Relevant bibliographies by topics / Silatrane

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  2. Dissertations / Theses
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Academic literature on the topic 'Silatrane'

Author: Grafiati
Published: 4 June 2021
Last updated: 1 February 2022

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Journal articles on the topic "Silatrane"

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Istratov, V. V., E. V. Andreeva, V. I. Gomzyak, and V. A. Vasnev. "SILATRANE-CONTAINING POLYMETHACRYLATES." Fine Chemical Technologies 14, no. 1 (2019): 82–89. http://dx.doi.org/10.32362/2410-6593-2019-14-1-82-89.

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The possibility of synthesizing silatrane-containing polymers was investigated using three different synthetic methods: the formation of silatrane fragments from polymers with trialkoxysilyl groups, the copolymerization of silatrane-containing monomers, and the reaction of silatranes with functional copolymers. The obtained polymethacrylate copolymers were characterized using gel permeation chromatography, IR and NMR spectroscopy. It was shown that depending on the synthesis scheme used, polymers were obtained in the form of three-dimensional structures or soluble products. It was established
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Wagner, Gabriele, Rudolf Herrmann, BjØrn Pedersen, and Wolfgang Scherer. "Synthesis and Structure of Chiral Silatranes Derived from Terpenes." Zeitschrift für Naturforschung B 56, no. 1 (2001): 25–38. http://dx.doi.org/10.1515/znb-2001-0105.

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Abstract Starting with the chiral pool compounds (-)-menthone, (-)-limonene, (-)-β-pinene, and (-)-carvone, new homochiral triethanolamine derivatives were obtained and converted to chi­ral silatranes. These silatranes were characterized by crystal structure analyses and NMR techniques. Conformational analyses in the solid state and in solution show that the chiral terpene residues determine the direction of the ring puckering of the silatrane moiety.
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Singh, Gurjaspreet, Akshpreet Singh, Jasbhinder Singh, et al. "First synthesis of pyrene-functionalized silatranes for mechanistic insights into their potential anti-parasitic and anti-oxidation activities." New Journal of Chemistry 41, no. 24 (2017): 15165–72. http://dx.doi.org/10.1039/c7nj03338a.

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The known silatranes have attached substituents such as hydrogen, organyl, organoxy, aminoalkyl, thioorganyl, acyloxy, halogen, pseudohalogen, and other groups; however, their functionalization with any polycyclic aromatic hydrocarbon substituent is not recognized; this creates a niche in silatrane chemistry.
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Sakaki, Shigeyoshi, Daisuke Kawai, and Shinya Tsukamoto. "Theoretical study of metallasilatranes; Bonding nature and prediction of new metallasilatrane." Collection of Czechoslovak Chemical Communications 76, no. 5 (2011): 619–29. http://dx.doi.org/10.1135/cccc2011054.

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The new bond between Pt atom and hypervalent six-coordinate Si species in platinum-silatrane reported recently was theoretically investigated mainly with DFT method and in part with MP2 method. The DFT method with B3PW91 and M06 functionals reproduces well the Pt–Si, Pt–Cl and Si–N bond distances. Though the Si–Cl distance is overestimated by all functionals employed here when one d polarization function is added to each of Si and Cl, the M06-optimized Si–Cl distance is close to the experimental value when two d polarization functions are added to each of Si and Cl, suggesting that the functio
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Sonsilchai, Phawittra, and Duangdao Aht-Ong. "Investigation of Flame Retardant Properties of Poly(ethylene Terephthalate)/Silatrane Complex/Montmorillonite Nanocomposites." Advanced Materials Research 747 (August 2013): 43–46. http://dx.doi.org/10.4028/www.scientific.net/amr.747.43.

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Poly (ethylene terephthalate) or PET was used in many applications such as packagings, textiles, electrical devices, and auto parts as well due to its good mechanical properties and dimensional stabilities, etc. However, the main drawback of PET is poor flame retardant and melt-dripping, which needed to be solved. Therefore, the aim of this research was to improve the flame retardant properties of PET by investigating the synergistic effects of flame retardant agents between silatrane complex and montmorillonite (MMT) at various concentrations. Silatrane complex was synthesized from silica thr
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Kemmitt, Tim, and William Henderson. "A New Route to Silicon Alkoxides from Silica." Australian Journal of Chemistry 51, no. 11 (1998): 1031. http://dx.doi.org/10.1071/c98060.

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A novel route to tetraethoxysilane and other silicon alkoxides is described, from amorphous silica (SiO2.nH2O) as the raw material. The reaction of amorphous silica with triethanolamine is enhanced by using an alkali metal hydroxide catalyst, to form a range of triethanolamine-substituted silatrane species. These can undergo alkoxide exchange in acidic alcohols to form alkoxysilatranes, tetraalkoxysilanes, hexaalkoxydisiloxanes and higher siloxanes. Reaction of triethanolamine-substituted silatranes with acetic anhydride produces acetoxysilatrane. Products were identified by multinuclear (1H,
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Istratov, V. V., V. I. Gomzyak, O. V. Yamskova, et al. "Novel polymer surfactants based on the branched silatrane-containing polyesters and polyethers." Fine Chemical Technologies 14, no. 5 (2019): 61–70. http://dx.doi.org/10.32362/2410-6593-2019-14-5-61-70.

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Objectives. Biologically active polymeric surfactants are a new promising class of macromolecules that can find application in medicine, cosmetology, and agriculture. In this study, a number of new biologically active amphiphilic polymers based on branched silatrane-containing polyesters and polyethers were obtained, and their surface-active properties were investigated.Methods. The branched polymers were represented by polyethers and polyesters, obtained respectively via the anionic polymerization of 1,2-epoxypropanol or a combination of equilibrium polycondensation and ring opening polymeriz
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Kemmitt, Tim, and William Henderson. "Dendrimeric silatrane wedges." Journal of the Chemical Society, Perkin Transactions 1, no. 5 (1997): 729–40. http://dx.doi.org/10.1039/a605135i.

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9

Bessi, Matteo, Marco Monini, Massimo Calamante, et al. "Synthesis of Silatrane-Containing Organic Sensitizers as Precursors for the Silyloxyl Anchoring Group in Dye-Sensitized Solar Cells." Synthesis 49, no. 17 (2017): 3975–84. http://dx.doi.org/10.1055/s-0036-1588836.

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A series of organic D-π-A dyes, endowed with different silicon-based anchoring groups, has been prepared to assess the stability of such anchoring moieties on nanocrystalline TiO2 in dye-sensitized solar cells. Due to the difficulties encountered in finding a reliable and robust preparation protocol to obtain pure trialkoxysilanes, replacement with a silatrane moiety was evaluated. It was found that the silatrane group could be easily introduced on three different molecular scaffolds by using a simple amide coupling reaction mediated by EDC-Cl. Furthermore, the spectroscopic properties and anc
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Romanovs, Vitalijs, Valery Sidorkin, Elena Belogolova, and Viatcheslav Jouikov. "Radical cations of phenyl silatrane." Dalton Transactions 46, no. 27 (2017): 8849–54. http://dx.doi.org/10.1039/c7dt00447h.

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Dissertations / Theses on the topic "Silatrane"

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Bouliez, Jean-Luc. "Conversions thermiques de nouveaux modèles de précéramiques multi-composants : les complexes « Silatrane-XCL4 » ; X = Ti, Zr." Compiègne, 1991. http://www.theses.fr/1991COMPD340.

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Nous avons étudié une nouvelle voie d'élaboration de précéramiques appartenant au système Si/Ti/N/C. Le composé de base retenu est un monomère organométallique à silicium hypervalent : le méthyl-azasilatrane. Cette molécule permet l'apport des éléments Si, N, C (4N pour 1 Si) et conditionne donc l'élaboration de poudres céramiques non-oxydes. Les autres éléments nécessaires à l'élaboration de ces poudres multi-composants (Ti-Zr) sont apportés sous la forme de chlorures et conduisent avec le méthyl-azasilatrane une association de type donneur-accepteur. L'originalité du travail est d'avoir opté
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Spennato, Richard. "Silices modifiées pour l'élimination des métaux lourds (Ag+,Cd2+,Pb2+ et Hg2+) : thiolates métalliques à fonction silatrane." Toulouse 3, 2004. http://www.theses.fr/2004TOU30124.

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Nous présentons l'étude comparative des réactions de complexation de métaux lourds par des ligands thiolates en solution et supportés sur silice. Cette étude permet d'étendre l'utilisation des silices modifiées à l'élimination de traces de cations toxiques dans l'eau. Des ligands thiolates (propanethiol, aminoéthanethiol et mercaptoacétamide) ont été greffés à la surface de la silice et utilisés sous forme de dérivés silatranes pour l'étude en solution. Lors des réactions de complexation les thiolates obtenus sont des oligomères indiquant que le silatrane est suffisamment encombrant pour limit
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Wang, Yu. "Synthèse, réactivité électrochimique et structure électronique de 1-R-métallatranes (M=Si,Sn)." Phd thesis, Université Rennes 1, 2012. http://tel.archives-ouvertes.fr/tel-00806250.

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Les métallatranes (M=Si, Ge, Sn) ont fait l'objet d'un intérêt important de la communauté scientifique durant les 50 dernières années et ont des applications dans de nombreux domaines, de la physique à la biologie en passant par la médecine, etc... Cependant, leurs propriétés électrochimiques n'ont été étudiées que de façon très incomplète à ce jour. Dans le travail présenté ici, nous avons réalisé la synthèse de nouveaux métallatranes et les avons caractérisés, et ce par plusieurs approches et techniques différentes (synthèse organique, voltammétrie cyclique, électrolyse préparative, EPR, spe
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Zheng, Ya-Yun, and 鄭雅云. "Silatrane-Based Zwitterionic Self-Assembled Coating for Antifouling Properties." Thesis, 2017. http://ndltd.ncl.edu.tw/handle/50390221897025078875.

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碩士<br>國立中央大學<br>生物醫學工程研究所<br>105<br>Zwitterionic coatings are a new class of antifouling materials for high biocompatibility. Development of the antifouling film has been of great interest over the last decades, particularly for silicon surface modification due to their potential biomedical applications. The most commonly used chemical functionalization of silicon surface is silane. However, silane is very sensitive to moisture which leads to polymerization on the silicon surface. Therefore, silatranes have received attention from the structures features. Because of a strong intramolecular don
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Books on the topic "Silatrane"

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Voronkov, M. G. Silatrany v medit︠s︡ine i selʹskom khozi︠a︡istve: Silatranes for medicine and agriculture. Irkutskiĭ in-t khimii SO RAN, 2005.

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IK- i KR-spektry silatranov i modelʹnykh soedineniĭ. Novosibirskiĭ in-t organicheskoĭ khimii SO AN SSSR, 1985.

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Book chapters on the topic "Silatrane"

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Eujen, Reint, Achim Roth, and David J. Brauer. "Preparation and Structure of 1-(Trifluoromethyl)silatrane." In Silicon Chemistry. Springer Vienna, 1999. http://dx.doi.org/10.1007/978-3-7091-6357-3_10.

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Iwamiya, Joseph H., and Gary E. Maciel. "Theoretical Study of Chemical Shielding in Silatrane and Its Derivatives." In Nuclear Magnetic Shieldings and Molecular Structure. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1652-7_26.

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Palavit, G., P. Vast, and J. Ph Rosnet. "Precursor of zirconia based ceramics Obtention and pyrolysis of ZrC14 silatrane complex." In Zirconia’88. Springer Netherlands, 1989. http://dx.doi.org/10.1007/978-94-009-1139-0_23.

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Lyubchenko, Yuri L., Luda S. Shlyakhtenko, and Alexander A. Gall. "Atomic Force Microscopy Imaging and Probing of DNA, Proteins, and Protein-DNA Complexes: Silatrane Surface Chemistry." In Methods in Molecular Biology™. Humana Press, 2009. http://dx.doi.org/10.1007/978-1-60327-015-1_21.

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Journal articles
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