nitrosyl complexes. Also of interest are strategies to deliver NO to biological targets on demand. One such strategy would be to employ a precursor which displays relatively low thermal reactivity but is photochemically active to release NO. This proposition led us to investigate laser flash and continuous photolysis kinetics of nitrosyl complexes such as the Roussin's
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Ashok, R. F. N., M. Gupta, K. S. Arulsamy та U. C. Agarwala. "Cyclopentadienyl ruthenium complexes. Part III. Reactivity of some η5-cyclopentadienylbis(triphenylphosphine)ruthenium(II) complexes with nitrosyl tribromide and dinitrogen trioxide". Canadian Journal of Chemistry 63, № 4 (1985): 963–70. http://dx.doi.org/10.1139/v85-160.

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Mixed ruthenium(II) nitrosyls have been synthesized in yields larger than 60% by a general reaction of [Ru(η5-C5H5)(PPh3)L]+X− (L = 2,2′-bipyridine or 1,10-phenanthroline, X = Cl or Br) or [Ru(η5-C5,H5)(PPh3)(L)X] (L = PPh3, pyridine, 3-picoline, 4-picoline, [Formula: see text], or [Formula: see text]; X− = Cl−, Br−, I−, CN−, NCS−, H−, or SnCl3−) with NOBr3 and N2O3. In these complexes NO seems to bind with the metal ion as NO+. The reactions of N2O3 gave either nitrito or nitrosyl dinitrito complexes. The reactions of NOBr3 with trichlorostannate complexes did not yield nitrosyl complexes, in
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Metzker, Gustavo, Inara de Aguiar, Maykon Lima Souza, Daniel Rodrigues Cardoso, and Douglas Wagner Franco. "Reaction of ruthenium(II) complexes with 2,2-diphenyl-1-picrylhydrazyl (DPPH•) and hydroxyl radicals." Canadian Journal of Chemistry 92, no. 8 (2014): 788–93. http://dx.doi.org/10.1139/cjc-2014-0082.

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The reaction of the complexes trans-[RuII(NO+)(NH3)4L] and [RuII(NO+)HEDTA] with 2,2-diphenyl-1-picrylhydrazyl (DPPH•) and hydroxyl (OH•) radicals has been investigated at 25.0 ± 0.1 °C using spectroscopic (UV-vis and electron paramagnetic resonance) and electrochemical techniques (differential pulse voltammetry and cyclic voltammetry). The redox potential of RuIII/RuII for the ruthenium nitrosyl complexes was determined and is in the range of +2.2 V (L = HEDTA) to +2.6 V (L = isn) versus the normal hydrogen electrode . The trans-[RuII(NO+)(NH3)4L]3+ and [RuII(NO+)HEDTA] complexes do not react
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Mir, Jan Mohammad, Bashir Ahmad Malik, and Ram Charitra Maurya. "Nitric oxide-releasing molecules at the interface of inorganic chemistry and biology: a concise overview." Reviews in Inorganic Chemistry 39, no. 2 (2019): 91–112. http://dx.doi.org/10.1515/revic-2018-0017.

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AbstractThe useful aspects of nitric oxide (NO) are nowadays widely known. Due to the need for this molecule in the maintenance of homeostasis, NO-releasing compounds are tested every year to optimize its levels in a patient suffering from low NO production. This manuscript is an update of some important historical concerns about nitrosyl complexes having the ability to act as NO-releasing compounds under the influence of different chemically modified environments. At present, the search for efficient and less harmful NO-releasing molecules at desirable targets and concentrations has gained co
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Su, Xianlong, Rongqing Zeng, Xianghong Li, Weijie Dang, Kaiyue Yao, and Dingguo Tang. "Cycloruthenated complexes: pH-dependent reversible cyclometallation and reactions with nitrite at octahedral ruthenium centers." Dalton Transactions 45, no. 17 (2016): 7450–59. http://dx.doi.org/10.1039/c6dt00576d.

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Barth, Michael, Xaver Kästele, and Peter Klüfers. "Nitrosyl Ruthenium Diolato Complexes." European Journal of Inorganic Chemistry 2005, no. 7 (2005): 1353–59. http://dx.doi.org/10.1002/ejic.200300925.

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Amabilino, Silvia, Marine Tasse, Pascal G. Lacroix, et al. "Photorelease of nitric oxide (NO) on ruthenium nitrosyl complexes with phenyl substituted terpyridines." New Journal of Chemistry 41, no. 15 (2017): 7371–83. http://dx.doi.org/10.1039/c7nj00866j.

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Krishnan, V. Mahesh, Hadi D. Arman, and Zachary J. Tonzetich. "Synthesis and characterisation of ruthenium–nitrosyl complexes in oxygen-rich ligand environments." Dalton Transactions 46, no. 4 (2017): 1186–93. http://dx.doi.org/10.1039/c6dt04717c.

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Ng, Ho-Yuen, Wai-Man Cheung, Enrique Kwan Huang, et al. "Ruthenium chalcogenonitrosyl and bridged nitrido complexes containing chelating sulfur and oxygen ligands." Dalton Transactions 44, no. 42 (2015): 18459–68. http://dx.doi.org/10.1039/c5dt02513c.

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Liu, Yingying, Siu-Mui Ng, Shek-Man Yiu, and Tai-Chu Lau. "Catalytic water oxidation by an in situ generated ruthenium nitrosyl complex bearing a bipyridine-bis(alkoxide) ligand." Dalton Transactions 50, no. 35 (2021): 12316–23. http://dx.doi.org/10.1039/d1dt01918j.

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A ruthenium(iii) water oxidation catalyst bearing a bipyridine-bis(alkoxide) ligand is readily converted by (NH4)2[Ce(NO3)6] to a ruthenium(ii) nitrosyl complex which is also an active water oxidation catalyst.
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Dissertations / Theses on the topic "Ruthenium nitrosyle complexe"

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Bocé, Mathilde. "Libération de NO photocontrôlée : complexes de ruthénium à ligand nitrosyle pour des applications innovantes en photothérapie." Thesis, Toulouse 3, 2018. http://www.theses.fr/2018TOU30158/document.

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Le monoxyde d'azote NO• est impliqué dans de nombreux processus biologiques. Il intervient, entre autres, dans la vasodilatation, la neurotransmission, il peut impliquer le développement ou l'apoptose des cellules et possède également des propriétés bactéricides. Le contrôle de la libération de ce radical est donc de grand intérêt pour des applications biomédicales en chimiothérapie photo-activée (PACT) ainsi qu'en inactivation photo-dynamique (PDI). La stratégie ici est de synthétiser des complexes de ruthénium à ligand nitrosyle photoréactifs, qui sont capables de libérer NO• sous irradiatio
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Khadeeva, Liya. "Photo-isomerization and photo-induced NO release in ruthenium nitrosyl compounds." Thesis, Rennes 1, 2016. http://www.theses.fr/2016REN1S067/document.

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Ce travail de thèse est centré sur l'étude expérimentale de deux types de transformations photo-induites observées dans différents complexes métalliques (Fe, Ru, ...) à ligand nitrosyle: (i) la photo-isomérisation au cours de laquelle le ligand NO passe d'un état lié par l'azote (M-NO, état stable GS) à un état lié par l'oxygène (M-ON, état métastable MSI). C'est un processus réversible et un second état métastable, 'side-on' MSII est observable au cours du processus inverse, MSI --> 'side-on' MSII --> GS; (ii) la libération photo-induite du radical NO°. La photo-isomérisation a été étud
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Carron, Véronique. "Etude du mécanisme d'oxydation des formes dissoutes du ruthénium dans les solutions d'acide nitrique : application à l'élimination du ruthénium des solutions de dissolution des combustibles nucléaires irradiés." Université Joseph Fourier (Grenoble), 2000. http://www.theses.fr/2000GRE10227.

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Le ruthenium est l'un des produits de fission les plus genants lors du retraitement des combustibles nucleaires. Son elimination en amont du procede purex, apres la dissolution du combustible dans l'acide nitrique, est envisagee. Le procede d'elimination ici etudie est l'electrovolatilisation. Il consiste a oxyder en ruo 4 volatil les especes dissoutes du ru : les complexes nitrates et nitres du ruthenium nitrosyle runo 3 +. La 1 e r e partie de ce travail concerne l'etude de l'oxydation directe du runo 3 + sur anode d'or ou de platine par voltammetrie cyclique et spectroscopie infrarouge et u
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Singh, Priti. "The electron transfer chemistry of nitrosyl complexes." [S.l. : s.n.], 2008. http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-34223.

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Shamran, Mohammed Hasan. "Photoisomerization and photo-induced nitric oxide release in ruthenium nitrosyl complexes with pyridyl and bipyridyl based ligands." Thesis, Toulouse 3, 2017. http://www.theses.fr/2017TOU30123.

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Les complexes de ruthénium à ligand nitrosyle sont très connus pour posséder des propriétés photochromes qui résultent des changements de coordination du fragment Ru-NO sous irradiation à basse température. Ce phénomène comporte de nombreuses applications telles que le stockage optique de données. Ces complexes ont aussi la capacité de délivrer l'oxyde nitrique de manière photo-contrôlée. Cela présente un grand intérêt car NO est impliqué dans de très nombreuses réactions physiologiques. Cette thèse est consacrée à l'étude des facteurs qui influencent les propriétés photochromes et la photolib
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Lima, Renata Galvão de. "Reatividade química e fotoquímica de complexos nitrosilos de rutênio do tipo [Ru(terpy)(L)NO]n+." Universidade de São Paulo, 2006. http://www.teses.usp.br/teses/disponiveis/59/59138/tde-26052009-170459/.

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O óxido nítrico (NO) é um mensageiro biológico que tem vital importância em muitos processos fisiológicos, tais como o controle cardiovascular, a sinalização neural e a defesa contra microorganismos e tumores. Sua natureza radicalar lhe confere grande reatividade e versatilidade e torna um desafio o entendimento de sua bioquímica. A molécula de NO reage rapidamente com alguns metais de transição e forma compostos estáveis denominados complexos nitrosilos, os quais podem ser utilizados como fonte geradora de óxido nítrico. Neste caso, faz-se necessário o entendimento do comportamento físico-quí
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Santana, Danielle Cristine Almeida Silva de. "Sistemas de liberação contendo um complexo nitrosilo de rutênio como doador de NO para a terapia fotodinâmica tópica." Universidade de São Paulo, 2010. http://www.teses.usp.br/teses/disponiveis/60/60137/tde-17062010-123625/.

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O NO é uma molécula endógena, envolvida em numerosos processos fisiológicos e patológicos. Diversas substâncias capazes de liberar NO in vivo têm sido estudadas, incluindo os complexos nitrosilo de rutênio, como o [Ru(terpy)(bdqi-COOH)NO](PF6)3, capaz de liberar NO após fotoestímulo. Considerando que as funções específicas do NO dependem de sua localização e cinética de liberação, e que a sua aplicação tópica pode evitar possíveis efeitos colaterais, o objetivo deste trabalho foi estudar a absorção cutânea passiva e iontoforética do complexo [Ru(bdqi-COOH)(terpy)(NO)](PF6)3, assim como a do NO
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Lee, Ik-Mo. "Studies on the syntheses, reactivities and structures of ruthenium nitrosyl complexes containing chelating triphosphines /." The Ohio State University, 1989. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487598748018994.

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Sanz, Garcia Juan. "Theoretical study of new nitrosyl ruthenium complexes : mechanisms of photoisomerization and photorelease of NO." Thesis, Toulouse 3, 2016. http://www.theses.fr/2016TOU30160/document.

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Au cours des dernières années, l'intérêt pour les complexes métalliques à ligand nitrosyle n'a pas cessé de croître dans les communautés pharmaceutique, chimique et en science des matériaux. Cet intérêt s'explique par leurs uniques propriétés physico-chimiques, plus concrètement par leur réponse aux perturbations lumineuses. Sous irradiation, ces composés sont capables de libérer NO, molécule qui a un rôle important dans le système vasculaire, ainsi que dans d'autres systèmes physiologiques importants. Ce n'est donc pas surprenant que de telles molécules aient attiré l'attention de la communau
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Hannon, Andrew Michael. "Exploring the Reactivity and Decomposition of Ruthenium Nitrosyl Complexes for the Production of Nitrogen Oxides." Diss., The University of Arizona, 2012. http://hdl.handle.net/10150/243113.

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Nitric oxide (NO) has been shown to both suppress and promote tumor growth, depending in part on concentration. Exogenous delivery of NO may lead to tumor suppression. Recent studies have proposed ruthenium nitrosyl complexes as catalytic donors of NO in reductive environments. Catalytic donation can provide a long-term, elevated NO flux compared to single use donors. Site-specific delivery is desirable to reduce systemic side effects, such as lowering of blood pressure. Three new ruthenium nitrosyl complexes were synthesized to impart site-specificity through amide coupling to polymers, si
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Book chapters on the topic "Ruthenium nitrosyle complexe"

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Ahmad, N., J. J. Levison, S. D. Robinson, M. F. Uttley, E. R. Wonchoba, and G. W. Parshall. "Complexes of Ruthenium, Osmium, Rhodium, and Iridium Containing Hydride Carbonyl, or Nitrosyl Ligands." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132463.ch13.

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da Silva, Roberto Santana, Renata Galvão de Lima, and Sérgio de Paula Machado. "Design, Reactivity, and Biological Activity of Ruthenium Nitrosyl Complexes." In NOx Related Chemistry. Elsevier, 2015. http://dx.doi.org/10.1016/bs.adioch.2014.11.001.

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deBoer, Tara R., and Pradip K. Mascharak. "Recent Progress in Photoinduced NO Delivery With Designed Ruthenium Nitrosyl Complexes." In NOx Related Chemistry. Elsevier, 2015. http://dx.doi.org/10.1016/bs.adioch.2014.11.002.

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Conference papers on the topic "Ruthenium nitrosyle complexe"

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"The influence of ligand structure of ruthenium nitrosyl complexes on their biological activity." In Bioinformatics of Genome Regulation and Structure/ Systems Biology. institute of cytology and genetics siberian branch of the russian academy of science, Novosibirsk State University, 2020. http://dx.doi.org/10.18699/bgrs/sb-2020-353.

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