Relevant bibliographies by topics / Secondary acetylenic alcohol

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Academic literature on the topic 'Secondary acetylenic alcohol'

Author: Grafiati
Published: 5 June 2025
Last updated: 1 August 2025

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Journal articles on the topic "Secondary acetylenic alcohol"

1

Juraboev, Fozil Mamasolievich. "SYNTHESIS OF ACETYLENIC DIOLS BASED ON ACETYLENIC ALCOHOLS." Research Focus 1, no. 2 (2022): 17–22. https://doi.org/10.5281/zenodo.7237916.

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<em>This article examines the influence of various factors on the performance of the main product in the synthesis of acetylene diols based on direct condensation of acetylene alcohols with aldehydes and ketones.The influence of factors such as the structure and nature of acetylene alcohols on the yield of acetylenediols, the composition and nature of carbonyl compounds, temperature, catalyst, reaction duration has been studied.</em>
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2

Juraboev, Fozil. "Research of the synthesis of new acetylene aminoalcohols." E3S Web of Conferences 486 (2024): 05011. http://dx.doi.org/10.1051/e3sconf/202448605011.

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The article describes the synthesis of acetylene amino alcohols based on secondary acetylene alcohol and amino compounds containing a hydroxyl group, the results of scientific research and their analysis to study the influence of factors such as temperature and catalyst on the yield of the product in the process. In the course of the work, a new type of acetylene amino alcohol was obtained with high efficiency as a result of the condensation reaction of ethanolamine (or diethanolamine) with hex-1-yn- 3-ol mediated by formaldehyde. Optimal conditions for carrying out synthesis processes have be
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3

Yoshida, Akihiro, and Koichi Mikami. "Dramatic Changeover of Regioselectivity in the Reduction of Propargylic Phosphates by Palladium(0)/SmI2/Proton Source System." Synlett 12, no. 12 (1997): 1375–76. http://dx.doi.org/10.1055/s-0032-1316827.

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Abstract Regiodivergent synthesis of allenes and acetylenes was established in the reduction of propargylic phosphates. The palladium(0)-catalyzed reduction of secondary propargylic phosphates with samarium(II) iodide gave allenes or acetylenes by tuning proton sources (tert-butyl alcohol or dimethyl L-tartrate).
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4

Toda, Fumio, and Koichi Tanaka. "Optical Resolution of Tertiary Acetylenic Alcohols and Secondary Alcohols by Complexation with Achiral Amines." Chemistry Letters 15, no. 11 (1986): 1905–8. http://dx.doi.org/10.1246/cl.1986.1905.

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Potkin, V. I., E. A. Dikusar, E. V. Vashkevich, N. G. Kozlov, and K. L. Moiseichuk. "Secondary Acetylenic Alcohols and Peroxides Derived from (Z)-3-chloro-3-(2-naphthyl)-2-propenal." Russian Journal of General Chemistry 73, no. 9 (2003): 1410–13. http://dx.doi.org/10.1023/b:rugc.0000015989.14867.e4.

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Rodríguez, Ricardo I., Elsie Ramírez, Francisco Yuste, Rubén Sánchez-Obregón, and José Alemán. "Asymmetric Synthesis of Secondary and Tertiary Propargylic Alcohols by Umpolung of Acetylenic Sulfones and ortho-Sulfinyl Carbanions." Journal of Organic Chemistry 83, no. 4 (2018): 1940–47. http://dx.doi.org/10.1021/acs.joc.7b02887.

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7

Velíšek, J., and K. Cejpek. "Biosynthesis of food constituents: Lipids. 1. Fatty acids and derivated compounds – a review." Czech Journal of Food Sciences 24, No. 5 (2011): 193–216. http://dx.doi.org/10.17221/3317-cjfs.

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This review article gives a survey of the principal biosynthetic pathways that lead to the most important common fatty acids and their derivatives occurring in foods and feeds. Fatty acids are further subdivided to saturated fatty acids and unsaturated fatty acids. This review is focused on the less common fatty acids including geometrical and positional isomers of unsaturated fatty acids, acetylenic fatty acids, branched-chain fatty acids, alicyclic fatty acids, epoxy fatty acids, hydroxy fatty acids, and oxo fatty acids. A survey is further given on the biosynthesis of the aliphatic very-lon
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8

Barlow, Michael G., Sabiha Tajammal, and Anthony E. Tipping. "Fluorinated acetylenes. Part 9 [1]. Reaction of furan with the phenylethanoate esters derived from trifluoropropynyl secondary alcohols." Journal of Fluorine Chemistry 62, no. 1 (1993): 51–61. http://dx.doi.org/10.1016/s0022-1139(00)80080-9.

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BARLOW, M. G., S. TAJAMMAL, and A. E. TIPPING. "ChemInform Abstract: Fluorinated Acetylenes. Part 9. Reaction of Furan with the Phenylethanoate Esters Derived from Trifluoropropynyl Secondary Alcohols." ChemInform 25, no. 44 (2010): no. http://dx.doi.org/10.1002/chin.199444128.

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10

Sobenina, L. N., D. N. Tomilin, O. V. Petrova, A. I. Mikhaleva, and B. A. Trofimov. "Synthesis of secondary propargyl alcohols from aromatic and heteroaromatic aldehydes and acetylene in the system KOH-H2O-DMSO." Russian Journal of Organic Chemistry 49, no. 3 (2013): 356–59. http://dx.doi.org/10.1134/s107042801303007x.

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Book chapters on the topic "Secondary acetylenic alcohol"

1

Li, Jie Jack, Chris Limberakis, and Derek A. Pflum. "Oxidation." In Modern Organic Synthesis in the Laboratory. Oxford University Press, 2008. http://dx.doi.org/10.1093/oso/9780195187984.003.0009.

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Activated manganese dioxide (MnO2) reliably oxidizes acetylenic, allylic, and benzylic alcohols to aldehydes and ketones. Saturated primary and secondary alcohols are also oxidized, albeit more slowly. The two main concerns are the activity of the manganese dioxide and the slow filtration of salts after the reaction. Activated MnO2 is available commercially or may be prepared. To a solution of 15.3 g (37.5 mmol) of the alcohol in 150 mL of hexanes was added 60 g of activated MnO2. The reaction mixture was stirred at 22 °C overnight and filtered, and the solid residue was washed with 30% EtOAc
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2

Taber, Douglass. "Enantioselective Assembly of Oxygenated Stereogenic Centers." In Organic Synthesis. Oxford University Press, 2011. http://dx.doi.org/10.1093/oso/9780199764549.003.0032.

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Reaction with an enantiomerically-pure epoxide is an efficient way to construct a molecule incorporating an enantiomerically-pure oxygenated stereogenic center. The Jacobsen hydrolytic resolution has made such enantiomerically-pure epoxides readily available from the corresponding racemates. Christopher Jones and Marcus Weck of the Georgia Institute of Technology have now (J. Am. Chem. Soc. 2007, 129, 1105) developed an oligomeric salen complex that effects the enantioselective hydrolysis at remarkably low catalyst loading. Any such approach depends on monitoring the progress of the hydrolysis,
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