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Journal articles on the topic 'SnCl2'

Author: Grafiati

Published: 4 June 2021

Last updated: 1 February 2022

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1

Alonzo, Giuseppe, Nuccio Bertazzi, John R. Ferraro, et al. "Mössbauer, Far-Infrared, and XPS Investigations of SnCl2 and SnCl4 Introduced in Polyconjugated Monosubstituted Acetylene Matrices." Applied Spectroscopy 49, no. 2 (1995): 237–40. http://dx.doi.org/10.1366/0003702953963742.

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Mössbauer, far-infrared, and X-ray photoemission spectroscopy (XPS) studies have been made on doped (SnCl2 or SnCl4) (PEFl) and polyphenylacetylene (PPA). The nature of the tin as it is incorporated into the polymer is examined. The resistance values of the doped polymers are followed with relative humidity. Results point to tetrahedral (SnCl4 and octahedral (SnCl4 · 2H2O) species in the SnCl4 doping. With SnCl2 doping, the nature of the species is less certain, although both Sn(II) and hexacoordinated Sn(IV) appear to be present. Index Headings: Mössbauer

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2

Brüggeller, Peter. "Polyphosphinhaltige Trichlorostannatoplatin(II)-Komplexe: Synthese und NMR(119Sn, 31P)-Charakterisierung / Trichlorostannatoplatinum(II) Complexes Containing Polyphosphines: Synthesis and NMR (119Sn, 31P) Characterization." Zeitschrift für Naturforschung B 41, no. 12 (1986): 1561–64. http://dx.doi.org/10.1515/znb-1986-1214.

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AbstractTrichlorostannatoplatinum(II) complexes containing bis(2-diphenylphosphinoethyl)phenyl- phosphine, etp, and the tripod ligand tris(2-diphenylphosphinoethyl)phosphine, PP3, respectively, have been prepared and characterized by 119Sn{1H} and 31P{1H} NMR spectroscopy. [(etp)PtCl](BPh4) (1a) reacts with SnCl2 via oxidative addition to give [(etp)PtSnCl3](BPh4) (1b). The 31P NMR spectral patterns of type 1 complexes are consistent with AX2 spin-systems and square planar structures in solution. There is 31P NMR evidence that in the presence of (Ph4P)Cl 1b adds further SnCl2. The possibility

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3

Song, Ning-Jing, and Canliang Ma. "The In-Situ Synthesis of a 3D SnS/N-Doped Graphene Composite with Enhanced Electrochemical Performance as a Low-Cost Anode Material in Sodium Ion Batteries." Materials 12, no. 12 (2019): 2030. http://dx.doi.org/10.3390/ma12122030.

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SnS/N-doped graphene (SnS/NG) composites are promising anode materials for sodium ion batteries. Generally, SnS is synthesized from SnCl2·2H2O. However, SnCl2·2H2O is not suitable for large-scale production due to its high price. Compared with SnCl2·2H2O, SnCl4·5H2O has a lower price, more stable chemical properties and better water solubility. Until now, there have been no related reports on the synthesis of SnS from SnCl4·5H2O. In this work, the fabrication of SnS/NG in a facile, two-step process, which combines a hot water bath and thermal annealing and uses SnCl4·5H2O as a precursor, is de

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4

Jiang, Heng, Gang Chu, Hong Gong, and Qingdong Qiao. "Tin Chloride Catalysed Oxidation of Acetone with Hydrogen Peroxide to Tetrameric Acetone Peroxide." Journal of Chemical Research 23, no. 4 (1999): 288–89. http://dx.doi.org/10.1177/174751989902300421.

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SnCl4·5H2O and SnCl2·2H2O are efficient catalysts for the oxidation of acetone with 30% hydrogen peroxide at room temperature and produce tetrameric acetone peroxide which is identified by molecular weight determination, elemental analysis, FTIR, NMR and MS.

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5

Pirnat, J., J. Lužnik, Z. Jagličić, and Z. Trontelj. "Dehydration of Solid SnCl2(OH2)· H2O to SnCl2." Zeitschrift für Naturforschung A 49, no. 1-2 (1994): 367–72. http://dx.doi.org/10.1515/zna-1994-1-254.

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Abstract The temperature and flow rate dependence of the dehydration of SnCl2(OH2) · H2O , having a layered structure, into SnCl2 in a dry inert gas stream is studied. The experimental results obtained via chlorine NQR and weight measurements are analysed in the light of the structural transformation of this compound. The mechanism of water depletion from the layered structure is discussed.

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6

Patt-Siebel, Ute, Somluck Ruangsuttinarupap, Ulrich Müller, Jürgen Pebler, and Kurt Dehnicke. "S5N5[SnCl5(CH3CN)]; Synthese, IR-Spektrum, 119Sn-Mößbauer-Spektrum und Kristallstruktur / S5N5[SnCl5(CH3CN)]; Synthesis, IR Spectrum , Mössbauer Spectrum and Crystal Structure." Zeitschrift für Naturforschung B 41, no. 10 (1986): 1191–95. http://dx.doi.org/10.1515/znb-1986-1001.

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S5N5[SnCl5(CH3CN)] is prepared by the reaction of SnCl2 with trithiazyl chloride in acetonitrile suspension. The compound is characterized by its IR spectrum, the 119Sn Mössbauer spectrum and by an X-ray crystal structure determination (1851 observed, independent reflexions, R = 0.024). S5N5[SnCl5(CH3CN)] crystallizes in the monoclinic space group P21/n with Z = 4 and the lattice dimensions a = 758.8; b = 1574.6; c = 1429.1 pm; β = 97.65°. The compound consists of planar S5N5® cations with the azulene-like structure, and anions [SnCl5(CH3CN)]e in which the tin atom has a distorted octahedral c

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7

Tam, Thomas M. "Cyclic Voltammogram of SnCl2 and SnCl2 + PdCl2 Sensitizing Solution." Journal of The Electrochemical Society 132, no. 5 (1985): 1152–54. http://dx.doi.org/10.1149/1.2114047.

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8

Bortoluzzi, Marco, Alessandro Ceriotti, Cristiana Cesari, et al. "Syntheses of [Pt6 (CO)8 (SnCl2 )(SnCl3 )4 ]4- and [Pt6 (CO)8 (SnCl2 )(SnCl3 )2 (PPh3 )2 ]2- Platinum-Carbonyl Clusters Decorated by SnII Fragments." European Journal of Inorganic Chemistry 2016, no. 24 (2016): 3939–49. http://dx.doi.org/10.1002/ejic.201600597.

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9

Cekic, Betul, Fazilet Zumrut Biber Muftuler, Ayfer Yurt Kilcar, Necati Gunay, Serhan Sakarya, and Perihan Unak. "Anti toxic effect of broccoli extract on stannous dichloride toxicity." Acta Cirurgica Brasileira 27, no. 9 (2012): 606–10. http://dx.doi.org/10.1590/s0102-86502012000900003.

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PURPOSE: Since Technetium-99m (99mTc) has favorable physical and chemical characteristics, it is widely used radioisotope in Nuclear Medicine. However, stannous dichloride (SnCl2) has been widely used as a reducing agent in labeling procedure of pharmaceutical with radionuclide, it has been realized that SnCl2 have genotoxic and cytotoxic effects on biological systems. In previous studies, it has been shown that some herbal extract can reduce genotoxic and cytotoxic effects of SnCl2. In the present study, it is aimed to evaluate the effect of the broccoli extract on the survival of E. coli ATC

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10

Bortoluzzi, Marco, Alessandro Ceriotti, Iacopo Ciabatti, et al. "Platinum carbonyl clusters stabilized by Sn(ii)-based fragments: syntheses and structures of [Pt6(CO)6(SnCl2)2(SnCl3)4]4−, [Pt9(CO)8(SnCl2)3(SnCl3)2(Cl2SnOCOSnCl2)]4−and [Pt10(CO)14{Cl2Sn(OH)SnCl2}2]2−." Dalton Transactions 45, no. 12 (2016): 5001–13. http://dx.doi.org/10.1039/c5dt04696c.

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11

Pirnat, J., and Z. Trontelj. "Two-dimensional protonic conductor SnCl2·1.5 H2O — comparison with SnCl2·2 H2O." Solid State Ionics 125, no. 1-4 (1999): 135–40. http://dx.doi.org/10.1016/s0167-2738(99)00167-8.

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12

Becht, Alexander, and Arnd Vogler. "Luminescence Quenching and Photooxidation of Trichlorostannate(II) by Oxygen." Zeitschrift für Naturforschung B 49, no. 6 (1994): 778–80. http://dx.doi.org/10.1515/znb-1994-0611.

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The luminescence of [SnCl3]- in acetonitrile (τ= 1.6 μs) is quenched by oxygen with k = 3.8x108 L mol-1 s-1. This quenching is associated with an electron transfer from [SnCl3]- in its 3P1 sp-excited state to O2. Secondary processes lead to the formation of SnOCl2(CH3CN)n with an overall quantum yield of φ = 1.5 at λirr = 254 nm. While this Sn(IV) complex is not light sensitive, [SnCl6]2- in CH3CN undergoes a photochemical reductive elimination with the generation of [SnCl3]- with φ - 0.015 at λirr = 254 nm

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13

Nachtigal, C., and W. Preetz. "Darstellung und Kristallstruktur von [P(C6H5)4]2[2-SnCl2(C6H5)B10H9] / Synthesis and Crystal Structure of [P(C6H5)4]2 [2-SnCl2(C6H5)B10H9]." Zeitschrift für Naturforschung B 52, no. 8 (1997): 975–77. http://dx.doi.org/10.1515/znb-1997-0815.

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By reaction of [N(C4H9)4]2[B10H10] with dichlorodiphenyltin in acetonitril at 80°C the 2- (dichlorophenyltin)-decaborate anion [2-SnCl2(C6H5)B10H9]2- is formed and can be isolated by ion exchange chromatography on diethylaminoethyl(DEAE) cellulose. The X-ray structure of [P(C6H5)4]2[2-SnCl2(C6H5)B10H9] (triclinic, space group P1̄ with a = 11.2342(11), b = 11,2549(13), c = 22.265(6) Å, α = 89.478(14), β = 84.511(13), γ = 74.049(8)°) reveals that the SnCl2(C6H5) substituent is bonded with a B2-Sn distance of 2.182(6) Å.

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14

Tang, Bao Hua. "Synthesis of Ethyl Acetate Catalyzed by Inorganic Salt." Advanced Materials Research 455-456 (January 2012): 1060–63. http://dx.doi.org/10.4028/www.scientific.net/amr.455-456.1060.

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Ethyl acetate was synthesized using inorganic salt as catalyst. The catalytic syntheses of Ethyl Acetate using NaHS04, Sncl2 and Fecl3 as catalysts were introduced. It showed that Sncl2 was excellent catalysts for synthesis Ethyl Acetate with higher yields and the catalyst can be reused, and the reaction does not cause pollution.

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15

Wrackmeyer, Bernd, Andreas Pedall, and Jürgen Weidinger. "N-Silylaminotin Trichlorides. Synthesis and Characterisation by Multinuclear Magnetic Resonance Spectroscopy." Zeitschrift für Naturforschung B 56, no. 10 (2001): 1009–14. http://dx.doi.org/10.1515/znb-2001-1008.

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N-Silyl-aminotin trichlorides, R1R2N-SnCl3[R1 = R2 = SiMe3 (1a), R1 = SiMe3, R2 = tBu (1b), R = SiMe3, R2 = 9-borabicyclo[3.3.1]nonyl (1c), R1R2 = Me2 SiCH2CH2SiMe2 (1d)] were prepared by the reaction of tin tetrachloride with the respective bis(amino)plumbylenes, (R1R2N)2Pb 4. The analogous reactions with bis(amino)stannylenes, (R1R2N)2Sn 3, afforded only mixtures of the aminotin trichlorides 1 and bis(amino)tin dichlorides, (R1R2N)2 SnCl2 2 . The products were characterised by 1H, 11B, 13C, 15N, 29Si and 119Sn NMR spectroscopy, and the NMR data of 1 were compared with those of the correspond

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16

Nara, Jun-ichi, and Sadao Adachi. "Optical properties of SnCl2 phosphor." Journal of Applied Physics 109, no. 8 (2011): 083539. http://dx.doi.org/10.1063/1.3576118.

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17

Janzen, Michael C., Michael C. Jennings, and Richard J. Puddephatt. "Self-assembly using stannylplatinum(IV) halide complexes as ligands for organotin halides." Canadian Journal of Chemistry 80, no. 11 (2002): 1451–57. http://dx.doi.org/10.1139/v02-093.

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The possibility of forming extended structures by self-association using transition metal halides as donors to organotin acceptors has been investigated. The stannylplatinum(IV) complex [PtClMe2(SnMe2Cl)(bu2bpy)] forms a 1:1 adduct [PtClMe2(SnMe2Cl)(bu2bpy)]·Me2SnCl2 with Me2SnCl2 in which the organoplatinum complex acts as a donor to the organotin halide. Similarly, [PtClMe2(SnMeCl2)(bu2bpy)] forms adducts [PtClMe2(SnMeCl2)(bu2bpy)]·MeSnCl3 or [PtClMe2(SnMeCl2)(bu2bpy)]·Me2SnCl2, and [{PtClMe2(bu2bpy)}2(µ-SnCl2)] forms [{PtClMe2(bu2bpy)}2(µ-SnCl2)]·Me2SnCl2. Structure determinations on select

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18

da Silva, C. V., T. M. Ramos-Oliveira, T. F. Mantilla, and P. M. de Freitas. "Frequency of Application of AmF/NaF/SnCl2 Solution and Its Potential in Controlling Human Enamel Erosion Progression: An in situ Study." Caries Research 51, no. 2 (2017): 141–48. http://dx.doi.org/10.1159/000455051.

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Although several studies have demonstrated the efficacy of AmF/NaF/SnCl2 solution in inhibiting dental erosion progression, measures for further improvement in its effectiveness are paramount. Thus, this in situ study evaluated whether the protective effect promoted by the AmF/NaF/SnCl2 solution would be enhanced by increasing its frequency of use. The study was conducted with 12 volunteers, a 4-phase (5 days each) randomized, crossover model. Extraoral erosive challenges (0.5% citric acid, pH 2.6, 6 × 2 min/day) and rinsing protocol (1 or 2 × 2 min/day) were performed. Before the in situ phas

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19

Zumstein, Katrin, Anne Peutzfeldt, Adrian Lussi, and Simon Flury. "The Effect of SnCl2/AmF Pretreatment on Short- and Long-Term Bond Strength to Eroded Dentin." BioMed Research International 2018 (2018): 1–8. http://dx.doi.org/10.1155/2018/3895356.

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This study investigated the effect of SnCl2/AmF pretreatment on short- and long-term bond strength of resin composite to eroded dentin mediated by two self-etch, MDP-containing adhesive systems. 184 dentin specimens were produced from extracted human molars. Half the specimens (n=92) were artificially eroded, and half were left untreated. For both substrates, half the specimens were pretreated with SnCl2/AmF, and half were left untreated. The specimens were treated with Clearfil SE Bond or Scotchbond Universal prior to application of resin composite. Microtensile bond strength (μTBS) was measu

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20

Li, Da Wei, Lu Jun Pan, Juan Juan Qian, and He Ma. "High Efficient Synthesis of Carbon Nanocoils by Catalysts Produced by a Fe and Sn Containing Solution." Advanced Materials Research 60-61 (January 2009): 251–55. http://dx.doi.org/10.4028/www.scientific.net/amr.60-61.251.

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Chemical vapor deposition, Catalyst, Carbon nanocoils, High efficient growth Abstract: Carbon nanocoils (CNCs) were prepared by thermal chemical vapor deposition (CVD) using a Fe and Sn containing solution as the catalyst predecessor. The solutions of Fe2(SO4)3/SnCl2, FeCl3/SnCl2 and Fe(NO3)3/SnCl2 with the mol ratios of 3:0.1 to 3:1 were used as catalysts. Comparing the catalysts in different composition ratios with the grown deposits after CVD, we found that the optimum mol ratio between Fe and Sn is 6:0.1. It is noted that the catalyst combination of Fe2(SO4)3 /SnCl2 obviously increases the

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21

Botros, Fady T., Minolfa C. Prieto-Carrasquero, Victoria L. Martin, and L. Gabriel Navar. "Heme oxygenase induction attenuates afferent arteriolar autoregulatory responses." American Journal of Physiology-Renal Physiology 295, no. 4 (2008): F904—F911. http://dx.doi.org/10.1152/ajprenal.90377.2008.

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Heme oxygenases (HO-1, HO-2) catalyze conversion of heme to iron, carbon monoxide (CO), and biliverdin/bilirubin. We studied the effects of renal HO-1 induction on afferent arteriole (Aff-Art) autoregulatory responses to increases in renal perfusion pressure (RPP). Rats were treated with hemin and SnCl2 to induce HO-1, and Aff-Art autoregulatory responses were evaluated using the rat blood-perfused juxtamedullary nephron preparation. Renal HO-1 expression was significantly increased in hemin- and SnCl2-treated rats, while HO-2 was not altered. Aff-Art autoregulatory constrictor responses to in

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22

Santos-Filho, Sebastião David, Adenilson de Souza da Fonseca, and Mario Bernardo-Filho. "The male reproductive system and the effect of an extract of a medicinal plant (Hypericum perforatum) on the labeling process of blood constituents with technetium-99m." Brazilian Archives of Biology and Technology 50, spe (2007): 97–104. http://dx.doi.org/10.1590/s1516-89132007000600011.

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Hypericum perforatum (hiperico) is a plant that has been used to treat diseases and also inhibits rat and human vas deferens contractility. In nuclear medicine, stannous chloride (SnCl2) is used as a reducing agent to obtain radiopharmaceuticals labeling with technetium-99m. As the SnCl2 seems to have adverse effects related with the reproductive performance of male rabbits as well as the human consumption of hiperico might affect sexual function. In the present work, consistent results show significant changes on the blood constituents labeled by technetium-99m obtained from young rats under

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23

Mattos, José Carlos Pelielo de, Ellen Serri da Motta, Márcia Betania Nunes de Oliveira, Flávio José da Silva Dantas, and Adriano Caldeira de Araujo. "Alkaline gel electrophoresis assay to detect DNA strand breaks and repair mechanisms in Escherichia coli." Brazilian Archives of Biology and Technology 51, spe (2008): 121–26. http://dx.doi.org/10.1590/s1516-89132008000700020.

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Reactive oxygen species (ROS) can induce lesions in different cellular targets, including DNA. Stannous chloride (SnCl2) is a ROS generator, leading to lethality in Escherichia coli (E. coli), with the base excision repair (BER) mechanism playing a role in this process. Many techniques have been developed to detect genotoxicity, as comet assay, in eukaryotic cells, and plasmid DNA agarose gel electrophoresis. In this study, an adaptation of the alkaline gel electrophoresis method was carried out to ascertain the induction of strand breaks by SnCl2 in bacterial DNA, from E. coli BER mutants, an

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24

Motta, Ellen S., Paulo Thiago Souza-Santos, Tuany R. Cassiano, Flávio J. S. Dantas, Adriano Caldeira-de-Araujo, and José Carlos P. De Mattos. "Endonuclease IV Is the Main Base Excision Repair Enzyme Involved in DNA Damage Induced by UVA Radiation and Stannous Chloride." Journal of Biomedicine and Biotechnology 2010 (2010): 1–9. http://dx.doi.org/10.1155/2010/376218.

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Stannous chloride (SnCl2) and UVA induce DNA lesions through ROS. The aim of this work was to study the toxicity induced by UVA preillumination, followed bySnCl2treatment.E. coliBER mutants were used to identify genes which could play a role in DNA lesion repair generated by these agents. The survival assays showed (i) Thenfomutant was the most sensitive toSnCl2; (ii) lethal synergistic effect was observed after UVA pre-illumination, plusSnCl2incubation, thenfomutant being the most sensitive; (iii) wild type andnfomutants, transformed with pBW21 plasmid (nfo+) had their survival increased foll

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25

Gaber, Ahmed, Walaa F. Alsanie, Robson F. de Farias, and Moamen S. Refat. "Preparation and Thermogravimetric and Antimicrobial Investigation of Cd (II) and Sn (II) Adducts of Mercaptopyridine, Amino Triazole Derivatives, and Mercaptothiazoline Organic Ligand Moieties." Bioinorganic Chemistry and Applications 2021 (April 16, 2021): 1–10. http://dx.doi.org/10.1155/2021/6638229.

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The solid adducts of SnCl2.(3amt).H2O, SnCl2.2(3amt).H2O, CdCl2.(3amt), CdCl2.2(3amt), SnCl2.(2mct).0.5H2O, SnCl2.2(2mct), CdCl2.(2mct), CdCl2.2(2mct).H2O, SnCl2.(2mcp).1.5H2O, >2.2(2mcp).4H2O, CdCl2.(2mcp), CdCl2.2(2mcp), SnCl2.(4amt).4H2O, SnCl2.2(4amt).1.5H2O, CdCl2.(4amt).H2O, and CdCl2.2(4amt) (where the 3amt, 4amt, 2mct, and 2mcp represent 3-amino-1,2,4-triazole, 4-amino-1,2,4-triazole, 2-mercaptothiazoline, and 2-mercaptopyridine simple organic chelates, respectively) were prepared using a solid-state route and investigated by CHN elemental analysis and infrared spectroscopy. Additio

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26

Bott, Simon G., Jonathan C. Machell, D. Michael P. Mingos, and Michael J. Watson. "Synthesis and structural characterisation of the complex mer-[{Rh(CNC8H9)3(SnCl3)(µ-SnCl2)}2]." J. Chem. Soc., Dalton Trans., S (1991): 859–62. http://dx.doi.org/10.1039/dt9910000859.

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27

Beck, H. P., and H. Nau. "Zur Kenntnis des quasi-bin�ren Systems InCl?SnCl2 und eine Anmerkung zum System KCl?SnCl2." Zeitschrift f�r anorganische und allgemeine Chemie 554, no. 11 (1987): 43–49. http://dx.doi.org/10.1002/zaac.19875541106.

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Aloysius, Mudji Triatmo Melkias, and Gunawan Gunawan. "Optimasi Metoda CV-AAS untuk Analisis Raksa(II)." Jurnal Kimia Sains dan Aplikasi 5, no. 2 (2002): 15–18. http://dx.doi.org/10.14710/jksa.5.2.15-18.

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Telah dilakukan optimasi metoda spektrometri serapan atom-uap dingin atau cold vapour-atomic absorption spectrometry (CV-AAS) untuk analisis raksa(II). Gas atom raksa(0) yang dihasilkan dari reduksi 50 mL raksa(II) 50 ppb dengan SnCl2 5% dalam lingkungan asam klorida, ditentukan respon analitiknya dengan kuat arus lampu katoda cekung 4 mA dan pada panjang gelombang 254,1 nm. Kondisi optimum yang diperoleh adalah volume SnCl2 5% sebanyak 1,5 mL; waktu pengadukan 2 menit; lingkungan asam 5 mL HCl 15% dan kecepatan pompa penghisap 0,3 L/menit.

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29

Shubina, Tatyana E., and Timothy Clark. "Catalysis of the Quadricyclane to Norbornadiene Rearrangement by SnCl2 and CuSO4." Zeitschrift für Naturforschung B 65, no. 3 (2010): 347—r369. http://dx.doi.org/10.1515/znb-2010-0319.

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Ab initio and density-functional theory (DFT) calculations have been used to investigate the model rearrangements of quadricyclane to norbornadiene catalysed by single CuSO4 and SnCl2 molecules. The isolated reactions with the two molecular catalysts proceed via electron-transfer catalysis in which the hydrocarbon is oxidised, in contrast to systems investigated previously in which the substrate was reduced. The even-electron SnCl2-catalysed reaction shows singlet-triplet two-state reactivity. Solvation by a single methanol molecule changes the mechanism of the rearrangement to a classical Lew

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30

MacDonald, Elizabeth, Lauren Doyle, Saurabh S. Chitnis, Ulrike Werner-Zwanziger, Neil Burford, and Andreas Decken. "Me3P complexes of p-block Lewis acids SnCl4, SnCl3+ and SnCl22+." Chemical Communications 48, no. 64 (2012): 7922. http://dx.doi.org/10.1039/c2cc33206j.

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Darabi, Hossein Reza, Kioumars Aghapoor, Farshid Mohsenzadeh, et al. "ChemInform Abstract: Heterogeneous SnCl2/SiO2 versus Homogeneous SnCl2 Acid Catalysis in the Benzo[N,N]-heterocyclic Condensation." ChemInform 42, no. 22 (2011): no. http://dx.doi.org/10.1002/chin.201122178.

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32

Xu, Fen, Lixian Sun, Xiaofen Lan, et al. "Mechanism of fast hydrogen generation from pure water using Al–SnCl2 and bi-doped Al–SnCl2 composites." International Journal of Hydrogen Energy 39, no. 11 (2014): 5514–21. http://dx.doi.org/10.1016/j.ijhydene.2014.01.154.

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33

Gordillo, G., L. C. Moreno, W. de la Cruz, and P. Teheran. "Preparation and characterization of SnO2 thin films deposited by spray pyrolysis from SnCl2 and SnCl4 precursors." Thin Solid Films 252, no. 1 (1994): 61–66. http://dx.doi.org/10.1016/0040-6090(94)90826-5.

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34

Hadef, Z., K. Kamli, A. Attaf, M. S. Aida, and B. Chouial. "Effect of SnCl2 and SnCl4 precursors on SnS x thin films prepared by ultrasonic spray pyrolysis." Journal of Semiconductors 38, no. 6 (2017): 063001. http://dx.doi.org/10.1088/1674-4926/38/6/063001.

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35

Dehnen, Stefanie, and Christian Zimmermann. "Oxidative Stannylation with K6Sn2Se6/SnCl2: Synthesis and Crystal Structures of SnCl3-Substitutedpseudo-Tetrahedral Cobalt(III) Complexes." European Journal of Inorganic Chemistry 2000, no. 7 (2000): 1471–73. http://dx.doi.org/10.1002/1099-0682(200007)2000:7<1471::aid-ejic1471>3.0.co;2-a.

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Tsai, Chang Shu, Wei Chung Liu, Hong Yi Chen, and Wei Chun Hsu. "Preparation and Characterization of Fe₃O₄ Magnetic Nanoparticles Labeled with Technetium-99m Pertectnetate." Applied Mechanics and Materials 459 (October 2013): 51–59. http://dx.doi.org/10.4028/www.scientific.net/amm.459.51.

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In the aspect of biomedical diagnosis, magnetic nanoparticle can be used as drug carrier and MRI/ SPECT/ PET contrast agents. Magnetic fluid hyperthermia is one of the most important cancer therapies. Magnetic nanoparticles display their unique features as heating mediators for hyperthermia. In this study, Fe3O4magnetic nanoparticle was prepared by using chemical co-precipitation method. Tc-99m pertechnetate with Fe3O4magnetic nanoparticles is prepared by using magnet adsorption method. An attempt was also made to evaluate the application in the field of magnetic targeted drug delivery and rad

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Yang, Nan, Qiu Ming Zhang, and Yi Fan Wang. "Preparation and Properties of Bacteriostatic Sponge." Key Engineering Materials 544 (March 2013): 120–23. http://dx.doi.org/10.4028/www.scientific.net/kem.544.120.

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In this paperthe silver particle was adhered to the sponge by different ways and the sponge became to resistance bacterium. The AgNO3 reduced by SnCl2 is the best way via testing the weight gain rate and the antibacterial effect. By comparing the weight gain rate and the antibacterial effect at different concentration, it was found that, when the sponge was soaked in SnCl2 solution at a concentration of 0.10mol/L and AgNO3 solution at a concentration of 1.00mol/L, the sponge prepared by this method had the best antibacterial effect of 99.9%, in which adhered silver particle had uniform distrib

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Tian, Xin, Tania Pape, and Norbert W. Mitzel. "Formamidinium Salts of Low Valent Metal Halide Anions MX3 – (M = Ge, Sn) and M2X62– (M = Ga, In)." Zeitschrift für Naturforschung B 59, no. 11-12 (2004): 1524–31. http://dx.doi.org/10.1515/znb-2004-11-1224.

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Tetramethylformamidinium trichlorogermanite, [CH(NMe2)2][GeCl3], tetramethylformamidinium trichlorostannite, [CH(NMe2)2][SnCl3], bis-(tetramethylformamidinium hexaiododigallate, [CH(NMe2)2]2[Ga2I6] and bis-(tetramethylformamidinium hexachlorodiindate, [CH(NMe2)2]2[In2Cl6] have been prepared by the reactions between tetramethylformamidinium chloride, [CH(NMe2)2]Cl, and the corresponding low valent halides GeCl2 (as dioxane adduct), SnCl2, “GaI” and InCl. Their crystal structures have been determined by single crystal X-ray diffraction. [CH(NMe2)2][GeCl3] aggregates in a centrosymmetric dimeric

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Toelle, Sophia, Agnes Holtkamp, Uwe Blunck, Sebastian Paris, and Falk Schwendicke. "Improving the Bond Strength of Radiographically Tagged Caries Lesions In Vitro." Materials 13, no. 17 (2020): 3702. http://dx.doi.org/10.3390/ma13173702.

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After selective carious tissue removal, residual carious lesions remain radiographically detectable. Radiopaque tagging resolves the resulting diagnostic uncertainty but impedes bond strengths of adhesives to tagged dentin. We developed a protocol mitigating these detrimental effects. A 30%/50%/70% SnCl2 solution was dissolved in distilled water or a 30%/50%/90% ethanol solution (E30/60/90) and applied to artificially induced dentin lesions. Tagging effects were radiographically evaluated using transversal wavelength-independent microradiography (n = 6/group). Groups with sufficient tagging ef

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Zybill, Chr, and G. G. Müller. "Synthese und Kristallstruktur von t-Butyloxyzinn(II)chlorid / Synthesis and Crystal Structure of t-Butyloxytin(II) Chloride." Zeitschrift für Naturforschung B 43, no. 1 (1988): 45–48. http://dx.doi.org/10.1515/znb-1988-0108.

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Abstract t-Butyloxytin(II) chloride (1) is prepared from SnCl2 and KO-z-Bu at -60 °C in tetrahydrofuran. Above -30 °C a reversible dismutation into SnCl2 and [(t-BuO)2Sn] is observed in THF. For this process Δ G = +38 kJ/mol is estimated from NMR data. Compound 1 is a centrosymmetric dimer in the solid state with bridging O atoms (Sn-O 2.153(2)/2.156(2) Å, O-Sn-O 73.0(1)°, Sn-O-Sn 107.0(1)°). Due to the acute intraring bond angles at Sn. the O···O distance across the four-membered ring is relatively short (2.563(3) Å). The dimers are very loosely connected to chains by bridging THF molecules.

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Sugiharti, Rizky Juwita, Iim Halimah, Maula Eka Sriyani, and Eva Maria Widyasari. "EVALUASI FORMULASI RADIOFARMAKA 99mTc-SIPROFLOKSASIN DENGAN REDUKTOR SnCl2·2H2O dan Sn-TARTRAT." Jurnal Sains dan Teknologi Nuklir Indonesia 20, no. 2 (2019): 57. http://dx.doi.org/10.17146/jstni.2019.20.2.5348.

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99mTc-siprofloksasin adalah radiofarmaka berbasis antibiotik untuk diagnosis infeksi yang disebabkan oleh bakteri. Pada penelitian ini radiofarmaka 99mTc-siprofloksasin disiapkan dengan menggunakan dua macam reduktor yaitu SnCl2·2H2O dan Sn-tartrat. Penelitian ini bertujuan membandingkan masing-masing reduktor untuk menghasilkan radiofarmaka 99mTc-siprofloksasin dengan nilai kemurnian radiokimia yang tinggi dan akumulasi yang baik di daerah infeksi. Hasil dari penelitian ini menunjukkan bahwa kondisi optimum diperoleh pada jumlah reduktor SnCl2·2H2O sebanyak 25 µg dengan kemurnian radiokimia s

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Chen, Ying, and Man Zhang. "Large-area growth of SnS2 nanosheets by chemical vapor deposition for high-performance photodetectors." RSC Advances 11, no. 48 (2021): 29960–64. http://dx.doi.org/10.1039/d1ra05779k.

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Masuyama, Yoshiro, Jun Nakata, and Yasuhiko Kurusu. "Carbonyl allylation by vinyl epoxides with SnCl2–TBA or SnCl2–Lil: application to the diastereoselective synthesis of 1,3-diols." J. Chem. Soc., Perkin Trans. 1, no. 10 (1991): 2598–99. http://dx.doi.org/10.1039/p19910002598.

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SARR, MODOU, AMINATA DIASSE-SARR, and LIBASSE DIOP. "SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS." Journal of Engineering Studies and Research 26, no. 3 (2020): 218–23. http://dx.doi.org/10.29081/jesr.v26i3.227.

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Three organotin (IV) derivatives PhPO3HSnBu2Cl, SnBu2Ph2PO2Cl×3/2H2O, Sn(PhPO3)Cl2×2H2O obtained on allowing PhPO3H2 or propylammonium PhPO3H to react with SnBu2Cl2, SnCl2×2H2O and two adducts [(C6H5CH2)2NH2]3O2C(CH2)2PO3×3SnPh3Cl, [CyNH3(HO2POCH2-N(CH2CO2H)2]2×3SnCl4.2H2O×NH4Cl obtained on allowing (C6H5CH2)NH2)3O2C(CH2)2PO3 or [CyNH3(HO2POCH2-N(CH2 CO2H)2]2 and SnPh3Cl or SnCl2×2H2O to react in ethanolic media have been characterized by elemental analyses, infrared and Mossbauer techniques. The suggested structures, while considering the anionic counterpart, are discrete, dimeric, double and

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White, Andrew P., Katherine N. Robertson, T. Stanley Cameron, et al. "Synthesis and characterization of [M(DMSO)6][SnCl6] complexes (M = Fe2+, Co2+, and Ni2+) — An old mystery solved." Canadian Journal of Chemistry 85, no. 5 (2007): 372–78. http://dx.doi.org/10.1139/v07-042.

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The synthesis of an "unknown" Fe(II) complex originally reported in 1973 and formulated then as [Fe(DMSO)5Cl][SnCl4] was thoroughly reproduced and the compound reformulated as the novel [Fe(DMSO)6][SnCl6] double complex salt. Current elemental analysis and IR and Mössbauer spectroscopy matched the original 1973 data, and Raman spectroscopy and single crystal X-ray diffraction provided additional confirmation of our reformulation. [Fe(DMSO)6][SnCl6] (1) crystallizes in the trigonal space group R[Formula: see text] with octahedral [Fe(DMSO)6]2+ and [SnCl6]2– complex ions with an Fe—O bond length

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Morinaga, Kenji, and Shigeru Fujino. "Preparation and properties of SnO–SnCl2–P2O5 glass." Journal of Non-Crystalline Solids 282, no. 1 (2001): 118–24. http://dx.doi.org/10.1016/s0022-3093(01)00334-9.

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Tan, Xiang-Hui, Yong-Quan Hou, Chao Huang, Lei Liu, and Qing-Xiang Guo. "SnCl2-mediated carbonyl allylation in fully aqueous media." Tetrahedron 60, no. 29 (2004): 6129–36. http://dx.doi.org/10.1016/j.tet.2004.05.046.

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Lomakin, S. M., G. E. Zaikov, and M. I. Artsis. "Polypropylene Flame Retardant System Based on Si-SnCl2." International Journal of Polymeric Materials 32, no. 1-4 (1996): 203–11. http://dx.doi.org/10.1080/00914039608029394.

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49

Taslimah, Taslimah, Ruslan Ismail, and Damin Sumardjo. "Sintesis Garam SnCl2 dari Bahan Kemasan Berlapis Timah." Jurnal Kimia Sains dan Aplikasi 6, no. 3 (2003): 5–8. http://dx.doi.org/10.14710/jksa.6.3.5-8.

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Telah dilakukan sintesis garam SnCl2 dengan bahan baku bahan kemasan berlapis timah. Sintesis dilakukan dengan merefluks oksida timah dengan larutan HCl, NaCl atau KCl selama 2 jam pada suhu 200 oC . Campuran disaring dalam keadaan panas, filtrat didinginkan, endapan yang terbentuk dipisahkan.Karakterisasi produk dilakukan dengan menentukan titik leleh dan daya reduksinya.Disimpulkan bahwa sebagai sumber ion Cl- yang baik berturut-turut HCl, KCl dan NaCl. Garam Yang dihasilkan berwarna putih keabu-abuan mempunyai kisaran titik leleh 243 – 248 oC dan bersifat sebagai reduktor.

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Gilbert, B. P., F. Taulelle, and B. Trémillon. "Investigation of SnCl2AlCl3 mixtures by Raman spectroscopy." Journal of Raman Spectroscopy 19, no. 1 (1988): 1–8. http://dx.doi.org/10.1002/jrs.1250190102.

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