Academic literature on the topic 'Silicalita'

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Journal articles on the topic "Silicalita"

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Cubillos-Lobo, Jairo Antonio, Felipe Bustamante-Londoño, and Alejandro Acosta-Cárdenas. "Modelación y simulación de un pervaporador acoplado a un proceso de sacarificación-fermentación para la producción de etanol." REVISTA FACULTAD DE INGENIERÍA 24, no. 40 (2015): 49. http://dx.doi.org/10.19053/01211129.3848.

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<p>Actualmente, la integración de procesos es considerada una opción viable para reducir costos en la producción de etanol a partir de biomasa. Simulaciones y resultados experimentales han demostrado los beneficios de la integración de las etapas de sacarificación y fermentación y del acoplamiento del proceso de fermentación a la recuperación in-situ de etanol por pervaporación en la producción de bioetanol; sin embargo, no se han publicado estudios de la integración del proceso de sacarificación-fermentación simultánea con membranas de separación, para la remoción insitu de etanol a par
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Prádanos, P., L. Palacio, A. Hernández, M. Vilaseca, J. Coronas, and J. Santamaría. "Estudio mediante afm de estructuras de silicalita para la separación de gases." Boletín de la Sociedad Española de Cerámica y Vidrio 43, no. 1 (2004): 19–22. http://dx.doi.org/10.3989/cyv.2004.v43.i1.608.

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Marthosa, Sutida, Wirote Youravong, Chaiwat Kongmanklang, and Watsa Khongnakorn. "Applications and characterization of silicalite-1/polydimethylsiloxane composite membranes for the pervaporation of a model solution and fermentation broth." Journal of Polymer Engineering 39, no. 2 (2019): 152–60. http://dx.doi.org/10.1515/polyeng-2018-0138.

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AbstractEthanol recovery via pervaporation is greatly influenced by membrane separation performance, which can be enhanced by adding hydrophobic fillers such as silicalite-1. Silicalite-1 was prepared by controlling the gel molar composition in hydrothermal synthesis, and it was incorporated into a polydimethylsiloxane (PDMS) membrane on Teflon. The silicalite-1 Si-O-Si structures interacted with the -Si(CH3)2-O- backbone of the PDMS chain. The thermal gravimetric analysis results showed that the silicalite-1 improved the thermal stability and raised the initial decomposition temperature from
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Sakai, Motomu, Yukichi Sasaki, Takuya Kaneko, and Masahiko Matsukata. "Contribution of Pore-Connectivity to Permeation Performance of Silicalite-1 Membrane; Part I, Pore Volume and Effective Pore Size." Membranes 11, no. 6 (2021): 382. http://dx.doi.org/10.3390/membranes11060382.

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The micropore volumes and effective pore sizes of two types of silicalite-1 membranes were compared with those of a typical silicalite-1 powder. The silicalite-1 membrane with fewer grain boundaries in the membrane layer showed similar micropore volume and effective pores size to those of the silicalite-1 powder. In contrast, when the silicalite-1 membrane contained many grain boundaries, relatively small micropore volume and effective pore size were observed, suggesting that narrowing and obstruction of the micropore would occur along grain boundaries due to the disconnection of the zeolite p
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Lu, Shih-Yuan, Hsiang-Yuan Huang, and Kwen-Hua Wu. "Silicalite/poly(dimethylsiloxane) nanocomposite pervaporation membranes for acetic acid/water separation." Journal of Materials Research 16, no. 11 (2001): 3053–59. http://dx.doi.org/10.1557/jmr.2001.0422.

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Composite separation membranes of poly(dimethylsiloxane) (PDMS) containing well-dispersed silicalite particles of 50 nm were successfully prepared and applied to the preferential pervaporation of acetic acid over water. The nanocomposite membranes showed improvement on both separation factor and permeation flux for the pervaporation process, as compared to plain PDMS membranes and composite membranes containing silicalite particles of 5 μm. The improvement can be attributed to higher readily accessible specific surface area and higher sorption selectivity toward acetic acid of the nano-size si
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Chen, Hong Liang, Ji Song Yang, Yan Wang, Hui Ying Li, Xin Xin Li, and Wei Shen Yang. "Preparation of Silicalite-1 Membranes with Seeding Method and its Separation Performance for Low Ethanol/Water Mixture." Advanced Materials Research 807-809 (September 2013): 591–95. http://dx.doi.org/10.4028/www.scientific.net/amr.807-809.591.

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High performance silicalite-1 membranes were successfully synthesized on silica tubes by seeding method after filling the tubes with water and glycerol mixtures. After seeding the silica tubes with 200 nm seeds, all the silicalite-1 membranes show acceptable separation performance towards ethanol/water mixture after 4-12 h hydrothermal synthesis, and the highest flux of membrane with 8 h hydrothermal synthesis reaches about 0.98 kg/m2.h and the separation factor reaches about 60 towards 3 wt.% ethanol/water mixture. This result shows that the as-synthesized silicalite-1 membrane can concentrat
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Cheng, Yue, Shun Long Pan, and Yuan Zhou. "Study on Magnetic Mn0.2Co0.8Fe2O4/Silicalite-2 Catalyst and its Electro-Catalytic Property." Advanced Materials Research 669 (March 2013): 30–33. http://dx.doi.org/10.4028/www.scientific.net/amr.669.30.

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Silicalite-2 zeolite was hydrothermally synthesized and Mn0.2Co0.8Fe2O4 magnetic nano-particle based on the Silicalite-2 zeolite carrier was prepared by a coprecipitation-impregnation method. The morphologies and microstructures of synthesized samples were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM). The heterogeneous catalytic oxidation electrolysis system of Mn0.2Co0.8Fe2O4/silicalite-2 was built by dispersing the catalysts in glass reactor for treating cationic brilliant red X-5GN wastewater. The SEM images showed that the structure of silicalite-2 zeolite r
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Chen, Sheng, Guofeng Li, and Qipeng Yuan. "High adsorption capacity by creating a hydrophobic/hydrophilic layer on the surface of silicalite-1." RSC Advances 6, no. 101 (2016): 99509–13. http://dx.doi.org/10.1039/c6ra21257c.

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Chen, Hong Liang, Bin Bin Yang, Ji Song Yang, Yan Wang, and Hui Ying Li. "Synthesis of Silicalite-1 Membrane with High-Thermal Stability on Silica Tubes by In Situ Hydrothermal Synthesis." Applied Mechanics and Materials 692 (November 2014): 391–95. http://dx.doi.org/10.4028/www.scientific.net/amm.692.391.

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Silicalite-1 membranes with high-thermal stability were prepared on silica tubes by two-step hydrothermal synthesis after filling the tubes with water and glycerol mixtures. It was found that the filling method can improve the membrane separation performance effectively. After filling the silica tubes with mixed solution, the average flux of silicalite-1 membranes was improved by 23% while keeping the separation selectivity nearly unchanged. The results showed that the silicalite-1 membrane still showed high separation performance towards ethanol/water mixture after the repeated calcination at
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Casal, H. L., and J. C. Scaiano. "Intrazeolite photochemistry. II. Evidence for site inhomogeneity from studies of aromatic ketone phosphorescence." Canadian Journal of Chemistry 63, no. 6 (1985): 1308–14. http://dx.doi.org/10.1139/v85-222.

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The luminescent properties of several aromatic ketones included in the hydrophobic zeolite Silicalite have been examined. Acetophenone, benzophenone, and β-phenylpropiophenone show readily detectable phosphorescence; by contrast, valerophenone does not luminesce, but undergoes the Norrish Type II reaction. Thus, irradiated samples of valerophenone in Silicalite show phosphorescence due to the accumulation of acetophenone. In the case of β-phenylpropiophenone the triplet lifetime is ca. 100 000 times longer than the solution value, suggesting severe conformational restrictions. Co-inclusion of
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Dissertations / Theses on the topic "Silicalita"

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Rigo, Reus Tiago. "S?ntese e caracteriza??o de membranas zeol?ticas tipo mfi e aplica??o em separa??o de arom?ticos." Universidade Federal do Rio Grande do Norte, 2013. http://repositorio.ufrn.br:8080/jspui/handle/123456789/17704.

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Made available in DSpace on 2014-12-17T15:42:06Z (GMT). No. of bitstreams: 1 ReusTR_DISSERT.pdf: 4094188 bytes, checksum: 4969fc6bf4243a6e241302a399783473 (MD5) Previous issue date: 2013-07-22<br>Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior<br>The synthesis of MFI-type zeolite membranes was carried by the process in situ or hydrothermal crystallization. We studied the homogenization time of the room temperature and gel filtration just before the crystallization step performed out in an oven, thus obtaining a more uniform zeolite film. The powder synthesized zeolite (structure
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Prieto, Arnal Alejandro. "Producción de óxido de propileno a partir de H2O2 generada in situ con el empleo de sistemas catalíticos bifuncionales." Doctoral thesis, Universitat Politècnica de València, 2017. http://hdl.handle.net/10251/83482.

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Propylene oxide (PO), one of the most important intermediate reagent from the industrial point of view, has been historically obtained through non environmentally-friendly processes. Fortunately, the increasing worldwide environmental awareness during the last decades has motivated a willingness to change these processes for more environmentally-friendly ones. Among all the alternative processes that could substitute the traditional methodologies, the epoxidation of propylene by means of titanium silicalite-1 zeolite seems to be one of the most promising. Discovered in the beginning of 80s,
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Halhead, Michael David. "Characterisation of silicalite and post synthesis modified silicalite using adsorption." Master's thesis, University of Cape Town, 2001. http://hdl.handle.net/11427/13894.

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Bibliography: leaves 89-96.<br>The study of adsorption on microporous materials such as zeolites is of tremendous scientific and industrial interest. The effective development and design of both equipment and processes is reliant on the availability of accurate information on the processes of adsorption in these materials. Zeolites, of the type studied in this thesis, are becoming increasingly important in a wide range of fields such as ion-exchange, purification, separations particularly of close boiling compounds and catalytic processes. The work presented had two primary objectives. The fir
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Morell, Heiko. "Analyse der Gast-Wirt-Wechselwirkungen von n-Alkanen C6 - C12 im Kanalsystem von Silicalit-I." [S.l. : s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=961810912.

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Sowerby, Beverley. "Drying of organic vapours by adsorption." Thesis, University of Bath, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.284567.

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Hargreaves, S. M. "Hydrocarbon adsorption in silicalite : experimental and numerical studies." Thesis, University of Cambridge, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.603712.

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The work contained in this thesis addresses the single and multicomponent adsorption of hydrocarbons in silicalite. Both experimental and numerical work is presented. Experimental measurements are made using a volumetric technique and many equilibrium adsorption studies are reported for the first time. Multicomponent adsorption studies have revealed several novel adsorption phenomena. Intermolecular interaction within silicalite has been probed using deuterium nuclear magnetic resonance (<SUP>2</SUP>H NMR) experiments. For the first time data are presented for both single and multicomponent ad
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Lee, Seung Ju. "Morphological control of silicalite-1 crystals using microemulsion mediated growth." Diss., Texas A&M University, 2005. http://hdl.handle.net/1969.1/2535.

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Zeolites are crystalline, microporous aluminosilicates that have been extensively used in heterogeneous catalysis, separations, and ion-exchange operations. It has long been understood that particle size and morphology play a central role in the successful application of zeolites. This dissertation reports on controlling the morphology of all-silica zeolite, silicalite-1, made in nonionic/ionic microemulsions under conventional synthesis conditions. Silicalite-1 materials formed in microemulsion-mediated syntheses possess different morphological properties as compared to samples grown using th
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Flynn, Tracey Karen. "Some sorption and salt occlusion properties of silicalite-1." Thesis, University of Edinburgh, 1987. http://hdl.handle.net/1842/14868.

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Boulicaut, Ludovic. "Sorption and diffusion in silicalite crystals studied by HPLC." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp04/mq23781.pdf.

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Simon, Jean-Marc, Nicole Floquet, Jean-Pierre Bellata, and Guy Weber. "Commensurate diffusion effects of n-heptane in silicalite-1." Universitätsbibliothek Leipzig, 2015. http://nbn-resolving.de/urn:nbn:de:bsz:15-qucosa-185690.

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Books on the topic "Silicalita"

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Grice, S. C. The diffusion of aromatic compounds in Silicalite 1. UMIST, 1997.

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Grassian, Vicki H., and Sarah C. Larsen. Synthesis, characterization and environmental applications of nanocrystalline zeolites. Edited by A. V. Narlikar and Y. Y. Fu. Oxford University Press, 2017. http://dx.doi.org/10.1093/oxfordhb/9780199533053.013.18.

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This article describes the synthesis, characterization and environmental applications of nanocrystalline zeolites. It begins by considering the use of nanocrystalline zeolites as building blocks in the preparation of hierarchical zeolite structures, followed by a discussion of the synthesis of silicalite-1 with systematically varied crystal sizes, along with the synthesis of nanocrystalline aluminosilicates, NaZSM-5 and NaY. It then looks at the various applications of nanozeolites and hierarchical zeolite structures for environmental catalysis, adsorption of volatile organic compounds and oth
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Book chapters on the topic "Silicalita"

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Sano, Tsuneji. "Silicalite Membrane." In Encyclopedia of Membranes. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-44324-8_43.

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Sano, Tsuneji. "Silicalite Membrane." In Encyclopedia of Membranes. Springer Berlin Heidelberg, 2015. http://dx.doi.org/10.1007/978-3-642-40872-4_43-1.

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Tatsumi, T., Y. Hirasawa, and J. Tsuchiya. "Alkane Oxidation on Vanadium Silicalite Compared to Titanium Silicalite." In ACS Symposium Series. American Chemical Society, 1996. http://dx.doi.org/10.1021/bk-1996-0638.ch028.

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Hayhurst, David T., Peter J. Melling, Wha Jung Kim, and William Bibbey. "Effect of Gravity on Silicalite Crystallization." In ACS Symposium Series. American Chemical Society, 1989. http://dx.doi.org/10.1021/bk-1989-0398.ch017.

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Patil, M. D., and I. M. Lachman. "Methanol Conversion on Ceramic Honeycombs Coated with Silicalite." In ACS Symposium Series. American Chemical Society, 1988. http://dx.doi.org/10.1021/bk-1988-0368.ch031.

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Wang, Yuguo, Fred L. Tungate, George Kokotailo, and Burtron H. Davis. "Shape Selectivity for Alkane Dehydrocyclization with Pt Silicalite Catalysts." In ACS Symposium Series. American Chemical Society, 1999. http://dx.doi.org/10.1021/bk-2000-0738.ch010.

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Sulikowski, Bogdan, and Jacek Klinowski. "Hydrothermal Isomorphous Substitution of Boron in Zeolite ZSM-5/Silicalite." In ACS Symposium Series. American Chemical Society, 1989. http://dx.doi.org/10.1021/bk-1989-0398.ch027.

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Vayssilov, Georgi N. "Theoretical Modelling of Propane Partial Oxidation over Titanium Silicalites." In Catalytic Activation and Functionalisation of Light Alkanes. Springer Netherlands, 1998. http://dx.doi.org/10.1007/978-94-017-0982-8_23.

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Boccuti, M. R., K. M. Rao, A. Zecchina, G. Leofanti, and G. Petrini. "Spectroscopic Characterization of Silicalite and Titanium-Silicalite." In Structure and Reactivity of Surfaces. Elsevier, 1989. http://dx.doi.org/10.1016/s0167-2991(08)60677-1.

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"Huashan Silicalite Member." In Geological Formation Names of China (1866–2000). Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-93824-8_3273.

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Conference papers on the topic "Silicalita"

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ANNA, H. R. Sant, A. G. BARRETO JR, F. W. TAVARES, C. R. A. ABREU, and J. F. do NASCIMENTO. "SIMULAÇÃO NUMÉRICA DA ADSORÇÃO DE METANO E NITROGÊNIO EM LEITO FIXO CONTENDO SILICALITA." In XX Congresso Brasileiro de Engenharia Química. Editora Edgard Blücher, 2015. http://dx.doi.org/10.5151/chemeng-cobeq2014-0499-25214-170906.

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LEE, YONGTAEK, HYOSEONG AHN, YOONJIN OH, and HYEREON LEE. "SILICALITE-1 MEMBRANE FOR ORGANIC/WATER PERVAPORATION." In Proceedings of the 4th International Conference. WORLD SCIENTIFIC, 2004. http://dx.doi.org/10.1142/9789812702623_0122.

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Tragl, Amadeus. "Surface Structure of Titanium Silicalite-1 Zeolites." In European Microscopy Congress 2020. Royal Microscopical Society, 2021. http://dx.doi.org/10.22443/rms.emc2020.1080.

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Casal, H. L., and P. W. Yang. "Diffuse Reflectance Infrared Spectroscopic Studies Of Aromatic Ketones Included In Silicalite." In 1985 International Conference on Fourier and Computerized Infrared Spectroscopy, edited by David G. Cameron and Jeannette G. Grasselli. SPIE, 1985. http://dx.doi.org/10.1117/12.970917.

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Min, H., Y. Jeon, J. Sung, et al. "Determination of absolute polar orientation of dyes incorporated into the channels of silicalite-1 films." In 2007 Conference on Lasers and Electro-Optics - Pacific Rim. IEEE, 2007. http://dx.doi.org/10.1109/cleopr.2007.4391326.

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Nguyen, Chi V., Danh C. Vu, Huong T. H. Nguyen, Tung P. Nguyen, and Quyen N. Tran. "Conversion of biomass-derived furfural into 1,5-pentadiol using effective Pt/silicalite-1 catalyst at mild condition." In 1ST VAN LANG INTERNATIONAL CONFERENCE ON HERITAGE AND TECHNOLOGY CONFERENCE PROCEEDING, 2021: VanLang-HeriTech, 2021. AIP Publishing, 2021. http://dx.doi.org/10.1063/5.0066461.

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Yang, Jianhua, Hui Lin Han, Bin Yuan, Liang Zhou, Chunlong Kong, and Jinqu Wang. "Preparation of silicalite-1 zeolite membrane by a two-stage-varying temperature synthesis for pervaporation separation of ethanol from water." In International Conference on Materials for Renewable Energy & Environment (ICMREE 2011). IEEE, 2011. http://dx.doi.org/10.1109/icmree.2011.5930829.

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Reports on the topic "Silicalita"

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Barnabas, M. V., D. W. Werst, and A. D. Trifunac. Transformations of toluene radical cation in ZSM-5 and Silicalite. Office of Scientific and Technical Information (OSTI), 1992. http://dx.doi.org/10.2172/10161958.

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