Academic literature on the topic 'Sarcophagine cage'

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Journal articles on the topic "Sarcophagine cage"

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Paterson, Brett M., Gojko Buncic, Lachlan E. McInnes, et al. "Bifunctional 64Cu-labelled macrobicyclic cage amine isothiocyanates for immuno-positron emission tomography." Dalton Transactions 44, no. 11 (2015): 4901–9. http://dx.doi.org/10.1039/c4dt02983f.

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Ling, Irene, Alexandre N. Sobolev, Rauzah Hashim, and Jack M. Harrowfield. "Stereochemistry of cage amine complexes – probing the ligand conformational flexibility with hydrogen bonds." CrystEngComm 16, no. 48 (2014): 11058–63. http://dx.doi.org/10.1039/c4ce01980f.

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Structure determinations for some Co(iii) sarcophagine complexes show that there is no evidence that the H-bonding involving the NH centres of the complex cations is influenced by electronic effects due to the substituents.
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Bottomley, GA, IJ Clark, II Creaser, et al. "The Synthesis and Structure of Encapsulating Ligands: Properties of Bicyclic Hexamines." Australian Journal of Chemistry 47, no. 1 (1994): 143. http://dx.doi.org/10.1071/ch9940143.

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Template syntheses based on tris (ethane-1,2-diamine)cobalt(III) lead to cobalt(III) complexes of cage hexamines of the ' sarcophagine ' type ( sarcophagine = sar = 3,6,10,13,16,19- hexaazabicyclo [6.6.6] icosane ) rapidly and in high yield. Reduction of these species to their cobalt(II) forms enables the ligands to be removed in concentrated acids at elevated temperatures, and in hot aqueous solutions containing excess cyanide ion. The free sarcophagine and 1,8-diaminosarcophagine [(NH2)2sar or diamsar] ligands are strong bases, accepting up to four and five protons, respectively, in aqueous
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Sargeson, Alan M., and Peter A. Lay. "Dependence of the Properties of Cobalt(III) Cage Complex as a Function of the Derivatization of Amine Substituents." Australian Journal of Chemistry 62, no. 10 (2009): 1280. http://dx.doi.org/10.1071/ch09368.

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Control of redox properties of cobalt macrobicyclic hexaamine (cage) complexes by substituent modification is important for their use as electron-transfer agents, and the resultant derivatives can also change the lipophilicity of the complexes for a variety of biological and other applications. Such derivatization is also important for incorporating cage complexes into a range of redoxactive conjugates. Here, the derivatization of the amine groups in the 1 and 8 positions of [Co(sar)]3+ (sar = sarcophagine = 3,6,10,13,16,19-hexaazabicyclo[6.6.6]icosane) are reported. The synthesis and properti
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Koutsantonis, George A., Jackson Lee, Nigel A. Lengkeek, Gareth L. Nealon, Brian W. Skelton, and Allan H. White. "Synthesis and characterisation of trinuclear metal complexes derived from carboxymethyl-substituted sarcophagine macrobicyclic cage amines." Journal of Inclusion Phenomena and Macrocyclic Chemistry 66, no. 1-2 (2009): 61–66. http://dx.doi.org/10.1007/s10847-009-9634-6.

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Li, Guoquan, Xinlu Wang, Shu Zong, Jing Wang, Peter S. Conti, and Kai Chen. "MicroPET Imaging of CD13 Expression Using a 64Cu-Labeled Dimeric NGR Peptide Based on Sarcophagine Cage." Molecular Pharmaceutics 11, no. 11 (2014): 3938–46. http://dx.doi.org/10.1021/mp500354x.

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Liu, Shuanglong, Dan Li, Chiun-Wei Huang, et al. "Efficient Construction of PET/Fluorescence Probe Based on Sarcophagine Cage: An Opportunity to Integrate Diagnosis with Treatment." Molecular Imaging and Biology 14, no. 6 (2012): 718–24. http://dx.doi.org/10.1007/s11307-012-0557-z.

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Engelhardt, LM, JM Harrowfield, AM Sargeson, and AH White. "Synthesis and Structure of (1,8-Diammonio-3,6,10,13,16,19-hexaazabicyclo[6.6.6]icosane)-nickel(II) Tetrachloride Monohydrate." Australian Journal of Chemistry 46, no. 1 (1993): 127. http://dx.doi.org/10.1071/ch9930127.

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The synthesis and single-crystal X-ray structure determination of the title compound are described. Crystals are monoclinic, P 21, a 16.164(9), b 8.277(3), c 8.829(4) Ǻ, β 102.86(4)°, Z 2; 2666 independent 'observed' diffractometer data [I > 3σ(I)] were refined to a residual of 0.045. The cation is unusual amongst complexes of sarcophagine (3,6,10,13,16,19-hexaazabicyclo[6.6.6]icosane) cage amines in adopting a lel2ob conformation, seemingly in response to hydrogen bonding/crystal packing forces. In consequence, unlike the tetranitrate analogue in which Ni-N bond distances are dispersed ove
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Creaser, I. I., J. M. Harrowfield, G. A. Lawrance, et al. "Rapid Reduction of [CuII(Sarcophagine)]2+ Ion and Elimination of Cu1 From the Cage: A Pulse Radiolysis Study." Journal of Coordination Chemistry 23, no. 1-4 (1991): 389–95. http://dx.doi.org/10.1080/00958979109408266.

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Anderson, PA, II Creaser, C. Dean, et al. "Synthesis, Resolution and Kinetics of Electron Self-Exchange of High-Spin Manganese(II)/(III) Cage Complexes." Australian Journal of Chemistry 46, no. 4 (1993): 449. http://dx.doi.org/10.1071/ch9930449.

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The ligand sarcophagine ( sar = 3,6,10,13,16,19-hexaazabicyclo[6.6.6] icosane ) rapidly reacts with [ Mn (OH2)6]2+ to form the nearly colourless [ Mn ( sar )]2+ ion, which can readily be oxidized to the bright orange [Mn ( sar )]3+ ion (E°′+0.53 V v. n.h.e. in 0.1 mol l-1 CF3SO3H at 295 K). A single-crystal structure determination on [ Mn ( sar )](NO3)3, space group I 42d, a 15.549(6), c 19.014(6) Ǻ, R 0.051, Rw 0.049 for 608 'observed' reflections, shows the coordination geometry of the manganese(III) ion, with site symmetry 2, to be subject to a Jahn-Teller distortion, giving three pairs of
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Dissertations / Theses on the topic "Sarcophagine cage"

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Nealon, Gareth L. "Substituted cage amines : towards new functional metalloassemblies." University of Western Australia. School of Biomedical and Chemical Sciences, 2007. http://theses.library.uwa.edu.au/adt-WU2007.0215.

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Walker, Glen William, and not available. "Electron Transfer Reactivity, Synthesis, Surface Chemistry and Liquid-Membrane Transport of Sarcophagine-Type Poly-Aza Cage Complexes." The Australian National University, 1997. http://thesis.anu.edu.au./public/adt-ANU20010702.124104.

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[Formulae and special characters can only be approximated here. Please see the pdf version of the Abstract for an accurate reproduction.] The kinetics for outer-sphere electron transfer between a series of cobalt(II) poly-aza cage ligand complexes and the iron(III) sarcophagine-type hexa-aza cage complex, [Fe(sar)]3+ (sar = 3,6,10,13,16,19-hexaazabicyclo[6.6.6]icosane), in aqueous solution have been investigated and the Marcus correlation is used to deduce the electron self-exchange rate constant for the [Fe(sar)]3+/2+ couple from these cross-reactions. The deduced electron self-exchange rate
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Walker, Glen William. "Electron Transfer Reactivity, Synthesis, Surface Chemistry and Liquid-Membrane Transport of Sarcophagine-Type Poly-Aza Cage Complexes." Phd thesis, 1997. http://hdl.handle.net/1885/49260.

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The kinetics for outer-sphere electron transfer between a series of cobalt(II) poly-aza cage ligand complexes and the iron(III) sarcophagine-type hexa-aza cage complex, [Fe(sar)]3+ (sar = 3,6,10,13,16,19-hexaazabicyclo[6.6.6]icosane), in aqueous solution have been investigated and the Marcus correlation is used to deduce the electron self-exchange rate constant for the [Fe(sar)]3+/2+ couple from these cross-reactions. The deduced electron self-exchange rate constant is in relatively good agreement with the experimentally determined rate constant (k ex calc = 4 ´ 10 5 M -1 s -1 ; k ex obs = 8 ´
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Ma, Michelle Therese. "Coordination of transition metals to peptides: (i) Ruthenium and palladium metal clips that induce pentapeptides to be α-helical in water; (ii) Synthesis of peptides incorporating a cage amine ligand for chelation of copper radioisotopes". 2010. http://repository.unimelb.edu.au/10187/6715.

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Coordination of transition metals to peptides, either through the incorporation of unnatural chelating groups or amino acid ligating side-chains, expands the utility of peptides for biological studies. The first part of this project describes induction of α-helical secondary structure in pentapeptides upon side-chain coordination of inert transition metal ions. The second part of this project describes the syntheses of biologically active peptide species that contain a macrobicyclic hexaamine ligand that can complex radioactive metal ions for diagnostic imaging purposes.<br>Short peptide seque
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Book chapters on the topic "Sarcophagine cage"

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KAJFEŽ, TOMISLAV. "A CASE OF MODERN-DAY BURIALS IN ANCIENT EGYPTIAN SARCOPHAGI." In Egypt and Austria XII - Egypt and the Orient: The Current Research. Archaeopress Publishing Ltd, 2020. http://dx.doi.org/10.2307/j.ctv177tjz3.25.

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Lucarelli, Rita, and Kea Johnston. "Ancient Egyptian Coffins in 3D: Digital Analysis, Visualization, and Dissemination." In Preserving Cultural Heritage in the Digital Age: Sending Out an S.O.S. Equinox Publishing Ltd., 2022. http://dx.doi.org/10.1558/equinox.42597.

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This chapter discusses the importance of digital data capture techniques such as digital photogrammetry for expanding access to texts carved on Egyptian sarcophagi by creating collections of digitized large mortuary objects. Such large objects are often stored in museum warehouses and not easily shared with scholars and the public. By providing a thorough explanation of the digital techniques and results of the “Book of the Dead in 3D” project at UC Berkeley, this chapter highlights the significance of conducting text analysis on the 3D models of the coffins by creating interactive annotations--including text transcription and translation of the magical spells--on the digital models themselves. This kind of embedded metadata is critical to scholars of Egyptology. The case study presented--the sarcophagus of Psamtik in the collections of the Phoebe Hearst Museum at Berkeley--describes in detail the technique of digital photogrammetry combined with custom programming to create the annotated 3D models.
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Fant, Clyde E., and Mitchell G. Reddish. "Southern Cyprus." In A Guide to Biblical Sites in Greece and Turkey. Oxford University Press, 2003. http://dx.doi.org/10.1093/oso/9780195139174.003.0052.

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In Southern Cyprus the principal site of interest is Paphos, where the Apostle Paul encountered the Roman governor of Cyprus, Sergius Paulus. But other fine sites of interest range from Paphos to Larnaca, a distance of approximately 80 miles. Since there are airports in both locations and ferries arrive at Limassol, a visit might begin at any one of these places. In any case, with an early start it is possible to make a round trip between Paphos and Larnaca in one day and see the principal sites. A much easier itinerary, however, involves seeing the sites in the Paphos area on one day and the sites in Larnaca on another day, along with those between Paphos and Larnaca. The two sites in the south referred to in the Bible are Paphos and Kition (Kittim), which is mentioned in the Hebrew scriptures. Related sites include St. Paul’s Pillar, the Catacombs of Agia Solomoni, the Tombs of the Kings, Paleopaphos, the Temple of Aphrodite, Kourion, the Temple of Apollo, and the Church of St. Lazarus, as well as several museums. The route below begins at Larnaca and proceeds toward Paphos, since that is the direction Paul and his companions traveled. At one time, Kition was one of the greatest naval powers in the Mediterranean, and its mercenaries even served in the deserts of southern Judea. Today its ruins still suggest the might of this ancient city. The site of ancient Kition, known in the Bible as Kittim, is located in the modern city of Larnaca. In the construction of Larnaca, whose name likely came from the Greek word for sarcophagus (larnax), or coffin, many sarcophagi were unearthed from ancient Kition. Larnaca was the location of a settlement of Mycenaeans as early as the 13th century B.C.E. Later abandoned, the site was rebuilt around 1200 B.C.E. by Achaean refugees following the destruction of the great Mycenaean centers of mainland Greece. A second wave of immigrants arrived about 1150 B.C.E. The original mud-brick city walls were rebuilt in the 12th century B.C.E. with cyclopean stones, huge rectangular ashlar blocks. After an earthquake in 1075 B.C.E., the city was resettled closer to the sea.
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Snead, James E. "Idol Pursuits: Artifacts and Authority after the Civil War." In Relic Hunters. Oxford University Press, 2018. http://dx.doi.org/10.1093/oso/9780198736271.003.0009.

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A particularly baroque literary appearance of the Kentucky Mummy highlights the transformation of public perceptions of indigenous antiquities in the United States in the Civil War decade. An imaginary romance of Mammoth Cave, Legends of the South (Smith 1869), describes a mysterious, annual journey of a “venerable Indian” down into the cavern. Ultimately the old man disappears into its depths, never to return. Decades later the author pursues the subterranean trail, encountering marvels that include the warning Siste viator—“Stop, traveler”— chalked on the cave wall. Nearby he finds the deceased elder, reduced to a “mummy-like dessication” clad in deerskin. Armed with an amulet taken from the body he pushes onward, ultimately entering a vast sepulcher in which . . . lay the warrior tribe, in their panoply complete. Supine—with their hands crossed upon their breasts, with their faces turned upward, as if acknowledging the presence of a superior being, they lay, like the marble effigies of the knights of old upon their sarcophagi. . . . In this catacomb the author is haunted by a ghostly “Sachem” who chides: “Are you not satisfied that your cruel warfare has exterminated us from the surface of the earth? Must you follow us to these chambers of death to scatter our ashes?” The supernatural figure then describes the wars of his dead people, prophesying that those events would be repeated in post-Civil War United States. “Nations from the rising sun shall make war upon the conquerors,” he pronounces “and then shall the Southern panther rise from his lair, and avenge his wrongs.” This subterranean tale amplified the myriad accounts of the Kentucky Mummy—a discovery two generations in the past by that time. By the mid-nineteenth century such visions of indigenous antiquity were increasingly commonplace, but the linkage between these histories and current events indicate increasingly deep associations with the American landscape. It was not simply abstract indigenous history that was being co-opted, however, but the material legacy of that experience—the ruins and artifacts that were ubiquitous in the increasingly populated countryside.
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Conference papers on the topic "Sarcophagine cage"

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Liu, Shuanglong, Chiun-Wei Huang, Li-Peng Yap, Ryan Park, Zibo Li, and Peter S. Conti. "Abstract 5731: PET and fluorescence imaging of brain cancer with a dual modality probe based on sarcophagine cage." In Proceedings: AACR 103rd Annual Meeting 2012‐‐ Mar 31‐Apr 4, 2012; Chicago, IL. American Association for Cancer Research, 2012. http://dx.doi.org/10.1158/1538-7445.am2012-5731.

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Costa, Ronald Pinto, Gabriel Cheles Nascimento Matos, Gabriel Ângelo Araújo de Souza, Mirela Leite Fernandes, and Frances Tatiane Tavares Trindade. "A IMPORTÂNCIA DOS INSETOS NECRÓTICOS NA ATUAÇÃO DA MEDICINA LEGAL." In I Congresso Brasileiro de Especialidades Biológicas On-line. Revista Multidisciplinar de Educação e Meio Ambiente, 2021. http://dx.doi.org/10.51189/rema/2649.

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Introdução: A entomologia forense é a ciência que estuda a aplicação de insetos, ácaros e outros artrópodes para fins legais. Nessa perspectiva, o uso de insetos necróticos como indicadores biológicos nos estágios de decomposição cadavérica constitui auxílio importante na investigação pericial, principalmente na estimativa do período pós-morte em vítimas de violência e na suposição do local de óbito. No Brasil, há expressiva biodiversidade de fauna cadavérica e, dadas as suas dimensões territoriais, cabe aos profissionais da perícia criminal o reconhecimento das entomofaunas regionais, das con
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