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1

Zhang, Ke, Qiang Zhang, Peng Fei Wang, Ling Bai, Wei Ping Shen, and Chang Chun Ge. "Silicon Nitride/Boron Nitride Composite by Combustion Synthesis." Materials Science Forum 561-565 (October 2007): 531–34. http://dx.doi.org/10.4028/www.scientific.net/msf.561-565.531.

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Machinable silicon nitride/ hexahedral boron nitride (Si3N4/h-BN) composites were in-situ synthesized in a nitrogen (N2) atmosphere by means of combustion synthesis gas-solid reaction with silicon (Si) powder and h-BN as raw materials. The effect of the volume fraction of h-BN on the machinable properties of Si3N4/BN composite was studied. The results show that Si powder was fully nitrified and no residual Si was found. Microstructures by a scanning electron microscopy (SEM) show Columnar crystals of β-Si3N4 are the main phase and acicular crystals of h-BN disperse β-Si3N4 intergranular. With the increasing of the volume content of h-BN, the machinability of the composite increases, but the bending strength of composite decreases firstly and then increases. The lowest bending strength is 84.96MPa at 25% volume fraction of h-BN.
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2

Richetto, Katia C. S., and Cosme Roberto Moreira Silva. "Synthesis of Silicon Nitride Using Taguchi Planning Methodology." Materials Science Forum 591-593 (August 2008): 760–65. http://dx.doi.org/10.4028/www.scientific.net/msf.591-593.760.

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Silicon Nitride is considered as an important material for use in structural applications. Its performance is severely influenced by modern synthesis processes. In the present work, silicon nitride powder synthesis was performed using liquid silicon tetrachloride and gaseous ammonia, at low temperature and inert atmosphere. Diimide pyrolisis was made on temperature between 1300 and 1500 0C. A Taguchi design of experiments methodology was applied, aiming to obtain powders with appropriated characteristics for structural applications. On pyrolisis, the use of alumina based substrates resulted on SIALON phase formation, probably originated from oxygen reaction, provided from alumina. Silicon carbide substrates and alumina recovered with silicon nitride enhance synthesis of pure silicon nitride powder.
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3

Andrievskii, Rostislav A. "Silicon nitride: synthesis and properties." Russian Chemical Reviews 64, no. 4 (April 30, 1995): 291–308. http://dx.doi.org/10.1070/rc1995v064n04abeh000151.

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4

Zerr, Andreas, Gerhard Miehe, George Serghiou, Marcus Schwarz, Edwin Kroke, Ralf Riedel, Hartmut Fueß, Peter Kroll, and Reinhard Boehler. "Synthesis of cubic silicon nitride." Nature 400, no. 6742 (July 1999): 340–42. http://dx.doi.org/10.1038/22493.

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5

Agrafiotis, Christos C., Jerzy Lis, Jan A. Puszynski, and Vladimir Hlavacek. "Combustion Synthesis of Silicon Nitride-Silicon Carbide Composites." Journal of the American Ceramic Society 73, no. 11 (November 1990): 3514–17. http://dx.doi.org/10.1111/j.1151-2916.1990.tb06488.x.

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6

Marita, Yusrini, and Iskandar Idris Yaacob. "Synthesis and Characterization of Nickel-Iron-Silicon Nitride Nanocomposite." Advanced Materials Research 97-101 (March 2010): 1360–63. http://dx.doi.org/10.4028/www.scientific.net/amr.97-101.1360.

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Nickel-iron-silicon nitride nanocomposite thin films were prepared by electrodeposition technique. The deposition was performed at current density of 11.5 A dm-2. Nano-size silicon nitride was mixed in the electrolyte bath as dispersed phase. The effects of silicon nitride nanoparticulates in the nickel-iron nanocomposite thin films were investigated in relation to the amount of silicon nitride in the plating bath. X-ray diffraction (XRD) analysis showed that the deposited nickel iron film has face-centered cubic structure (FCC). However, a mixture of body-centered cubic (BCC) and face-centered cubic (FCC) phases were observed for nickel iron-silicon nitride nanocomposite films. The crystallite size of Ni-Fe nanocomposite coating decreased with increasing amount of silicon nitride in the film. From elemental mapping procedure, Si3N4 nanopaticles were uniformly distributed in the Ni-Fe film. The presence of silicon nitride increased the hardness of the film. The microhardness of the nickel-iron nanocomposite increased from 495 HV for nickel-iron film to 846 HV for nickel-iron nanocomposite film with 2 at. % Si. The coercivity of Ni-Fe nanaocomposite films increases with decreasing crystallite size.
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7

Sekine, Toshimori. "Shock Synthesis of Cubic Silicon Nitride." Journal of the American Ceramic Society 85, no. 1 (December 20, 2004): 113–16. http://dx.doi.org/10.1111/j.1151-2916.2002.tb00050.x.

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8

Orthner, H. R., R. Brink, and P. Roth. "Synthesis of ultrafine silicon nitride powders." International Journal of Materials and Product Technology 15, no. 6 (2000): 495. http://dx.doi.org/10.1504/ijmpt.2000.001261.

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9

Riedel, Ralf, Elisabeta Horvath-Bordon, Hans Joachim Kleebe, Peter Kroll, G. Miehe, P. A. van Aken, and Stefan Lauterbach. "New Ceramic Phases in the Ternary Si-C-N System." Key Engineering Materials 403 (December 2008): 147–48. http://dx.doi.org/10.4028/www.scientific.net/kem.403.147.

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The ultra-high pressure and temperature synthesis of spinel silicon nitride and germanium nitride on the one hand as well as the successful synthesis of tin nitride at ambient pressure on the other hand have caused an enormous impact on both basic science and technological development of advanced nitrides. Aim and scope of the research in this field is to synthesize novel nitrides for structural and functional applications. High presssure nitrides may combine ultra-high hardness with high thermal stability in terms of decomposition in different environments and are expected to show interesting optoelectronic properties. Here, the state of the art and the progress in the field of novel advanced nitrides and related materials synthesized reproducibly under high pressure are reviewed.
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10

Zakorzhevskii, V. V., and I. P. Borovinskaya. "Combustion synthesis of silicon nitride using ultrafine silicon powders." Powder Metallurgy and Metal Ceramics 48, no. 7-8 (July 2009): 375–80. http://dx.doi.org/10.1007/s11106-009-9155-2.

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11

Skury, Ana Lúcia Diegues, Shirlene Chagas, and Sérgio Neves Monteiro. "Superhard Composite Containing Boron Nitride and Silicon Nitride." Solid State Phenomena 194 (November 2012): 199–203. http://dx.doi.org/10.4028/www.scientific.net/ssp.194.199.

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As a superhard material, next to diamond, the cubic boron nitride (cBN) is of great interest owing to its efficiency in machining ferrous alloys. In nature, only the hexagonal, hBN, exists. In practice, high pressure and high temperature (HPHT) synthesis has to be used to produce small cBN crystals. For larger size machining inserts, the powder-like cBN crystals need to be sintered at specific HPHT conditions using a metallic binder. The present work investigates the sintering of cBN inserts using a Si3N4 binder agent. The results disclosed relatively high hardness for the inserts and revealed their effectiveness in machining high strength steels.
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12

Sidorova, O. V., A. S. Nikitin, A. V. Kadetova, and L. A. Aleshina. "Structure of silicon nitride obtained by plasma-chemical synthesis.." Transaction Kola Science Centre 11, no. 3-2020 (November 25, 2020): 162–68. http://dx.doi.org/10.37614/2307-5252.2020.3.4.035.

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X-ray diffraction results of short-range order in nanoscale powders of silicon nitride obtained by plasma-chemical synthesis are presented. It is shown that the most probable structure of nanopowder silicon nitride can be characterized by a model of a disordered network of SiN4tetrahedra.
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13

Tian, Jiemo, Jinwang Li, and Limin Dong. "Synthesis of Silicon Nitride/Silicon Carbide Nanocomposite Powders through Partial Reduction of Silicon Nitride by Pyrolyzed Carbon." Journal of the American Ceramic Society 82, no. 9 (September 1999): 2548–50. http://dx.doi.org/10.1111/j.1151-2916.1999.tb02118.x.

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14

Barinova, T. V., I. P. Borovinskaya, T. I. Ignat’eva, Yu N. Barinov, and A. S. Shchukin. "Polycrystalline silicon nitride fibers by combustion synthesis." International Journal of Self-Propagating High-Temperature Synthesis 25, no. 4 (October 2016): 224–28. http://dx.doi.org/10.3103/s1061386216040038.

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15

Yao, Huai, Qiao Yu Xu, and Jing You Tang. "Synthesis and Stability of Cubic Silicon Nitride." Advanced Materials Research 79-82 (August 2009): 1467–70. http://dx.doi.org/10.4028/www.scientific.net/amr.79-82.1467.

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Experiments using a planar metal disc flyer driven by explosives and a cylindrical chamber was designed to synthesize cubic silicon nitride with the mixtures of α-Si3N4 and copper powders as starting materials. The ratio of transformation from α-Si3N4 to γ-Si3N4 approached to 80% percent at 45 GPa pressures and 4000K temperatures. The purity of γ-Si3N4 reached 100% after the synthesized samples were treated with hydrofluoric acid at 440K for 9-10h. High pressure sintering was carried out with a DS6×800A link-type cubic anvil apparatus at a pressure of 5.7GPa and calculated temperature of 1370-1670K over the course of 15 minutes. The result showed that γ-Si3N4 was completely transformed into β-Si3N4 at 5.7GPa, 1420-1670k and was partly transformed into β-Si3N4 at 5.7 GPa, 1370k. Micro-analysis indicated that the typical microstructure of sintered Si3N4 was elongated β-Si3N4 rod crystals in disordered orientation, the highest relative density of the sintered samples was 99.06% and Vickers hardness of them was 21.15GPa.
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16

Chen, Yi-Xiang, Jiang-Tao Li, and Ji-Sheng Du. "Cost effective combustion synthesis of silicon nitride." Materials Research Bulletin 43, no. 6 (June 2008): 1598–606. http://dx.doi.org/10.1016/j.materresbull.2007.06.051.

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17

Du, Hongli, Wei Zhang, and Yan Li. "Silicon Nitride Nanorings: Synthesis and Optical Properties." Chemistry Letters 43, no. 8 (August 5, 2014): 1360–62. http://dx.doi.org/10.1246/cl.140389.

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18

Zerr, Andreas, Gerhard Miehe, George Serghiou, Marcus Schwarz, Edwin Kroke, Ralf Riedel, Hartmut Fuess, Peter Kroll, and Reinhard Boehler. "ChemInform Abstract: Synthesis of Cubic Silicon Nitride." ChemInform 30, no. 39 (June 13, 2010): no. http://dx.doi.org/10.1002/chin.199939236.

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19

Lenčéš, Zoltán, Kiyoshi Hirao, Yukihiko Yamauchi, and Shuzo Kanzaki. "Reaction Synthesis of Magnesium Silicon Nitride Powder." Journal of the American Ceramic Society 86, no. 7 (July 2003): 1088–93. http://dx.doi.org/10.1111/j.1151-2916.2003.tb03429.x.

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20

Yunoshev, A. S. "Shock-Wave Synthesis of Cubic Silicon Nitride." Combustion, Explosion, and Shock Waves 40, no. 3 (May 2004): 370–73. http://dx.doi.org/10.1023/b:cesw.0000028951.97322.d9.

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21

Calka, A., J. S. Williams, and P. Millet. "Synthesis of silicon nitride by mechanical alloying." Scripta Metallurgica et Materialia 27, no. 12 (December 1992): 1853–57. http://dx.doi.org/10.1016/0956-716x(92)90032-a.

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22

Wang, Ming-Jong, and Harue Wada. "Synthesis and characterization of silicon nitride whiskers." Journal of Materials Science 25, no. 3 (March 1990): 1690–98. http://dx.doi.org/10.1007/bf01045372.

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23

Zhang, Ke, Ling Bai, Wei Ping Shen, and Chang Chun Ge. "Low-Pressure Preheating Combustion Synthesis of Silicon Nitride." Advanced Materials Research 26-28 (October 2007): 441–44. http://dx.doi.org/10.4028/www.scientific.net/amr.26-28.441.

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Silicon nitride was prepared by means of low-pressure preheating combustion synthesis in this paper. When N2 pressure is less than or equal to 2MPa, the lowest preheating temperature is about 653K, reactant could make silicon nitride by combustion synthesis. The additive of ammonium fluoride and ammonium chloride, as the reactive diluent, and Si react and make some useful intermediate products to α -Si3N4 after thermal decomposition. The reactive diluent content must be appropriate. At the same time, with the improvement of Si3N4, as the inert diluent, content in reactant, the adiabatic flame temperature of system would reduce, and combustion reaction rate of Si also drops, so it is propitious to make high level of α -Si3N4.
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24

Young Kim, Hwa, Jeunghee Park, and Hyunik Yang. "Synthesis of silicon nitride nanowires directly from the silicon substrates." Chemical Physics Letters 372, no. 1-2 (April 2003): 269–74. http://dx.doi.org/10.1016/s0009-2614(03)00428-7.

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25

AGRAFIOTIS, C. C., J. LIS, J. A. PUSZYNSKI, and V. HLAVACEK. "ChemInform Abstract: Combustion Synthesis of Silicon Nitride-Silicon Carbide Composites." ChemInform 22, no. 6 (August 23, 2010): no. http://dx.doi.org/10.1002/chin.199106299.

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26

Lin, Dahcheng, and Shoichi Kimura. "Kinetics of Silicon Monoxide Ammonolysis for Nanophase Silicon Nitride Synthesis." Journal of the American Ceramic Society 79, no. 11 (November 1996): 2947–55. http://dx.doi.org/10.1111/j.1151-2916.1996.tb08730.x.

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27

Gundiah, Gautam, G. V. Madhav, A. Govindaraj, Md Motin Seikh, and C. N. R. Rao. "Synthesis and characterization of silicon carbide, silicon oxynitride and silicon nitride nanowires." Journal of Materials Chemistry 12, no. 5 (April 3, 2002): 1606–11. http://dx.doi.org/10.1039/b200161f.

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28

Ho, Pauline, Richard J. Buss, and Ronald E. Loehman. "Glow-discharge synthesis of silicon nitride precursor powders." Journal of Materials Research 4, no. 4 (August 1989): 873–81. http://dx.doi.org/10.1557/jmr.1989.0873.

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A radio-frequency glow discharge is used for the synthesis of submicron, amorphous, silicon nitride precursor powders from silanc and ammonia. Powders are produced with a range of Si/N ratios, including stoichiometric, Si-rich, and N-rich, and contain substantial amounts of hydrogen. The powders appear to be similar to silicon diimide and are easily converted to oxide by water vapor. The powders lose weight and crystallize to a mixture of α and β–Si3N4 after prolonged heating at 1600 °C. Studies of spectrally and spatially resolved optical emission from the plasma are reported.
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29

Ødegård, Ivar Andre, Julien Romann, Anita Fossdal, Arne Røyset, and Gabriella Tranell. "Synthesis and properties of silicon/magnesium silicon nitride diatom frustule replicas." J. Mater. Chem. A 2, no. 39 (2014): 16410–15. http://dx.doi.org/10.1039/c4ta03750b.

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A novel method for the conversion of diatom bio-silica structures into nano-porous 3D silicon/magnesium silicon nitride replicas utilising simultaneous metallothermic reduction and nitriding is described. Optical, chemical and structural characterization of the replicas is also presented.
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30

Zhang, Guo-Jun, Yoshihisa Beppu, Motohide Ando, Jian-Feng Yang, and Tatsuki Ohji. "In Situ Reaction Synthesis of Silicon Carbide-Boron Nitride Composite from Silicon Nitride-Boron Oxide-Carbon." Journal of the American Ceramic Society 85, no. 11 (December 20, 2004): 2858–60. http://dx.doi.org/10.1111/j.1151-2916.2002.tb00544.x.

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31

Wu, X. C., W. H. Song, B. Zhao, W. D. Huang, M. H. Pu, Y. P. Sun, and J. J. Du. "Synthesis of coaxial nanowires of silicon nitride sheathed with silicon and silicon oxide." Solid State Communications 115, no. 12 (August 2000): 683–86. http://dx.doi.org/10.1016/s0038-1098(00)00255-6.

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32

LARKER, R., and B. LOBERG. "DIFFUSION REACTIONS BETWEEN SILICON OXYNITRIDE AND SILICON NITRIDE DURING HIP-SYNTHESIS." Le Journal de Physique Colloques 49, no. C5 (October 1988): C5–219—C5–225. http://dx.doi.org/10.1051/jphyscol:1988523.

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33

Fruhstorfer, Jens, Florian Kerber, Christian Weigelt, Kirsten Moritz, and Christos G. Aneziris. "Activated reaction synthesis of silicon oxynitride from silica and silicon nitride." Ceramics International 44, no. 7 (May 2018): 8467–75. http://dx.doi.org/10.1016/j.ceramint.2018.02.044.

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34

Wang, Hongyu, and Gary S. Fischman. "In Situ Synthesis of Silicon Carbide Whiskers from Silicon Nitride Powders." Journal of the American Ceramic Society 74, no. 7 (July 1991): 1519–22. http://dx.doi.org/10.1111/j.1151-2916.1991.tb07134.x.

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35

Antsiferov, V. N., V. G. Khalturin, and A. F. Ainagos. "Laser synthesis of ultrafine powders of silicon nitride and silicon carbide." Powder Metallurgy and Metal Ceramics 37, no. 1-2 (January 1998): 33–36. http://dx.doi.org/10.1007/bf02677227.

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36

Jong, B. W., G. J. Slavens, and D. E. Traut. "Synthesis of silicon and silicon nitride powders by vapour-phase reactions." Journal of Materials Science 27, no. 22 (1992): 6086–90. http://dx.doi.org/10.1007/bf01133754.

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37

Xie, Zhi Peng, Wei You Yang, He Zhuo Miao, Li Gong Zhang, and Li Nan An. "Synthesis and Growth Mechanism of Silicon Nitride Nanostructures." Materials Science Forum 475-479 (January 2005): 1239–42. http://dx.doi.org/10.4028/www.scientific.net/msf.475-479.1239.

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A new method to synthesize Si3N4 nanostructures via catalyst-assisted polymeric precursor pyrolysis is present in this article. The as-prepared nanobelts are single crystals with a uniform thickness and width along the entire length, and contain no detectable defects such as dislocations or stacking faults. The thickness and width of Si3N4 nanobelts range from 40 to 60 nm and 600 to 1200 nm, respectively, and the lengths can be up to several millimeters. The growth directions of a-Si3N4 nanobelts are [101] and [100]. A solid-liquid-solid and gas-solid reaction/crystallization is proposed for the growth of S3N4 nonastructures.
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38

Inagaki, Yoshiaki, Yasuhiro Shigegaki, Motohide Ando, and Tatsuki Ohji. "Synthesis and evaluation of anisotropic porous silicon nitride." Journal of the European Ceramic Society 24, no. 2 (January 2004): 197–200. http://dx.doi.org/10.1016/s0955-2219(03)00603-4.

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39

Lenčéš, Z., L. Benco, J. Madejová, Y. Zhou, L. Kipsová, and K. Hirao. "Reaction synthesis and characterisation of lanthanum silicon nitride." Journal of the European Ceramic Society 28, no. 9 (January 2008): 1917–22. http://dx.doi.org/10.1016/j.jeurceramsoc.2007.11.017.

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40

Maalmi, Mostafa, Arvind Varma, and William C. Strieder. "Reaction-bonded silicon nitride synthesis: experiments and model." Chemical Engineering Science 53, no. 4 (February 1998): 679–89. http://dx.doi.org/10.1016/s0009-2509(97)00344-8.

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41

Chen, Dianying, Baolin Zhang, Hanrui Zhuang, and Wenlan Li. "Combustion synthesis of network silicon nitride porous ceramics." Ceramics International 29, no. 4 (January 2003): 363–64. http://dx.doi.org/10.1016/s0272-8842(02)00145-1.

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42

SEKINE, Toshimori. "Synthesis and Sintering of Cubic Silicon Nitride (cSi3N4)." Review of High Pressure Science and Technology 13, no. 1 (2003): 55–60. http://dx.doi.org/10.4131/jshpreview.13.55.

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43

Vuckovic, Aleksandra, Snezana Boskovic, and Ljiljana Zivkovic. "Synthesis of "in situ" reinforced silicon nitride composites." Journal of the Serbian Chemical Society 69, no. 1 (2004): 59–67. http://dx.doi.org/10.2298/jsc0401059v.

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The objective of this work was to investigate the effect of two different sintering additives (CeO2 and Y2O3 + Al2O3), sintering time and amount of ?-Si3N4 seeds on the densification, mechanical properties and microstructure of self-reinforced Si3N4 based composites obtained by pressureless sintering. Preparation of ?-Si3N4 seeds, also obtained by a pressureless sintering procedure, is described. Samples without seeds were prepared for comparison. The results imply that self-reinforced silicon nitride based composites with densities close to the theoretical values and with fracture toughness of 9.3MPa m1/2 can be obtained using a presureless sintering procedure.
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44

Lange, Horst, Gerhard Wötting, and Gerhard Winter. "Silicon Nitride—From Powder Synthesis to Ceramic Materials." Angewandte Chemie International Edition in English 30, no. 12 (December 1991): 1579–97. http://dx.doi.org/10.1002/anie.199115791.

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45

Hüttinger, K. J., and T. W. Pieschnick. "A Synthesis of Mono-Crystalline Silicon Nitride Filaments." Key Engineering Materials 89-91 (August 1993): 87–94. http://dx.doi.org/10.4028/www.scientific.net/kem.89-91.87.

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46

Lu, Yuan, Jianfeng Yang, Weizhong Lu, Rongzhen Liu, Guanjun Qiao, and Chonggao Bao. "Synthesis of Porous Silicon Nitride Ceramics from Diatomite." Materials and Manufacturing Processes 25, no. 9 (August 31, 2010): 998–1000. http://dx.doi.org/10.1080/10426910903229396.

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47

Dasog, Mita, and Jonathan G. C. Veinot. "Solid-state synthesis of luminescent silicon nitride nanocrystals." Chemical Communications 48, no. 31 (2012): 3760. http://dx.doi.org/10.1039/c2cc16971a.

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48

Ghosh Chaudhuri, M., Sk Ahmadullah, R. Dey, G. C. Das, S. Mukherjee, and M. K. Mitra. "Novel technique for synthesis of silicon nitride nanowires." Advances in Applied Ceramics 110, no. 4 (May 2011): 211–14. http://dx.doi.org/10.1179/1743676111y.0000000003.

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49

H�ttinger, K. J., and T. W. Pieschnick. "A synthesis of mono-crystalline silicon nitride filaments." Journal of Materials Science 29, no. 11 (1994): 2879–83. http://dx.doi.org/10.1007/bf01117596.

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50

HILLINGER, G., and V. HLAVACEK. "ChemInform Abstract: Direct Synthesis and Sintering of Silicon Nitride/Titanium Nitride Composite." ChemInform 27, no. 18 (August 5, 2010): no. http://dx.doi.org/10.1002/chin.199618003.

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