Academic literature on the topic 'Single-Ion electrolyte'

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Journal articles on the topic "Single-Ion electrolyte"

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Hoffman, Zach J., Alec S. Ho, Saheli Chakraborty, and Nitash P. Balsara. "Limiting Current Density in Single-Ion-Conducting and Conventional Block Copolymer Electrolytes." Journal of The Electrochemical Society 169, no. 4 (2022): 043502. http://dx.doi.org/10.1149/1945-7111/ac613b.

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The limiting current density of a conventional polymer electrolyte (PS-PEO/LiTFSI) and a single-ion-conducting polymer electrolyte (PSLiTFSI-PEO) was measured using a new approach based on the fitted slopes of the potential obtained from lithium-polymer-lithium symmetric cells at a constant current density. The results of this method were consistent with those of an alternative framework for identifying the limiting current density taken from the literature. We found the limiting current density of the conventional electrolyte is inversely proportional to electrolyte thickness as expected from
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Issa, Sébastien, Roselyne Jeanne-Brou, Sumit Mehan, et al. "New Crosslinked Single-Ion Silica-PEO Hybrid Electrolytes." Polymers 14, no. 23 (2022): 5328. http://dx.doi.org/10.3390/polym14235328.

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New single-ion hybrid electrolytes have been synthetized via an original and simple synthetic approach combining Michael addition, epoxidation, and sol–gel polycondensation. We designed an organic PEO network as a matrix for the lithium transport, mechanically reinforced thanks to crosslinking inorganic (SiO1.5) sites, while highly delocalized anions based on lithium vinyl sulfonyl(trifluoromethane sulfonyl)imide (VSTFSILi) were grafted onto the inorganic sites to produce single-ion hybrid electrolytes (HySI). The influence of the electrolyte composition in terms of the inorganic/organic ratio
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Yang, Yuying, Yabin Zhang, Yuxin Song, Tingbin Ma, Luqing Zhang, and Shuxiang Zhang. "Highly Conductive Single-Ion Polymeric Electrolyte for Long-Cycle-Life Lithium Metal Batteries." Energies 17, no. 14 (2024): 3398. http://dx.doi.org/10.3390/en17143398.

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Considerable research has been conducted on single-ion conductive polymeric electrolytes with high lithium ion transference numbers. However, low ionic conductivity is a long-standing challenge for lithium metal batteries, hindering the development of extending their cycle life. In this study, we synthesized a novel fluorine-containing single-ion polymeric electrolyte, LiP(VDF-co-MAF)BB (Polyvinylidene fluoride trifluoromethyl acrylate lithium borate polymer; subsequently referred to as PPMBB), exhibiting a room temperature conductivity of 1.03 × 10−3 S/cm. This electrolyte demonstrates a high
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Dong, Xu, Dominik Steinle, and Dominic Bresser. "Single-Ion Conducting Polymer Electrolytes for Sodium Batteries." ECS Meeting Abstracts MA2023-01, no. 5 (2023): 954. http://dx.doi.org/10.1149/ma2023-015954mtgabs.

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Sodium-ion batteries have attracted extensive attention recently owing to the announcements of several companies to commercialize this technology in the (very) near future. Just like commercial lithium-ion batteries, though, these batteries are comprising and/or will comprise a liquid electrolyte – with all its advantages and challenges. Thinking one step ahead (as also done by a few companies already), the next step might be the transition to (“zero-excess”) sodium-metal batteries, which will require fundamentally new electrolyte solutions, and just like for lithium-metal batteries, these mig
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Ock, Jiyoung, Anisur Rahman, Catalin Gainaru, Alexei Sokolov, and Xi Chen. "Ion Transport in Polymer/Inorganic Composite Electrolytes – a Comparison between Broadband Dielectric Spectroscopy and Impedance Spectroscopy." ECS Meeting Abstracts MA2023-01, no. 7 (2023): 2886. http://dx.doi.org/10.1149/ma2023-0172886mtgabs.

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Significant efforts have been made to develop composite electrolytes combining polymer matrix with Li-ion conducting inorganic solids for feasible construction of solid-state batteries. However, the Li-ion transfer kinetics at the interface between polymer/inorganic electrolyte is unfavorable for Li-ion conduction in the composite electrolyte because of the interfacial resistance and the activation energy barrier for interfacial Li-ion transfer. The activation energy barrier for the Li-ion transfer reaction at the interface is correlated with the interaction between Li-ion and polymer matrix i
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Ghorbanzade, Pedram, Laura C. Loaiza, and Patrik Johansson. "Plasticized and salt-doped single-ion conducting polymer electrolytes for lithium batteries." RSC Advances 12, no. 28 (2022): 18164–67. http://dx.doi.org/10.1039/d2ra03249j.

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Jagger, Ben, Shobhan Dhir, Junyi Zhao, and Mauro Pasta. "Fundamental Investigations on the Ionic Transport and Thermodynamic Properties of Potassium-Ion Electrolytes." ECS Meeting Abstracts MA2024-02, no. 2 (2024): 246. https://doi.org/10.1149/ma2024-022246mtgabs.

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Potassium-ion batteries (KIBs) represent a promising complementary technology to lithium-ion batteries (LIBs) due to the availability and low cost of potassium. KIBs could also be produced with graphite (G) anodes and Prussian blue analog (PBA) cathodes, reducing the demand for rare, costly elements necessary in LIBs.1 However, there is currently no electrolyte capable of providing practical coulombic efficiencies in high-voltage G||PBA cells, requiring further electrolyte development.2 Current research primarily focuses on developing electrolytes able to simultaneously passivate Al current co
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Zhang, Heng, Chunmei Li, Michal Piszcz, et al. "Single lithium-ion conducting solid polymer electrolytes: advances and perspectives." Chemical Society Reviews 46, no. 3 (2017): 797–815. http://dx.doi.org/10.1039/c6cs00491a.

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Single lithium-ion conducting solid polymer electrolytes (SLIC-SPEs), with a high lithium-ion transference number, the absence of the detrimental effect of anion polarization, and low dendrite growth rate, could be an excellent choice of safe electrolyte materials for lithium batteries in the future.
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Badi, Nacer, Azemtsop Manfo Theodore, Saleh A. Alghamdi, et al. "The Impact of Polymer Electrolyte Properties on Lithium-Ion Batteries." Polymers 14, no. 15 (2022): 3101. http://dx.doi.org/10.3390/polym14153101.

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In recent decades, the enhancement of the properties of electrolytes and electrodes resulted in the development of efficient electrochemical energy storage devices. We herein reported the impact of the different polymer electrolytes in terms of physicochemical, thermal, electrical, and mechanical properties of lithium-ion batteries (LIBs). Since LIBs use many groups of electrolytes, such as liquid electrolytes, quasi-solid electrolytes, and solid electrolytes, the efficiency of the full device relies on the type of electrolyte used. A good electrolyte is the one that, when used in Li-ion batte
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Park, Habin, Anthony Engler, Nian Liu, and Paul Kohl. "Dynamic Anion Delocalization of Single-Ion Conducting Polymer Electrolyte for High-Performance of Solid-State Lithium Metal Batteries." ECS Meeting Abstracts MA2022-02, no. 3 (2022): 227. http://dx.doi.org/10.1149/ma2022-023227mtgabs.

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Lithium metal batteries (LMBs) have been considered as next-generation energy storages due to their extremely high theoretical specific capacity (3860 mAh g-1). However, current LMBs, using conventional liquid electrolytes, still could not fulfill the demand of soaring expansion of energy era, such as electrical vehicles, because of their safety issues, originated by uncontrollable electrolytic side reaction on the lithium, resulting unstable solid-electrolyte interphase (SEI) and vicious lithium dendritic growth [1]. Also, carbonate-based liquid electrolytes have an intrinsic flammability, an
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Dissertations / Theses on the topic "Single-Ion electrolyte"

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Meyer, Mathieu. "Membranes électrolytes à porteurs de charge Li+." Thesis, Montpellier 2, 2014. http://www.theses.fr/2014MON20119/document.

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La demande actuelle en batteries lithium-ion « tout solide » adaptées aux applications mobiles asuscité d'importantes recherches sur des membranes électrolytes polymères de plus en plussophistiquées. Cette thèse porte sur la synthèse et la caractérisation mécanique, thermique etstructurale de nouveaux matériaux électrolytes polymères nanocomposites résultant de la réticulationpar procédé sol-gel de chaînes de poly(oxyde d'éthylène) (PEO) fonctionnalisées aux deux extrémitéspar des groupements alkoxysilane. Les nano-domaines polysilsesquioxanes ainsi formés par hydrolysecondensation,génèrent un
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Single, Fabian [Verfasser]. "Theory-based Investigation of the Solid Electrolyte Interphase in Lithium-ion Systems / Fabian Single." Ulm : Universität Ulm, 2021. http://nbn-resolving.de/urn:nbn:de:bsz:289-oparu-38988-7.

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LINGUA, GABRIELE. "Newly designed single-ion conducting polymer electrolytes enabling advanced Li-metal solid-state batteries." Doctoral thesis, Politecnico di Torino, 2022. http://hdl.handle.net/11583/2969103.

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Schneider, Armin Conrad. "Potentiometrische Bestimmung von Einzelionenaktivitätskoeffizienten wässriger Elektrolyte mit Hilfe ionenselektiver Elektroden / Potentiometric Determination of Single Ion Activity Coefficients of Aqueous Electrolyte Solutions Using Ion Selective Electrodes." Gerhard-Mercator-Universitaet Duisburg, 2005. http://www.ub.uni-duisburg.de/ETD-db/theses/available/duett-02112005-091206/.

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Single ion activity coeffients of NaCl, KCl, HCl and CaCl2 in aqueous solution have been estimated by means of ion selective electrode (ISE) potentiometric measurements. Two methods are described for the calibration of the electrodes within the extended Debye-Hückel concentration range, using the Henderson-Bates approximation for the diffusion potential arising at the reference electrode. The consistency of the results indicates that the junction potentials in the examined systems calculated by the Henderson-Bates approximation are of reasonable precision. The published methods and data might
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Bernard, Laurent. "Caractérisation multi-échelle de la structure et du transport de cristaux liquides ioniques : vers des électrolytes solides innovants pour batteries lithium." Thesis, Université Grenoble Alpes (ComUE), 2019. http://www.theses.fr/2019GREAY002.

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Le remplacement des électrolytes liquides conventionnels des batteries lithium-ion est un enjeu majeur pour améliorer leurs performances et leur sécurité. Dans ce contexte, ce travail de thèse est focalisé sur la synthèse d’une nouvelle classe d’électrolytes solides organiques : les cristaux liquides ioniques thermotropiques, ainsi que la caractérisation multi-échelle des nanostructures obtenues et du transport ionique. Tout d’abord, nous présentons les structures chimiques choisies pour créer des assemblages de molécules cristal liquide à conduction « single-ion ». Ensuite, nous détaillons l’
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Frenck, Louise. "Study of a buffer layer based on block copolymer electrolytes, between the lithium metal and a ceramic electrolyte for aqueous Lithium-air battery." Thesis, Université Grenoble Alpes (ComUE), 2016. http://www.theses.fr/2016GREAI041/document.

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La technologie Lithium-air développée par EDF utilise une électrode à air qui fonctionne avec un électrolyte aqueux ce qui empêche l’utilisation de lithium métal non protégé comme électrode négative. Une membrane céramique (LATP:Li1+xAlxTi2-x(PO4)3) conductrice d’ion Li+ est utilisée pour séparer le milieu aqueux de l’électrode négative. Cependant, cette céramique n'est pas stable au contact du lithium, il est donc nécessaire d'intercaler entre le lithium et la céramique un matériau conducteur des ions Li+. Celui-ci devant être stable au contact du lithium et empêcher ou fortement limiter la c
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Leclere, Mélody. "Synthèse de (poly)électrolytes pour accumulateur Li-ion à haute densité d'énergie." Thesis, Lyon, 2016. http://www.theses.fr/2016LYSEI001/document.

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Les travaux de thèse présentés dans ce manuscrit portent sur le développement nouveaux électrolytes sans recours aux solvants conventionnels inflammables afin de répondre à la problématique de sécurité des batteries. La première partie de ce travail vise à développer des électrolytes gélifiés à partir de liquide ionique phosphonium. Une étude est réalisée sur la compatibilité entre l'électrolyte et le polymère hôte époxy/amine ainsi que de l'influence du LI sur la polymérisation du réseau. Les propriétés thermiques, viscoélastiques et de transport ionique des gels sont discutées. Parmi les éle
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Issa, Sébastien. "Synthèse et caractérisation d'électrolytes solides hybrides pour les batteries au lithium métal." Electronic Thesis or Diss., Aix-Marseille, 2022. http://www.theses.fr/2022AIXM0046.

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Les problématiques engendrées par l’extraction et l’utilisation intensives des ressources fossiles ont forcé l’humanité à se tourner vers le développement d’énergies renouvelables et de véhicules électriques. Cependant, ces technologies doivent être couplées à des moyens de stockage de l’énergie efficaces pour exploiter leur potentiel. Les systèmes embarquant une anode de lithium métallique sont particulièrement intéressants car ils présentent une densité d’énergie élevée. Cependant, cette technologie souffre de la formation de dendrites pouvant déclencher des courts-circuits provoquant l’expl
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Kuo, Tsung-Chieh, and 郭宗杰. "Nanofiber electrolytes of Single-Ion Conductors for lithium battery." Thesis, 2017. http://ndltd.ncl.edu.tw/handle/b3tatt.

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碩士<br>國立中山大學<br>化學系研究所<br>105<br>In this study, a nonwoven nanofabric single-ion conducting electrolyte (SICE) membrane exhibiting excellent electrochemical performance in ambient environment has been fabricated. Compared to commercial polypropylene separators, the SICE membrane, fabricated via electrospinning of the hybrid solution containing lithium poly[4-styrenesulfonyl(phenylsulfonyl)imide] and polyacrylonitrile, possesses excellent solvation characteristics due to porous morphology that facilitates transportation of lithium ions. It shows superior ionic conductivity of 3.9 × 10−3 S cm−1
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"A New Class of Solid State, Single-ion Conductors (H+ and Li+): Silicon-based Plastic Crystals." Doctoral diss., 2016. http://hdl.handle.net/2286/R.I.40721.

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abstract: Plastic crystals as a class are of much interest in applications as solid state electrolytes for electrochemical energy conversion devices. A subclass exhibit very high protonic conductivity and its members have been investigated as possible fuel cell electrolytes, as first demonstrated by Haile’s group in 2001 with CsHSO4. To date these have been inorganic compounds with tetrahedral oxyanions carrying one or more protons, charge-balanced by large alkali cations. Above the rotator phase transition, the HXO4- anions re-orient at a rate dependent on temperature while the centers of mas
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Book chapters on the topic "Single-Ion electrolyte"

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Holze, Rudolf. "Single ion conductivities of acetonitrile in nonaqueous electrolyte solutions." In Electrochemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-49251-2_1961.

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Holze, Rudolf. "Single ion conductivities of Ag+ ion in aqueous electrolyte solutions at infinite dilution." In Electrochemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-49251-2_1655.

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Holze, Rudolf. "Single ion conductivities of Al3+ ion in aqueous electrolyte solutions at infinite dilution." In Electrochemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-49251-2_1656.

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Holze, Rudolf. "Single ion conductivities of Ba2+ ion in aqueous electrolyte solutions at infinite dilution." In Electrochemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-49251-2_1660.

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Holze, Rudolf. "Single ion conductivities of Be2+ ion in aqueous electrolyte solutions at infinite dilution." In Electrochemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-49251-2_1661.

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Holze, Rudolf. "Single ion conductivities of Br− ion in aqueous electrolyte solutions at infinite dilution." In Electrochemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-49251-2_1662.

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Holze, Rudolf. "Single ion conductivities of bmim+ ion in aqueous electrolyte solutions at infinite dilution." In Electrochemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-49251-2_1664.

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Holze, Rudolf. "Single ion conductivities of formate ion in aqueous electrolyte solutions at infinite dilution." In Electrochemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-49251-2_1665.

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Holze, Rudolf. "Single ion conductivities of methylammonium ion in aqueous electrolyte solutions at infinite dilution." In Electrochemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-49251-2_1667.

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Holze, Rudolf. "Single ion conductivities of monochloroacetate ion in aqueous electrolyte solutions at infinite dilution." In Electrochemistry. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-49251-2_1669.

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Conference papers on the topic "Single-Ion electrolyte"

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Esfahany, Hamid Reza. "The Study of Diffusion Ions and Water in Powder and Liquid Epoxy Coatings of Pipeline with Using Fluorescence Microscopy and AFM Methodology." In CORROSION 2011. NACE International, 2011. https://doi.org/10.5006/c2011-11022.

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Abstract FBE coatings are known to absorb moisture and pass current. They allow current to pass and exhibit a reduced electrical resistance under cathodic protection. The results of cathodic disbonding and EIS tests for FBE coatings show that with increasing of permittivity factor of coating, the radius of cathodic disbandment increases. When epoxy exposes in electrolyte, the diffusion of ions and water in coating caused of reduction of electrical resistance. The cathodic disbonding radius (r) decreases with diminish passing ions and water from epoxy coating. The precise mode by which water an
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Jawle, Bharat, Ashwin Selvakumar, Jagadeeswaran Subramanian, Kumar P. Nagaraj, and Ajith Kumaran. "Single-Particle model with thermal and electrolyte dynamics for lithium-Ion cell." In 2023 IEEE International Transportation Electrification Conference (ITEC-India). IEEE, 2023. http://dx.doi.org/10.1109/itec-india59098.2023.10471458.

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Grandjean, Thomas R. B., Liuying Li, Maria Ximena Odio, and Widanalage D. Widanage. "Global Sensitivity Analysis of the Single Particle Lithium-Ion Battery Model with Electrolyte." In 2019 IEEE Vehicle Power and Propulsion Conference (VPPC). IEEE, 2019. http://dx.doi.org/10.1109/vppc46532.2019.8952455.

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Baschuk, J., and Xianguo Li. "Applying the Generalized Stefan-Maxwell Equations to Ion and Water Transport in the Polymer Electrolyte of a PEM Fuel Cell." In ASME 2007 International Mechanical Engineering Congress and Exposition. ASMEDC, 2007. http://dx.doi.org/10.1115/imece2007-41660.

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Ion and water transport phenomena in the polymer electrolyte plays a significant role in the energy conversion process of a polymer electrolyte membrane (PEM) fuel cell. A mathematical model for ion and water transport in the polymer electrolyte is presented, based on non-equilibrium thermodynamics and the Generalized Stefan-Maxwell equations. The physical constants of the model, such as the binary diffusion coefficients of the Generalized Stefan-Maxwell equations, are obtained from published, experimental data for membrane water diffusion and conductivity. The electrolyte transport model is i
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Lin, Xianke, Xiaoguang Hao, Zhenyu Liu, and Weiqiang Jia. "Optimal Charging Of Li-Ion Batteries Based On An Electrolyte Enhanced Single Particle Model." In 2018 Canadian Society for Mechanical Engineering (CSME) International Congress. York University Libraries, 2018. http://dx.doi.org/10.25071/10315/35325.

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Tanim, Tanvir R., Christopher D. Rahn, and Chao-Yang Wang. "A reduced order electrolyte enhanced single particle lithium ion cell model for hybrid vehicle applications." In 2014 American Control Conference - ACC 2014. IEEE, 2014. http://dx.doi.org/10.1109/acc.2014.6858617.

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Islam, Rabiul, Cameron Nolen, and Kwangkook Jeong. "Effects of Sulfuric Acid Concentration on Volume Transfer Across Ion-Exchange Membrane in a Single-Cell Vanadium Redox Flow Battery." In ASME 2017 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2017. http://dx.doi.org/10.1115/imece2017-72359.

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The vanadium redox flow battery (VRFB) is one of the technologies to be used for storing large-scale renewable energy. The objective of this research is to electrochemically synthesize the V(III) electrolytes with combinations of 2 M VOSO4 and 2–6 M H2SO4, and to investigate the effects of concentration of H2SO4 on vanadium and water transfer across membrane. Transfer of water and vanadium across the membrane was reduced from 19.6 to 6.2 % as the concentration of H2SO4 in the electrolyte increased from 2 to 6 M. Change in volume transferred across the membrane decreased with each successive ch
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Sakamoto, Y., Y. Ishii, and S. Kawasaki. "Electrode property of single-walled carbon nanotubes in all-solid-state lithium ion battery using polymer electrolyte." In INTERNATIONAL CONFERENCE ON NANO-ELECTRONIC TECHNOLOGY DEVICES AND MATERIALS 2015 (IC-NET 2015). Author(s), 2016. http://dx.doi.org/10.1063/1.4948826.

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Fan, Guodong, and Marcello Canova. "Model Order Reduction of Electrochemical Batteries Using Galerkin Method." In ASME 2015 Dynamic Systems and Control Conference. American Society of Mechanical Engineers, 2015. http://dx.doi.org/10.1115/dscc2015-9788.

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This paper presents a model order reduction (MOR) method for modeling and estimation of a first-principles electrochemical Lithium-ion battery. The MOR approach combines the Galerkin method with coordinate transformation and is applied to solve the spherical diffusion problem with non-zero flux boundary conditions. The order of the reduced-order model (ROM) is carefully selected based on analysis in the frequency domain. With the reduced-order diffusion model, an enhanced single particle model which incorporates the electrolyte dynamics is developed and validated against the experimental data.
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Parhizi, Mohammad, Jason Ostanek, Vinay Premnath, and Judith Jeevarajan. "Reduced Order Modeling of Thermal Runaway Propagation in Li-Ion Battery Packs With Comprehensive Treatment of Heat Source Terms." In ASME 2024 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2024. https://doi.org/10.1115/imece2024-144403.

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Abstract This work aims to develop a novel framework for thermal runaway and propagation modeling, focusing on balancing between computational efficiency and accuracy. The proposed framework leverages a zero-dimensional (0D) modeling approach for heat transfer, facilitating ease of extension to battery pack-level simulations. The model integrates multiphysics phenomena such as decomposition reactions, internal heat generation, gas generation, electrolyte evaporation, and a simplified model for burning the vent gas to enhance accuracy without sacrificing computational efficiency. The thermal no
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Reports on the topic "Single-Ion electrolyte"

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Feld, William A., and Denise M. Weimers. Single Lithium Ion Conducting Polymer Electrolyte. Defense Technical Information Center, 1998. http://dx.doi.org/10.21236/ada353668.

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Feld, William A. Aerospace Power Scholarly Research Program. Delivery Order 0007: Single Lithium Ion Conducting Polymer Electrolyte. Defense Technical Information Center, 2005. http://dx.doi.org/10.21236/ada444661.

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