Academic literature on the topic 'Safer Solvents'

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Journal articles on the topic "Safer Solvents"

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Sharma, Apekshya, Evan Yu, Gregory Morose, David Trung Nguyen, and Wan-Ting Chen. "Designing Safer Solvents to Replace Methylene Chloride for Liquid Chromatography Applications Using Thin-Layer Chromatography as a Screening Tool." Separations 8, no. 10 (2021): 172. http://dx.doi.org/10.3390/separations8100172.

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Methylene chloride, commonly known as dichloromethane (DCM), is a widely used chemical for chromatography separation within the polymer, chemical, and pharmaceutical industries. With the ability to effectively solvate heterocyclic compounds, and properties including a low boiling point, high density, and low cost, DCM has become the solvent of choice for many different applications. However, DCM has high neurotoxicity and is carcinogenic, with exposure linked to damage to the brain and the central nervous system, even at low exposure levels. This research focuses on sustainability and works to
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Sherwood, James, James H. Clark, Ian J. S. Fairlamb, and John M. Slattery. "Solvent effects in palladium catalysed cross-coupling reactions." Green Chemistry 21, no. 9 (2019): 2164–213. http://dx.doi.org/10.1039/c9gc00617f.

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Mohammad, Asif, Abida, and Touquir Alam MD. "An Overview on Execution of Green Chemistry as an Alternative Technique in Organic Synthesis." Journal of Advances in Pharmacy Practices 1, no. 2 (2019): 29–35. https://doi.org/10.5281/zenodo.3344597.

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<em>The implementation of green chemistry (GC) in various aspects of chemistry to overcome the problems of health, safety for workers, in addition to the environmental problems is associated with compounds from their manufacturing, use and disposition as waste. GC is a rapid promising branch of chemistry. GC is a manner that maximizes its benefits while removed its adverse impacts by the application of principles. The principles of GC focused on methods that deals with avoidance of waste, maximize atom economy, less harmful chemical formed, metathesis, synthesized safer chemicals, using safer
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Malinski, Thomas J., and David E. Bergbreiter. "Safer solvents for reactive organometallic reagents." Tetrahedron Letters 59, no. 44 (2018): 3926–29. http://dx.doi.org/10.1016/j.tetlet.2018.09.041.

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Sangon, Suwiwat, Nontipa Supanchaiyamat, James Sherwood, Con R. McElroy, and Andrew J. Hunt. "Direct comparison of safer or sustainable alternative dipolar aprotic solvents for use in carbon–carbon bond formation." Reaction Chemistry & Engineering 5, no. 9 (2020): 1798–804. http://dx.doi.org/10.1039/d0re00174k.

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Direct comparison of safer dipolar aprotic solvents for use in carbon–carbon bond formation is of vital importance for industrial applications. Cyrene exhibited high initial reaction rates, yields and solvent recovery in the Baylis–Hillman reaction.
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Parker, S. E. "Use and Abuse of Volatile Substances in Industry." Human Toxicology 8, no. 4 (1989): 271–75. http://dx.doi.org/10.1177/096032718900800404.

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1 Although there are trends towards the use of 'safer' or non-solvent materials, the overall consumption of solvents will probably not change very much over the next few years. Substitution of solvents by 'safer' materials is a complex and difficult process and the rate of change is correspondingly slow. 2 HSE exposure data show that generally industry controls most solvent use quite well. High personal exposures are not widespread and tend to occur in a fairly small number of premises involving 'end user' processes (mixing, spraying, etc). 3 Exposure in industry is generally to mixtures of so
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Wolf, Katy, Azita Yazdani, and Pamela Yates. "Chlorinated Solvents: Will the Alternatives be Safer?" Journal of the Air & Waste Management Association 41, no. 8 (1991): 1055–61. http://dx.doi.org/10.1080/10473289.1991.10466899.

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Castelvecchi, Davide. "Cleaning treasures: Safer solvents for restoring frescoes." Science News 171, no. 20 (2009): 310. http://dx.doi.org/10.1002/scin.2007.5591712008.

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Sherwood, James, Thomas J. Farmer, and James H. Clark. "Catalyst: Possible Consequences of the N-Methyl Pyrrolidone REACH Restriction." Catalysis 4, no. 9 (2018): 2010–12. https://doi.org/10.1016/j.chempr.2018.08.035.

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The authors work at the Green Chemistry Centre of Excellence (GCCE) at the University of York and are all currently involved in the H2020-BBI-funded project ReSolve for the development of safer bio-based solvents. Solvent applications for dihydrolevoglucosenone (Cyrene) and 2,2,5,5-tetramethyloxloane (TMO) are among their prominent discoveries. Dr. James Sherwood leads the Alternative Solvents Technology Platform at the GCCE. His research interests include solvent effects in organic synthesis and the substitution of hazardous solvents with novel bio-based solvents. Dr. Thomas Farmer is leader
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Jin, Saimeng, Fergal Byrne, Con Robert McElroy, James Sherwood, James H. Clark, and Andrew J. Hunt. "Challenges in the development of bio-based solvents: a case study on methyl(2,2-dimethyl-1,3-dioxolan-4-yl)methyl carbonate as an alternative aprotic solvent." Faraday Discussions 202 (2017): 157–73. http://dx.doi.org/10.1039/c7fd00049a.

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Many traditional solvents have drawbacks including sustainability and toxicity issues. Legislation, such as REACH, is driving the move towards less hazardous chemicals and production processes. Therefore, safer bio-based solvents need to be developed. Herein, a 10 step method has been proposed for the development of new bio-based solvents, which utilises a combination of in silico modelling of Hansen solubility parameters (HSPs), experimental Kamlet–Abboud–Taft parameters, a selection of green synthetic routes followed by application testing and toxicity measurements. The challenges that the c
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Dissertations / Theses on the topic "Safer Solvents"

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Okumu, Antony A. "Development of a Safe and Efficient Alkyl Azide Synthesis using Arylsulfonyl Azide." Youngstown State University / OhioLINK, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1290962115.

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Zivic, Nicolas. "Synthèse de naphtalimides et dicétopyrrolopyrroles originaux pour les photopolymérisations radicalaire et cationique dans des conditions d'irradiation douces." Thesis, Aix-Marseille, 2017. http://www.theses.fr/2017AIXM0056/document.

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La photopolymérisation joue un rôle prééminent dans l'industrie comme en témoigne son nombre d'applications croissant dans des domaines classiques tels que les revêtements, les encres et les adhésifs mais aussi dans des domaines de haute technologie comme l’optoélectronique, l’imagerie laser, la stéréolithographie et la nanotechnologie. En effet, la photopolymérisation présente de nombreux avantages. C’est un processus rapide. Elle peut être réalisée à température ambiante et/ou sans solvant, permettant ainsi de limiter la formation de COV. Enfin, la photopolymérisation permet de réticuler dan
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Zivic, Nicolas. "Synthèse de naphtalimides et dicétopyrrolopyrroles originaux pour les photopolymérisations radicalaire et cationique dans des conditions d'irradiation douces." Electronic Thesis or Diss., Aix-Marseille, 2017. http://www.theses.fr/2017AIXM0056.

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La photopolymérisation joue un rôle prééminent dans l'industrie comme en témoigne son nombre d'applications croissant dans des domaines classiques tels que les revêtements, les encres et les adhésifs mais aussi dans des domaines de haute technologie comme l’optoélectronique, l’imagerie laser, la stéréolithographie et la nanotechnologie. En effet, la photopolymérisation présente de nombreux avantages. C’est un processus rapide. Elle peut être réalisée à température ambiante et/ou sans solvant, permettant ainsi de limiter la formation de COV. Enfin, la photopolymérisation permet de réticuler dan
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Books on the topic "Safer Solvents"

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Illinois. Dept. of Human Services. Datos que usted debe saber inhalantes. Illinois Dept. of Human Services, Bureau of Customer and Provider Assistance, 2004.

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Pagano, Marco. The Sovereign-Bank Nexus and the Case for European Safe Bonds. Oxford University Press, 2018. http://dx.doi.org/10.1093/oso/9780198815815.003.0008.

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During the Euro debt crisis, banks’ holdings of domestic sovereign debt amplified the transmission of sovereign stress to bank lending and solvency risk in stressed countries. Yet, current proposals to reform European banking regulation of bank sovereign exposures meet with obstacles, some structural—namely, the scarcity and asymmetric provision of safe assets—and others transitional—chiefly the danger that regulatory change may trigger instability in the sovereign debt market. But both types of obstacles can be overcome by introducing a synthetic security resulting from the securitization of
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Frenier, Wayne W. Technology for Chemical Cleaning of Industrial Equipment. 2nd ed. NACE International, The Worldwide Corrosion Authority15835 Park Ten Place Houston, TX 77084, 2018. https://doi.org/10.5006/37634.

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This book presents new developments that have affected the commercial use of chemicals and devices to clean industrial equipment. This second edition will emphasize the mechanisms of important cleaning processes and solvents and will give an overview of the science and technology of the formation and removal of fouling deposits in the industrial equipment environment. It is directed to a general technically trained audience, with emphasis placed on the basic chemical and mechanical principles of industrial cleaning (IC). Author Wayne W. Frenier, FNACE, introduces this edition by describing the
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Shane, Kryss. The Educator’s Guide to LGBT+ Inclusion. Jessica Kingsley Publishers, 2020. http://dx.doi.org/10.5040/9781805015048.

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The rates of bullying, truancy due to lack of safety in schools, and subsequent suicidality for LGBT+ youth are exponentially higher than for non-LGBT+ youth. As a result, many American K-12 students are suffering needlessly and many school leaders are unsure of what to do. This book solves that problem. Setting out best practices and professional guidance for creating LGBT+ inclusive learning in schools, this approachable and easy-to-follow book guides teachers, educators, administrators, and school staff toward appropriate and proven ways to create safer learning environments, update school
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Book chapters on the topic "Safer Solvents"

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Veloso, Gabriela Brasil Romão, Rebecca S. Andrade, Regina Maria Barretto Cicarelli, Miguel Iglesias, and Bruna Galdorfini Chiari-Andréo. "Ionic Liquids as “Green Solvents”: Are they Safe?" In Nanotechnology-Based Industrial Applications of Ionic Liquids. Springer International Publishing, 2020. http://dx.doi.org/10.1007/978-3-030-44995-7_1.

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"SAFER SOLVENTS AND PROCESSES." In Handbook of Solvents. Elsevier, 2014. http://dx.doi.org/10.1016/b978-1-895198-65-2.50010-7.

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"SUBSTITUTION OF SOLVENTS BY SAFER PRODUCTS." In Handbook of Solvents. Elsevier, 2019. http://dx.doi.org/10.1016/b978-1-927885-41-3.50010-3.

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Singh, Anuradha, Kavya Singh, and Swastika Singh. "Green Solvents for Sustainable Organic Synthesis." In Green Chemistry for the Development of Eco-Friendly Products. IGI Global, 2022. http://dx.doi.org/10.4018/978-1-7998-9851-1.ch005.

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Green or sustainable chemistry is now recognised as an important scientific subject, and research in this area has led to the creation of cleaner and safer chemical processes, with many new advances occurring each year. Researchers are very interested in unconventional or alternative solvents for chemical synthesis. Chemical solvents make up around 80% of all chemical compounds utilised in a variety of essential chemical processes, notably in the chemical industry. Unfortunately, many of these solvents are volatile organic compounds (VOCs) produced from petrochemicals, which pose a variety of
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"Substitution of Solvents by Safer Products." In Handbook of Solvents, Volume 2. Elsevier, 2024. http://dx.doi.org/10.1016/b978-1-77467-042-2.50012-x.

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Bhandari, Divya Dhawal, Tejinder Kaur, Gaurav Joshi, and Neha Kondal. "GREEN SOLVENTS: AN APPROACH TOWARDS SUSTAINABLE DEVELOPMENT." In Futuristic Trends in Pharmacy & Nursing Volume 3 Book 19. Iterative International Publisher, Selfypage Developers Pvt Ltd, 2024. http://dx.doi.org/10.58532/v3bgpn19p1ch1.

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Presently, organic synthetic chemistry is the one major part of science which is using various solvents among which few are toxic and carcinogenic. In synthetic reactions, the use of protective equipment such as goggles, breathing apparatus, face-guard masks can reduce the exposure to harmful chemicals in daily life. The biggest threat is organic solvents which are used in all chemical reactions and mostly released in environment as volatile organic compounds (VOCs) due to leakage. This is because the VOC’s are more in any reaction than reagents and side products. So the main problem lies to e
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Weller, Mark, Jonathan Rourke, Tina Overton, and Fraser Armstrong. "Green chemistry." In Inorganic Chemistry. Oxford University Press, 2018. http://dx.doi.org/10.1093/hesc/9780198768128.003.0028.

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This chapter introduces the concepts of green chemistry and highlights the important role that inorganic chemistry is playing in promoting environmentally sustainable technologies in the industry. Acknowledging that sustainable development has become the cultural, scientific, and technical imperative of the twenty first century, the chapter reviews the guiding principles around which green chemistry is practised. These principles cover issues from the efficiency of reactions, waste production, seeking alternate and safer solvents, to designing for less hazardous by-products and products and in
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Nelson, William M. "Philosophy of the Environment." In Green Solvents for Chemistry. Oxford University PressNew York, NY, 2003. http://dx.doi.org/10.1093/oso/9780195157369.003.0001.

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Abstract Let us put chemical usage in context. There is justifiably a concern over the adverse effects of chemicals on human health and the environment. The source of chemicals may be industrial, commercial, or adventitious. Environmental quality is a concern in the United States and throughout the world. This concern is important today. Our world has heightened environmental awareness, fueled by public interest groups and the media. Public awareness is growing of the processes involved in the use, manufacturing, and effect of many chemicals on the environment, including the generation of wast
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Kharb, Sonaxi, and Anshul Singh. "GREEN CHEMISTRY: A FOOTSTEP TOWARDS SUSTAINABLE DEVELOPMENT." In Futuristic Trends in Chemical Material Sciences & Nano Technology Volume 3 Book 22. Iterative International Publishers, Selfypage Developers Pvt Ltd, 2024. http://dx.doi.org/10.58532/v3becs22p1ch5.

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The word chemical comes into our mind with something harmful or negative. This aspect is transmitted from our surroundings - deployed from the maltreatment of chemicals. The idea of green chemistry has arisen in response to keeping down the harmful impacts of man-made materials. This branch of Chemical Science is usually described by the 12 principles possessing the key elements: minimizing waste reduction, product toxicity, energy consumption, and enhancing the use of renewable and safer resources. This chapter briefly presents the initiatives taken by the government to improve research in th
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Ortega-Zamora, C., and J. González-Sálamo. "Deep Eutectic Solvents (DESs) in Green Sample Preparation." In Green Sample Preparation Techniques. The Royal Society of Chemistry, 2023. http://dx.doi.org/10.1039/bk9781839166419-00212.

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Current trends in Analytical Chemistry are focused on the development and application of safer and more environmentally friendly procedures that meet the Green Analytical Chemistry principles. In this sense, since their introduction by Abbott et al. in 2003, deep eutectic solvents (DESs) have gained importance as solvents of great utility in extraction processes, due to their low toxicity, easy preparation, and good physicochemical properties, as well as their low cost and their biodegradability. In recent years, DESs synthesized from natural compounds such as sugars, alcohols, and amino acids
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Conference papers on the topic "Safer Solvents"

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Gomez, Todd, John Winfrey, and Dudley J. Primeaux. "Old Coat, New Threads." In SSPC 2013 Greencoat. SSPC, 2013. https://doi.org/10.5006/s2013-00022.

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Abstract Gel coat has traditionally been used in environments where color, gloss and relative long-term performance are important. This premise is still true today; however, a much more advanced technology has been developed that provides improved characteristics of color and gloss stability, higher mechanical properties and zero Volatile Organic Compounds (VOC’s). This newest advancement in coating technology can be utilized in a wide variety of applications and substrates including concrete, fiberglass, and metal while meeting SSPC (The Society for Protective Coatings) standards. The belief
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Hoy, Edgar F. "The Removal of Arsenic-Based Inhibitors from Petrochemical Equipment." In CORROSION 1988. NACE International, 1988. https://doi.org/10.5006/c1988-88218.

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Abstract Environmental concerns have forced the discontinuance of arsenic compounds as inhibitors in the petrochemical industry. This environmental concern has led to their replacement with either less toxic antimony or organic inhibitors. During the change of inhibitor systems, arsenic removal and toxic arsine gas production are major concerns. Arsenic dissolution rates, total scale removal, and arsine gas production were compared using several commercial solvents. Laboratory and field data confirm that a two-stage solvent involving tetraammonium ethylenediaminetetraacetic acid and hydrogen p
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Nuzzo, Charles A. "The Art & Science of Water-Based Intumescent Fireproofing." In SSPC 2007. SSPC, 2007. https://doi.org/10.5006/s2007-00066.

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Abstract Today’s water-based intumescent coatings provide improved fire resistance, allowing architectural exposed structural steel (AESS) to be featured prominently. This article examines the environmental/health benefits of water-based coatings over traditional, solvent-based coatings, and provides recommendations on how to apply these materials in a safe and attractive manner, and ensure long-term performance.
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Procopio, Leo J. "Protection of an Historic Lighthouse with Waterborne Acrylic Coatings: a 20-Year Case Study of the Hunting Island Lighthouse." In SSPC 2002. SSPC, 2002. https://doi.org/10.5006/s2002-00020.

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Abstract The use of waterborne coatings in industrial maintenance applications has increased greatly over the past two decades. The reason for this increase is due to several factors. Current and proposed future regulations on volatile organic content (VOC) are designed to limit the impact of coatings on the environment, and waterborne coatings provide a route to lower VOC. Other safety and health advantages include lower concern over worker exposure to hazardous solvents, easy and safe cleanup, and less hazardous disposal. Finally, extensive testing has shown that waterborne coatings can also
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Tombaugh, Late Ray, Tyler Colby, and Davinder Khangura. "Automated Surface Preparation and Lining Installation in Penstocks and Large Diameter Water Pipes." In Coatings+ 2021. SSPC, 2021. https://doi.org/10.5006/s2021-00007.

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Abstract Since the catastrophic accident at the Cabin Creek penstock in Georgetown, CO on October 2, 2007 where five coating applicator’s lives were lost (Ref 1), the hydroelectric and water transmission industry has been looking for safer practices to line the interior of penstocks and other large diameter water pipes. In nearly all applications, owners and specifiers have required the use of 100% solids coatings as opposed to the previously used solvent borne coatings. Safety protocols have been established that limit the amount of solvent and other flammable liquids in the pipe. However, in
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Hasan, M. M. Faruque. "Designing for the Future: The Role of Process Design in Decarbonization and Energy Transition." In Foundations of Computer-Aided Process Design. PSE Press, 2024. http://dx.doi.org/10.69997/sct.112547.

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The overarching goal of process design (Figure 1) is to find technologically feasible, operable, economically attractive, safe and sustainable processing pathways and process configurations with specifications for the connectivity and design of unit operations that perform a set of tasks using selected functional materials (e.g., catalysts, solvents, sorbents, etc.) to convert a set of feed-stocks or raw materials into a set of products with desired quality at a scale that satisfies the demand. Process synthesis and integration can further screen, optimize and improve these pathways for given
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Khambatta, Jal, and Bill Warner. "Modern Water-Borne Coating Technology : Stops Corrosion and Preserves the Environment." In CORROSION 1985. NACE International, 1985. https://doi.org/10.5006/c1985-85008.

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Abstract Modern water-borne coating systems are being proven as effective as conventional solvent-based coatings for stopping corrosion. Their additional benefits include being evironmentally safe, tolerating minimal surface preparation and cleaning up with water. Recent advances in acrylic resin technology have made possible improved acrylic modified cementitious coatings. They have excellent adhesion when applied on minimally prepared surfaces as primers. And, in areas where resistance to chloride ion penetration is essential and where UV degredation is a problem, these coatings also make ex
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Dasari, S. K., A. G. Raraz, J. E. Indacochea, and S. M. McDeavitt. "UREX+ 304L Stainless Steel Centrifugal Contactor Corrosion Due to Hydrodynamic Effects." In CORROSION 2010. NACE International, 2010. https://doi.org/10.5006/c2010-10235.

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Abstract UREX+ is a solvent extraction process for partitioning spent fuel constituents to lead to safer and cheaper disposal of high-level waste. The procedure is based on an annular centrifugal stainless steel contactor developed for solvent extraction. During the centrifugal contactor operation there are two immiscible fluid phases, aqueous and organic, that move in opposite directions as they flow from stage to stage. These phases, which are mixed to accomplish separation and later separated, flow through two different centrifugal contactor regions called “mixing” and “separation” zones. I
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Blankenship, Kristen. "FEVE Fluoropolymer Coatings for High Performance Waterbased Applications." In SSPC 2017 Greencoat. SSPC, 2017. https://doi.org/10.5006/s2017-00007.

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Abstract Performance, cost, and safety drive the coatings industry. Safer and environmentally friendly coatings continue to be a hot topic of discussion globally; however, the adoption of greener coating technologies is slow, especially in the US. This could be attributed to many factors, but from the formulator's perspective, performance is key. Waterborne coatings have been used in architectural applications for decades, but typically these coatings are valued mostly for aesthetics, ease of use, and low cost. The use of waterborne coatings in industrial applications, where higher performance
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Bowman, Nicole, Remi Briand, and Jeremy Ethington. "Liquid Applied Insulation Coatings: from the Lab to the Field." In SSPC 2017 Greencoat. SSPC, 2017. https://doi.org/10.5006/s2017-00008.

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Abstract Waterborne coatings are safer to use than their traditional solvent borne counterparts and can reduce environmental impacts. As the market share for waterborne coatings has grown, there has been increased focus on their performance. Simultaneously, the building industry has been challenging coatings manufacturers to provide functional coatings. No longer are aesthetics, corrosion prevention and protection enough; a coating can and should provide multiple benefits to the user. One of the fastest growing segments of the functional waterborne coatings market is liquid applied insulation
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Reports on the topic "Safer Solvents"

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Naim, Michael, Gary R. Takeoka, Haim D. Rabinowitch, and Ron G. Buttery. Identification of Impact Aroma Compounds in Tomato: Implications to New Hybrids with Improved Acceptance through Sensory, Chemical, Breeding and Agrotechnical Techniques. United States Department of Agriculture, 2002. http://dx.doi.org/10.32747/2002.7585204.bard.

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The tomato, a profitable vegetable crop in both the USA and Israel, has benefited significantly from intensive breeding efforts in both countries, and elsewhere (esp. Holland). : Modem hybrids are highly prolific and resistant to a variety of major pests. They produce attractive, firm fruit for both processing and fresh-marketing. In all cases, however, reduction in flavor and aroma have occurred concomitantly with the increase in yield. Sugars-acids ratio dominate fruit taste, whereas aroma volatiles (potent at minute ppb and ppt levels) contribute to the total characteristic tomato flavor. A
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