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1

Xu, Hua Ping, Hui Hu, Gao Feng Song, Chong He Li, and Xie Min Mao. "Behavior and Preparation of Single Crystal of Cu-Al-Ni-Be SMA." Materials Science Forum 561-565 (October 2007): 1463–66. http://dx.doi.org/10.4028/www.scientific.net/msf.561-565.1463.

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In this paper, single crystal of CuAlNiBe shape memory alloy (SMA) was prepared in a high temperature gradient directional solidification furnace with a selective growing crystallizer. And its performance characters were systematically studied. The results show that the mechanical and shape memory properties of the single crystal of CuAlNiBe SMA alloy has much better than that of the polycrystalline material. This may be explained that the stress concentration at grain boundary caused by the difference of bilateral strains is the dominant reason of deterioration of fatigue properties; therefor
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2

Xu, Hua Ping, Gao Feng Song, and Xie Min Mao. "Influence of Be and Ni to Cu-Al Alloy Shape Memory Performance." Advanced Materials Research 197-198 (February 2011): 1258–62. http://dx.doi.org/10.4028/www.scientific.net/amr.197-198.1258.

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With Bridgeman directional solidification method the single crystal alloys of CuAl base shape memory alloy (SMA) with different components were prepared. And their shape memory performance characters were systematically investigated. The results show that the single crystal of CuAlNiBe quaternary shape memory alloy has much better shape memory properties than that of the CuAlBe and CuAlNi ternary alloy. That meant that in the CuAl base SMA alloy the mixed addition of Be and Ni changed the quenching microstructure has a strengthening effect to improve the shape memory performance of the SMA all
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3

Xu, Hua Ping, Gao Feng Song, and Xie Min Mao. "A Study on Shape Memory Performance of Cu-Al-Ni-Be Alloy Single Crystal." Advanced Materials Research 287-290 (July 2011): 21–25. http://dx.doi.org/10.4028/www.scientific.net/amr.287-290.21.

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In this paper, single crystal of CuAlNiBe quaternary shape memory alloy was prepared in a high temperature gradient directional solidification furnace with a selective growing crystallizer. And its shape memory performance characters were systematically compared with other series copper base shape memory alloys. The results show that the single crystal of CuAlNiBe quaternary shape memory alloy has better shape memory properties.
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4

Siredey, N., A. Hautcoeur, and A. Eberhardt. "Lifetime of superelastic Cu–Al–Be single crystal wires under bending fatigue." Materials Science and Engineering: A 396, no. 1-2 (2005): 296–301. http://dx.doi.org/10.1016/j.msea.2005.01.021.

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5

Пульнев, С. А., А. И. Прядко, А. В. Чикиряка та В. И. Николаев. "Эффект локализации деформации в монокристаллах Cu-Al-Ni при изгибе продольной силой". Письма в журнал технической физики 44, № 21 (2018): 91. http://dx.doi.org/10.21883/pjtf.2018.21.46860.17425.

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AbstractThe behavior of a superelastic Cu−14.2% Al−4%Ni single crystal in the case of high reversible strains under a longitudinal bending force was investigated. The effect of strain confinement along the crystal length was revealed and studied. The highest reversible strains (up to 10%) were shown to be confined within the central part of the bent crystal.
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6

Gonzalez, C. H., C. J. De Araújo, N. F. Quadros, G. Guénin, and M. Morin. "Study of martensitic stabilisation under stress in Cu–Al–Be shape memory alloy single crystal." Materials Science and Engineering: A 378, no. 1-2 (2004): 253–56. http://dx.doi.org/10.1016/j.msea.2003.11.069.

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7

Kortan, A. R., H. S. Chen, and J. V. Waszczak. "Single-crystal x-ray diffraction from an icosahedral quasicrystal." Journal of Materials Research 2, no. 3 (1987): 294–97. http://dx.doi.org/10.1557/jmr.1987.0294.

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Single-crystal x-ray diffraction measurements made on a millimeter-size single icosahedral quasicrystal of an Al–Li–Cu alloy are reported. The point symmetries observed directly by real-time transmission Laue x-ray diffraction and the measured angles between the major symmetry axis are consistent with an icosahedral quasicrystal, and the peaks observed in the single-crystal diffraction scans are found to be indexable with six indices that belong to a primitive icosahedral Bravais quasilattice.
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8

Pavlyuk, Nazar, Grygoriy Dmytriv, Volodymyr Pavlyuk, and Helmut Ehrenberg. "Li20Mg6Cu13Al42: a new ordered quaternary superstructure to the icosahedral T-Mg32(Zn,Al)49 phase with fullerene-like Al60 cluster." Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials 75, no. 2 (2019): 168–74. http://dx.doi.org/10.1107/s2052520619000349.

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The new quaternary aluminide Li20Mg6Cu13Al42 was synthesized from the elements in a sealed tantalum crucible. The crystal structure was studied by single crystal and confirmed by X-ray powder diffraction. Li20Mg6Cu13Al42 {cI162, Im{\overline 3}, a = 13.8451 (2), R[F 2 > 2σ(F 2)] = 0.023} crystallizes as an ordered version of Mg32(Al,Zn)49 and Li—Cu—X (X = Al, Ga, Si) periodic crystals containing icosahedral clusters. The Li20Mg6Cu13Al42 structure can also be described as three-shell icosahedral clusters of [CuAl12@Li20Cu12@Al60], enclosed inside a distorted triacontahedron. The electronic s
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9

Ho, Ching Hwa, Chia Chi Pan, Jian Rong Cai, et al. "Structural and Band-Edge Properties of Cu(AlxIn1-X)S2 (0≤x≤1) Series Chalcopyrite Semiconductors." Solid State Phenomena 194 (November 2012): 133–38. http://dx.doi.org/10.4028/www.scientific.net/ssp.194.133.

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We have demonstrated structural and electronic properties of a series solar energy crystals Cu(AlxIn1-x)S2 (0<=x<=1) by using measurement techniques of X-ray diffraction, polarized thermoreflectance (PTR), and X-ray photoelectron spectroscopy (XPS). Single crystals of Cu(AlxIn1-x)S2 (0<=x<=1) (0 and E ^ polarizations. The PTR spectra clearly showed that the energy value of D increases with the increase of Al content x in the Cu(AlxIn1-x)S2 (0<=x<=1) series due to the enhanced strain in the lattice. The composition-dependent crystal-field-splitting energies can be evaluated an
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10

Siredey-Schwaller, N., A. Eberhardt, and P. Bastie. "Parameters influencing the fatigue life of a Cu–Al–Be single-crystal shape memory alloy under repeated bending." Smart Materials and Structures 18, no. 2 (2009): 025014. http://dx.doi.org/10.1088/0964-1726/18/2/025014.

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11

Krawczyk, Jacek, Wojciech Gurdziel, Włodzimierz Bogdanowicz, and Krzysztof Flisiński. "Temperature Influence on Stress-Strain Relationship of Al-Cu-Fe Crystal-Quasicrystal Composites." Solid State Phenomena 163 (June 2010): 282–85. http://dx.doi.org/10.4028/www.scientific.net/ssp.163.282.

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The columnar composites obtained “in situ” through solidification of Al61Cu27Fe12 alloy by the Bridgman method were studied. It has been verified that the matrix consisted of cubic single crystal β phase and the reinforcement of icosahedral quasicrystal ψ phase and monoclinic crystal λ phase, which have the form of rods. This kind of composites will be named the Al-Cu-Fe crystal-quasicrystal (CQ) composites. The effect of heating from a temperature of about 100°C to about 650°C on the stress-strain relationships σ(ε) of parallel samples was studied. Additionally, the σ(ε) relationship was defi
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12

Kuczera, Pawel, Janusz Wolny, and Walter Steurer. "Comparative structural study of decagonal quasicrystals in the systems Al–Cu–Me (Me = Co, Rh, Ir)." Acta Crystallographica Section B Structural Science 68, no. 6 (2012): 578–89. http://dx.doi.org/10.1107/s0108768112041134.

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A comparative single-crystal X-ray diffraction structure analysis of the family of Al–Cu–Me (Me = Co, Rh and Ir) decagonal quasicrystals is presented. In contrast to decagonal Al–Cu–Co, the other two decagonal phases do not show any structured disorder diffuse scattering indicating a higher degree of order. Furthermore, the atomic sites of Rh and Ir can be clearly identified, while Cu and Co cannot be distinguished because of their too similar atomic scattering factors. The structure models, derived from charge-flipping/low-density elimination results, were refined within the tiling-decoration
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13

Tokarski, Tomasz, Grzegorz Cios, Dorota Moszczynska, Boguslawa Adamczyk-Cieslak, Milena Koralnik, and Jaroslaw Mizera. "Texture Evolution of a Single Crystal Cu-8% at. Al Subjected to the Drawing Process." Crystals 12, no. 10 (2022): 1435. http://dx.doi.org/10.3390/cryst12101435.

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Single crystals of Cu-8.% at. Al were subjected to cold drawing up to 1.1 true strain. Development of the crystallographic texture was analysed at various stages of the drawing process. Investigations revealed significant crystal rotation and reorientation due to a twinning process, while general 4-fold symmetry around the drawing direction was preserved. Local texture analysis performed on cross-sections perpendicular to the drawing direction showed that due to crystal rotation, the original crystal was initially fragmented into four quadrants. However, within the volume near the central axis
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14

Adamo, I., G. D. Gatta, N. Rotiroti, V. Diella, and A. Pavese. "Gemmological investigation of a synthetic blue beryl: a multi-methodological study." Mineralogical Magazine 72, no. 3 (2008): 799–808. http://dx.doi.org/10.1180/minmag.2008.072.3.799.

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AbstractA multi-methodological investigation of a synthetic Cu/Fe-bearing blue beryl [IV(Be2.86Cu0.14)∑=3.00VI(Al1.83Fe3+0.14Mn2+0.03Mg0.03)∑=2.03IV(Si5.97Al0.03∑=6.00O18.(Li0.12Na0.04.0.40H2O)] has been performed by means of gemmological standard testing, electron microprobe chemical analyses, laser ablation inductively coupled plasma mass spectroscopy, thermo-gravimetric analyses, infrared spectroscopy and single-crystal X-ray diffraction in order to determine the gemmological properties, crystal structure and crystal-chemistry of this material. The increasing production of marketable hydrot
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15

Castillo, Fernando Néstor García, Rafael Schouwenaars, Jacinto Cortés Pérez, Vicente Amigó Borrás, and Miguel Ángel Ramírez Toledo. "ANALYSIS OF THE MARTENSITE VARIANT SELECTION IN A SINGLE CRYSTAL CU-AL-BE SHAPE MEMORY ALLOY IN A TENSILE TEST." Journal of Engineering Research 2, no. 12 (2022): 2–11. http://dx.doi.org/10.22533/at.ed.3172122230067.

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16

Ramani, Atul S., Lucille A. Giannuzzi, Altaf H. Carim, William R. Bitler, and Paul R. Howell. "New phases in the Al-Co-Cu alloy system : Marked variations from the “true” decagonal phase." Proceedings, annual meeting, Electron Microscopy Society of America 50, no. 1 (1992): 32–33. http://dx.doi.org/10.1017/s0424820100120564.

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The decagonal phase in the Al-Co-Cu alloy system was first discovered by He et al. We shall call this phase the “true” decagonal phase (TD) phase because it is the one most commonly observed in the Al-Co-Cu alloy system. It is well known that quasicrystalline phases such as the TD phase contain the phason defect peculiar to incommensurate phases that causes subtle variations from perfect decagonal symmetry. In this paper we report on the existence of new phases in the Al-Co-Cu alloy system, that are related to the TD phase but yet show marked variations from the TD phase. These variations are
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17

Ren, Wei Min, Zi Yong Chen, Zhi Lei Xiang, and Li Hua Chai. "Microstructure and Properties of Rapidly Solidified Al-Zn-Mg-Cu Alloy." Materials Science Forum 993 (May 2020): 203–7. http://dx.doi.org/10.4028/www.scientific.net/msf.993.203.

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Refining grain plays an important role in improving the mechanical properties of aluminum alloys. However, the conventional casting method with a slow cooling rate can be easy to cause coarseness of the microstructure and serious segregation. In this paper, the rapid solidification of Al-Zn-Mg-Cu alloy was prepared by the single-roller belt method. The alloy strip was studied by X-ray diffraction (XRD), scanning electron microscopy (SEM) and hardness test to study the microstructure and properties of the rapidly solidified aluminum alloy. The results show that the roller speed was an important
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18

Schaper, Jacob A. "Imaging and analysis of submicron single-crystal aluminum whiskers in Al/Cu/Si deposited films." Proceedings, annual meeting, Electron Microscopy Society of America 50, no. 2 (1992): 1290–91. http://dx.doi.org/10.1017/s0424820100131085.

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The formation of stress-relieving hillocks, also referred to as single-crystal whiskers is a well-known occurrence in the preparation of metallic thin films. In the manufacture of Application Specific Integrated Circuits, devices at the wafer level are often processed through the first metallic thin film process, coated with a plasma enhanced oxide (PEO), then stockpiled either at the manufacturer's site or the customer's to await final option-level programming. Whisker growth has been detected on wafers retrieved from the stockpile inventory. This paper describes the techniques employed for i
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19

MAÑOSA, LLUÍS, ANTONI PLANES, EDUARD VIVES, ERELL BONNOT, and RICARDO ROMERO. "THE USE OF SHAPE-MEMORY ALLOYS FOR MECHANICAL REFRIGERATION." Functional Materials Letters 02, no. 02 (2009): 73–78. http://dx.doi.org/10.1142/s1793604709000594.

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This letter reports on stress–strain experiments on a Cu – Zn – Al single crystal performed using a purpose-built tensile device which enables the load applied to the specimen to be controlled while elongation is continuously monitored. From the measured isothermal tensile curves, the stress-induced entropy changes are obtained at different temperatures. These data quantify the elastocaloric effect associated with the martensitic transition in shape-memory alloys. The large temperature changes estimated for this effect, suggest the possibility of using shape-memory alloys as mechanical refrige
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20

Uehara, Kazuma, Zhou Zihan, Zhicheng Huang, Kei Hayashi, and Yuzuru Miyazaki. "Preparation, Crystal Structure and Electrochemical Properties of Mg1-X Cu2+X O3." ECS Meeting Abstracts MA2024-02, no. 9 (2024): 1345. https://doi.org/10.1149/ma2024-0291345mtgabs.

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Magnesium copper oxide MgCu2O3 belongs to the space group Pmmn (setting 2) and has a crystal structure (GA phase) consisting of zigzag edge-sharing CuO4 planes arranged in 2D Cu2O3 layers and MgO6 octahedra. The Mg2+ between the Cu2O3 layers can be inserted and removed in the crystallographic c-axis direction as shown in Fig. 1. Hence, MgCu2O3 can be a potential cathode material for magnesium ion batteries. According to M. Paranthaman et al., the crystal structure changes depending on sintering temperature; apart from the GA phase, there are phases called GB and GX whose detailed crystal struc
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21

Motoyama, Munekazu, Katsutoshi Sakurai, Hisao Kiuchi, et al. "(Invited) Effects of the Alloy Composition on Cycling Performance of Cu-Ni Alloy Cathodes in All-Solid-State-Fluoride-Shuttle Batteries." ECS Meeting Abstracts MA2022-02, no. 47 (2022): 1734. http://dx.doi.org/10.1149/ma2022-02471734mtgabs.

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Metal fluorides generally have low electric conductivities. Hence, if a single metal (e.g. Cu) is used as the cathode active material for a fluoride-shuttle battery (FSB), the electric resistance in the cathode increases after the fluoridation reaction (charging).1,2 Hence, repeating charging and discharging leads to significant drop in capacity. If an alloy consisting of two metal elements with different fluorination/defluorination potentials is used as the cathode active material, one metal element behaves as a conductive metal even when the other metal element is fluorinated, and the increa
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22

Krasnikov, Vasiliy S., and Alexander E. Mayer. "Initiation and Mechanisms of Plasticity in Bimetallic Al-Cu Composite." Metals 13, no. 1 (2023): 102. http://dx.doi.org/10.3390/met13010102.

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We studied the shear deformation of a laminar Al-Cu composite with (100) and (110) interfaces with a shear perpendicular to the lamellae in comparison with pure single crystal Al and Cu at strain rates of 109 s−1 and 108 s−1 and different initial pressures in the range from −3 GPa to +50 GPa. The results of molecular dynamics (MD) for the plasticity initiation are generalized by means of an artificial neural network (ANN) trained by MD data for the (100) interface, and a rate sensitivity parameter identified using MD data for different strain rates. The ANN-based approach allows us to extrapol
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23

Zhou, Yuting, Xingxing Jiang, Yueshao Zheng, Sheng-Yi Xie, Yexin Feng, and Keqiu Chen. "Predicted stable high-pressure phases of copper-nitrogen compounds." Journal of Physics: Condensed Matter 34, no. 2 (2021): 025401. http://dx.doi.org/10.1088/1361-648x/ac2f10.

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Abstract The nitrogen-rich compounds are promising candidates for high-energy-density applications, owing to the large difference in the bonding energy between triple and single/double nitrogen bonds. The exploration of stable copper–nitrogen (Cu–N) compounds with high-energy-density has been challenging for a long time. Recently, through a combination of high temperatures and pressures, a new copper diazenide compound (P63/mmc-CuN2) has been synthesized (Binns et al 2019 J. Phys. Chem. Lett. 10 1109–1114). But the pressure-composition phase diagram of Cu–N compounds at different temperatures
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24

Kuczera, Pawel, and Walter Steurer. "High temperature structural study of decagonal Al-Cu-Rh quasicrystal." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C94. http://dx.doi.org/10.1107/s2053273314099057.

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The structure of d(ecagonal)-Al-Cu-Rh has been studied as a function of temperature by in-situ single-crystal X-ray diffraction in order to contribute to the discussion on energy or entropy stabilization of quasicrystals (QC) [1]. The experiments were performed at 293 K, 1223 K, 1153 K, 1083 K, and 1013 K. A common subset of 1460 unique reflections was used for the comparative structure refinements at each temperature. The results obtained for the HT structure refinements of d-Al-Cu-Rh QC seem to contradict a pure phasonic-entropy-based stabilization mechanism [2] for this QC. The trends obser
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25

Al-Zoubi, Noura. "Elastic Parameters of Paramagnetic Fe–20Cr–20Ni-Based Alloys: A First-Principles Study." Metals 9, no. 7 (2019): 792. http://dx.doi.org/10.3390/met9070792.

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The single-crystal and polycrystalline elastic parameters of paramagnetic Fe0.6−xCr0.2Ni0.2Mx (M = Al, Co, Cu, Mo, Nb, Ti, V, and W; 0 ≤ x ≤ 0.08) alloys in the face-centered cubic (fcc) phase were derived by first-principles electronic structure calculations using the exact muffin-tin orbitals method. The disordered local magnetic moment approach was used to model the paramagnetic phase. The theoretical elastic parameters of the present Fe–Cr–Ni-based random alloys agree with the available experimental data. In general, we found that all alloying elements have a significant effect on the elas
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26

Plumhoff, Alexandra M., Jakub Plášil, Edgar Dachs, et al. "Thermodynamic properties, crystal structure and phase relations of pushcharovskite [Cu(AsO<sub>3</sub>OH)(H<sub>2</sub>O) ⋅ 0.5H<sub>2</sub>O], geminite [Cu(AsO<sub>3</sub>OH)(H<sub>2</sub>O)] and liroconite [Cu<sub>2</sub>Al(AsO<sub>4</sub>)(OH)<sub>4</sub> ⋅ 4H<sub>2</sub>O]." European Journal of Mineralogy 32, no. 3 (2020): 285–304. http://dx.doi.org/10.5194/ejm-32-285-2020.

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Abstract. The phases pushcharovskite, geminite and liroconite were synthesized or acquired and characterized by powder X-ray diffraction, infrared spectroscopy, electron microprobe analysis, thermogravimetric analysis and optical emission spectrometry, as needed. Their thermodynamic properties were determined by a combination of acid-solution calorimetry and relaxation calorimetry, resulting in Gibbs free energies of formation (ΔfGo, all values in kilojoules per mole) of -1036.4±3.8 (pushcharovskite, Cu(AsO3OH)(H2O)⋅0.5H2O) and -926.7±3.2 (geminite, Cu(AsO3OH)(H2O)). For the natural liroconite
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27

Lucas, Christopher A. A., and Yvonne Grunder. "Probing the Structure of the Electrochemical Interface Using in-Situ Surface X-Ray Scattering Techniques." ECS Meeting Abstracts MA2024-01, no. 46 (2024): 2606. http://dx.doi.org/10.1149/ma2024-01462606mtgabs.

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Surface X-ray Scattering (SXS) or Surface X-ray Diffraction (SXRD) using synchrotron radiation is a powerful tool for the study of single crystal metal electrodes in the electrochemical environment. The single crystal surfaces have well defined adsorption sites and this enables fundamental links to be made between the surface atomic structure and the electrochemical response as has been illustrated, for example, in electrocatalysis [1]. As the development of electrochemical surface science progresses, there is a growing need for a comprehensive understanding of the atomic sturcture of electroc
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28

Yoshida, Kenichi, T. Yasuda, D. Tani, and H. Nishino. "Dynamic Behavior of Two Types of Martensitic Transformations in Cu-Al-Ni Shape Memory Alloy Single Crystal by Acoustic Emission Method." Advanced Materials Research 13-14 (February 2006): 305–12. http://dx.doi.org/10.4028/www.scientific.net/amr.13-14.305.

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Dynamic behavior of two types of martensitic transformations during tensile deformation of Cu-Al-Ni shape memory alloy single crystal has been investigated using an acoustic emission waveform analysis. Two kinds of martensitic transformations consist of β1 ⇔ β1′ (structural change of DO3 to 18R) and β1 ⇒ γ1′ (structural change of DO3 to 2H), each of which is called super-elastic and thermo-elastic martensitic transformations, respectively. These two types of martensitic transformations could be obtained during tensile deformation because of different heat treatment. The rise time at the source
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29

Koseki, Kaito, Yumeng Zheng, and Kentaro Kinoshita. "Effects of Anion or Cation Structures on the Interaction of Ionic Liquid with Cu3(BTC)2 Metal-Organic Frameworks." ECS Meeting Abstracts MA2024-02, no. 37 (2024): 2542. https://doi.org/10.1149/ma2024-02372542mtgabs.

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Metal-organic frameworks (MOFs) are a class of porous materials with highly periodic nanopores and enormous specific surface area, which allow us to achieve gas adsorption and catalytic applications superior to those based on conventional porous materials [1]. However, the structural degradation due to moisture absorption and fragility in many MOFs led to challenges for practical application. We have found a solution to inhibit this moisture degradation by filling ionic liquid (IL) into the nanopores of MOF; the composite materials are referred to as IL@MOF. In addition, in IL@MOF, it was also
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30

Vereshchagin, Oleg, Olga Frank-Kamenetskaya, and Ira Rozhdestvenskaya. "Bond valence constraints on the composition of 3d-elements bearing tourmalines." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C1118. http://dx.doi.org/10.1107/s2053273314088810.

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F.C. Hawthorne (2002) and F. Bosi (2011) showed that bond valence approach is to be applied to stability prediction of tourmaline structure with different chemical composition. Using this approach we considered bond valence constraints on occupation of Y, Z, V and W sites of Cu-, Ni-bearing tourmalines. From the standpoint of the bond valence approach, [3YW] unit is unstable if W site is fully occupied by O2-. The stability of [3YW] unit decreases along a row: 3 divalent cations → 2 divalent cations + 1 trivalent cation → 2 trivalent cation + 1 divalent cations → 3 trivalent cations if W site
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31

Kovács, Zs, N. Q. Chinh, and J. Lendvai. "Orientation dependence of Portevin–Le Châtelier plastic instabilities in depth-sensing microindentation." Journal of Materials Research 16, no. 4 (2001): 1171–77. http://dx.doi.org/10.1557/jmr.2001.0161.

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Plastic instabilities were investigated in an Al–Zn–Mg–Cu alloy by depth-sensing microhardness testing in Vickers geometry. The alloy investigated showed strong age hardening as a consequence of Guiner–Preston zone formation at room temperature. The orientation dependence of the Portevin–Le Chátelier (PLC) effect was investigated by microindentation tests in differently oriented grains. If the direction of the indentation was close to the 〈100〉 crystal axis and the diagonal of the Vickers indenter coincides with the 〈110〉 crystal direction, the PLC effect was more pronounced. Under these condi
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32

Xu, Xiaoyu, Jiahua Liu, Yuang Cao, et al. "Preparation and Application of Si@Al Adsorbents for Different Pollutants Removal from Aqueous Solution." Separations 11, no. 1 (2024): 29. http://dx.doi.org/10.3390/separations11010029.

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This study tried to use electroflocculating precipitated waste to prepare a Si@Al adsorbent by simply mixing sodium silicate at a mass ratio of 4:1 and calcining at 200 °C for 2 h. The adsorbent was low cost, high efficiency, and could remove a variety of contaminants (organic pollutants, antibiotics, and metal ions) from water. In this study, adsorbent characterization and pollutant adsorption experiments were carried out. The results showed that: Si@Al adsorbent had uniform particles, distinct layers, a loose porous appearance, and the internal structure was scattered without a crystal struc
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33

Mills, S. J., A. G. Christy, C. Schnyder, G. Favreau, and J. R. Price. "The crystal structure of camerolaite and structural variation in the cyanotrichite family of merotypes." Mineralogical Magazine 78, no. 7 (2014): 1527–52. http://dx.doi.org/10.1180/minmag.2014.078.7.02.

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AbstractWe present Raman data for camerolaite, cyanotrichite and carbonatecyanotrichite, and using synchrotron single-crystal X-ray diffraction have solved the structure of camerolaite from the Tistoulet Mine, Padern, Aude Department, France. Camerolaite crystallizes in space group P1 with the unit-cell parameters: a = 6.3310(13) Å, b = 2.9130(6) Å, c = 10.727(2) Å, α = 93.77(3)°, β = 96.34(3)°, γ =79.03(3)º, V = 192.82(7) Å3 and Z = ⅓, with respect to the ideal formula from the refinement, Cu6Al3(OH)18(H2O)2[Sb(OH)6](SO4). The crystal structure was solved to R1 = 0.0890 for all 1875 observed
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34

Hall, E. L., A. Mogro-Campero, N. Lewis, and L. G. Turner. "Microstructural characterization of YBaCuO Films on LaAlO3 substrates." Proceedings, annual meeting, Electron Microscopy Society of America 47 (August 6, 1989): 180–81. http://dx.doi.org/10.1017/s0424820100152872.

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There have been a large number of recent studies of the growth of Y-Ba-Cu-O thin films, and these studies have employed a variety of substrates and growth techniques. To date, the highest values of Tc and Jc have been found for films grown by sputtering or coevaporation on single-crystal SrTiO3 substrates, which produces a uniaxially-aligned film with the YBa2Cu3Ox c-axis normal to the film plane. Multilayer growth of films on the same substrate produces a triaxially-aligned film (regions of the film have their c-axis parallel to each of the three substrate &lt;100&gt; directions) with lower v
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35

Schock, Hans-W. "CulnSe2 and Other Chalcopyrite-Based Solar Cells." MRS Bulletin 18, no. 10 (1993): 42–44. http://dx.doi.org/10.1557/s0883769400038288.

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CuInSe2 and related chalcopyrite semiconductors are among the compound semiconductors that have been considered for thin solar cells for about the past 20 years. Recently, high efficiencies close to 17% have been achieved. This result could be the starting point for a new category of solar cells—high-performance thin-film cells—that would combine the high performance of single-crystal cells with possible low-cost thin-film processing.The development of CuInSe2 cells started in 1974, when single-crystal cells with an efficiency of 12% were reported by a group at Bell Laboratories. Soon after, t
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36

Mills, Stuart J., Andrew G. Christy, Fernando Colombo, and Jason R. Price. "The crystal structure of cyanotrichite." Mineralogical Magazine 79, no. 2 (2015): 321–35. http://dx.doi.org/10.1180/minmag.2015.079.2.10.

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AbstractWe report the single-crystal average structure of cyanotrichite, Cu4Al2[SO4](OH)12(H2O)2, from the Maid of Sunshine mine, Arizona, USA. Cyanotrichite crystallizes in space group C2/m, with the unit-cell parameters a = 12.625(3), b = 2.8950(6), c = 10.153(2) Å and β = 92.17(3)o. All non-hydrogen atoms were located and refined to R1 = 0.0394 for all 584 observed reflections [Fo &gt; 4σFo] and 0.0424 for all 622 unique reflections. The cyanotrichite structure consists of a principal building unit of a three-wide [Cu2Al(OH)6] ribbon of edge-sharing Cu and Al polyhedra || b, similar to that
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37

Ito, Yuga, Tatsuya Takeguchi, and Koichi Ui. "Effect of Deposition Conditions on Properties of Aluminum Deposit Obtained from Aluminum Chloride-Acetamide Melts." ECS Meeting Abstracts MA2024-02, no. 57 (2024): 3809. https://doi.org/10.1149/ma2024-02573809mtgabs.

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Introduction Since the standard electrode potential of aluminum (Al) (-1.67 V vs. SHE) is lower than that of hydrogen, Al electrodeposition from aqueous solution systems is difficult. Therefore, Al electrodeposition using nonaqueous solution systems, such as molten salts, ionic liquids, organic solvents, and deep eutectic solvents, have been widely studied. However, the synthesis cost of nonaqueous solution systems is not small. Therefore, Al electrodeposition using deep eutectic solvents has been studied, including from the viewpoint of low cost. For example, in the AlCl3-urea melt, the effec
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38

Mahmud, Mohd Sabri, Zahira Yaakob, Abu Bakar Mohamad, Wan Ramli Wan Daud, and Vo Nguyen Dai Viet. "AMORPHOUS STRUCTURE IN CU-ZN-V-AL OXIDE COMPOSITE CATALYST FOR METHANOL REFORMING." IIUM Engineering Journal 19, no. 1 (2018): 197–214. http://dx.doi.org/10.31436/iiumej.v19i1.808.

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Cu-Zn-V-Al oxide composite catalysts were prepared using a co-precipitation method to investigate hydrogen and carbon monoxide yield of a methanol reforming reaction. The mass compositions of metals were initially determined on the Simplex Centroid statistical design. The effects of various metal compositions on the physicochemical properties of the catalyst were studied via X-ray diffractogram (XRD), temperature-programmed reduction (TPR) analyses, and reaction. XRD revealed crystals in the samples. Crystalline CuO in Cu30V30Al40 formed with the addition of zinc oxide at the metal loading bel
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39

Heenan, Alexander Reynell, Johan Hamonnet, and Aaron Timothy Marshall. "Understanding the Inconsistencies in the Literature for the CO2 Reduction Reaction on Polycrystalline Copper." ECS Meeting Abstracts MA2022-01, no. 49 (2022): 2086. http://dx.doi.org/10.1149/ma2022-01492086mtgabs.

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As the desire to for carbon neutral processes increases with the prominence of global warming, the electrochemical reduction of carbon dioxide has the ability to not only reduce atmospheric CO2 levels, but also produce value added chemicals such as CO, C2H4, and CHOOH using renewable energy. Polycrystalline copper is a popular electrocatalyst for the CO2 reduction reaction (CO2RR) as it is the only pure metal catalyst to reduce CO2 to products that require more than two electrons, at reasonable faradaic efficiencies [1]. This has led to the development of many novel copper-based catalysts, suc
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40

Acharya, Biplav, Tyler N. Pardue, Liangliang Su, Alex I. Smirnov, Donald W. Brenner, and Jacqueline Krim. "Nanotribological Performance Factors for Aqueous Suspensions of Oxide Nanoparticles and Their Relation to Macroscale Lubricity." Lubricants 7, no. 6 (2019): 49. http://dx.doi.org/10.3390/lubricants7060049.

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Quartz crystal microbalance (QCM) measurements of nanotribological properties of statistically diverse materials combinations of nanoparticles and substrate electrodes in aqueous suspensions are reported and compared to macroscale measurements of the same materials combinations for a subset of the nanoparticle combinations. Four ceramic nanoparticles, TiO2, SiO2, Al2O3, and maghemite (γ-Fe2O3) and ten substrate materials (Au, Al, Cr, Cu, Mo, Ni, Pt, SiO2, Al2O3, and SS304) were studied. The QCM technique was employed to measure frequency and motional resistance changes upon introduction of nan
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41

Mordberg, L. E., C. J. Stanley, and K. Germann. "Mineralogy and geochemistry of trace elements in bauxites: the Devonian Schugorsk deposit, Russia." Mineralogical Magazine 65, no. 1 (2001): 81–101. http://dx.doi.org/10.1180/002646101550145.

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AbstractProcesses of mineral alteration involving the mobilization and deposition of more than 30 chemical elements during bauxite formation and epigenesis have been studied on specimens from the Devonian Schugorsk bauxite deposit, Timan, Russia. Chemical analyses of the minerals were obtained by electron microprobe and element distribution in the minerals was studied by element mapping. Interpretation of these data also utilized high-resolution BSE and SE images.The main rock-forming minerals of the Vendian parent rock are calcite, dolomite, feldspar, aegirine, riebeckite, mica, chlorite and
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42

Kosaki, Takahiro, Hiroki Hayashi, Hiroki Nara, Asano Gota, and Toshiyuki Momma. "Charge-Discharge Behavior of NMC111 Cathode in Aqueous Zinc Battery." ECS Meeting Abstracts MA2024-02, no. 9 (2024): 1350. https://doi.org/10.1149/ma2024-0291350mtgabs.

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Currently, aqueous zinc batteries (AZBs) with zinc anode and aqueous electrolyte are focused on as one of the post-lithium-ion batteries because they can be a safe and inexpensive energy storage device. To date, a number of compounds, such as manganese oxide, vanadium oxide, Prussian blue analogues, and so on, have been investigated as cathode materials for AZBs. Although these materials are promising, suitable materials for cathode are still being studied for practical use. A variety of charge-discharge mechanisms are found in cathode of AZBs, which is influenced by many factors such as the c
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43

Yu, Wei Yuan, Wen Jiang Lu, and Nai Rui Li. "Effects of Cu and Zr on the Formation and Thermal Stability of Al–Ni–Zr–Cu–Y Amorphous Alloy." Applied Mechanics and Materials 271-272 (December 2012): 36–41. http://dx.doi.org/10.4028/www.scientific.net/amm.271-272.36.

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Al85Ni10Zr3Y2 and Al80Ni10Zr8-xCuxY2(x=1,2,3,5) alloy ribbons had been prepared by single roller melt-spinning process under vacuum conditions. The ribbons were investigated by X–ray diffraction and differential scanning calorimetry (DSC). The results revealed the strong effect of content of Cu、Zr elements on the glass forming ability and the thermal stability of the alloys. The formation of amorphous alloys are sensitive to contens of these two elements. The completely amorphous alloy or the primary amorphous phase alloy can be obtained when the content of Cu or Zr reach an optimization, othe
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44

Wang, Jinxue, Khashayar Khanlari, Yali Chen, Bo Lin, Yang Zhang, and Weiwen Zhang. "Numerical/Experimental Study of Process Optimization Conducted on an Al-Cu Alloy Produced by Combined Fields of Applied Pressure and Ultrasonic Vibration." Crystals 13, no. 10 (2023): 1466. http://dx.doi.org/10.3390/cryst13101466.

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Single-pressure and ultrasonic action have their own unique advantages in the treatment of metal melts. When the two are combined into a composite field, the advantages of a single physical field can be fully utilized. So, the cavitation and acoustic streaming effects characteristics of an Al-5.0Cu alloy treated under different coupling process parameters, related to applied extrusion pressure and ultrasonic vibration, were analyzed by combining numerical simulation and experimental verification. The simulation results were experimentally verified by quantitative analysis of the microstructure
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45

Srikar, V. T., and C. V. Thompson. "Diffusion and Electromigration of Cu in Single Crystal Al Interconnects." MRS Proceedings 516 (January 1998). http://dx.doi.org/10.1557/proc-516-71.

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AbstractThe electromigration-induced transport properties of Cu in Al-Cu alloys, and their effect on electromigration lifetimes in interconnects with bamboo grain structures are not well understood. To isolate and study the mechanisms and kinetics of Cu diffusion and electromigration in interconnects for which grain boundary transport is not dominant, we have developed a test structure consisting of parallel Al single crystal lines, with every alternate line terminating in contact pads. Cu is locally added to the same regions in all the lines, and the effect of temperature and electric field c
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46

Yawny, A. A., M. Sade, and F. C. Lovey. "Actuator Applications with Single-Crystals of Cu-Zn-Al Shape Memory Alloy." MRS Proceedings 459 (1996). http://dx.doi.org/10.1557/proc-459-369.

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ABSTRACTIn the present work the use of single-crystals of Cu-Zn-Al Shape Memory Alloys (SMA) in actuator applications is analyzed. The actuator considered here, a device capable of doing work in response to temperature changes, is based on a single-crystal nucleus of a Cu-Zn-Al SMA coupled to a conventional spring that represents the load to be displaced. A special experimental stage was designed for performing controlled thermal cycles under load. In this way the effects of different parameters (cycle number, friction, temperature range, load level) on the actuator behavior can be studied. Fr
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47

Romero, Francisco Javier, José-María Martín-Olalla, María Carmen Gallardo, et al. "Scale-invariant avalanche dynamics in the temperature-driven martensitic transition of a Cu-Al-Be single crystal." Physical Review B 99, no. 22 (2019). http://dx.doi.org/10.1103/physrevb.99.224101.

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48

Yakubovich, Olga V., Galina V. Kiriukhina, Sergey V. Simonov, Anatoly S. Volkov, and Olga V. Dimitrova. "(Na,Li)3(Cl,OH)[Cu3OAl(PO4)3]: a first salt-inclusion aluminophosphate oxocuprate with a new type of crystal structure." Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials 79, no. 1 (2023). http://dx.doi.org/10.1107/s2052520622011696.

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The synthesis and characterization of a first salt-inclusion aluminophosphate oxocuprate, (Na,Li)3(Cl,OH)[Cu3OAl(PO4)3], obtained as single crystals, is reported. A novel phase, with a strongly pseudo-orthorhombic structure, is described as a monoclinic crystal structure established by the study of a pseudomerohedric microtwin. It was investigated using scanning electron microscopy, microprobe analysis and low-temperature X-ray diffraction. The composite crystal structure represents an original framework assembled from Cu-centered polyhedra, AlO6 octahedra and PO4 tetrahedra with channels, whi
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49

Lograsso, T. A., and A. R. Ross. "Processing Of Al-Cu-Fe Quasicrystalline Single Grains." MRS Proceedings 553 (1998). http://dx.doi.org/10.1557/proc-553-3.

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AbstractThe phase equilibria of the Al-Cu-Fe quasicrystalline phase (y phase) is complex and conventional crystal growth techniques like the Bridgman and Czochralski methods are not applicable in preparation of large crystals. Large single grains of the y phase been have prepared by either slow cooling or isothermal anneals. In the later technique, arc melted ingots were subjected to either single or multiple heat treatments between 825 and 840°C to encourage grain growth. Following heat treatment, grains of the icosahedral phase are found either as isolated pentagonal-faceted crystals within
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50

Moyer, L. E., G. S. Cargill, W. Yang, B. C. Larson, and G. E. Ice. "X-ray Microbeam Diffraction Measurements in Polycrystalline Aluminum and Copper Thin Films." MRS Proceedings 795 (2003). http://dx.doi.org/10.1557/proc-795-u1.7.

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ABSTRACTThermally induced residual strains in polycrystalline Cu and Al films on single crystal Si and glass substrates, respectively, have been examined on a grain-by-grain basis by x-ray microbeam diffraction. The crystallographic orientation and the deviatoric strain tensor, εij*, are determined for each grain by white beam Laue diffraction. From grain orientation mapping and strain tensor measurements, information is obtained about the distributions of strains for similarly oriented grains, about strain variations within single grains, and about grain-to-grain correlations of strains. This
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