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Journal articles on the topic 'Semiorganic NLO'

Author: Grafiati

Published: 3 June 2025

Last updated: 1 August 2025

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1

M., Andiappan, Selvarajan P., and Perumal S. "GROWTH AND STUDIES OF UREA CADMIUM SULFATE CRYSTALS." International Journal of Applied and Advanced Scientific Research 2, no. 2 (2017): 257–63. https://doi.org/10.5281/zenodo.1067138.

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Nonlinear optical (NLO) materials have applications in harmonic frequency generation devices, hybrid bistable devices, modulators, parametric amplifiers and IR converters, optical bistability, phase conjugation, frequency tripling in deep UV conversion, optical communication, optical computing, optical data processing, photonics etc. Organic nonlinear optical (NLO) crystals have poor mechanical strength, poor thermal stability and highly volatile and these disadvantages can be avoided in inorganic and semiorganic NLO crystals. In this research work, a semiorganic crystal namely urea cadmium su

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2

Thomas, P. C., S. Aruna, A. Anuradha, J. Packiam Julius, A. Joseph Arul Pragasam, and P. Sagayaraj. "Growth and characterization of semiorganic NLO crystals of LAHClBr." Crystal Research and Technology 41, no. 12 (2006): 1231–35. http://dx.doi.org/10.1002/crat.200610755.

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3

Santhakumari, R., K. Ramamurthi, R. Ramesh Babu, Helen Stoeckli Evans, G. Bhagavannarayana, and R. Hema. "Growth and characterization of thiosemicarbazide hydrochloride: A semiorganic NLO material." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 82, no. 1 (2011): 102–7. http://dx.doi.org/10.1016/j.saa.2011.07.007.

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4

Dhanaraj, P. V., and N. P. Rajesh. "Growth and characterization of triglycine calcium dibromide, a semiorganic NLO material." Physica B: Condensed Matter 405, no. 19 (2010): 4105–10. http://dx.doi.org/10.1016/j.physb.2010.06.061.

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5

Jeyakumari, A. Pricilla, S. Dhanuskodi, and S. Manivannan. "Phase matchable semiorganic NLO material for frequency doubling: l-Arginine tetrafluoroborate." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 63, no. 1 (2006): 91–95. http://dx.doi.org/10.1016/j.saa.2005.04.051.

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6

Gandhimathi, R., C. Muthu Krishnan, and P. Selvarajan. "Growth and characterization of Manganese Sulpho Tartrate (MST)—A semiorganic NLO crystal." Optik 126, no. 21 (2015): 2925–29. http://dx.doi.org/10.1016/j.ijleo.2015.07.052.

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7

Dhanuskodi, S., A. Pricilla Jeyakumari, and S. Manivannan. "Semiorganic NLO material for short-wavelength generation 2-amino-5-nitropyridinium bromide." Journal of Crystal Growth 282, no. 1-2 (2005): 72–78. http://dx.doi.org/10.1016/j.jcrysgro.2005.04.108.

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8

Sudhakar, G., and D. Rajan Babu. "Growth and characterization of piperazine oxalic acid monochloride semiorganic NLO single crystals." Optical Materials 150 (April 2024): 115123. http://dx.doi.org/10.1016/j.optmat.2024.115123.

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9

Martin Britto Dhas, S. A., and S. Natarajan. "Growth and characterization of Lithium hydrogen oxalate monohydrate, a new semiorganic NLO material." Materials Letters 62, no. 6-7 (2008): 1136–38. http://dx.doi.org/10.1016/j.matlet.2007.07.069.

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10

Chandrasekaran, J., P. Ilayabarathi, and P. Maadeswaran. "Crystal growth and characterization of L-valine cadmium acetate a semiorganic NLO crystals." Optics Communications 285, no. 18 (2012): 3872–76. http://dx.doi.org/10.1016/j.optcom.2012.05.009.

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11

Dhanuskodi, S., K. Vasantha, and P. A. Angeli Mary. "Structural and thermal characterization of a semiorganic NLO material: l-alanine cadmium chloride." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 66, no. 3 (2007): 637–42. http://dx.doi.org/10.1016/j.saa.2005.06.052.

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12

Esthaku Peter, M., and P. Ramasamy. "Synthesis, growth and characterization of a novel semiorganic NLO crystal: Triglycine calcium dibromide." Journal of Crystal Growth 312, no. 12-13 (2010): 1952–56. http://dx.doi.org/10.1016/j.jcrysgro.2010.03.015.

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13

T R, Beena. "GROWTH AND CHARACTERIZATION OF A SEMIORGANIC NLO MATERIAL: L-HISTIDINE BARIUM CHLORIDE DIHYDRATE." Green Chemistry & Technology Letters 2, no. 1 (2016): 26–30. http://dx.doi.org/10.18510/gctl.2015.215.

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L-Histidine Barium Chloride dihydrate (LHBC), a semi organic nonlinear optical material was grown from aqueous solution by slow solvent evaporation method at room temperature. The LHBC crystals were characterized by X-ray powder diffraction analysis. The presence of functional groups was identified through Fourier Transform Infrared Spectroscopy. Thermogravimetric and Differential Thermal Analysis confirm that the crystal is stable up to 269oC. The mechanical properties of the grown crystals have been studied using Vickers microhardness test. The second harmonic generation behavior of LHBC cry

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14

Uma, J., and V. Rajendran. "Growth and characterization of semiorganic NLO crystal of l-glutamic acid hydrochlorobromide (LGHCB)." Journal of Thermal Analysis and Calorimetry 117, no. 3 (2014): 1157–63. http://dx.doi.org/10.1007/s10973-014-3898-9.

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15

U., Rajesh Kannan, Narayanasamy G., Subramanian S., and Selvarajan P. "INVESTIGATION ON GROWTH AND CHARACTERIZATION OF TETRAKIS-THIOUREA NICKEL SULPHATE CRYSTALS." International Journal of Advanced Trends in Engineering and Technology 2, no. 2 (2017): 185–93. https://doi.org/10.5281/zenodo.1066102.

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Nonlinear optical (NLO) crystals are classified into organic, inorganic and semiorganic crystals and these crystals are used in the fields of optical communication, optical computing, frequency doubling, optical data processing and opto electronics. In this work a semi-organic crystal namely tetrakis-thiourea nickel sulphate (TTNS) crystal was prepared. Slow evaporation technique was adopted to grow the single crystals of tetrakis-thiourea nickel sulphate after the growth period of 25 days. Bulk crystals were harvested from the supersaturated solution at room temperature. The harvested crystal

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16

Thiyagaraj, S., and G. Meenakshi. "Ocular Suitability of Fertilizer (Urea) Doped Semiorganic NLO Single Crystal: Tri-Glycine Potassium Chloride." International Journal of Computer Applications 51, no. 13 (2012): 44–48. http://dx.doi.org/10.5120/8106-1705.

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17

Hou, Dianwei, Bing-Hua Lei, Shilie Pan, Bingbing Zhang, and Zhihua Yang. "Influence of original and simulated microscopic units on SHG response in semiorganic NLO materials." RSC Advances 6, no. 46 (2016): 39534–40. http://dx.doi.org/10.1039/c6ra02474b.

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18

Zhang, Yun, Hua Li, Bin Xi, Yunxia Che, and Jimin Zheng. "Growth and characterization of l-histidine nitrate single crystal, a promising semiorganic NLO material." Materials Chemistry and Physics 108, no. 2-3 (2008): 192–95. http://dx.doi.org/10.1016/j.matchemphys.2007.09.006.

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19

Paul Chinnappan, Christuraj, Anbarasu Selvaraj, Joseph Pitchaimuthu Stalin, and Prem Anand Devarajan. "Growth and characterization studies of l-threonine phosphate (LTP) a new semiorganic NLO crystal." Optik 126, no. 24 (2015): 5517–21. http://dx.doi.org/10.1016/j.ijleo.2015.09.090.

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20

Dhanuskodi, S., and J. Ramajothi. "Crystal growth, thermal and optical studies of L-histidine tetrafluoroborate: A semiorganic NLO material." Crystal Research and Technology 39, no. 7 (2004): 592–97. http://dx.doi.org/10.1002/crat.200310229.

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21

Sindhusha, S., C. M. Padma, B. Gunasekaran, and H. Marshan Robert. "Structural, optical and thermal analysis of creatininium borate – A new semiorganic nlo single crystal." Journal of Molecular Structure 1209 (June 2020): 127981. http://dx.doi.org/10.1016/j.molstruc.2020.127981.

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22

Dalal, Jyoti, Nidhi Sinha, Harsh Yadav, and Binay Kumar. "Structural, electrical, ferroelectric and mechanical properties with Hirshfeld surface analysis of novel NLO semiorganic sodium p-nitrophenolate dihydrate piezoelectric single crystal." RSC Advances 5, no. 71 (2015): 57735–48. http://dx.doi.org/10.1039/c5ra10501c.

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Structural and Hirshfeld surface analysis of sodiump-nitrophenolate dihydrate single crystal with excellent ferroelectric, mechanical, photoluminescence and NLO properties for optoelectronic device applications.

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23

Rajesh, K., A. Mani, V. Thayanithi, and P. Praveen Kumar. "Optical, Thermal, and Mechanical Properties of L-Serine Phosphate, a Semiorganic Enhanced NLO Single Crystal." International Journal of Optics 2016 (2016): 1–5. http://dx.doi.org/10.1155/2016/9070714.

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Single crystals of L-serine phosphate (LSP) were grown by slow evaporation technique. The optical studies reveal the transparency of the crystal in the entire visible region. Grown crystal was subjected to single crystal XRD diffraction technique. Thermal studies of LSP confirm the thermal stability of the crystal and it is stable up to 210°C. The functional groups and optical behaviour of the crystal were identified from FT-IR and UV-Vis analysis. The crystals were also characterized by microhardness and photoconductivity to determine the mechanical strength and the optical conductivity. Lase

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24

Suvitha, A., and P. Murugakoothan. "Synthesis, growth, structural, spectroscopic and optical studies of a semiorganic NLO crystal: Zinc guanidinium phosphate." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 86 (February 2012): 266–70. http://dx.doi.org/10.1016/j.saa.2011.10.034.

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25

Uma, B., K. Sakthi Murugesan, R. Jayavel, S. Krishnan, and B. Milton Boaz. "Growth, spectral, optical, and dielectric studies on novel semiorganic NLO single crystal: d-phenylglycine hydrochloride." Applied Physics B 115, no. 2 (2013): 215–24. http://dx.doi.org/10.1007/s00340-013-5592-1.

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26

Anandan, Pandurangan, and Ramasamy Jayavel. "Crystal growth and characterization of semiorganic single crystals of l-histidine family for NLO applications." Journal of Crystal Growth 322, no. 1 (2011): 69–73. http://dx.doi.org/10.1016/j.jcrysgro.2011.02.021.

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27

PASUPATHI, G., and P. PHILOMINATHAN. "CRYSTAL GROWTH, THERMAL, OPTICAL AND MICROHARDNESS STUDIES OF TRIS (THIOUREA) MAGNESIUM SULPHATE: A SEMIORGANIC NLO MATERIAL." Modern Physics Letters B 23, no. 25 (2009): 3035–43. http://dx.doi.org/10.1142/s0217984909021107.

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Single crystals of tris (Thiourea) magnesium sulphate (MTS) were grown from aqueous solution by low temperature solution growth technique. The grown crystals have been characterized by X-ray diffraction to confirm the formation of the crystalline phases. The presence of functional groups was identified by Fourier transform infrared spectroscopy. The optical transmission spectrum showed that a lower cut-off wavelength of MTS crystal is below 300 nm and it has a wide transparency window, which is suitable for second harmonic generation of laser in the blue region. The thermal stabilities were st

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28

Mary Linet, J., S. Dinakaran, and S. Jerome Das. "Optical and microhardness studies on unidirectional grown triaqua glycine sulfato zinc (II): A semiorganic NLO crystal." Journal of Alloys and Compounds 509, no. 9 (2011): 3832–36. http://dx.doi.org/10.1016/j.jallcom.2010.12.083.

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29

Ramajothi, J., S. Dhanuskodi, and K. Nagarajan. "Crystal growth, thermal, optical and microhardness studies of tris (thiourea) zinc sulphate - a semiorganic NLO material." Crystal Research and Technology 39, no. 5 (2004): 414–20. http://dx.doi.org/10.1002/crat.200310204.

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30

Natarajan, S., G. P. Chitra, S. A. Martin Britto Dhas, and S. Athimoolam. "Growth, structural, thermal and optical studies on L-glutamic acid hydrobromide – A new semiorganic NLO material." Crystal Research and Technology 43, no. 7 (2008): 713–19. http://dx.doi.org/10.1002/crat.200711089.

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31

Lu, Jing, Xin Liu, Min Zhao, et al. "Discovery of NLO Semiorganic (C5H6ON)+(H2PO4)−: Dipole Moment Modulation and Superior Synergy in Solar-Blind UV Region." Journal of the American Chemical Society 143, no. 9 (2021): 3647–54. http://dx.doi.org/10.1021/jacs.1c00959.

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32

Priakumari, R. Omegala, S. Grace Sahaya Sheba, and M. Gunasekaran. "Growth and characterisation of l-lysine hydrochlorobromide (LYHCBr), a novel semiorganic non-linear optical (NLO) single crystal." Materials Research Innovations 20, no. 3 (2016): 177–81. http://dx.doi.org/10.1179/1433075x15y.0000000042.

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33

Prabu, P., B. Vijayabhaskaran, G. Vasuki, and C. Ramachandra Raja. "Growth, structural, optical and thermal properties of a new semiorganic NLO crystal: L-prolyl mercury (II) chloride." Optics & Laser Technology 98 (January 2018): 12–18. http://dx.doi.org/10.1016/j.optlastec.2017.07.033.

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34

Srineevasan, R., A. Anbarasi, T. Revathi, and S. M. Ravi Kumar. "Growth and characterizations of a new semiorganic nonlinear optical material thiourea potassium hydrogen phthalate for NLO applications." Materials Chemistry and Physics 177 (July 2016): 25–30. http://dx.doi.org/10.1016/j.matchemphys.2016.03.024.

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35

Maadeswaran, P., J. Chandrasekaran, and S. Thirumalairajan. "Synthesis, growth, spectral, thermal and photoluminescence properties of a new semiorganic NLO crystal—Thiosemicarbazide lithium chloride [TSLC]." Optik 122, no. 3 (2011): 259–62. http://dx.doi.org/10.1016/j.ijleo.2009.11.031.

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36

Jothi, R. Arul, R. U. Mullai, S. Gopinath, S. Vetrivel, and E. vinoth. "Material synthesis and characterization of NLO-active potassium hydrogen phthalate fumaric acid semiorganic crystal for frequency conversion." Journal of Materials Science: Materials in Electronics 31, no. 1 (2019): 791–98. http://dx.doi.org/10.1007/s10854-019-02587-0.

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37

Dhanabal, T., and G. Amirthaganesan. "Growth, spectral, thermal and dielectric studies on a new semiorganic NLO material: Di-N-methylanilinium tetrachlorocadmiate(II)." Optik 125, no. 1 (2014): 238–42. http://dx.doi.org/10.1016/j.ijleo.2013.06.066.

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38

Azhar, S. M., S. S. Hussaini, M. D. Shirsat, et al. "Growth and optical studies of tris (thiourea) potassium barium sulphate crystal: a novel semiorganic NLO bimetallic crystal." Materials Research Innovations 23, no. 3 (2017): 123–28. http://dx.doi.org/10.1080/14328917.2017.1392694.

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39

Anbarasi, A., S. M. Ravi Kumar, M. Packiya Raj, et al. "Synthesis, growth and characterization of semiorganic nonlinear optical single crystal bis(thiourea) barium nitrate (BTBN) for frequency conversion." Materials Science-Poland 37, no. 3 (2019): 381–88. http://dx.doi.org/10.2478/msp-2019-0039.

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AbstractA novel semiorganic nonlinear optical (NLO) crystal, bis(thiourea) barium nitrate (BTBN) was synthesized and grown by slow evaporation method. Structure of the new crystalline compound was confirmed by single crystal X-ray diffraction analysis and it showed that BTBN belongs to orthorhombic crystal system. The crystalline nature of the BTBN was confirmed by powder X-ray diffraction study. Important functional groups of BTBN were identified by FT-IR spectroscopic analysis. UV-Vis-NIR spectral study showed that the grown crystal is transparent in the entire visible region with low cut of

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40

Vinoth, E., S. Vetrivel, S. Gopinath, R. Aruljothi, T. Suresh, and R. U. Mullai. "Growth and characterization of 4-(((4-aminophenyl)sulfonyl)oxy)-2,3-dihydroxy-4-oxobutanoic acid with Ce3+: for semiorganic nonlinear optical application." Materials Science-Poland 38, no. 4 (2020): 584–93. http://dx.doi.org/10.2478/msp-2020-0078.

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Abstract This work aims at the growth and characterization of novel semi-organometallic nonlinear optical (NLO) crystal 4-(((4- aminophenyl) sulfonyl) oxy)-2,3-dihydroxy-4-oxobutanoic acid (ASODA) with ammonium ceric (II) sulfate dehydrate (ACS). The crystal 4-(((4-aminophenyl) sulfonyl) oxy)-2,3-dihydroxy-4-oxobutanoic acid with Ce3+ (STA) was grown by slow evaporation solution growth technique using deionized water as a solvent. Crystalline system of the grown STA crystal was identified by a single crystal X-ray diffraction study and confirmed as monoclinic crystalline system with non-centro

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41

Dinakaran, S., Sunil Verma, and S. Jerome Das. "Solubility, crystal growth, morphology, crystalline perfection and optical homogeneity of lithium p-nitrophenolate trihydrate, a semiorganic NLO crystal." CrystEngComm 13, no. 7 (2011): 2375. http://dx.doi.org/10.1039/c0ce00663g.

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42

Boaz, B. Milton, P. Santhana Raman, S. Xavier Jesu Raja, and S. Jerome Das. "The structural, microhardness and thermal properties of a semiorganic NLO crystal: Lithium paranitrophenolate trihydrate (NO2–C6H4–OLi·3H2O)." Materials Chemistry and Physics 93, no. 1 (2005): 187–93. http://dx.doi.org/10.1016/j.matchemphys.2005.03.046.

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43

Manivannan, S., S. Dhanuskodi, K. Kirschbaum, and S. K. Tiwari. "Design of an Efficient Solution Grown Semiorganic NLO Crystal for Short Wavelength Generation: 2-Amino-5-nitropyridinium Tetrafluoroborate." Crystal Growth & Design 5, no. 4 (2005): 1463–68. http://dx.doi.org/10.1021/cg049562a.

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44

Dhanuskodi, S., and K. Vasantha. "X-ray diffraction, spectroscopic and thermal studies on a potential semiorganic NLO material: lithium bis-l-malato borate." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 61, no. 8 (2005): 1777–82. http://dx.doi.org/10.1016/j.saa.2004.07.008.

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45

Dhavud, S. Shek, and J. ThomasJoseph Prakash. "Effect of semiorganic additive on the growth and characterization of NLO properties of NaAP single crystals for optoelectronic applications." International Journal of Advanced Research 4, no. 8 (2016): 685–95. http://dx.doi.org/10.21474/ijar01/1265.

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46

Shkir, Mohammed, V. K. Jain, S. AlFaify, M. M. Abutalib, I. S. Yahiya, and M. Ajmal Khan. "Molecular structure, spectroscopic (IR, Raman, Ultra Violet-Visible) and nonlinear optical investigation on DCBLPZ: A novel semiorganic NLO material." Journal of Theoretical and Computational Chemistry 14, no. 08 (2015): 1550061. http://dx.doi.org/10.1142/s0219633615500613.

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Dichlorobis(L-proline) zinc(II) (DCBLPZ) is an excellent nonlinear optical (NLO) material because of its ability to exhibit high second harmonic generation and having significant optical transparency. In this work, electro-optical properties of the titled material has been thoroughly investigated by Hartree–Fock (HF) and Density functional theory using different basis sets in C1 symmetry. The calculated geometrical parametres and vibrational frequencies were found to be in good agreement with reported experimental results. Highest occupied molecular orbital (HOMO) and lowest unoccupied molecul

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47

Subhashini, R., P. S. Latha Mageshwari, V. Sivashankar, and S. Arjunan. "Design of an efficient solution grown semiorganic NLO crystal for short wavelength generation: Bis(L-Threonine) magnesium (II) monohydrate." Materials Letters 200 (August 2017): 109–12. http://dx.doi.org/10.1016/j.matlet.2017.04.084.

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48

Vetrivel, S., P. Anandan, K. Kanagasabapathy, Suman Bhattacharya, S. Gopinath, and R. Rajasekaran. "Effect of zinc chloride on the growth and characterization of L-proline cadmium chloride monohydrate semiorganic NLO single crystals." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 110 (June 2013): 317–23. http://dx.doi.org/10.1016/j.saa.2013.03.074.

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49

N., Rathna, S. John V., Chithambarathanu T., and Selvarajan P. "GROWTH AND CHARACTERIZATION OF PURE AND SODIUM SULPHATE DOPED CRYSTALS OF GLYCINE POTASSIUM SULPHATE." International Journal of Current Research and Modern Education 3, no. 1 (2018): 284–90. https://doi.org/10.5281/zenodo.1198788.

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Single crystals of undoped (pure) glycine potassium sulphate (GPS) and sodium sulphate doped glycine potassium sulphate have been grown by the free evaporation method and the grown crystals have been characterized by various studies. Effect of sodium sulphate on the properties of glycine potassium sulphate (GPS) has been investigated here. X-ray diffraction analysis indicates the structure of the crystals as orthorhombic. The functional groups have been identified using Fourier transform infrared spectral analysis. The UV –Vis-NIR spectral analysis shows that these crystals have their cu

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50

Johnson, J., R. Srineevasan, and D. Sivavishnu. "Crystal growth, optical bandgap, thermal, mechanical, dielectric studies on NLO active semiorganic 4-dimethylaminopyridine sodium chloride crystal for frequency conversion." Journal of Materials Science: Materials in Electronics 30, no. 24 (2019): 21199–209. http://dx.doi.org/10.1007/s10854-019-02493-5.

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