Log in

Relevant bibliographies by topics / Sodium Phenoxide / Journal articles

To see the other types of publications on this topic, follow the link: Sodium Phenoxide.

Journal articles on the topic 'Sodium Phenoxide'

Author: Grafiati

Published: 4 June 2021

Last updated: 26 July 2025

Create a spot-on reference in APA, MLA, Chicago, Harvard, and other styles

Select a source type:

Consult the top 50 journal articles for your research on the topic 'Sodium Phenoxide.'

Next to every source in the list of references, there is an 'Add to bibliography' button. Press on it, and we will generate automatically the bibliographic reference to the chosen work in the citation style you need: APA, MLA, Harvard, Chicago, Vancouver, etc.

You can also download the full text of the academic publication as pdf and read online its abstract whenever available in the metadata.

Browse journal articles on a wide variety of disciplines and organise your bibliography correctly.

1

Fraser, Marie E., Suzanne Fortier, Mary K. Markiewicz, André Rodrigue, and John W. Bovenkamp. "The crystal structures of the 1:1:1 complexes of dicyclohexano-18-crown-6 (isomer B) with potassium phenoxide and phenol and dicyclohexano-18-crown-6 (isomer A) with sodium phenoxide and phenol." Canadian Journal of Chemistry 65, no. 11 (1987): 2558–63. http://dx.doi.org/10.1139/v87-425.

Full text

Abstract:

The crystal structures of the 1:1:1 complexes of dicyclohexano-18-crown-6 (isomer B) with potassium phenoxide and phenol, and of dicyclohexano-18-crown-6 (isomer A) with sodium phenoxide and phenol have been determined. The potassium phenoxide complex crystallizes in space group Pnca with a = 14.150(3), b = 23.794(6), c = 9.491(1) Å, and Z = 4. Thesodium phenoxide complex crystallizes in space group Pbca with a = 21.201(4), b = 24.406(6), c = 12.492(3) Å, and Z = 8. Both structures were solved by direct methods and refined by full matrix least-squares calculations to residuals, R, of 0.059 for

APA, Harvard, Vancouver, ISO, and other styles

2

Wang, Jintao, Qijun Pei, Yang Yu, et al. "Investigation on the Formation of Rare-Earth Metal Phenoxides via Metathesis." Inorganics 11, no. 3 (2023): 115. http://dx.doi.org/10.3390/inorganics11030115.

Full text

Abstract:

A number of alkali organometallic complexes with suitable thermodynamic properties and high capacity for hydrogen storage have been synthesized; however, few transition metal–organic complexes have been reported for hydrogen storage. Moreover, the synthetic processes of these transition metal–organic complexes via metathesis were not well characterized previously, leading to a lack of understanding of the metathesis reaction. In the present study, yttrium phenoxide and lanthanum phenoxide were synthesized via metathesis of sodium phenoxide with YCl3 and LaCl3, respectively. Quasi in situ NMR,

APA, Harvard, Vancouver, ISO, and other styles

3

Domiński, Adrian, Tomasz Konieczny, Magdalena Zięba, Magdalena Klim та Piotr Kurcok. "Anionic Polymerization of β-Butyrolactone Initiated with Sodium Phenoxides. The Effect of the Initiator Basicity/Nucleophilicity on the ROP Mechanism". Polymers 11, № 7 (2019): 1221. http://dx.doi.org/10.3390/polym11071221.

Full text

Abstract:

It was shown that selected sodium phenoxide derivatives with different basicity and nucleophilicity, such as sodium p-nitrophenoxide, p-chlorophenoxide, 1-napthoxide, phenoxide and p-methoxyphenoxide, are effective initiators in anionic ring-opening polymerization (AROP) of β-butyrolactone in mild conditions. It was found that phenoxides as initiators in anionic ring-opening polymerization of β-butyrolactone behave as strong nucleophiles, or weak nucleophiles, as well as Brønsted bases. The resulting polyesters possessing hydroxy, phenoxy and crotonate initial groups are formed respectively by

APA, Harvard, Vancouver, ISO, and other styles

4

Fraser, Marie E., Suzanne Fortier, André Rodrigue, and John W. Bovenkamp. "The crystal structures of the 1:2 host:guest complexes of dicyclohexano-18-crown-6 (isomers A and B) with sodium and potassium phenoxide." Canadian Journal of Chemistry 64, no. 4 (1986): 816–23. http://dx.doi.org/10.1139/v86-134.

Full text

Abstract:

The crystal structures of the 1:2 host:guest complexes of dicyclohexano-18-crown-6 (isomer B) with potassium phenoxide and dicyclohexano-18-crown-6 (isomer A) with sodium phenoxide have been determined. The potassium phenoxide complex crystallizes in space group [Formula: see text] with a = 10.023(2), b = 11.238(2), c = 7.546(2) Å, α = 95.73(2), β = 103.04(2), γ = 92.03(2)°, and Z = 1. The sodium phenoxide complex crystallizes in space group P21/n with a = 19.185(12), b = 13.266(5), c = 13.038(5) Å, β = 96.55(4)°, and Z = 4. Both structures were solved by direct methods and refined by full mat

APA, Harvard, Vancouver, ISO, and other styles

5

Dunn, Edward J., Robert Y. Moir, Erwin Buncel, J. Garfield Purdon, and Robert A. B. Bannard. "Metal ion catalysis in nucleophilic displacement reactions at carbon, phosphorus, and sulfur centers. II. Metal ion catalysis in the reaction of p-nitrophenyl diphenylphosphinate with alkali metal phenoxides in ethanol." Canadian Journal of Chemistry 68, no. 10 (1990): 1837–45. http://dx.doi.org/10.1139/v90-286.

Full text

Abstract:

The reactions of p-nitrophenyl diphenylphosphinate (1) with lithium, sodium, potassium, and benzyltrimethylammonium phenoxides (BTMAOPh) have been studied by spectrophotometric techniques in anhydrous ethanol at 25 °C. The reactivity (kobs) of the alkali metal phenoxides increases in the order BTMAOPh < KOPh < NaOPh < LiOPh. The rate of reaction of 1 with LiOPh is enhanced when lithium salts (LiSCN, LiNO3, LiClO4, LiOAc) are added to the reaction media. The addition of the alkali metal complexing agents dicyclohexyl-18-crown-6 ether or [2.2.2]cryptand for Na+, and [2.1.1]cryptand for

APA, Harvard, Vancouver, ISO, and other styles

6

Murchie, Michael P., John W. Bovenkamp, André Rodrigue, Kimberley A. Watson, and Suzanne Fortier. "Complexes of 15-crown-5 and cyclohexano-15-crown-5 with lithium, sodium, and potassium phenoxide having macrocycle: salt ratios of 1:1 and 1:2. The crystal structures of two polymorphs of 15-crown-5•2LiOPh." Canadian Journal of Chemistry 66, no. 10 (1988): 2515–23. http://dx.doi.org/10.1139/v88-395.

Full text

Abstract:

The syntheses, in ethereal solvents, of the complexes of 15-crown-5 and cyclohexano-15-crown-5 with lithium, sodium, and potassium phenoxide are described. The two macrocycles form complexes with lithium and sodium phenoxide with host:guest ratios of 1:2. Potassium phenoxide, however, was complexed by the two macrocycles to give products with macrocycle:salt ratios of 1:1. Crystals of 15-crown-5•2LiOPh were obtained for X-ray diffraction structure determinations. In fact, the crystal structures of two co-crystallizing polymorphs of this complex (1a and 1b) have been determined. Polymorph 1a cr

APA, Harvard, Vancouver, ISO, and other styles

7

Rodrigue, André, John W. Bovenkamp, Benoit V. Lacroix, Robert A. B. Bannard, and Gerald W. Buchanan. "Complexes of 18-crown-6 macrocyclic ethers obtained from ethereal solvents. Complexes of potassium and sodium salts with host:guest ratios of 1:2 and 1:3." Canadian Journal of Chemistry 64, no. 4 (1986): 808–15. http://dx.doi.org/10.1139/v86-133.

Full text

Abstract:

This paper describes the synthesis, in ethereal solvents, of the complexes of 18-crown-6, the cis–syn–cis and the cis–anti–cis isomers of dicyclohexano-18-crown-6, and dibenzo-18-crown-6 with the potassium and sodium salts of phenoxide and thiocyanate (as well as some potassium oximate salts). In general, the macrocycles break down the aggregates of the potassium salts so that the complexes of the contact ion pairs are isolated. The complex of the cis–anti–cis isomer of dicyclohexano-18-crown-6, however, which has a low stability constant, complexes the dimer of potassium phenoxide to give a c

APA, Harvard, Vancouver, ISO, and other styles

8

Fang, Yao-ren, Zhu-gen Lai, and Kenneth Charles Westaway. "Isotope effects in nucleophilic substitution reactions X. The effect of changing the nucleophilic atom on ion-pairing in an SN2 reaction." Canadian Journal of Chemistry 76, no. 6 (1998): 758–64. http://dx.doi.org/10.1139/v98-056.

Full text

Abstract:

The effect of ion-pairing in an SN2 reaction is very different when the nucleophilic atom is changed from sulfur to oxygen, i.e., changing the nucleophile from thiophenoxide ion to phenoxide ion. When the nucleophile is sodium thiophenoxide, ion-pairing markedly alters the secondary α -deuterium kinetic isotope effect (transition state structure) and the substituent effect found by changing the para substituent on the nucleophile. When the nucleophile is sodium phenoxide, ion-pairing does not significantly affect the secondary α -deuterium or the chlorine leaving group kinetic isotope effects

APA, Harvard, Vancouver, ISO, and other styles

9

Mohammad, Omar, Jude A. Onwudili, and Qingchun Yuan. "Potential Large-Scale CO2 Utilisation for Salicylic Acid Production via a Suspension-Based Kolbe–Schmitt Reaction in Toluene." Molecules 29, no. 11 (2024): 2527. http://dx.doi.org/10.3390/molecules29112527.

Full text

Abstract:

Conversion of CO2 into organic chemicals offers a promising route for advancing the circularity of carbon capture, utilisation, and storage in line with the international 2050 Net Zero agenda. The widely known commercialised chemical fixation of CO2 into organic chemicals is the century-old Kolbe–Schmitt reaction, which carboxylates phenol (via sodium phenoxide) into salicylic acid. The carboxylation reaction is normally carried out between the gas–solid phases in a batch reactor. The mass and heat transfer limitations of such systems require rather long reaction times and a high pressure of C

APA, Harvard, Vancouver, ISO, and other styles

10

Freund, Amy S., Michael Calichman, and Christopher W. Allen. "The Reactions of Hexafluorocyclotriphosphazene with Sodium Phenoxide." Zeitschrift f�r anorganische und allgemeine Chemie 630, no. 12 (2004): 2059–62. http://dx.doi.org/10.1002/zaac.200400310.

Full text

APA, Harvard, Vancouver, ISO, and other styles

11

Bhagwat, Santosh, Prakash Patil, Ramdas Pawar, Santosh Shinde, Dinesh Amalnerkar, and Dnyaneshwar Shinde. "Development and validation of a method for quantitative determination of the genotoxic impurity diethyl sulfate in pitolisant hydrochloride via high-performance liquid chromatography." RSC Advances 15, no. 20 (2025): 16125–33. https://doi.org/10.1039/d5ra01217a.

Full text

Abstract:

Diethyl sulfate, a carcinogenic by-product in pitolisant hydrochloride synthesis, is converted to ethoxybenzene using sodium phenoxide, enabling its quantification by HPLC-UV to help minimize risk in the drug substance.

APA, Harvard, Vancouver, ISO, and other styles

12

Sann, Christine Le, and Andrew D. Abell. "Synthesis and Properties of a Mesylated ArgoGel Resin." Australian Journal of Chemistry 57, no. 4 (2004): 355. http://dx.doi.org/10.1071/ch03247.

Full text

Abstract:

Treatment of ArgoGel-OH with methanesulfonylchloride and triethylamine gives ArgoGel-OMs to which can be coupled the salt of a hydroxycarboxylic acid (quinates 1c, 3b, or sodium salicylate) and the caesium salt of N-Boc–amino acid. The phenoxide derived from 4-hydroxybenzyl alcohol can also be coupled to this new resin to give a Wang linker.

APA, Harvard, Vancouver, ISO, and other styles

13

Xu, Wen-Ying, and Di Wu. "Characterization of char from slow pyrolysis of sewage sludge." Water Science and Technology 73, no. 10 (2016): 2370–78. http://dx.doi.org/10.2166/wst.2016.090.

Full text

Abstract:

The effects of final pyrolysis temperature Tend from 300 ºC to 550 ºC, heating rates β of 2 ºC/min, 3 ºC/min and 5 ºC/min, retention time RT from 45 min to 90 min, and the moisture content MC from 0 to 70% on characteristics of the pyrolysis char from sewage sludge were investigated using a tube furnace in this study. The resulting chars were characterized by sorption of nitrogen (surface area and pore volume). Their adsorption characteristics were evaluated via iodine value and methylene blue value. Either the pore structures or adsorption characteristics depend on the pyrolysis processing an

APA, Harvard, Vancouver, ISO, and other styles

14

Yu, Yang, Teng He, Anan Wu, et al. "Reversible Hydrogen Uptake/Release over a Sodium Phenoxide–Cyclohexanolate Pair." Angewandte Chemie 131, no. 10 (2018): 3134–39. http://dx.doi.org/10.1002/ange.201810945.

Full text

APA, Harvard, Vancouver, ISO, and other styles

15

Yu, Yang, Teng He, Anan Wu, et al. "Reversible Hydrogen Uptake/Release over a Sodium Phenoxide–Cyclohexanolate Pair." Angewandte Chemie International Edition 58, no. 10 (2019): 3102–7. http://dx.doi.org/10.1002/anie.201810945.

Full text

APA, Harvard, Vancouver, ISO, and other styles

16

Dahlhoff, Wilhelm V., Gerhard Schroth, Barbara Gabor та Roland Köster. "Synthesis and Stereoselective Glycosylations of 3-O-Acetyl-2,4-O-phenylboranediyl-β-D-ribopyranosyl Bromide". Zeitschrift für Naturforschung B 45, № 4 (1990): 547–51. http://dx.doi.org/10.1515/znb-1990-0421.

Full text

Abstract:

Crystalline 3-O-acetyl-2,4-O-phenylboranediyl-β-D-ribopyranosyl bromide (5) is prepared by an easy four-step synthesis from D-ribose (1), the first three steps of which are realised in an one-pot manner. 5 reacts stereoselectively with sodium methoxide and phenoxide to give the pure methyl and phenyl a-D-ribopyranosides 7 a and 7 b after deboronation and deacetylation.

APA, Harvard, Vancouver, ISO, and other styles

17

Bhaskar, T., R. Mithina, N. Banumathi, and P. Vijaya. "Synthesis, DFT and Anti-microbial study of 2-amino-2-phenoxypropane-1,3-diol." Research Journal of Chemistry and Environment 28, no. 12 (2024): 56–62. https://doi.org/10.25303/2812rjce056062.

Full text

Abstract:

The compound 2-amino-2-phenoxypropane-1,3-diol was synthesised from bronopol reduced compound 2-amino-2-bromo propane-1,3-diol with sodium phenoxide in ethanol. The compound was characterised by FTIR, 1H-NMR, 13C-NMR spectroscopy and structure was confirmed by proposed mechanism. The compound was also studied for the antimicrobial activity of the three samples against three pathogenic bacterial strains. The computational DFT analysis was also carried out for the synthesised compound.

APA, Harvard, Vancouver, ISO, and other styles

18

David, Michèle, Jean Sauleau та Armelle Sauleau. "Époxydes α-éthyléniques et phénate de sodium: accès à des éthers phénoliques et phénols ortho-allyliques". Canadian Journal of Chemistry 63, № 9 (1985): 2449–54. http://dx.doi.org/10.1139/v85-405.

Full text

Abstract:

The ring cleavage reactions of α-ethylenic epoxides by sodium phenoxide afforded a mixture of products. Problems of competitive attack by this nucleophile, at the less substituted carbon (compounds A) or at the β-ethylenic carbon atom (compounds B and C), were encountered and could be resolved by judicious choice of reaction conditions (solvents, stereochemistry of the oxiranes). The regioselectivity of the attack was dependent on the transition states, implying weak steric hindrance and a conjugation oxirane – double bond.

APA, Harvard, Vancouver, ISO, and other styles

19

Asano, Narumi, Keita Sasaki, Isabelle Chataigner, Masanori Shigeno, and Yoshinori Kondo. "Sodium Phenoxide Mediated Hydroxymethylation of Alkynylsilanes with N -[(Trimethylsiloxy)methyl]phthalimide." European Journal of Organic Chemistry 2017, no. 46 (2017): 6926–30. http://dx.doi.org/10.1002/ejoc.201701440.

Full text

APA, Harvard, Vancouver, ISO, and other styles

20

Yang, Hung-Ming, and Ch'un-Min Wu. "Phase-transfer catalyzed allylation of sodium phenoxide in a solid–liquid system." Journal of Molecular Catalysis A: Chemical 153, no. 1-2 (2000): 83–91. http://dx.doi.org/10.1016/s1381-1169(99)00304-0.

Full text

APA, Harvard, Vancouver, ISO, and other styles

21

Pickett, David J., and Ebrahim Akhavan-Alizadeh. "A study of the electrochemical regeneration of phenol from sodium phenoxide solutions." Journal of Applied Chemistry and Biotechnology 24, no. 1-2 (2007): 63–70. http://dx.doi.org/10.1002/jctb.2720240108.

Full text

APA, Harvard, Vancouver, ISO, and other styles

22

Yang, Hung-Ming, and Chin-Chen Huang. "Kinetics for benzoylation of sodium phenoxide by liquid–liquid phase-transfer catalysis." Applied Catalysis A: General 299 (January 2006): 258–65. http://dx.doi.org/10.1016/j.apcata.2005.10.042.

Full text

APA, Harvard, Vancouver, ISO, and other styles

23

Zhang, Haodong, Junmei Zhang, Wencai Jiang, Xuechen Mu, Yuanzheng Tang, and Zhenya Duan. "Molecular dynamics simulation of the Kolbe-Schmitt carboxylation mechanism of sodium phenoxide." Chemical Engineering Science 286 (March 2024): 119690. http://dx.doi.org/10.1016/j.ces.2023.119690.

Full text

APA, Harvard, Vancouver, ISO, and other styles

24

Harrowfield, Jack M., Raj Pal Sharma, Brian W. Skelton, and Allan H. White. "Structural Systematics of 2/4-Nitrophenoxide Complexes of Closed-Shell Metal Ions. IV [Acid Salts] of the 4-Nitrophenoxides of Group 1." Australian Journal of Chemistry 51, no. 8 (1998): 747. http://dx.doi.org/10.1071/c97101.

Full text

Abstract:

Room-temperature single-crystal X-ray studies are recorded for a number of ‘acid salts’ formed between Group 1 salts of 4-nitrophenol, M(4-np), and the parent ligand 4-npH, variously hydrated. The 1 : 1 salts M(4-np)(4-npH).x H2O are found for all of M = Li, Na, K, Rb and Cs. The lithium adduct (tetrahydrate) is monoclinic, C2/c, a 19·438(4), b 11·207(2), c 7·421(2) Å, β 91·38(2)°, Z = 4, conventional R on |F| being 0·043 for 1369 independent ‘observed’ (I > 3σ(I)) diffractometer reflections. The sodium adduct (dihydrate) is monoclinic, C2, a 2·174(3), b 3·674(2), c 10·358(1) Å, β 117·21(1)

APA, Harvard, Vancouver, ISO, and other styles

25

Bredikhina, Z. A., A. V. Pashagin, and A. A. Bredikhin. "Reactions of 4-chloromethyl-1,3,2-dioxathiolane 2-oxides with sodium phenoxide. A reinvestigation." Russian Chemical Bulletin 49, no. 10 (2000): 1753–56. http://dx.doi.org/10.1007/bf02496348.

Full text

APA, Harvard, Vancouver, ISO, and other styles

26

Banks, Benjamin, Matthew R. Cargill, Graham Sandford, et al. "Reactions of dibromotetrafluorobenzene derivatives with sodium phenoxide salts. Competing hydrodebromination and SNAr processes." Journal of Fluorine Chemistry 131, no. 5 (2010): 627–34. http://dx.doi.org/10.1016/j.jfluchem.2010.02.005.

Full text

APA, Harvard, Vancouver, ISO, and other styles

27

Francisco Sánchez Viesca and Reina Gómez Gómez. "On dulcin detection by halochromism." International Journal of Scholarly Research in Chemistry and Pharmacy 4, no. 1 (2024): 001–4. http://dx.doi.org/10.56781/ijsrcp.2024.4.1.0023.

Full text

Abstract:

Dulcin has been detected by reaction with fuming nitric acid followed by interaction with phenol and sulphuric acid. Other tests use electron capturing reagents such as mercuric nitrate or silver nitrate. The test under study is not based in degradations initiated by nitration, nor by oxidations by electron removal, but by molecular fission after prototropy enhanced by heating. p-Phenetidine is obtained and forms the ammonium salt with sulphuric acid. After cooling and water addition, the solution is carefully covered with ammonium or sodium hydroxide. The interphase is coloured blue or violet

APA, Harvard, Vancouver, ISO, and other styles

28

Hrudková, Hana, Pavel Čefelín, and Václav Janout. "Polymer sulfoxides based on poly(vinyl alcohol) as effective catalysts of nucleophilic substitution reactions." Collection of Czechoslovak Chemical Communications 52, no. 9 (1987): 2204–11. http://dx.doi.org/10.1135/cccc19872204.

Full text

Abstract:

Using the addition of alcohols to ethyl vinyl sulfoxide, a number of 2-alkoxyethyl ethyl sulfoxides were prepared, containing the following alkyls: methyl, ethyl, isopropyl, benzyl, and cyclohexyl. With a 10 mole % excess of alcohol the extent of the reaction was 70-95%. By a polymeranalogous reaction with poly(vinyl alcohol) and poly(ethylene-co-vinyl alcohol), copolymers poly[1-hydroxyethylene (74 mole %)-co-1-(2-ethylsulfinylethoxy)ethylene (26 mole %)] and poly[ethylene (62 mole %)-co-1-hydroxyethylene (35 mole %)-co-1-(2-ethylsulfinylethoxy)ethylene (3 mole %)] were prepared; the reaction

APA, Harvard, Vancouver, ISO, and other styles

29

Yu, Yang, Qijun Pei, Teng He, and Ping Chen. "Kinetic studies of reversible hydrogen storage over sodium phenoxide-cyclohexanolate pair in aqueous solution." Journal of Energy Chemistry 39 (December 2019): 244–48. http://dx.doi.org/10.1016/j.jechem.2019.04.008.

Full text

APA, Harvard, Vancouver, ISO, and other styles

30

Whitmire, Kenton H., Herbert W. Roesky, Sally Brooker, and George M. Sheldrick. "CF bond activation in the reaction of BiCl3 with sodium 2,4,6-tris(trifluoromethyl)phenoxide." Journal of Organometallic Chemistry 402, no. 1 (1991): C4—C7. http://dx.doi.org/10.1016/0022-328x(91)80091-w.

Full text

APA, Harvard, Vancouver, ISO, and other styles

31

Kunert, Michael, Eckhard Dinjus, Maria Nauck, and Joachim Sieler. "Structure and Reactivity of Sodium Phenoxide - Following the Course of the Kolbe-Schmitt Reaction." Chemische Berichte 130, no. 10 (1997): 1461–65. http://dx.doi.org/10.1002/cber.19971301017.

Full text

APA, Harvard, Vancouver, ISO, and other styles

32

Tušek-Božić, L. J. "Complexes of 18-Crown-6 Macrocyclic Ethers with Sodium Monoalkyl [2-Sodium Phenoxide[[4-(Phenylazo)-Phenyl] Amino] Methyl] Phosphonate." Journal of Coordination Chemistry 26, no. 4 (1992): 345–50. http://dx.doi.org/10.1080/00958979209407937.

Full text

APA, Harvard, Vancouver, ISO, and other styles

33

Hemer, Ivan, Věra Moravcová, and Václav Dědek. "Reaction of 1,4-dibromohexafluoro-2-butene with O- and N-nucleophiles." Collection of Czechoslovak Chemical Communications 53, no. 3 (1988): 619–25. http://dx.doi.org/10.1135/cccc19880619.

Full text

Abstract:

Reaction of 1,4-dibromohexafluoro-2-butene (I) with sodium methoxide, ethoxide or isopropoxide in the corresponding alcohols proceeds with allylic rearrangement under formation of 3-alkoxy-4-bromohexafluoro-1-butenes II-IV. A kinetic study has proven the SN2’ mechanism for reaction of I with potassium phenoxide leading to 4-bromo-3-phenoxyhexafluoro-1-butene (V). Also the reaction of I with ammonia, affording 3-amino-4-bromo-2,4,4-trifluoro-2-butenenitrile (IX), is compatible with the allylic rearrangement by SN2’ mechanism. On the contrary, reaction of I with diethylamine gave no rearrangemen

APA, Harvard, Vancouver, ISO, and other styles

34

Čefelín, Pavel, Hana Hrudková, Václav Janout, Vitalii I. Kalchenko, and Bohumír Valter. "Polymer-Supported Oligo(oxyethylene)s, Sulfoxides, and Crown Ethers in Nucleophilic Substitution Reactions." Collection of Czechoslovak Chemical Communications 57, no. 3 (1992): 472–86. http://dx.doi.org/10.1135/cccc19920472.

Full text

Abstract:

The efficiency of polymer analogues of oligo(oxyethylene)s and sulfoxides in the activation of nucleophilic substitution reactions were compared by testing to the reaction between sodium phenoxide and 1-bromooctane in 1,4-dioxane. With polymer analogues of crown ethers and polymer networks having the pseudo-crown ether structure the polymer effect can be achieved, i.e. a higher activation efficiency of the polymer analogue (in the L-S system) compared with the efficiency of the unimmobilized compound (in the homogeneous system). The results suggest that several molecules of the linear activato

APA, Harvard, Vancouver, ISO, and other styles

35

Goering, Harlan L., and Steven D. Paisley. "Oxiranylidene intermediate in the reaction of trans-2-chloro-3- tert-butyloxirane with sodium phenoxide." Tetrahedron Letters 27, no. 37 (1986): 4399–402. http://dx.doi.org/10.1016/s0040-4039(00)84962-x.

Full text

APA, Harvard, Vancouver, ISO, and other styles

36

Yu, Yang, Teng He, Anan Wu, et al. "Rücktitelbild: Reversible Hydrogen Uptake/Release over a Sodium Phenoxide–Cyclohexanolate Pair (Angew. Chem. 10/2019)." Angewandte Chemie 131, no. 10 (2019): 3262. http://dx.doi.org/10.1002/ange.201901616.

Full text

APA, Harvard, Vancouver, ISO, and other styles

37

Banks, Benjamin, Matthew R. Cargill, Graham Sandford, et al. "ChemInform Abstract: Reactions of Dibromotetrafluorobenzene Derivatives with Sodium Phenoxide Salts. Competing Hydrodebromination and SNAr Processes." ChemInform 41, no. 38 (2010): no. http://dx.doi.org/10.1002/chin.201038069.

Full text

APA, Harvard, Vancouver, ISO, and other styles

38

Martinelli, Joseph R, Thomas P Clark, Donald A Watson, Rachel H Munday, and Stephen L Buchwald. "Palladium-Catalyzed Aminocarbonylation of Aryl Chlorides at Atmospheric Pressure: The Dual Role of Sodium Phenoxide." Angewandte Chemie International Edition 46, no. 44 (2007): 8460–63. http://dx.doi.org/10.1002/anie.200702943.

Full text

APA, Harvard, Vancouver, ISO, and other styles

39

Bredikhina, Z. A., A. V. Pashagin, and A. A. Bredikhin. "ChemInform Abstract: Reactions of 4-Chloromethyl-1,3,2-dioxathiolane 2-Oxides with Sodium Phenoxide. A Reinvestigation." ChemInform 32, no. 14 (2001): no. http://dx.doi.org/10.1002/chin.200114044.

Full text

APA, Harvard, Vancouver, ISO, and other styles

40

Martinelli, Joseph R, Thomas P Clark, Donald A Watson, Rachel H Munday, and Stephen L Buchwald. "Palladium-Catalyzed Aminocarbonylation of Aryl Chlorides at Atmospheric Pressure: The Dual Role of Sodium Phenoxide." Angewandte Chemie 119, no. 44 (2007): 8612–15. http://dx.doi.org/10.1002/ange.200702943.

Full text

APA, Harvard, Vancouver, ISO, and other styles

41

Janout, Václav, Hana Hrudková, Bohumír Valter, and Pavel Čefelín. "Solid phase cosolvents: Polymer analogs of N,N-dialkylamides based on polystyrene." Collection of Czechoslovak Chemical Communications 54, no. 7 (1989): 1830–38. http://dx.doi.org/10.1135/cccc19891830.

Full text

Abstract:

Polymers of styrene of various type can be readily amidomethylated by a reaction with N-(hydroxymethyl)amides. Analogs of N-methyl-2-pyrrolidone, N-methyl-6-hexanelactam, N-methyl-8-octanelactam, and N,N-dimethylacetamide were prepared by the polymeranalogous amidomethylation. The reaction between poly(styrene-co-divinylbenzene) and N-(hydroxymethyl)-2-pyrrolidone proceeds by an acceleration mechanism. The extent of the reaction depends on the structure of the polymer and N-(hydroxymethylamide), on the concentration of the catalyst (trifluoroacetic acid) and on the way in which the polymer swe

APA, Harvard, Vancouver, ISO, and other styles

42

Francisco Sánchez Viesca and Reina Gómez Gómez. "On the interaction of morphine with Lugol’s iodine in alkaline medium." Open Access Research Journal of Chemistry and Pharmacy 4, no. 2 (2023): 052–54. http://dx.doi.org/10.53022/oarjcp.2023.4.2.0086.

Full text

Abstract:

The purpose of this communication is to clear up what is happening in the test tube during the interaction of an alkaline solution of morphine with Lugol’s iodine (Kippenberger test for morphine). The formation mode and reactivity of potassium triiodide, the salt present in Lugol’s solution, are commented. Reaction of iodine molecule (formed in a reversible manner) with sodium hydroxide gives rise to hypo-iodous acid. This reacts with the morphine phenolate formed in situ yielding an organic hypoiodite. This labile intermediate loses iodide ion, producing a ketone and Umpolung at the ortho-pos

APA, Harvard, Vancouver, ISO, and other styles

43

Hatano, Manabu, Eri Takagi, and Kazuaki Ishihara. "Sodium Phenoxide−Phosphine Oxides as Extremely Active Lewis Base Catalysts for the Mukaiyama Aldol Reaction with Ketones." Organic Letters 9, no. 22 (2007): 4527–30. http://dx.doi.org/10.1021/ol702052r.

Full text

APA, Harvard, Vancouver, ISO, and other styles

44

WHITMIRE, K. H., H. W. ROESKY, S. BROOKER, and G. M. SHELDRICK. "ChemInform Abstract: C-F Bond Activation in the Reaction of BiCl3 with Sodium 2,4,6-Tris(trifluoromethyl)phenoxide." ChemInform 22, no. 16 (2010): no. http://dx.doi.org/10.1002/chin.199116138.

Full text

APA, Harvard, Vancouver, ISO, and other styles

45

Kojčinović, Aleksa, Blaž Likozar, and Miha Grilc. "Sustainable CO2 Fixation onto Bio-Based Aromatics." Sustainability 15, no. 23 (2023): 16321. http://dx.doi.org/10.3390/su152316321.

Full text

Abstract:

Carboxylation reactions using carbon dioxide (CO2) as a reactant to produce new C-C bonds represent one of the most promising routes in carbon capture and utilization practices, which yield higher-atom and energy-efficient products. Kolbe–Schmitt-type reactions represent the carboxylation of aromatic compounds to their carboxylic acid derivatives. This study was the first and only to systematically investigate, thoroughly explain preparation procedures, and minutely describe the analytical methods of Kolbe–Schmitt and Marasse carboxylation of phenol. Most importantly, this study provides guide

APA, Harvard, Vancouver, ISO, and other styles

46

Yu, Yang, Teng He, Anan Wu, et al. "Back Cover: Reversible Hydrogen Uptake/Release over a Sodium Phenoxide–Cyclohexanolate Pair (Angew. Chem. Int. Ed. 10/2019)." Angewandte Chemie International Edition 58, no. 10 (2019): 3228. http://dx.doi.org/10.1002/anie.201901616.

Full text

APA, Harvard, Vancouver, ISO, and other styles

47

Rodrigue, André, John W. Bovenkamp, Michael P. Murchie, Gerald W. Buchanan, and Suzanne Fortier. "Complexes of 18-crown-6 macrocyclic ethers containing both an alkali metal phenoxide salt and phenol. Crown:salt:phenol ratios of 1:1:1 and 1:1:2." Canadian Journal of Chemistry 65, no. 11 (1987): 2551–57. http://dx.doi.org/10.1139/v87-424.

Full text

Abstract:

Sodium and potassium phenoxide, in the presence of one equivalent of dicyclohexano-18-crown-6 (cis–anti–cis isomer) and dibenzo-18-crown-6, form complexes that have a ratio of 1:1:1 (crown:salt:phenol) in ethereal solvents containing excess phenol. On the other hand, complexes having 1:1:2 ratios (crown:salt:phenol) are obtained under the same conditions when the macrocycle is 18-crown-6 or dicyclohexano-18-crown-6 (cis–syn–cis isomer). When only one equivalent of phenol is present, then 1:1:1 complexes are obtained with 18-crown-6 and dicyclohexano- 18-crown-6 (cis–syn–cis isomer). No complex

APA, Harvard, Vancouver, ISO, and other styles

48

Roitershtein, Dmitrii M., Kseniya I. Minashina, Mikhail E. Minyaev, et al. "Different coordination modes of trans-2-{[(2-methoxyphenyl)imino]methyl}phenoxide in rare-earth complexes: influence of the metal cation radius and the number of ligands on steric congestion and ligand coordination modes." Acta Crystallographica Section C Structural Chemistry 74, no. 10 (2018): 1105–15. http://dx.doi.org/10.1107/s2053229618012421.

Full text

Abstract:

A simple and effective synthetic route to homo- and heteroleptic rare-earth (Ln = Y, La and Nd) complexes with a tridentate Schiff base anion has been demonstrated using exchange reactions of rare-earth chlorides with in-situ-generated sodium (E)-2-{[(2-methoxyphenyl)imino]methyl}phenoxide in different molar ratios in absolute methanol. Five crystal structures have been determined and studied, namely tris(2-{[(2-methoxyphenyl)imino]methyl}phenolato-κ3 O 1,N,O 2)lanthanum, [La(C14H12NO2)3], (1), tris(2-{[(2-methoxyphenyl)imino]methyl}phenolato-κ3 O 1,N,O 2)neodymium tetrahydrofuran disolvate, [

APA, Harvard, Vancouver, ISO, and other styles

49

Samruddhi, Mane, Akash Bhatkar, Marimuthu Prabu, et al. "Selective O-alkylation of Phenol Using Dimethyl Ether." Reactions 3, no. 4 (2022): 602–14. http://dx.doi.org/10.3390/reactions3040040.

Full text

Abstract:

Anisole is a straw-colored aromatic compound mainly used in making solvents, flavoring agents, perfumes, fuel additives, and in the synthesis industries. Anisole, also known as methoxybenzene, is synthesized from sodium phenoxide or phenol using various methylating agents. The use of dimethyl ether (DME) as an alkylating agent is seldom reported in the literature. Herein, we have synthesized anisole through the O-alkylation process of phenol and DME to obtain zero discharge from this process. The thermodynamic equilibrium for the reaction of phenol and DME is simulated by using Aspen HYSYS (Hy

APA, Harvard, Vancouver, ISO, and other styles

50

S., C. Chaudhry, Kumar Anil, Kumari Raj, S. Bhatt S., and Sharma Neeraj. "Synthesis, characterization and reactivity of tin(II) 2,4-dinitrophenoxide." Journal of Indian Chemical Society Vol. 84, Mar 2007 (2007): 230–35. https://doi.org/10.5281/zenodo.5814995.

Full text

Abstract:

Department of Chemistry, Himachal Pradesh University, Summer Hill, Shimla-171 005, Himachal Pradesh, India <em>E-mail</em> : scchaudhry@sanchrnet.in <em>Manuscript received 26 December 2006, accepted 5 January 2007</em> Compound of composition Sn(dnp)<sub>2</sub> (where dnp : anion of 2,4-dinitrophenol i.e.<sup> -</sup>OC<sub>6</sub>H<sub>3</sub>(NO<sub>2</sub>)<sub>2</sub>-2,4) has been synthesized by reacting anhydrous stannous chloride with 2,4-dinitrophenol in the presence of diethylamine in predetermined molar ratios (1 ; 2 : 2) in tetrahydrofuran and characterized by elemental analy

APA, Harvard, Vancouver, ISO, and other styles

We offer discounts on all premium plans for authors whose works are included in thematic literature selections. Contact us to get a unique promo code!