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Journal articles on the topic 'Self-assembled monolayers'

Author: Grafiati

Published: 4 June 2021

Last updated: 26 July 2025

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1

Baker, MV, and J. Landau. "Self Assembled Alkanethiolate Monolayers as Thin Insulating Films." Australian Journal of Chemistry 48, no. 6 (1995): 1201. http://dx.doi.org/10.1071/ch9951201.

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Simple devices that contain alkanethiolate monolayers sandwiched between conducting films were prepared by fixing a gold film to the surface of an alkanethiolate monolayer (on a gold substrate) with silver paint. These devices, and similar devices that did not contain alkanethiolate monolayers, were tested as resistors in d.c . circuits. The devices that contained octadecanethiolate monolayers had resistances of approximately 1012 Ω, 10 orders of magnitude higher than the resistance of devices that contained no monolayers. Sulfur- terminated alkanethiolate monolayers were prepared by treatment

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2

Pradeep, T. "Self assembled monolayers." Resonance 4, no. 1 (1999): 53–62. http://dx.doi.org/10.1007/bf02837153.

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3

Kudernac, Tibor, Natalia Shabelina, Wael Mamdouh, Sigurd Höger, and Steven De Feyter. "STM visualisation of counterions and the effect of charges on self-assembled monolayers of macrocycles." Beilstein Journal of Nanotechnology 2 (October 11, 2011): 674–80. http://dx.doi.org/10.3762/bjnano.2.72.

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Despite their importance in self-assembly processes, the influence of charged counterions on the geometry of self-assembled organic monolayers and their direct localisation within the monolayers has been given little attention. Recently, various examples of self-assembled monolayers composed of charged molecules on surfaces have been reported, but no effort has been made to prove the presence of counterions within the monolayer. Here we show that visualisation and exact localisation of counterions within self-assembled monolayers can be achieved with scanning tunnelling microscopy (STM). The p

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4

Baralia, Gabriel G., Antoine Pallandre, Bernard Nysten, and Alain M. Jonas. "Nanopatterned self-assembled monolayers." Nanotechnology 17, no. 4 (2006): 1160–65. http://dx.doi.org/10.1088/0957-4484/17/4/053.

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5

Smith, Rachel K., Penelope A. Lewis, and Paul S. Weiss. "Patterning self-assembled monolayers." Progress in Surface Science 75, no. 1-2 (2004): 1–68. http://dx.doi.org/10.1016/j.progsurf.2003.12.001.

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6

Muskal, Nechama, Iva Turyan, Avital Shurky, and Daniel Mandler. "Chiral Self-Assembled Monolayers." Journal of the American Chemical Society 117, no. 3 (1995): 1147–48. http://dx.doi.org/10.1021/ja00108a039.

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7

Dickie, Adam J., Ashok K. Kakkar, and Michael A. Whitehead. "Molecular modelling of self-assembled alkynyl monolayer structures Unnatural symmetry units, surface bonding, and topochemical polymerization1." Canadian Journal of Chemistry 81, no. 11 (2003): 1228–40. http://dx.doi.org/10.1139/v03-110.

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Geometric modelling techniques are used to map the potential energies of packing for self-assembled alkyl- and phenyl-backboned monolayers across a range of intermolecular separations. Natural packing distances of 4.24.4 Å produce less stable, more isotropic monolayers because of repulsive interchain contacts. Optimizations at unnatural surface densities found thin films of lower energy and higher symmetry existed at increased chainchain separations. Head-group bonding is therefore identified as a force for controlling monolayer order. Analysis of the natural monolayer structures on a silico

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8

Jadhav, Sushilkumar. "Self-assembled monolayers (SAMs) of carboxylic acids: an overview." Open Chemistry 9, no. 3 (2011): 369–78. http://dx.doi.org/10.2478/s11532-011-0024-8.

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AbstractThe field of self-assembled monolayers (SAMs) of organic compounds on different substrates is of importance because it provides a suitable and efficient method of surface modification. The formation of robust, stable monolayers from carboxylic acids on two and three dimensional surfaces of different substrates have been reported. Carboxylic acids are promising class of organic compounds for monolayer formations where traditional alkanethiols or alkoxysilanes show limitations.

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9

Losic, Dusan, Ken Short, Joe G. Shapter, and Justin J. Gooding. "Atomic Force Microscopy Imaging of Glucose Oxidase using Chemically Modified Tips." Australian Journal of Chemistry 56, no. 10 (2003): 1039. http://dx.doi.org/10.1071/ch03122.

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Atomic force microscopy (AFM) tips have been chemically modified using a variety of approaches mostly based on self-assembled monolayers (SAMs). Tips with both a hydrophobic and hydrophilic nature have been prepared and used to image glucose oxidase covalently attached to a self-assembled monolayer.

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10

Hoque, E., J. A. DeRose, P. Hoffmann, B. Bhushan, and H. J. Mathieu. "Alkylperfluorosilane Self-Assembled Monolayers on Aluminum: A Comparison with Alkylphosphonate Self-Assembled Monolayers." Journal of Physical Chemistry C 111, no. 10 (2007): 3956–62. http://dx.doi.org/10.1021/jp066101m.

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11

Seelenbinder, John A., Chris W. Brown, and Daniel W. Urish. "Self-Assembled Monolayers of Thiophenol on Gold as a Novel Substrate for Surface-Enhanced Infrared Absorption." Applied Spectroscopy 54, no. 3 (2000): 366–70. http://dx.doi.org/10.1366/0003702001949645.

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A unique method of obtaining surface-enhanced infrared absorption (SEIRA) spectra for chemicals that will not chemically attach to a metal surface has been investigated. Surface enhancements are greatest for molecules that bind to metals. In order to achieve greater enhancement for those analytes that do not bind to SEIRA metals, we have investigated self-assembled monolayers as a means of linking analytes to a gold substrate. Monolayers of thiophenol were formed onto sputter-coated gold–silicon substrates. Analytes were deposited onto the thiophenol-coated gold–silicon wafers, and external re

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12

Yi, Ruowei, Yayun Mao, Yanbin Shen, and Liwei Chen. "Self-Assembled Monolayers for Batteries." Journal of the American Chemical Society 143, no. 33 (2021): 12897–912. http://dx.doi.org/10.1021/jacs.1c04416.

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13

Wink, Th, S. J. van Zuilen, A. Bult, and W. P. van Bennekom. "Self-assembled Monolayers for Biosensors." Analyst 122, no. 4 (1997): 43R—50R. http://dx.doi.org/10.1039/a606964i.

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14

Ashwell, Geoffrey J., Gary A. N. Paxton, Anne J. Whittam, Wayne D. Tyrrel, Martial Berry, and Dejian Zhou. "Merocyanine dyes: self-assembled monolayers." Journal of Materials Chemistry 12, no. 6 (2002): 1631–35. http://dx.doi.org/10.1039/b110676g.

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15

Batchelder, D. N., S. D. Evans, T. L. Freeman, L. Haeussling, H. Ringsdorf, and H. Wolf. "Self-Assembled Monolayers containing Polydiacetylenes." Journal of the American Chemical Society 116, no. 3 (1994): 1050–53. http://dx.doi.org/10.1021/ja00082a028.

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16

Hostetler, Michael J., and Royce W. Murray. "Colloids and self-assembled monolayers." Current Opinion in Colloid & Interface Science 2, no. 1 (1997): 42–50. http://dx.doi.org/10.1016/s1359-0294(97)80007-6.

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17

Knobler, Charles M., and Daniel K. Schwartz. "Langmuir and self-assembled monolayers." Current Opinion in Colloid & Interface Science 4, no. 1 (1999): 46–51. http://dx.doi.org/10.1016/s1359-0294(99)00002-3.

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18

Willicut, Robert J., and Robin L. McCarley. "Electrochemically polymerizable self-assembled monolayers." Advanced Materials 7, no. 8 (1995): 759–62. http://dx.doi.org/10.1002/adma.19950070819.

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19

Wang, Yayun, Jun Cai, Hubert Rauscher, Rolf Jürgen Behm, and Werner A. Goedel. "Maleimido-Terminated Self-Assembled Monolayers." Chemistry - A European Journal 11, no. 13 (2005): 3968–78. http://dx.doi.org/10.1002/chem.200400896.

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20

Carson, George A., and Steve Granick. "Self-assembly of octadecyltrichlorosilane monolayers on mica." Journal of Materials Research 5, no. 8 (1990): 1745–51. http://dx.doi.org/10.1557/jmr.1990.1745.

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A method is described to deposit a securely attached, self-assembled monolayer of octadecyltrichlorosilane (OTS) on the surface of freshly cleaved muscovite mica. Comparison of the infrared methylene spectra with those of closely packed Langmuir-Blodgett films implies that the surface coverage of the OTS films was a fraction 0.8–0.9 that of films formed by Langmuir-Blodgett (LB) methods. However, LB monolayers are less securely attached to the substrate. The contact angle of water on these self-assembled monolayers remained over 100° for over 24 h and it suffered no noticeable degradation afte

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21

Herr, Brian R., and Chad A. Mirkin. "Self-Assembled Monolayers of Ferrocenylazobenzenes: Monolayer Structure vs Response." Journal of the American Chemical Society 116, no. 3 (1994): 1157–58. http://dx.doi.org/10.1021/ja00082a058.

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22

Breton, Gary W. "1-[2,6-Dimethyl-4-(pent-4-yn-1-yloxy)phenyl]-4-phenyl-1,2,4-triazolidine-3,5-dione." Molbank 2023, no. 1 (2023): M1578. http://dx.doi.org/10.3390/m1578.

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Urazolyl radicals are a class of persistent nitrogen-centered radicals. In a previous work, we successfully formed self-assembled monolayers of substituted urazolyl radicals on gold surfaces. To extend the scope of these investigations, we sought to form a self-assembled monolayer using a urazolyl radical species that we knew existed predominantly in the dimerized N-N form instead of existing predominantly as free N-centered radical species, as had previously been investigated. We successfully synthesized the precursor urazole compound needed to generate the desired urazolyl radical, and compl

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23

Neves, B. R. A., M. E. Salmon, E. B. Troughton, and P. E. Russell. "Self-healing on OPA self-assembled monolayers." Nanotechnology 12, no. 3 (2001): 285–89. http://dx.doi.org/10.1088/0957-4484/12/3/315.

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24

Wang, Zhen, Yan-Li Shi, and Hu-Lin Li. "Investigation of two-component mixed self-assembled monolayers on gold." Canadian Journal of Chemistry 79, no. 3 (2001): 328–36. http://dx.doi.org/10.1139/v01-022.

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Two-component mixed self-assembled monolayers (SAMs) composed of 2-mercapto-5-methyl-1,3,4-oxadiazole (MMO) and 1-dodecanethiol (C12SH) in various molar percentages were prepared on gold surfaces by self-assembly. X-ray photoelectron spectroscopy (XPS) and wettability results gave evidence that the coverage of MMO was controlled by the composition of MMO in the assembling solution. The monolayer coverage and apparent rate constant of the redox active probes in solution of different molar ratios of mixed SAMs could be calculated using impedance measurements. The cyclic voltammetry reveals that

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25

Hinckley, Adam P., and Anthony J. Muscat. "Wet Chemical Cleaning of Organosilane Monolayers." Solid State Phenomena 314 (February 2021): 54–59. http://dx.doi.org/10.4028/www.scientific.net/ssp.314.54.

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Thin organic self-assembled monolayer films are used to promote adhesion and seal the pores of metal oxides as well as direct the deposition of layers on patterned surfaces. Defects occur as the self-assembled monolayer forms, and the number and type of defects depend on surface preparation, deposition solvent, temperature, time and other parameters. Particles commonly deposit during organosilane self-assembly on metal oxide surfaces. The particles are defects because they are prone to react in subsequent processing, which may not be desirable if the organosilane serves as a pore sealant or pa

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26

Aslam, M., N. K. Chaki, Jadab Sharma, and K. Vijayamohanan. "Device applications of self-assembled monolayers and monolayer-protected nanoclusters." Current Applied Physics 3, no. 2-3 (2003): 115–27. http://dx.doi.org/10.1016/s1567-1739(02)00180-3.

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27

Gimenez-Lopez, Maria del Carmen, Jules A. Gardener, Adam Q. Shaw, et al. "Endohedral metallofullerenes in self-assembled monolayers." Phys. Chem. Chem. Phys. 12, no. 1 (2010): 123–31. http://dx.doi.org/10.1039/b915170b.

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28

del Carmen Gimenez-Lopez, Maria, Minna T. Räisänen, Thomas W. Chamberlain, et al. "Functionalized Fullerenes in Self-Assembled Monolayers." Langmuir 27, no. 17 (2011): 10977–85. http://dx.doi.org/10.1021/la200654n.

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29

Freitas, Sidónio C., Alejandra Correa-Uribe, M. Cristina L. Martins, and Alejandro Pelaez-Vargas. "Self-Assembled Monolayers for Dental Implants." International Journal of Dentistry 2018 (2018): 1–21. http://dx.doi.org/10.1155/2018/4395460.

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Implant-based therapy is a mature approach to recover the health conditions of patients affected by edentulism. Thousands of dental implants are placed each year since their introduction in the 80s. However, implantology faces challenges that require more research strategies such as new support therapies for a world population with a continuous increase of life expectancy, to control periodontal status and new bioactive surfaces for implants. The present review is focused on self-assembled monolayers (SAMs) for dental implant materials as a nanoscale-processing approach to modify titanium surf

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30

Evans, Deborah, and Rodric Wampler. "Electron Transmission through Self-Assembled Monolayers." Journal of Physical Chemistry B 103, no. 22 (1999): 4666–71. http://dx.doi.org/10.1021/jp984811p.

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31

Ejgenberg, Michal, and Yitzhak Mastai. "Conglomerate crystallization on self-assembled monolayers." Chemical Communications 47, no. 44 (2011): 12161. http://dx.doi.org/10.1039/c1cc14952k.

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32

Chang, Ryongsok, Syifa Asatyas, Ganchimeg Lkhamsuren, et al. "Water near bioinert self-assembled monolayers." Polymer Journal 50, no. 8 (2018): 563–71. http://dx.doi.org/10.1038/s41428-018-0075-1.

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33

Casalini, Stefano, Carlo Augusto Bortolotti, Francesca Leonardi, and Fabio Biscarini. "Self-assembled monolayers in organic electronics." Chemical Society Reviews 46, no. 1 (2017): 40–71. http://dx.doi.org/10.1039/c6cs00509h.

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34

D’Acunto, Mario. "Onset wear in self-assembled monolayers." Nanotechnology 17, no. 12 (2006): 2954–62. http://dx.doi.org/10.1088/0957-4484/17/12/022.

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35

Delamarche, E., B. Michel, H. Kang, and Ch Gerber. "Thermal Stability of Self-Assembled Monolayers." Langmuir 10, no. 11 (1994): 4103–8. http://dx.doi.org/10.1021/la00023a033.

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36

Horn, Andrew B., David A. Russell, Lora J. Shorthouse, and Tim R. E. Simpson. "Ageing of alkanethiol self-assembled monolayers." Journal of the Chemical Society, Faraday Transactions 92, no. 23 (1996): 4759. http://dx.doi.org/10.1039/ft9969204759.

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37

Singh, Aniruddh, In Sung Lee, Kitae Kim, and Allan S. Myerson. "Crystal growth on self-assembled monolayers." CrystEngComm 13, no. 1 (2011): 24–32. http://dx.doi.org/10.1039/c0ce00030b.

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38

Rieke, P. C., D. R. Baer, G. E. Fryxell, M. H. Engelhard, and M. S. Porter. "Beam damage of self‐assembled monolayers." Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films 11, no. 4 (1993): 2292–97. http://dx.doi.org/10.1116/1.578364.

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39

Gooding, J. Justin, Penny S. Hale, Leone M. Maddox, and Joe G. Shapter. "Surface pKa of Self-Assembled Monolayers." Journal of Chemical Education 82, no. 5 (2005): 779. http://dx.doi.org/10.1021/ed082p779.

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40

Ulman, Abraham. "Self-Assembled Monolayers of 4-Mercaptobiphenyls." Accounts of Chemical Research 34, no. 11 (2001): 855–63. http://dx.doi.org/10.1021/ar0001564.

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41

Ulman, Abraham, Jung F. Kang, Yitzhak Shnidman, et al. "Self-assembled monolayers of rigid thiols." Reviews in Molecular Biotechnology 74, no. 3 (2000): 175–88. http://dx.doi.org/10.1016/s1389-0352(00)00013-1.

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42

Braach-Maksvytis, Vijoleta, and Burkhard Raguse. "Highly Impermeable “Soft” Self-Assembled Monolayers." Journal of the American Chemical Society 122, no. 39 (2000): 9544–45. http://dx.doi.org/10.1021/ja000917y.

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43

Mandler, Daniel. "Chiral self-assembled monolayers in electrochemistry." Current Opinion in Electrochemistry 7 (January 2018): 42–47. http://dx.doi.org/10.1016/j.coelec.2017.09.030.

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44

Muskal, Nechama, Iva Turyan, and Daniel Mandler. "Self-assembled monolayers on mercury surfaces." Journal of Electroanalytical Chemistry 409, no. 1-2 (1996): 131–36. http://dx.doi.org/10.1016/0022-0728(96)04529-9.

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45

Aoki, Koichi. "Statistical mechanics of self-assembled monolayers." Journal of Electroanalytical Chemistry 327, no. 1-2 (1992): 73–83. http://dx.doi.org/10.1016/0022-0728(92)80137-s.

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46

Mizutani, Wataru. "Patterning and Functionalizing Self-Assembled Monolayers." Japanese Journal of Applied Physics 38, Part 1, No. 12B (1999): 7260–63. http://dx.doi.org/10.1143/jjap.38.7260.

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47

Pipolo, Silvio, and Stefano Corni. "Wettability of Azobenzene Self-Assembled Monolayers." Langmuir 30, no. 15 (2014): 4415–21. http://dx.doi.org/10.1021/la404922f.

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48

Wang, Wenyong, Takhee Lee, and Mark A. Reed. "Electron tunnelling in self-assembled monolayers." Reports on Progress in Physics 68, no. 3 (2005): 523–44. http://dx.doi.org/10.1088/0034-4885/68/3/r01.

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49

Schmid, Friederike, Christoph Stadler, and Dominik Düchs. "Computer simulations of self-assembled monolayers." Journal of Physics: Condensed Matter 13, no. 38 (2001): 8653–59. http://dx.doi.org/10.1088/0953-8984/13/38/308.

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50

Chaudhury, Manoj K. "Self-assembled monolayers on polymer surfaces." Biosensors and Bioelectronics 10, no. 9-10 (1995): 785–88. http://dx.doi.org/10.1016/0956-5663(95)99216-8.

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