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Journal articles on the topic 'Sarcophagine cage'

Author: Grafiati
Published: 4 June 2021
Last updated: 31 January 2023

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1

Paterson, Brett M., Gojko Buncic, Lachlan E. McInnes, et al. "Bifunctional 64Cu-labelled macrobicyclic cage amine isothiocyanates for immuno-positron emission tomography." Dalton Transactions 44, no. 11 (2015): 4901–9. http://dx.doi.org/10.1039/c4dt02983f.

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2

Ling, Irene, Alexandre N. Sobolev, Rauzah Hashim, and Jack M. Harrowfield. "Stereochemistry of cage amine complexes – probing the ligand conformational flexibility with hydrogen bonds." CrystEngComm 16, no. 48 (2014): 11058–63. http://dx.doi.org/10.1039/c4ce01980f.

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Structure determinations for some Co(iii) sarcophagine complexes show that there is no evidence that the H-bonding involving the NH centres of the complex cations is influenced by electronic effects due to the substituents.
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3

Bottomley, GA, IJ Clark, II Creaser, et al. "The Synthesis and Structure of Encapsulating Ligands: Properties of Bicyclic Hexamines." Australian Journal of Chemistry 47, no. 1 (1994): 143. http://dx.doi.org/10.1071/ch9940143.

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Template syntheses based on tris (ethane-1,2-diamine)cobalt(III) lead to cobalt(III) complexes of cage hexamines of the ' sarcophagine ' type ( sarcophagine = sar = 3,6,10,13,16,19- hexaazabicyclo [6.6.6] icosane ) rapidly and in high yield. Reduction of these species to their cobalt(II) forms enables the ligands to be removed in concentrated acids at elevated temperatures, and in hot aqueous solutions containing excess cyanide ion. The free sarcophagine and 1,8-diaminosarcophagine [(NH2)2sar or diamsar] ligands are strong bases, accepting up to four and five protons, respectively, in aqueous
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4

Sargeson, Alan M., and Peter A. Lay. "Dependence of the Properties of Cobalt(III) Cage Complex as a Function of the Derivatization of Amine Substituents." Australian Journal of Chemistry 62, no. 10 (2009): 1280. http://dx.doi.org/10.1071/ch09368.

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Control of redox properties of cobalt macrobicyclic hexaamine (cage) complexes by substituent modification is important for their use as electron-transfer agents, and the resultant derivatives can also change the lipophilicity of the complexes for a variety of biological and other applications. Such derivatization is also important for incorporating cage complexes into a range of redoxactive conjugates. Here, the derivatization of the amine groups in the 1 and 8 positions of [Co(sar)]3+ (sar = sarcophagine = 3,6,10,13,16,19-hexaazabicyclo[6.6.6]icosane) are reported. The synthesis and properti
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5

Koutsantonis, George A., Jackson Lee, Nigel A. Lengkeek, Gareth L. Nealon, Brian W. Skelton, and Allan H. White. "Synthesis and characterisation of trinuclear metal complexes derived from carboxymethyl-substituted sarcophagine macrobicyclic cage amines." Journal of Inclusion Phenomena and Macrocyclic Chemistry 66, no. 1-2 (2009): 61–66. http://dx.doi.org/10.1007/s10847-009-9634-6.

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6

Li, Guoquan, Xinlu Wang, Shu Zong, Jing Wang, Peter S. Conti, and Kai Chen. "MicroPET Imaging of CD13 Expression Using a 64Cu-Labeled Dimeric NGR Peptide Based on Sarcophagine Cage." Molecular Pharmaceutics 11, no. 11 (2014): 3938–46. http://dx.doi.org/10.1021/mp500354x.

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7

Liu, Shuanglong, Dan Li, Chiun-Wei Huang, et al. "Efficient Construction of PET/Fluorescence Probe Based on Sarcophagine Cage: An Opportunity to Integrate Diagnosis with Treatment." Molecular Imaging and Biology 14, no. 6 (2012): 718–24. http://dx.doi.org/10.1007/s11307-012-0557-z.

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8

Engelhardt, LM, JM Harrowfield, AM Sargeson, and AH White. "Synthesis and Structure of (1,8-Diammonio-3,6,10,13,16,19-hexaazabicyclo[6.6.6]icosane)-nickel(II) Tetrachloride Monohydrate." Australian Journal of Chemistry 46, no. 1 (1993): 127. http://dx.doi.org/10.1071/ch9930127.

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The synthesis and single-crystal X-ray structure determination of the title compound are described. Crystals are monoclinic, P 21, a 16.164(9), b 8.277(3), c 8.829(4) Ǻ, β 102.86(4)°, Z 2; 2666 independent 'observed' diffractometer data [I > 3σ(I)] were refined to a residual of 0.045. The cation is unusual amongst complexes of sarcophagine (3,6,10,13,16,19-hexaazabicyclo[6.6.6]icosane) cage amines in adopting a lel2ob conformation, seemingly in response to hydrogen bonding/crystal packing forces. In consequence, unlike the tetranitrate analogue in which Ni-N bond distances are dispersed ove
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9

Creaser, I. I., J. M. Harrowfield, G. A. Lawrance, et al. "Rapid Reduction of [CuII(Sarcophagine)]2+ Ion and Elimination of Cu1 From the Cage: A Pulse Radiolysis Study." Journal of Coordination Chemistry 23, no. 1-4 (1991): 389–95. http://dx.doi.org/10.1080/00958979109408266.

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10

Anderson, PA, II Creaser, C. Dean, et al. "Synthesis, Resolution and Kinetics of Electron Self-Exchange of High-Spin Manganese(II)/(III) Cage Complexes." Australian Journal of Chemistry 46, no. 4 (1993): 449. http://dx.doi.org/10.1071/ch9930449.

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The ligand sarcophagine ( sar = 3,6,10,13,16,19-hexaazabicyclo[6.6.6] icosane ) rapidly reacts with [ Mn (OH2)6]2+ to form the nearly colourless [ Mn ( sar )]2+ ion, which can readily be oxidized to the bright orange [Mn ( sar )]3+ ion (E°′+0.53 V v. n.h.e. in 0.1 mol l-1 CF3SO3H at 295 K). A single-crystal structure determination on [ Mn ( sar )](NO3)3, space group I 42d, a 15.549(6), c 19.014(6) Ǻ, R 0.051, Rw 0.049 for 608 'observed' reflections, shows the coordination geometry of the manganese(III) ion, with site symmetry 2, to be subject to a Jahn-Teller distortion, giving three pairs of
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11

Creaser, II, LM Engelhardt, JM Harrowfield, AM Sargeson, BW Skelton, and AH White. "Syntheses and Structures of Manganese(II) and Manganese(III) Nitrate Diaminosarcophagine Complexes." Australian Journal of Chemistry 46, no. 4 (1993): 465. http://dx.doi.org/10.1071/ch9930465.

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The syntheses of [ Mn ((NH3)2sar)](NO3)4.H2O and [ Mn ((NH3)2sar)](NO3)5.2H2O, manganese(II) and manganese(III) complexes of the cage amine ligand diaminosarcophagine ( di-aminosarcophagine = (NH2)2sar = 1,8-diamino-3,6,10,13,16,19-hexaazabicyclo[6.6.6] icosane ) in its diprotonated form are recorded, together with their single-crystal X-ray structure determinations at c. 295 K. The monoclinic P21 array of the manganese(II) complex (a 12.386(5), b 12.431(4), c 8.598(4) Ǻ, β 93.89(4)°, V 1321(1) Ǻ3,Z 2) is archetypical for similar complexes of a wide variety of transition metals; for the presen
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12

Liu, Shuanglong, Zibo Li, and Peter Conti. "Development of Multi-Functional Chelators Based on Sarcophagine Cages." Molecules 19, no. 4 (2014): 4246–55. http://dx.doi.org/10.3390/molecules19044246.

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13

Harrowfield, Jack M., George A. Koutsantonis, Heinz-Bernhard Kraatz, et al. "Cages on Surfaces: Thiol Functionalisation of CoIII Sarcophagine Complexes." European Journal of Inorganic Chemistry 2007, no. 2 (2007): 263–78. http://dx.doi.org/10.1002/ejic.200600626.

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14

Briceño-Vela, Deimy, Florencio Ramírez-Cruz, and Shirley Madeleine Valderrama-Alfaro. "Cadaverous entomofauna associated with the incinerated remains of Sus scrofa domestica L., in the town of Chuyugual, La Libertad, Peru." Manglar 19, no. 3 (2022): 221–26. http://dx.doi.org/10.17268/manglar.2022.027.

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The determination of the postmortem interval through entomological evidence is a widely used method for clarifying crimes in forensic entomology. The objective of this research was to determine the cadaveric entomofauna and the ecological biodiversity associated with the remains of Sus scrofa domestica L. The work was carried out in the town of Chuyugual, La Libertad, a specimen of "pig" of 15 kg, was incinerated with diesel oil and protected with a metal cage. The insects were collected using conventional entomological techniques, species were determined with specialized taxonomic keys; for t
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15

Mendez, Julio. "Ein Fall von Räuberei bei überirdisch nistenden tropischen Termiten (Isoptera: Termitidae) durch zwei Fleischfliegenarten (Diptera: Sarcophagidae)." Entomologia Generalis 34, no. 1-2 (2012): 156–60. http://dx.doi.org/10.1127/entom.gen/34/2012/156.

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16

Cavallari, Maria Luiza, Fabio Navarro Baltazar, Silvio Shigueo Nihei, Daniel Romero Muñoz, and José Eduardo Tolezano. "Dipterofauna Associated withSus scrofaLinné, 1758, Carcasses in Urban and Coastal Regions of São Paulo State, Brazil." Psyche: A Journal of Entomology 2015 (2015): 1–12. http://dx.doi.org/10.1155/2015/983980.

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Cadaverous entomofauna successions vary according to the region, environment, and climate, and such differences may occur within the same country due to seasonal variations. The present study aimed to analyze and compare the dipterofauna that visit or colonize carcasses in the urban and coastal areas of São Paulo, Brazil, during summer and winter seasons. Four swine (Sus scrofaLinné, 1758) carcasses of approximately 12 kg were used. The animals were previously euthanized and then placed in metal cages covered with a flight intercept trap (Shannon, modified). In total, 10,495 flies from 39 fami
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17

Silva, José Orlando A., Leandro S. Brasil, Caroline C. De-Souza, and Fernando S. Carvalho-Filho. "Helicobia neuzalmeidae sp. nov., A New Species of Sarcophagidae (Diptera) Reared From a Pig Carcass in the Brazilian Savanna." Journal of Medical Entomology, July 28, 2022. http://dx.doi.org/10.1093/jme/tjac098.

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Abstract A new species of Sarcophagidae (Diptera) in the genus Helicobia Coquillett, Helicobia neuzalmeidae sp. nov., is described based on two male specimens obtained from pig carcasses in savanna-like vegetation in northeastern Brazil (state of Maranhão) during a forensic study. The holotype was obtained from a larva that abandoned the pig carcass to pupate, whereas the paratype was collected with a trap placed above the cage containing the carcass. This is the first record of a Helicobia species reared from a vertebrate carcass.
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18

Gesztelyi, Tamás. "Médeia az antik képzőművészetben." Studia Litteraria 56, no. 1-4 (2017). http://dx.doi.org/10.37415/studia/2017/56/4104.

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Images of Medea were closely linked to sepulchral thoughts from the very beginning, but this meaning was, from time to time, carried by a different motif of her story. In the age of archaic and partly classical style it was the magic of rejuvenation that represented the thought of overcoming death. Obtaining the Golden Fleece as depicted on the late classical South Italian vases as well as on the stucco of early imperial Basilica Sotterranea can be interpreted as a motif of redemption. Imagery of infanticide and rising on a dragon-drawn carriage also appears on South–Italian vases. Just like w
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