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1

Pagliaro, Mario, Cristina Della Pina, Francesco Mauriello, and Rosaria Ciriminna. "Catalysis with Silver: From Complexes and Nanoparticles to MORALs and Single-Atom Catalysts." Catalysts 10, no. 11 (2020): 1343. http://dx.doi.org/10.3390/catal10111343.

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Silver catalysis has a rich and versatile chemistry now expanding from processes mediated by silver complexes and silver nanoparticles to transformations catalyzed by silver metal organic alloys and single-atom catalysts. Focusing on selected recent advances, we identify the key advantages offered by these highly selective heterogeneous catalysts. We conclude by offering seven research and educational guidelines aimed at further progressing the field of new generation silver-based catalytic materials.
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2

Ding, Xun-Lei, Dan Wang, Rui-Jie Li, Heng-Lu Liao, Yan Zhang, and Hua-Yong Zhang. "Adsorption of a single gold or silver atom on vanadium oxide clusters." Physical Chemistry Chemical Physics 18, no. 14 (2016): 9497–503. http://dx.doi.org/10.1039/c6cp00808a.

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3

Karim, Nabila A., Nor Shahirah Shamsul, and Siti Kartom Kamarudin. "Catalytic Activity of Silver Metal Supported on Doped Graphene in Alkaline Medium for Oxygen Reduction Reaction." Advanced Materials Research 1155 (August 2019): 55–69. http://dx.doi.org/10.4028/www.scientific.net/amr.1155.55.

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The platinum (Pt) degradation, poisoning and carbon corrosion in acidic fuel cell has led to explore the research in alkaline fuel cell. However, the high cost of Pt has brought a lot of studies to find replacement for Pt catalyst. Due to that, silver metal is selected as non-Pt catalyst and supported by the nitrogen and phosphorus-doped on graphene for oxygen reduction reaction in alkaline medium. The adsorption energy and mechanism of the oxygen reduction reaction is studied by using density functional theory (DFT) calculation. The support catalyst of graphene is doped with three atom nitrog
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4

Jiang, Xun‐Heng, Long‐Shuai Zhang, Hai‐Yan Liu, et al. "Silver Single Atom in Carbon Nitride Catalyst for Highly Efficient Photocatalytic Hydrogen Evolution." Angewandte Chemie 132, no. 51 (2020): 23312–16. http://dx.doi.org/10.1002/ange.202011495.

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5

Jiang, Xun‐Heng, Long‐Shuai Zhang, Hai‐Yan Liu, et al. "Silver Single Atom in Carbon Nitride Catalyst for Highly Efficient Photocatalytic Hydrogen Evolution." Angewandte Chemie International Edition 59, no. 51 (2020): 23112–16. http://dx.doi.org/10.1002/anie.202011495.

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6

Hulva, Jan, Matthias Meier, Roland Bliem, et al. "Unraveling CO adsorption on model single-atom catalysts." Science 371, no. 6527 (2021): 375–79. http://dx.doi.org/10.1126/science.abe5757.

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Understanding how the local environment of a “single-atom” catalyst affects stability and reactivity remains a challenge. We present an in-depth study of copper1, silver1, gold1, nickel1, palladium1, platinum1, rhodium1, and iridium1 species on Fe3O4(001), a model support in which all metals occupy the same twofold-coordinated adsorption site upon deposition at room temperature. Surface science techniques revealed that CO adsorption strength at single metal sites differs from the respective metal surfaces and supported clusters. Charge transfer into the support modifies the d-states of the met
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7

Ding, Jie, Xuefang Liu, Mengge Shi, et al. "Single-atom silver–manganese catalysts for photocatalytic CO2 reduction with H2O to CH4." Solar Energy Materials and Solar Cells 195 (June 2019): 34–42. http://dx.doi.org/10.1016/j.solmat.2019.02.009.

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8

Xia, Mingyu, Jie Ding, Xiaowei Du, Ruilin Shang, and Qin Zhong. "Ambient hydrogenation of CO2 to methane with highly efficient and stable single-atom silver-manganese catalysts." Journal of Alloys and Compounds 777 (March 2019): 406–14. http://dx.doi.org/10.1016/j.jallcom.2018.10.352.

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9

Bowmaker, Graham A., Narongsak Chaichit, Chaveng Pakawatchai, Brian W. Skelton, and Allan H. White. "Structural and spectroscopic studies of some adducts of silver(I) salts with ethylenethiourea." Canadian Journal of Chemistry 87, no. 1 (2009): 161–70. http://dx.doi.org/10.1139/v08-112.

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Syntheses, single crystal X-ray structural and spectroscopic characterizations are described for a variety of adducts of silver salts with ethylenethiourea (etu). Ag2SO4/etu (1:6) is isomorphous with its previously studied copper(I) counterpart, the [Ag(S-etu)3]+ species disposed with their silver atoms on crystallographic 3-axes, one of the two independent cations being slightly perturbed by a distant O-sulfate approach along that axis. In AgCl/etu (1:3), the silver atom is in a four-coordinate ClAgS3 environment, while AgNO3/etu (1:3) takes the form [(etu)2Ag(µ-S-etu)2Ag(etu)2](NO3)2. AgBr/e
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10

Chen, Shuai, Zhe‐Ning Chen, Wei‐Hui Fang, Wei Zhuang, Lei Zhang, and Jian Zhang. "Ag 10 Ti 28 ‐Oxo Cluster Containing Single‐Atom Silver Sites: Atomic Structure and Synergistic Electronic Properties." Angewandte Chemie International Edition 58, no. 32 (2019): 10932–35. http://dx.doi.org/10.1002/anie.201904680.

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11

Rassolov, A. V., G. O. Bragina, G. N. Baeva, I. S. Mashkovsky, and A. Yu Stakheev. "Alumina-Supported Palladium–Silver Bimetallic Catalysts with Single-Atom Pd1 Sites in the Liquid-Phase Hydrogenation of Substituted Alkynes." Kinetics and Catalysis 61, no. 6 (2020): 869–78. http://dx.doi.org/10.1134/s0023158420060129.

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12

Ding, Jie, Maohong Fan, Qin Zhong, and Armistead G. Russell. "Single-atom silver-manganese nanocatalysts based on atom-economy design for reaction temperature-controlled selective hydrogenation of bioresources-derivable diethyl oxalate to ethyl glycolate and acetaldehyde diethyl acetal." Applied Catalysis B: Environmental 232 (September 2018): 348–54. http://dx.doi.org/10.1016/j.apcatb.2018.03.058.

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13

Shustov, Gennady V., Melanie K. Chandler, and Saul Wolfe. "Stereoselective synthesis of multiply substituted [1,2]oxazinan-3-ones via ring-closing metathesis." Canadian Journal of Chemistry 83, no. 2 (2005): 93–103. http://dx.doi.org/10.1139/v04-174.

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The title compounds are α-amino acids whose nitrogen atoms are enclosed within 4,5-disubstituted, six-membered cyclic hydroxamates and they are of interest as potential β-lactam surrogates. The compounds have been synthesized in the present work by functionalization of the double bonds of N-substituted 6H-[1,2]oxazin-3-ones, which are obtained upon successive reaction of the triflates of S-α-hydroxy esters with O-allylhydroxylamine and acryloyl chloride, followed by cyclization of the resulting R-α-N-acryloyl-N-allyloxyamino esters in the presence of the ring-closing metathesis (RCM) catalyst
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14

van der Linden, Marte, Arnoldus J. van Bunningen, Lucia Amidani, et al. "Single Au Atom Doping of Silver Nanoclusters." ACS Nano 12, no. 12 (2018): 12751–60. http://dx.doi.org/10.1021/acsnano.8b07807.

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15

Zhong, Wenhui, Guozhen Zhang, Yachao Zhang, et al. "Enhanced Activity of C2N-Supported Single Co Atom Catalyst by Single Atom Promoter." Journal of Physical Chemistry Letters 10, no. 22 (2019): 7009–14. http://dx.doi.org/10.1021/acs.jpclett.9b02906.

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16

蔡, 秋兰. "Recent Research Progresses on Single Atom Catalyst." Material Sciences 11, no. 01 (2021): 48–54. http://dx.doi.org/10.12677/ms.2021.111007.

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17

Cheng, Niancai, and Xueliang Sun. "Single atom catalyst by atomic layer deposition technique." Chinese Journal of Catalysis 38, no. 9 (2017): 1508–14. http://dx.doi.org/10.1016/s1872-2067(17)62903-6.

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18

Bakandritsos, Aristides, Ravishankar G. Kadam, Pawan Kumar, et al. "Single‐Atom Catalysis: Mixed‐Valence Single‐Atom Catalyst Derived from Functionalized Graphene (Adv. Mater. 17/2019)." Advanced Materials 31, no. 17 (2019): 1970125. http://dx.doi.org/10.1002/adma.201970125.

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19

Huang, Zhiwei, Xiao Gu, Qingqing Cao, et al. "Catalytically Active Single-Atom Sites Fabricated from Silver Particles." Angewandte Chemie 124, no. 17 (2012): 4274–79. http://dx.doi.org/10.1002/ange.201109065.

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20

Huang, Zhiwei, Xiao Gu, Qingqing Cao, et al. "Catalytically Active Single-Atom Sites Fabricated from Silver Particles." Angewandte Chemie International Edition 51, no. 17 (2012): 4198–203. http://dx.doi.org/10.1002/anie.201109065.

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21

Zhang, Xiaoyan, Zaicheng Sun, Bin Wang, et al. "C–C Coupling on Single-Atom-Based Heterogeneous Catalyst." Journal of the American Chemical Society 140, no. 3 (2018): 954–62. http://dx.doi.org/10.1021/jacs.7b09314.

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22

Bakandritsos, Aristides, Ravishankar G. Kadam, Pawan Kumar, et al. "Mixed‐Valence Single‐Atom Catalyst Derived from Functionalized Graphene." Advanced Materials 31, no. 17 (2019): 1900323. http://dx.doi.org/10.1002/adma.201900323.

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23

Wang, Dewen, Qun Li, Ce Han, Zhicai Xing, and Xiurong Yang. "Single-atom ruthenium based catalyst for enhanced hydrogen evolution." Applied Catalysis B: Environmental 249 (July 2019): 91–97. http://dx.doi.org/10.1016/j.apcatb.2019.02.059.

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24

Wang, Jian, Lujie Jia, Jun Zhong, et al. "Single-atom catalyst boosts electrochemical conversion reactions in batteries." Energy Storage Materials 18 (March 2019): 246–52. http://dx.doi.org/10.1016/j.ensm.2018.09.006.

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25

Fang, Zhiwei, and Guihua Yu. "Single atom catalyst towards ammonia synthesis at mild conditions." Science China Chemistry 61, no. 9 (2018): 1045–46. http://dx.doi.org/10.1007/s11426-018-9285-0.

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26

Zhao, Chao, Can Xiong, Xiaokang Liu, et al. "Unraveling the enzyme-like activity of heterogeneous single atom catalyst." Chemical Communications 55, no. 16 (2019): 2285–88. http://dx.doi.org/10.1039/c9cc00199a.

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Herein, we report a heterogeneous single iron atom catalyst exhibiting excellent peroxidase, oxidase and catalase enzyme-like activities (defined as single atom enzymes, SAEs), exceeding those of Fe<sub>3</sub>O<sub>4</sub> nanozymes by a factor of 40.
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27

Fu, Zhanzhao, Chongyi Ling, and Jinlan Wang. "A Ti3C2O2 supported single atom, trifunctional catalyst for electrochemical reactions." Journal of Materials Chemistry A 8, no. 16 (2020): 7801–7. http://dx.doi.org/10.1039/d0ta01047b.

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28

Li, Can. "Single Co atom catalyst stabilized in C/N containing matrix." Chinese Journal of Catalysis 37, no. 9 (2016): 1443–45. http://dx.doi.org/10.1016/s1872-2067(16)62520-2.

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29

Chen, Jingguang G. "Electrochemical CO2 Reduction via Low-Valent Nickel Single-Atom Catalyst." Joule 2, no. 4 (2018): 587–89. http://dx.doi.org/10.1016/j.joule.2018.03.018.

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30

Yang, Fa, Ping Song, Xiaozhi Liu, et al. "Highly Efficient CO2 Electroreduction on ZnN4 -based Single-Atom Catalyst." Angewandte Chemie 130, no. 38 (2018): 12483–87. http://dx.doi.org/10.1002/ange.201805871.

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31

Yang, Fa, Ping Song, Xiaozhi Liu, et al. "Highly Efficient CO2 Electroreduction on ZnN4 -based Single-Atom Catalyst." Angewandte Chemie International Edition 57, no. 38 (2018): 12303–7. http://dx.doi.org/10.1002/anie.201805871.

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32

Song, Ping, Mi Luo, Xiaozhi Liu, et al. "Zn Single Atom Catalyst for Highly Efficient Oxygen Reduction Reaction." Advanced Functional Materials 27, no. 28 (2017): 1700802. http://dx.doi.org/10.1002/adfm.201700802.

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33

Kim, Jiwhan, Chi-Woo Roh, Suman Kalyan Sahoo, et al. "Highly Durable Platinum Single-Atom Alloy Catalyst for Electrochemical Reactions." Advanced Energy Materials 8, no. 1 (2017): 1701476. http://dx.doi.org/10.1002/aenm.201701476.

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34

Xiao, Meiling, Jianbing Zhu, Gaoran Li, et al. "A Single‐Atom Iridium Heterogeneous Catalyst in Oxygen Reduction Reaction." Angewandte Chemie International Edition 58, no. 28 (2019): 9640–45. http://dx.doi.org/10.1002/anie.201905241.

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35

Xiao, Meiling, Jianbing Zhu, Gaoran Li, et al. "A Single‐Atom Iridium Heterogeneous Catalyst in Oxygen Reduction Reaction." Angewandte Chemie 131, no. 28 (2019): 9742–47. http://dx.doi.org/10.1002/ange.201905241.

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36

Zai, Huachao, Yizhou Zhao, Shanyu Chen, et al. "Heterogeneously supported pseudo-single atom Pt as sustainable hydrosilylation catalyst." Nano Research 11, no. 5 (2018): 2544–52. http://dx.doi.org/10.1007/s12274-017-1879-6.

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37

Chen, Fang, Tianbo Li, Xiaoli Pan, et al. "Pd1/CeO2 single-atom catalyst for alkoxycarbonylation of aryl iodides." Science China Materials 63, no. 6 (2019): 959–64. http://dx.doi.org/10.1007/s40843-019-1204-y.

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38

Lin, Xiaoyun, Lulu Li, Xin Chang, Chunlei Pei, Zhi-Jian Zhao, and Jinlong Gong. "Black phosphorus-hosted single-atom catalyst for electrocatalytic nitrogen reduction." Science China Materials 64, no. 5 (2020): 1173–81. http://dx.doi.org/10.1007/s40843-020-1522-y.

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39

Kim, In Ho, Joonwon Lim, and Sang Ouk Kim. "Discovery of Single-Atom Catalyst: Customized Heteroelement Dopants on Graphene." Accounts of Materials Research 2, no. 6 (2021): 394–406. http://dx.doi.org/10.1021/accountsmr.1c00016.

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40

Jiang, Bizhi, Hao Sun, Tao Yuan, et al. "Framework-Derived Tungsten Single-Atom Catalyst for Oxygen Reduction Reaction." Energy & Fuels 35, no. 9 (2021): 8173–80. http://dx.doi.org/10.1021/acs.energyfuels.1c00758.

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41

Wang, Qi, Zhe Zhang, Chao Cai, et al. "Single Iridium Atom Doped Ni2P Catalyst for Optimal Oxygen Evolution." Journal of the American Chemical Society 143, no. 34 (2021): 13605–15. http://dx.doi.org/10.1021/jacs.1c04682.

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42

Bi, Qingyuan, Xiaotao Yuan, Yue Lu, et al. "One-Step High-Temperature-Synthesized Single-Atom Platinum Catalyst for Efficient Selective Hydrogenation." Research 2020 (April 29, 2020): 1–10. http://dx.doi.org/10.34133/2020/9140841.

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Although single-atom catalysts significantly improve the atom utilization efficiency, the multistep preparation procedures are complicated and difficult to control. Herein, we demonstrate that one-step in situ synthesis of the single-atom Pt anchored in single-crystal MoC (Pt1/MoC) by using facile and controllable arc-discharge strategy under extreme conditions. The high temperature (up to 4000°C) provides the sufficient energy for atom dispersion and overall stability by forming thermodynamically favourable metal-support interactions. The high-temperature-stabilized Pt1/MoC exhibits outstandi
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43

Nigam, Sandeep, and Chiranjib Majumder. "Single atom alloy catalyst for SO3 decomposition: enhancement of platinum catalyst's performance by Ag atom embedding." Nanoscale 10, no. 44 (2018): 20599–610. http://dx.doi.org/10.1039/c8nr05179h.

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Single Ag atom embedded Pt particle as novel catalyst for SO<sub>3</sub> decomposition. They show lower activation barrier and have potential towards better thermal resistance and better recyclability.
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44

Shi, Qi, Yongjun Ji, Wenxin Chen, et al. "Single-atom Sn-Zn pairs in CuO catalyst promote dimethyldichlorosilane synthesis." National Science Review 7, no. 3 (2019): 600–608. http://dx.doi.org/10.1093/nsr/nwz196.

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Abstract Single-atom catalysts are of great interest because they can maximize the atom-utilization efficiency and generate unique catalytic properties; however, much attention has been paid to single-site active components, rarely to catalyst promoters. Promoters can significantly affect the activity and selectivity of a catalyst, even at their low concentrations in catalysts. In this work, we designed and synthesized CuO catalysts with atomically dispersed co-promoters of Sn and Zn. When used as the catalyst in the Rochow reaction for the synthesis of dimethyldichlorosilane, this catalyst ex
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45

Yang, Weijie, Mingliang Zhao, Xunlei Ding, et al. "The effect of coordination environment on the kinetic and thermodynamic stability of single-atom iron catalysts." Physical Chemistry Chemical Physics 22, no. 7 (2020): 3983–89. http://dx.doi.org/10.1039/c9cp05349b.

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46

Ling, Chongyi, Li Shi, Yixin Ouyang, Xiao Cheng Zeng, and Jinlan Wang. "Nanosheet Supported Single-Metal Atom Bifunctional Catalyst for Overall Water Splitting." Nano Letters 17, no. 8 (2017): 5133–39. http://dx.doi.org/10.1021/acs.nanolett.7b02518.

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47

Tang, Yan, Yang-Gang Wang, and Jun Li. "Theoretical Investigations of Pt1@CeO2 Single-Atom Catalyst for CO Oxidation." Journal of Physical Chemistry C 121, no. 21 (2017): 11281–89. http://dx.doi.org/10.1021/acs.jpcc.7b00313.

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48

Wang, Lan, Xiaokang Liu, Linlin Cao, et al. "Active Sites of Single-Atom Iron Catalyst for Electrochemical Hydrogen Evolution." Journal of Physical Chemistry Letters 11, no. 16 (2020): 6691–96. http://dx.doi.org/10.1021/acs.jpclett.0c01943.

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49

Aich, Payoli, Haojuan Wei, Bridget Basan, et al. "Single-Atom Alloy Pd–Ag Catalyst for Selective Hydrogenation of Acrolein." Journal of Physical Chemistry C 119, no. 32 (2015): 18140–48. http://dx.doi.org/10.1021/acs.jpcc.5b01357.

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50

Helveg, S., C. F. Kisielowski, J. R. Jinschek, P. Specht, G. Yuan, and H. Frei. "Observing gas-catalyst dynamics at atomic resolution and single-atom sensitivity." Micron 68 (January 2015): 176–85. http://dx.doi.org/10.1016/j.micron.2014.07.009.

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