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1

Renom-Carrasco, Marc, Philipp Mania, Reine Sayah, et al. "Supported Ru olefin metathesis catalysts via a thiolate tether." Dalton Transactions 48, no. 9 (2019): 2886–90. http://dx.doi.org/10.1039/c8dt04592e.

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2

Beaudoin, Marcel C., Omisola Womiloju, Anqiu Fu, Jamila Amor Nait Ajjou, Gordon L. Rice, and Susannah L. Scott. "Silica-supported alkylidene complexes: their preparation, characterization and reactivity, especially towards olefins." Journal of Molecular Catalysis A: Chemical 190, no. 1-2 (2002): 159–69. http://dx.doi.org/10.1016/s1381-1169(02)00248-0.

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3

Mougel, Victor, Celine B. Santiago, Pavel A. Zhizhko, et al. "Quantitatively Analyzing Metathesis Catalyst Activity and Structural Features in Silica-Supported Tungsten Imido–Alkylidene Complexes." Journal of the American Chemical Society 137, no. 20 (2015): 6699–704. http://dx.doi.org/10.1021/jacs.5b03344.

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4

Blanc, Frédéric, Alain Salameh, Jean Thivolle-Cazat, et al. "Grafting mechanism and olefin metathesis activity of well-defined silica-supported Mo imido alkyl alkylidene complexes." Comptes Rendus Chimie 11, no. 1-2 (2008): 137–46. http://dx.doi.org/10.1016/j.crci.2007.02.017.

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5

Holmes, S. A., F. Quignard, A. Choplin, R. Teissier, and J. Kervennal. "Tetraneopentyltitanium Derived Silica Supported Complexes." Journal of Catalysis 176, no. 1 (1998): 182–91. http://dx.doi.org/10.1006/jcat.1998.2043.

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6

Rhers, Bouchra, Alain Salameh, Anne Baudouin, et al. "A Well-Defined, Silica-Supported Tungsten Imido Alkylidene Olefin Metathesis Catalyst." Organometallics 25, no. 15 (2006): 3554–57. http://dx.doi.org/10.1021/om060279d.

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7

Amor Nait Ajjou, Jamila, Susannah L. Scott, and Valérie Paquet. "Synthesis and Characterization of Silica-Stabilized Chromium(IV) Alkylidene Complexes." Journal of the American Chemical Society 120, no. 2 (1998): 415–16. http://dx.doi.org/10.1021/ja973177a.

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8

Schmid, Rochus, and Tom Ziegler. "Ethylene-polymerization by surface supported Cr(IV) species: possible reaction mechanisms revisited by theoretical calculations." Canadian Journal of Chemistry 78, no. 2 (2000): 265–69. http://dx.doi.org/10.1139/v99-242.

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Possible reaction mechanisms of olefin polymerization catalyzed by surface supported Cr(IV) species have been investigated by first principles density functional theory (DFT). Pathways starting from neutral alkylidene or bisalkyl complexes were found to suffer from high ethylene insertion barriers, whereas a cationic system formed by protonation of the alkylidene show a low barrier for chain propagation.Key words: density functional theory, alkylidene, olefin polymerization, Cr(IV) species.
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9

Ortiz, Carlos G., Khalil A. Abboud, and James M. Boncella. "Synthesis of Chelate-Supported Dialkyl and Alkylidene Complexes of Molybdenum(VI)." Organometallics 18, no. 21 (1999): 4253–60. http://dx.doi.org/10.1021/om990124o.

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10

Schmidt, Joseph A. R., Stephen A. Chmura, and John Arnold. "Alkyl and Alkylidene Tantalum−Lithium Complexes Supported by an Anionic Triazacyclononane Ligand." Organometallics 20, no. 6 (2001): 1062–64. http://dx.doi.org/10.1021/om0010621.

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11

Wang, Hongshe, and Weixing Zhao. "An Efficient Synthesis of SymmetricalN,N’-Alkylidene Bisamides Catalyzed by Silica Supported Perchloric Acid." Chinese Journal of Organic Chemistry 33, no. 8 (2013): 1822. http://dx.doi.org/10.6023/cjoc201303027.

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12

Kinting, Annegret, Hanswalter Krause, and Martin Čapka. "Silica-supported chiral rhodium complexes for asymmetric hydrogenation." Journal of Molecular Catalysis 33, no. 2 (1985): 215–23. http://dx.doi.org/10.1016/0304-5102(85)85104-x.

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13

Groysman, Stanislav, Israel Goldberg, Moshe Kol, Elisheva Genizi, and Zeev Goldschmidt. "Exploring Routes to Tantalum(V) Alkylidene Complexes Supported by Amine Tris(phenolate) Ligands." Advanced Synthesis & Catalysis 347, no. 2-3 (2005): 409–15. http://dx.doi.org/10.1002/adsc.200404273.

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14

Conley, Matthew P., Victor Mougel, Dmitry V. Peryshkov, et al. "A Well-Defined Silica-Supported Tungsten Oxo Alkylidene Is a Highly Active Alkene Metathesis Catalyst." Journal of the American Chemical Society 135, no. 51 (2013): 19068–70. http://dx.doi.org/10.1021/ja410052u.

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15

Mohammad Shafiee, Mohammad Reza. "Silica-supported barium chloride (SiO2–BaCl2) — Efficient and heterogeneous catalyst for the environmentally friendly preparation of N,N′-alkylidene bisamides under solvent-free conditions." Canadian Journal of Chemistry 89, no. 5 (2011): 555–61. http://dx.doi.org/10.1139/v11-007.

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A series of N,N′-alkylidene bisamides were prepared via a green and environmentally friendly synthetic protocol from the reaction of phenyl acetylene or hex-1-yne, aromatic aldehyde, and benzamide or acetamide. Silica-supported barium chloride (SiO2–BaCl2) catalyzes the process of the reaction. The prepared catalysts were characterized by X-ray diffraction, and the products were obtained with high conversions and yields.
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16

Zbirovský, Vladimír, and Martin Čapka. "Silica supported cationic rhodium(I) complexes as hydrogenation catalysts." Collection of Czechoslovak Chemical Communications 51, no. 4 (1986): 836–41. http://dx.doi.org/10.1135/cccc19860836.

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Cationic silica-supported Rh(I) complexes prepared from Rh(COD) (acac) and phosphines of the type (C2H5O)3Si(CH2)nP(C6H5)2 (n = 1,3) in the presence of p-toluenesulphonic acid were found to be efficient catalysts for hydrogenation of alkenes, alkadienes, and Z-α-acetamidocinnamic acid at 40 °C and normal hydrogen pressure. Kinetic measurements showed that the most efficient catalysts are obtained at the P : Rh mol. ratio = 2. When this ratio was ensured for each molecule of the immobilized complex, such catalysts were three to four times more active than their homogeneous analogues.
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17

Tonzetich, Zachary J., Annie J. Jiang, Richard R. Schrock та Peter Müller. "Cationic Imido Alkylidene Complexes of Molybdenum Supported by β-Diketonate and β-Diketiminate Ligands". Organometallics 25, № 20 (2006): 4725–27. http://dx.doi.org/10.1021/om060518x.

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18

Lepetit, C., M. Kermarec, M. Che, and J. M. Thomas. "Silica-supported nickel(I)—benzene complexes resulting from acetylene cyclotrimerization." Colloids and Surfaces A: Physicochemical and Engineering Aspects 72 (June 1993): 265–74. http://dx.doi.org/10.1016/0927-7757(93)80475-t.

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19

Deshmukh, J. M., L. H. Mahind, S. A. Waghmode, and S. P. Dagade. "Study of Catalytic Activity of Silica Supported Schiff Base Complexes." Asian Journal of Chemistry 29, no. 7 (2017): 1455–58. http://dx.doi.org/10.14233/ajchem.2017.20509.

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20

Saint-Arroman, R. Petroff, B. Didillon, A. de Mallmann, J. M. Basset, and F. Lefebvre. "Deperoxidation of cyclohexyl hydroperoxide by silica-supported alkoxo-tantalum complexes." Applied Catalysis A: General 337, no. 1 (2008): 78–85. http://dx.doi.org/10.1016/j.apcata.2007.12.002.

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21

Mohammad Shafiee, Mohammad Reza. "One-pot preparation of N,N′-alkylidene bisamide derivatives catalyzed by silica supported polyphosphoric acid (SiO2-PPA)." Journal of Saudi Chemical Society 18, no. 2 (2014): 115–19. http://dx.doi.org/10.1016/j.jscs.2011.06.005.

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22

R.M. Shafiee, Mohammad. "One-Pot Preparation of N,N'-Alkylidene Bisamide Derivatives Catalyzed by Silica Supported Magnesium Chloride (SiO2-MgCl2)." Letters in Organic Chemistry 8, no. 8 (2011): 562–67. http://dx.doi.org/10.2174/157017811797249344.

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23

Ziegler, Felix, Hamzeh Kraus, Mathis J. Benedikter, et al. "Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes." ACS Catalysis 11, no. 18 (2021): 11570–78. http://dx.doi.org/10.1021/acscatal.1c03057.

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24

Alladin, Tagenine, Marcel C. Beaudoin, and Susannah L. Scott. "Thermolysis of silica-supported bis(neopentyl) complexes of titanium and zirconium." Inorganica Chimica Acta 345 (March 2003): 292–98. http://dx.doi.org/10.1016/s0020-1693(02)01272-0.

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25

LI, Junbo, Xiwen LIU, Cancan CAO, Jia GUO, and Zhiquan PAN. "Silica-gel Supported V Complexes: Preparation, Characterization and Catalytic Oxidative Desulfurization." Chinese Journal of Chemical Engineering 21, no. 8 (2013): 860–66. http://dx.doi.org/10.1016/s1004-9541(13)60558-3.

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26

Hamzaoui, Bilel, Jérémie D. A. Pelletier, Edy Abou-Hamad, and Jean-Marie Basset. "Well-defined silica-supported zirconium–imido complexes mediated heterogeneous imine metathesis." Chemical Communications 52, no. 25 (2016): 4617–20. http://dx.doi.org/10.1039/c6cc00471g.

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27

SKUPINSKI, WINCENTY, and PRZEMYSLAW WALCZUK. "Isoprene polymerization on titanium (IV) complexes supported on alumina-silica gel." Polimery 31, no. 10 (1986): 393–95. http://dx.doi.org/10.14314/polimery.1986.393.

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28

Booth, B. L., G. C. Ofunne, C. Stacey, and P. J. T. Tait. "Silica-supported cyclopentadienyl-rhodium(I), -cobalt(I), and -titanium(IV) complexes." Journal of Organometallic Chemistry 315, no. 2 (1986): 143–56. http://dx.doi.org/10.1016/0022-328x(86)80433-8.

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29

FRAILE, J., J. GARCIA, J. MAYORAL, and E. VISPE. "Catalytic sites in silica-supported titanium catalysts: silsesquioxane complexes as models." Journal of Catalysis 233, no. 1 (2005): 90–99. http://dx.doi.org/10.1016/j.jcat.2005.04.018.

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30

Tzschucke, Carl?Christoph, and Willi Bannwarth. "Fluorous-Silica-Supported Perfluoro-Tagged Palladium Complexes CatalyzeSuzuki Couplings in Water." Helvetica Chimica Acta 87, no. 11 (2004): 2882–89. http://dx.doi.org/10.1002/hlca.200490260.

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31

Díaz, Estefanía, Albeiro Restrepo, and Francisco Núñez-Zarur. "Reactivity of a Silica-Supported Mo Alkylidene Catalyst toward Alkanes: A DFT Study on the Metathesis of Propane." Organometallics 37, no. 13 (2018): 2023–36. http://dx.doi.org/10.1021/acs.organomet.8b00090.

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32

Pucino, Margherita, Victor Mougel, Roman Schowner, Alexey Fedorov, Michael R. Buchmeiser, and Christophe Copéret. "Cationic Silica-Supported N-Heterocyclic Carbene Tungsten Oxo Alkylidene Sites: Highly Active and Stable Catalysts for Olefin Metathesis." Angewandte Chemie 128, no. 13 (2016): 4372–74. http://dx.doi.org/10.1002/ange.201510678.

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33

Pucino, Margherita, Victor Mougel, Roman Schowner, Alexey Fedorov, Michael R. Buchmeiser, and Christophe Copéret. "Cationic Silica-Supported N-Heterocyclic Carbene Tungsten Oxo Alkylidene Sites: Highly Active and Stable Catalysts for Olefin Metathesis." Angewandte Chemie International Edition 55, no. 13 (2016): 4300–4302. http://dx.doi.org/10.1002/anie.201510678.

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34

Blanc, Frédéric, Christophe Copéret, Jean Thivolle-Cazat, and Jean-Marie Basset. "Alkane Metathesis Catalyzed by a Well-Defined Silica-Supported Mo Imido Alkylidene Complex: [(SiO)Mo(NAr)(CHtBu)(CH2tBu)]." Angewandte Chemie International Edition 45, no. 37 (2006): 6201–3. http://dx.doi.org/10.1002/anie.200602171.

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35

Blanc, Frédéric, Christophe Copéret, Jean Thivolle-Cazat, and Jean-Marie Basset. "Alkane Metathesis Catalyzed by a Well-Defined Silica-Supported Mo Imido Alkylidene Complex: [(SiO)Mo(NAr)(CHtBu)(CH2tBu)]." Angewandte Chemie 118, no. 37 (2006): 6347–49. http://dx.doi.org/10.1002/ange.200602171.

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36

Leitao, Erin M., Warren E. Piers, and Masood Parvez. "A thermally robust ruthenium phosphonium alkylidene catalyst — the effect of more bulky N-heterocyclic carbene ligands on catalyst performance in olefin metathesis reactions." Canadian Journal of Chemistry 91, no. 10 (2013): 935–42. http://dx.doi.org/10.1139/cjc-2013-0156.

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Three new ruthenium phosphonium alkylidene complexes incorporating N-heterocyclic carbene ligands with bulky N-aryl groups (2,6-diethyl, L = 1,3-bis(2,6-diethylphenyl)imidazolin-2-ylidene (H2IDEP) and 2,6-diisopropyl, L = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene (H2ID-i-PP)) were synthesized and characterized. The H2ID-i-PP supported complex was found to exhibit excellent thermal stabilities relative to the parent N-mesityl (N-Mes) complexes as well as the H2IDEP supported complexes. All three phosphonium alkylidenes were evaluated in comparison to the N-Mes derivative and Grubbs sec
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37

Rascón, Fernando, and Christophe Copéret. "Alkylidene and alkylidyne surface complexes: Precursors and intermediates in alkane conversion processes on supported single-site catalysts." Journal of Organometallic Chemistry 696, no. 25 (2011): 4121–31. http://dx.doi.org/10.1016/j.jorganchem.2011.07.015.

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38

Shafiee, Mohammad R. M. "ChemInform Abstract: One-Pot Preparation of N,N′-Alkylidene Bisamide Derivatives Catalyzed by Silica Supported Magnesium Chloride (SiO2-MgCl2)." ChemInform 43, no. 6 (2012): no. http://dx.doi.org/10.1002/chin.201206059.

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39

Legagneux, Nicolas, Erwann Jeanneau, Amélie Thomas, et al. "Grafting Reaction of Platinum Organometallic Complexes on Silica-Supported or Unsupported Heteropolyacids." Organometallics 30, no. 7 (2011): 1783–93. http://dx.doi.org/10.1021/om1003539.

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40

Ishihara, Atsushi, Kenji Shirouchi, and Toshiaki Kabe. "Hydrodesulfurization of Dibenzothiophene Catalyzed by Silica-Alumina Supported Anionic Molybdenum Carbonyl Complexes." Chemistry Letters 22, no. 4 (1993): 589–92. http://dx.doi.org/10.1246/cl.1993.589.

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41

Ishii, Kazuyuki, Yuu Kikukawa, Masahiko Shiine, et al. "Synthesis and Photophysical Properties of Silica‐Gel‐Supported Photofunctional (Phthalocyaninato)silicon Complexes." European Journal of Inorganic Chemistry 2008, no. 19 (2008): 2975–81. http://dx.doi.org/10.1002/ejic.200800208.

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42

Liu, Pei-Nian, Pei-Ming Gu, Jin-Gen Deng, Yong-Qiang Tu, and Ya-Ping Ma. "Efficient Heterogeneous Asymmetric Transfer Hydrogenation Catalyzed by Recyclable Silica-Supported Ruthenium Complexes." European Journal of Organic Chemistry 2005, no. 15 (2005): 3221–27. http://dx.doi.org/10.1002/ejoc.200500074.

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43

Serra, Osvaldo A., Eduardo J. Nassar, Gilson Zapparolli, and Ieda L. V. Rosa. "Organic complexes of Eu3+ supported in functionalized silica gel: highly luminescent material." Journal of Alloys and Compounds 207-208 (June 1994): 454–56. http://dx.doi.org/10.1016/0925-8388(94)90262-3.

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44

Ozawa, Kazutaka, and Kazuyuki Ishii. "Photophysical and magnetic properties of magnetic silica gel-supported silicon phthalocyanine complexes." Phys. Chem. Chem. Phys. 11, no. 7 (2009): 1019–22. http://dx.doi.org/10.1039/b811128f.

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45

Garrone, E., S. Abello, E. Borello, G. Ghiotti, and A. Zecchina. "Carbon dioxide and nitrous oxide complexes of Cr(II) supported on silica." Materials Chemistry and Physics 29, no. 1-4 (1991): 369–78. http://dx.doi.org/10.1016/0254-0584(91)90031-o.

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46

Copéret, Christophe, Olivier Maury, Jean Thivolle-Cazat та Jean-Marie Basset. "σ-Bond Metathesis of Alkanes on a Silica-Supported Tantalum(V) Alkyl Alkylidene Complex: First Evidence for Alkane Cross-Metathesis". Angewandte Chemie International Edition 40, № 12 (2001): 2331–34. http://dx.doi.org/10.1002/1521-3773(20010618)40:12<2331::aid-anie2331>3.0.co;2-p.

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47

Copéret, Christophe, Olivier Maury, Jean Thivolle-Cazat та Jean-Marie Basset. "σ-Bond Metathesis of Alkanes on a Silica-Supported Tantalum(V) Alkyl Alkylidene Complex: First Evidence for Alkane Cross-Metathesis". Angewandte Chemie 113, № 12 (2001): 2393–96. http://dx.doi.org/10.1002/1521-3757(20010618)113:12<2393::aid-ange2393>3.0.co;2-1.

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48

Sarkar, Shaheen M., Md Eaqub Ali, Md Shaharul Islam, et al. "Mesoporous Silica-Supported Sulfonyldiamine Ligand for Microwave-Assisted Transfer Hydrogenation." Journal of Nanomaterials 2015 (2015): 1–6. http://dx.doi.org/10.1155/2015/674752.

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N-Sulfonyl-1,2-diamine ligands, derived from 1,2-diaminocyclohexane and 1,2-diaminopropane, were immobilized onto mesoporous SBA-15 silica. The SBA-15-supported sulfonyldiamine-Ru complex was preparedin situunder microwave heating at 60 W for 3 min. The prepared sulfonyldiamine-Ru complex was used as an efficient catalyst for the transfer hydrogenation of ketones to the corresponding secondary alcohols. The heterogeneous complex showed extremely high catalytic activity with 99% conversion rate under microwave heating condition. The complexes were regenerated by simple filtration and reused two
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49

Ray, Biswajit, Victoria Volkis, Anatoly Lisovskii та Moris S. Eisen. "Polymerization of α-Olefins Using Benzamidinate Zirconium Complexes Supported on Mesoporous Silica Materials". Israel Journal of Chemistry 42, № 4 (2002): 333–42. http://dx.doi.org/10.1560/0hew-nlnj-qdjx-vctj.

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50

Millot, M. C., B. Sebille, A. Halli, H. Hommel, and A. P. Legrand. "Chromatographic and EPR study of poly(vinylimidazole) copper(II) complexes supported on silica." Chromatographia 37, no. 11-12 (1993): 584–92. http://dx.doi.org/10.1007/bf02274106.

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