Dissertations / Theses on the topic 'Soil mechanics South Australia'

The annual production of biosolids in the Perth region during the period of this study was approximately 13,800 t dry solids (DS), being supplied by three major wastewater treatment plants. Of this, 70% was typically used as a low-grade fertiliser in agriculture, representing an annual land use area of around 1,600 ha when spread between 5 and 7 t DS/ha. Loading rates of biosolids are typically based on the nitrogen (N) requirements of the crop to be grown, referred to as the N Limiting Biosolids Application Rate (NLBAR). A consequence of using the NLBAR to calculate loading rates is that phosphorus (P) is typically in excess of plant requirement. The resultant high loading rates of P are considered in the guidelines developed for the agricultural use of biosolids in Western Australia, but lack research data specific to local conditions and soil types. Regulatory changes throughout Australia and globally to protect the environment from wastewater pollution have created a need for more accountable and balanced nutrient data. Experiments presented in this thesis were undertaken to ascertain: the percentage relative effectiveness (RE) of biosolids as a source of plant available P compared with inorganic P fertiliser; loading rates to best supply P for optimum crop growth; P loading rates of risk to the environment; and the forms of P in local biosolids. Therefore, both the agronomic and environmental viewpoints were considered. Anaerobically digested and dewatered biosolids produced from Beenyup Wastewater Treatment Plant, Perth with a mean total P content of 2.97% dry weight basis (db) were used in a series of glasshouse, field and laboratory experiments. The biosolids were sequentially fractionated to identify the forms of P present and likewise in soil samples after applying biosolids or monocalcium phosphate (MCP).The biosolid P was predominantly inorganic (92%), and hence the organic fraction (8%) available for mineralisation at all times would be extremely low. The most common forms of biosolid P were water-soluble P and exchangeable inorganic P (66%), followed by bicarbonate extractable P (19%) and the remaining P as inorganic forms associated with Fe, Al and Ca (14%). Following the application of biosolids to a lateritic soil, the Fe and Al soil fractions sorbed large amounts of P, not unlike the distribution of P following the addition of MCP. Further investigation would be required to trace the cycling of biosolid P in the various soil pools. The growth response of wheat (Triticum aestivum L.) to increasing rates of biosolids and comparable rates of inorganic P as MCP, to a maximum of 150 mg P/kg soil was examined in the glasshouse. The percentage relative effectiveness (RE) of biosolids was calculated using fitted curve coefficients from the Mitscherlich equation: y = a (1-b exp–cx) for dry matter (DM) production and P uptake. The initial effectiveness of biosolid P was comparable to that of MCP with the percentage RE of biosolids averaging 106% for DM production of wheat shoots and 118% for shoot P uptake at 33 days after sowing (DAS) over three consecutive crops. The percentage residual value (RV) declined at similar rates for DM production in MCP and biosolids, decreasing to about 33% relative to freshly applied MCP in the second crop and to approximately 16% in the third crop. The effectiveness of biosolid P was reduced significantly compared with inorganic P when applied to a field site 80 km east of Perth (520 mm annual rainfall). An infertile lateritic podsolic soil, consistent with the glasshouse experiment and representative of a soil type typically used for the agricultural application of biosolids in Western Australia was used.Increasing rates of biosolids and comparable rates of triple superphosphate (TSP), to a maximum of 145 kg P/ha were applied to determine a P response curve. The percentage RE was calculated for seasonal DM production, final grain yield and P uptake in wheat followed by lupin (Lupinus angustifolius L.) rotation for the 2001 and 2002 growing seasons, respectively. In the first year of wheat, the RE for P uptake in biosolids compared with top-dressed TSP ranged from 33% to 55% over the season and by grain harvest was 67%. In the second year, and following incorporation with the disc plough at seeding, the RE for P uptake by lupins in biosolids averaged 79% over the growing season compared with top-dressed TSP, and by grain harvest the RE was 60%. The residual value (RV) of lupins at harvest in biosolids compared with freshly applied TSP was 47%. The non-uniform placement of biosolids (i.e. spatial heterogeneity) was primarily responsible for the decreased ability of plant roots to absorb P. The P was more effective where biosolids were finely dispersed throughout the soil, less so when roughly cultivated and least effective when placed on the soil surface without incorporation. The RE for grain harvest of wheat in the field decreased from 67% to 39% where biosolids were not incorporated (i.e. surface-applied). The RE could also be modified by factors such as soil moisture and N availability in the field, although it was possible to keep these variables constant in the glasshouse. Consequently, absolute values determined for the RE need to be treated judiciously. Calculations showed that typical loading rates of biosolids required to satisfy agronomic P requirements of wheat in Western Australia in the first season could vary from 0 to 8.1 t DS/ha, depending on soil factors such as the P Retention Index (PRI) and bicarbonate available P value.Loading rates of biosolids were inadequate for optimum P uptake by wheat at 5 t DS/ha (i.e. 145 kg P/ha) based on the NLBAR on high P sorbing soils with a low fertiliser history (i.e. PRI >15, Colwell bicarbonate extractable P <15 mg P/kg). On soils of PRI <2 mL/g however, biosolids applied at identical loading rates would result in high concentrations of available P. Further work on sites not P deficient would be necessary to validate these findings on farmed soils with a regular history of P fertiliser. The sieving of soil samples used in the field experiment to remove stones and coarse organic matter prior to chemical analysis inadvertently discarded biosolids particles >2 mm, and thus their was little relationship between soil bicarbonate extractable P and P uptake by plants in the field. The risk of P leaching in biosolids-amended soil was examined over a number of different soil types at comparable rates of P at 140 mg P/kg (as either biosolids or MCP) in a laboratory experiment. Given that biosolids are restricted on sites prone to water erosion, the study focussed on the movement of water-soluble P by leaching rather than by runoff of water-soluble P and particulate P. In general the percentage soluble reactive P recovered was lower in soils treated with biosolids than with MCP, as measured in leachate collected using a reverse soil leachate unit. This was particularly evident in acid washed sand with SRP measuring 14% for biosolids and 71% for MCP, respectively, although the differences were not as large in typical agricultural soils. Specific soil properties, such as the PRI, pH, organic carbon and reactive Fe content were negatively correlated to soluble reactive P in leachate and thus reduced the risk of P leaching in biosolids-amended soil.Conversely, the total P and bicarbonate extractable P status of the soils investigated were unreliable indicators as to the amount of P leached. On the basis of the experiments conducted, soils in Western Australia were categorised according to their ability to minimise P enrichment and provide P necessary for crop growth at loading rates determined by the NLBAR. Biosolids applied at the NLBAR to soils of PRI >2mL/g with reactive Fe >200 mg/kg were unlikely to necessitate P loading restrictions. Although specific to anaerobically digested biosolids cake applied to Western Australian soils, the results will be of relevance to any industry involved in the land application of biosolids, to prevent P contamination in water bodies and to make better use of P in crop production.

Diskette for IBM/PC in pocket on back end paper. Copies of author's previously published articles inserted. Bibliography: leaves 186-207. An evaluation of spatial and temporal variation in composition of soil solutions collected from a hydro-toposequence with seasonally saturated soils ranging from Xeralfs to Aqualfs. The sub-catchment is under native eucalyptus and is formed from granite gneiss. The study shows that mineral weathering under eucalypt vegetation contributes substantially to the quantity of elements measured in soil solution with some aeolian salts. Migration of soil solutions to low lying areas promotes dryland salinity in these landscapes.

The annual production of biosolids in the Perth region during the period of this study was approximately 13,800 t dry solids (DS), being supplied by three major wastewater treatment plants. Of this, 70% was typically used as a low-grade fertiliser in agriculture, representing an annual land use area of around 1,600 ha when spread between 5 and 7 t DS/ha. Loading rates of biosolids are typically based on the nitrogen (N) requirements of the crop to be grown, referred to as the N Limiting Biosolids Application Rate (NLBAR). A consequence of using the NLBAR to calculate loading rates is that phosphorus (P) is typically in excess of plant requirement. The resultant high loading rates of P are considered in the guidelines developed for the agricultural use of biosolids in Western Australia, but lack research data specific to local conditions and soil types. Regulatory changes throughout Australia and globally to protect the environment from wastewater pollution have created a need for more accountable and balanced nutrient data. Experiments presented in this thesis were undertaken to ascertain: the percentage relative effectiveness (RE) of biosolids as a source of plant available P compared with inorganic P fertiliser; loading rates to best supply P for optimum crop growth; P loading rates of risk to the environment; and the forms of P in local biosolids. Therefore, both the agronomic and environmental viewpoints were considered. Anaerobically digested and dewatered biosolids produced from Beenyup Wastewater Treatment Plant, Perth with a mean total P content of 2.97% dry weight basis (db) were used in a series of glasshouse, field and laboratory experiments. The biosolids were sequentially fractionated to identify the forms of P present and likewise in soil samples after applying biosolids or monocalcium phosphate (MCP).<br>The biosolid P was predominantly inorganic (92%), and hence the organic fraction (8%) available for mineralisation at all times would be extremely low. The most common forms of biosolid P were water-soluble P and exchangeable inorganic P (66%), followed by bicarbonate extractable P (19%) and the remaining P as inorganic forms associated with Fe, Al and Ca (14%). Following the application of biosolids to a lateritic soil, the Fe and Al soil fractions sorbed large amounts of P, not unlike the distribution of P following the addition of MCP. Further investigation would be required to trace the cycling of biosolid P in the various soil pools. The growth response of wheat (Triticum aestivum L.) to increasing rates of biosolids and comparable rates of inorganic P as MCP, to a maximum of 150 mg P/kg soil was examined in the glasshouse. The percentage relative effectiveness (RE) of biosolids was calculated using fitted curve coefficients from the Mitscherlich equation: y = a (1-b exp–cx) for dry matter (DM) production and P uptake. The initial effectiveness of biosolid P was comparable to that of MCP with the percentage RE of biosolids averaging 106% for DM production of wheat shoots and 118% for shoot P uptake at 33 days after sowing (DAS) over three consecutive crops. The percentage residual value (RV) declined at similar rates for DM production in MCP and biosolids, decreasing to about 33% relative to freshly applied MCP in the second crop and to approximately 16% in the third crop. The effectiveness of biosolid P was reduced significantly compared with inorganic P when applied to a field site 80 km east of Perth (520 mm annual rainfall). An infertile lateritic podsolic soil, consistent with the glasshouse experiment and representative of a soil type typically used for the agricultural application of biosolids in Western Australia was used.<br>Increasing rates of biosolids and comparable rates of triple superphosphate (TSP), to a maximum of 145 kg P/ha were applied to determine a P response curve. The percentage RE was calculated for seasonal DM production, final grain yield and P uptake in wheat followed by lupin (Lupinus angustifolius L.) rotation for the 2001 and 2002 growing seasons, respectively. In the first year of wheat, the RE for P uptake in biosolids compared with top-dressed TSP ranged from 33% to 55% over the season and by grain harvest was 67%. In the second year, and following incorporation with the disc plough at seeding, the RE for P uptake by lupins in biosolids averaged 79% over the growing season compared with top-dressed TSP, and by grain harvest the RE was 60%. The residual value (RV) of lupins at harvest in biosolids compared with freshly applied TSP was 47%. The non-uniform placement of biosolids (i.e. spatial heterogeneity) was primarily responsible for the decreased ability of plant roots to absorb P. The P was more effective where biosolids were finely dispersed throughout the soil, less so when roughly cultivated and least effective when placed on the soil surface without incorporation. The RE for grain harvest of wheat in the field decreased from 67% to 39% where biosolids were not incorporated (i.e. surface-applied). The RE could also be modified by factors such as soil moisture and N availability in the field, although it was possible to keep these variables constant in the glasshouse. Consequently, absolute values determined for the RE need to be treated judiciously. Calculations showed that typical loading rates of biosolids required to satisfy agronomic P requirements of wheat in Western Australia in the first season could vary from 0 to 8.1 t DS/ha, depending on soil factors such as the P Retention Index (PRI) and bicarbonate available P value.<br>Loading rates of biosolids were inadequate for optimum P uptake by wheat at 5 t DS/ha (i.e. 145 kg P/ha) based on the NLBAR on high P sorbing soils with a low fertiliser history (i.e. PRI >15, Colwell bicarbonate extractable P <15 mg P/kg). On soils of PRI <2 mL/g however, biosolids applied at identical loading rates would result in high concentrations of available P. Further work on sites not P deficient would be necessary to validate these findings on farmed soils with a regular history of P fertiliser. The sieving of soil samples used in the field experiment to remove stones and coarse organic matter prior to chemical analysis inadvertently discarded biosolids particles >2 mm, and thus their was little relationship between soil bicarbonate extractable P and P uptake by plants in the field. The risk of P leaching in biosolids-amended soil was examined over a number of different soil types at comparable rates of P at 140 mg P/kg (as either biosolids or MCP) in a laboratory experiment. Given that biosolids are restricted on sites prone to water erosion, the study focussed on the movement of water-soluble P by leaching rather than by runoff of water-soluble P and particulate P. In general the percentage soluble reactive P recovered was lower in soils treated with biosolids than with MCP, as measured in leachate collected using a reverse soil leachate unit. This was particularly evident in acid washed sand with SRP measuring 14% for biosolids and 71% for MCP, respectively, although the differences were not as large in typical agricultural soils. Specific soil properties, such as the PRI, pH, organic carbon and reactive Fe content were negatively correlated to soluble reactive P in leachate and thus reduced the risk of P leaching in biosolids-amended soil.<br>Conversely, the total P and bicarbonate extractable P status of the soils investigated were unreliable indicators as to the amount of P leached. On the basis of the experiments conducted, soils in Western Australia were categorised according to their ability to minimise P enrichment and provide P necessary for crop growth at loading rates determined by the NLBAR. Biosolids applied at the NLBAR to soils of PRI >2mL/g with reactive Fe >200 mg/kg were unlikely to necessitate P loading restrictions. Although specific to anaerobically digested biosolids cake applied to Western Australian soils, the results will be of relevance to any industry involved in the land application of biosolids, to prevent P contamination in water bodies and to make better use of P in crop production.

Plantations provide a range of benefits, including the potential to ameliorate salinity and soil erosion, enhance biodiversity, and provide timber and wood chips. They are increasingly important because of their role in carbon sequestration (Adolphson, 2000; Anonymous, 2005; Jones et al. , 2005; Kozlowski, 2002; Paul and Polglase, 2004). Recent research has highlighted the connection between plantation health and soil fertility (Johnston and Crossley Jr, 2002). Within an Australian context there is little published data on the composition of the soil and litter fauna and their contribution to litter decomposition under plantation systems (Adolphson, 2000). The Albany Effluent Irrigated Tree Farm provided an opportunity to research plantation (Eucalyptus globulus ) soil flora and fauna communities, rates of litter decomposition and to describe the impact of irrigation (both mains-water and effluent) on these communities.

Bibliography: leaves 164-193. This study aims to quantify the belowground input of organic carbon by barrel medic using techniques that account for root death and decomposition as well as root secretion and exudation. It also investigates the effect of defoliation on carbon allocation within the plant so as to determine the potential for optimising carbon input to the soil through grazing management.

Bauxite mining is a major activity in the jarrah (Eucalyptus marginata Donn ex Sm.) forest of south-western Australia. After mining, poor tree growth can occur in some areas. This thesis aimed to determine whether soil constraints, including reduced depth and compaction, were responsible for poor tree growth at low-quality restored bauxite mines. In particular, this study determined the response of jarrah root morphology, leaf-scale physiology and growth/development to soil constraints at two contrasting (low-quality and high-quality) restored bauxite-mine sites. Jarrah root excavations at a low-quality restored site revealed that deep-ripping equipment failed to penetrate the cemented lateritic subsoil, causing coarse roots to be restricted to the top 0.5 m of the soil profile, resulting in fewer and smaller jarrah trees. An adjacent area within the same mine pit (high-quality site) had a kaolinitic clay subsoil, which coarse roots were able to penetrate to the average ripping depth of 1.5 m. Impenetrable subsoil prevented development of taproots at the low-quality site, with trees instead producing multiple lateral and sinker roots. Trees in riplines, made by deep-ripping, at the high-quality site accessed the subsoil via a major taproot, while those on crests developed large lateral and sinker roots. Bauxite mining is a major activity in the jarrah (Eucalyptus marginata Donn ex Sm.) forest of south-western Australia. After mining, poor tree growth can occur in some areas. This thesis aimed to determine whether soil constraints, including reduced depth and compaction, were responsible for poor tree growth at low-quality restored bauxite mines. In particular, this study determined the response of jarrah root morphology, leaf-scale physiology and growth/development to soil constraints at two contrasting (low-quality and high-quality) restored bauxite-mine sites. Jarrah root excavations at a low-quality restored site revealed that deep-ripping equipment failed to penetrate the cemented lateritic subsoil, causing coarse roots to be restricted to the top 0.5 m of the soil profile, resulting in fewer and smaller jarrah trees. An adjacent area within the same mine pit (high-quality site) had a kaolinitic clay subsoil, which coarse roots were able to penetrate to the average ripping depth of 1.5 m. Impenetrable subsoil prevented development of taproots at the low-quality site, with trees instead producing multiple lateral and sinker roots. Trees in riplines, made by deep-ripping, at the high-quality site accessed the subsoil via a major taproot, while those on crests developed large lateral and sinker roots.

This thesis examines the response to P fertiliser by wheat crops growing in the vertosol soils of the low rainfall areas of the northern grain zone of eastern Australia. Farmers in this region depend on water accumulated from rainfall over a fallow period and stored in the subsoil to increase wheat grain yield beyond that normally achievable from in-crop rainfall and to decrease the production risks due to rainfall variability. The large variability in stored water, seasonal rainfall and subsoil properties result in extremely varied yield and yield responses to P fertiliser between seasons and between sites. Finally, as a practical guide to predicting wheat response to P fertilizer: 1/. current sampling strategies of determining P only in the surface 10 cm appear to be adequate for soils with bicarbonate P concentrations greater than 15 mg/kg. 2/. For soils with lower concentrations in the surface, sampling of 80 cm is recommended. Crops with a mean concentration of bicarbonate P greater than 7 mg/kg between 10 - 80 cm are unlikely to respond to P fertiliser. 3/. No increase in profitable grain yield response was found for fertiliser applications greater than 10 kg P/ha.<br>Doctor of Philosophy (PhD)

Copy of author's previously published work inserted. Bibliography: leaves 261-306. The objectives of the project were: i. to determine whether there are competitive interactions between Aporrectodea trapezoides and A. caliginosa and A. rosea.--ii. to investigate compeditive interactions between A. calignosa, Microscolex dubius and A. trapezoides.--iii . to determine the likely impact of A. longa on soil fauna, especially the native earthworm, Gemascolex lateralis, in native ecosystems.

Spicers Creek catchment is located approximately 400 km west of Sydney in the Central West region of New South Wales, Australia. Dryland salinity has been recognised as a major environmental issue impacting soil and water resources in the Central West region of NSW for over 70 years. Due to the geological complexity of the catchment and the presence of high salt loads contained within the soils, groundwater and surface waters, the Spicers Creek catchment was identified as a large contributor of salinity to the Macquarie River catchment. Over fifty-two dryland salinity occurrences have been identified in the Spicers Creek catchment and it appears that dryland salinity is controlled by the presence of geological structures and permeability contrasts in the shallow aquifer system. Combinations of climatic, geological and agricultural factors are escalating salinity problems in the catchment. The main aim of this thesis was to identify the factors affecting salinisation processes in the Spicers Creek catchment. These include the role of geological structures, the source(s) of salts to the groundwater system and the geochemical processes influencing seepage zone development. To achieve these aims a multidisciplinary approach was untaken to understand the soils, geology, hydrogeology and hydrogeochemistry of the catchment. Investigative techniques employed in this project include the use of geophysics, soil chemistry, soil spectroscopy, hydrogeochemistry and environmental isotopes. Evaluation of high-resolution airborne magnetics data showed a major north-east to south-west trending shear zone. This structure dissects the catchment and several other minor faults were observed to be splays off this major structure. These structures were found to be conducive to groundwater flow and are influencing the groundwater chemistry in the fractured aquifer system. Two distinctive groundwater chemical types were identified in the catchment; the saline Na(Mg)-Cl-rich groundwaters associated with the fractured Oakdale Formation and the Na-HCO3-rich groundwaters associated with the intermediate groundwater system. The groundwater chemistry of other deep groundwaters in the catchment appears to be due to mixing between these end-member groundwaters within the fractured bedrock system. The spatial distribution of electrical conductivity, Cl-, Sr2+ and 87Sr/86Sr isotopic ratios showed the correlation between saline groundwaters and the location of faults. Elevated salinities were associated with the location of two crosscutting fault zones. The spatial distribution of HCO3-, K+, Li+ and ?????3CDIC highlighted the extent of Na-HCO3-rich groundwaters in the catchment and showed that these groundwaters are mixing further east than previously envisaged. These findings show that Na(Mg)-Cl-rich groundwaters are geochemically distinctive and have evolved due to extensive water-rock interaction processes within the fracture zones of the Oakdale Formation. These saline groundwaters contain elevated concentrations of trace elements such as As, V and Se, which pose a potential risk for water resources in the area. 87Sr/86Sr isotopic ratios indicated that the source of salinity to the Na(Mg)-Cl-rich groundwaters was not purely from marine or aerosol input. Salt is most likely contributed from various allochthonous and autochthonous sources. This research found that the main mechanism controlling the formation of dryland salinity seepage zones in the Spicers Creek catchment is due to the presence of geological structures. These groundwater seepage zones act as mixing zones for rainfall recharge and deeper groundwaters. The main sources of salt to the seepage zones are from deeper Na(Mg)-Cl-rich groundwaters and rainfall accession. The major importance of this research highlights the need for an integrated approach for the use of various geoscientific techniques in dryland salinity research within geologically complex environments.

This thesis is an evaluation of the use the USLE to estimate soil loss from two pastoral land uses - commercial properties and "hobby farms" in Murrumbateman. Sensitivity analysis was used to evaluate the USLE components. Sediment measurement in farm dams was taken to estimate sediment yield from several sites, as an alternative approach to study soil loss. The annual soil loss from entire study area was 0.25 t/ha/year whilst these figures from commercial properties and hobby farms were 0.29 t/ha/year and 0.21 t/ha/year, respectively. The annual average sediment yield from three catchments in hobby farms was 0.3 t/ha/year. The USLE was found to be highly sensitive to slope steepness, ground cover and stocking rates. The critical values were 16% for slopes, 35% for the ground cover and 19 Dry Sheep Equivalent/ha for stocking rate. I tentatively conclude that the USLE is sufficiently sensitive to detect differences in soil loss between the two land uses. There is, however, a need to improve the operation of the model in some respects. The use of farm dams for estimating sediment yield also shows promise.

Following over 100 years of agriculture and continuous phosphorus (P) fertilizer application in the south west of Western Australia, there is a growing risk of P transport from cropping and pasture land to streams. However, soil and landscape factors affecting the likelihood of P losses and of stream water contamination have not yet been assessed for the South coast region of Western Australia. The present investigation was conducted in the Fitzgerald River catchment located ~ 400 km south east of Perth, to identify risk of P losses from agricultural land to streams, through an understanding of how P is retained within complex landscapes and released via surface and subsurface flow paths. The 104,000 ha catchment is in a moderately dissected landscape (average annual rainfall 450 mm) and discharges into the World Heritage listed Fitzgerald Biosphere. The main use of cleared land in the catchment is broad-scale agriculture, primarily winter grain cropping and pasture for livestock. The aim of an initial study was to identify the areas with high soil P concentrations and their relationship to factors such as soil type, topography, management (e.g. fertilizer and manure inputs, and uptake by crops or forage) and how variations in soil P concentrations were related to soil physico-chemical properties, P fertilizer management and landscape position. A wide variation in P concentrations was observed across the catchment, but few of the samples exceeded Colwell extractable P levels of 30 mg/kg in the 0-10 cm layer which is regarded as a critical level for crop and pasture productivity. The western area of the catchment, which was cleared earlier (before 1966) than the eastern area had a greater prevalence of loam soils, and higher Colwell-extractable P concentrations (average)22 mg/kg vs. 13 mg P/kg) due to soil type effects and higher P accumulation over time. Risk of P loss from the east and west of the catchment is expected to vary due to textural and topographic differences and P history (P fertilizer input and uptake by crops). The CaCl2-extractable P in the catchment was negatively correlated with oxalate extractable Fe (Feox) in soils. This suggests that P may be transported as particulate P (PP) on loam and clay soils due to sorption of P on oxides surfaces, while on sand soil leaching losses may be more likely. On loam and clay soils, higher sodicity and the dispersive nature of subsoils may increase the risk of both dissolved P (DP) and PP loss due to the effects on hydraulic conductivity of the profile. Hedley's fractionation scheme was used to quantify P fractions in the order of decreasing lability, viz: resin-P > NaOH-Pi > NaOH-Po > acid-P (H2SO4-P) > residual-P. Surface soil had higher resin and NaOH-Pi, which are regarded as water-soluble and readily exchangeable P forms, respectively and expected to contribute to DP in the runoff losses. The residual P was the largest fraction followed by the hydroxide extractable organic-P fraction (NaOH-Po): the former was positively correlated (r) with clay content, organic carbon (OC) and pyrophosphate extractable Fe and Al (0.48**, 0.61**, 0.69** and 0.58**, P < 0.01). A relatively higher value of NaOH-Po in the subsurface layer and positive correlation with OC (r = 0.45**, P < 0.01) suggests potential mobility of P as soluble organic P in run-off, throughflow and leachate. Phosphorus sorption and its relationship to soil properties was used to assess the potential P release from the catchment soils. Values of P sorption maxima varied from 1111-3333 mg/kg for surface soils and 1010-2917 mg/kg for subsoils. The P sorption isotherms conformed better to the Freundlich equation than the Langmuir equation. A highly significant negative correlation between CaCl2 extractable P and Feox in surface soils (r = -0.65**, P < 0.01) suggests that P was bound to hydrated Fe oxide surfaces and this may determine the concentration and dynamics of loosely bound P equilibrating with leachates and eroded particulate materials. On the other hand, high surface organic matter and the high proportion of total dissolved P in organically bound form may inhibit P sorption on clays and sesquioxides, which would increase P mobility through leaching or runoff losses. The relationship between soil P concentration and degree of P stratification in the top 0-10 cm of soils along five toposequences was examined to predict the effect on runoff P losses. The total Colwell-P content of the 0-10 cm layer of soils in the catchment was very low in comparison to other studies on P losses from agricultural soils, but soils showed higher P concentration at 0-1 cm depth compared to 5-10 cm (average 37 mg/kg vs. 19 mg/kg). The higher extractable P concentration in the 0-1 cm layer will create a greater P mobilization risk in surface runoff and leachate than analysis of the 0-10 cm layer might suggest. Assessment of P risk using the 0-10 cm data would still be reliable as P concentration in the 0-1 cm layer was linearly related (R2 = 0.59) with concentration in the 0-10 cm layer. The sampling at varied soil depths will result in different critical P levels for estimating the risk of P enrichment in runoff. In a glasshouse study with intact soil columns, initial high P concentrations in leachate decreased with leaching events suggesting that macropore flow dominated in initial leaching events changing later to matrix flow. The hydraulic behavior of clay and loam soil below 10 cm depends largely on structure and the type of clay minerals and exchangeable Na. Higher levels of exchangeable Na in the subsoil might increase dispersion of clay particles resulting in low permeability leading to ponding of surface water or lateral movement of water at the interface of sand A and clay B horizons. Lateral water movements increase the risk of P losses in the form of DP, dissolved organic P (DOP) or PP. The P concentration in all the P forms (DRP, DOP and TDP) increased significantly with P rates of application (P < 0.01). The DRP concentration was < 2 mg/l in unfertilized columns but an increase to 11 mg/l was observed with P application at 40 kg P/ha. The higher proportion of DOP relative to DRP and its correlation with TDP indicates that the DOP was the major form of P in leachate. However, the estimation of DOP which was by subtraction of DRP from TDP generally overestimates OP concentration. The TDP load from unfertilized soil was < 0.20 mg/l in runoff and < 2.40 mg/l in throughflow but increased with P application (20, 40 kg P/ha) for both packed box and field studies. Under field conditions, higher P loss was found with broadcast P application compared to drill placement. The higher load of DOP as a proportion of TDP and its significant relationship with TDP in runoff (R2sand = 0.81; R2clay = 0.79) and throughflow (R2sand = 0.94; R2clay = 0.98) in field and box studies also suggests DOP was the major form of P loss from soil. Dissolved OP concentration increased significantly with increase in soluble organic carbon (SOC) in soil solution at 5 cm depth (P < 0.05). Consequently, the amount of organic matter dissolved in soil solution may influence P sorption and mobility. Relatively higher affinity of soil for sorption of DRP compared to DOP might allow DOP to be more mobile through the profile. Higher PP load in clay soil in throughflow indicates subsurface lateral flow along the interface with the horizon of dispersive clay might be an additional risk factor regarding P mobility in clay soils of the catchment. The runoff, throughflow and leachate were dominated by eroded particles of clay and colloidal organic materials. However, the soil solution collected though 0.1 m pores in the Rhizon samplers had a similar dominance of DOP to the < 0.45 jum filtered samples in runoff and throughflow. This reduces the likelihood that the so-called DOP fraction was mostly P associated with PP in the 0.1 to 0.45 jum size fraction. The composition of DOP in soil solution collected through Rhizon samplers (< 0.1 jum) might provide important insights for P mobility since this more effectively excluded PP than in the < 0.45 jum filtrate used for runoff and throughflow samples. The DOP in soil solution (< 0.1 jum) might be associated with fine colloidal compound such as silicates, metallic hydroxides, humic acids, polysaccharides, fulvic acids and proteins. If so, then most, but not all of the DOP fraction would be organically bound. However, this requires verification. In conclusion, soil P levels across the catchment were never very high when assessed in the 0-10 cm layer, but levels in the 0-1 cm layer were more than twice as high. Overall, < 1 % of land area of the upper Fitzgerald River catchment had Colwell-P levels > 30 mg/kg (0-10 cm) and hydrological connection to streams. In addition, another 7 % of land had Colwell-P levels > 15 mg/kg, which appears to be a change point in soils for the release of CaCl2 extractable P. These areas, which are predicted to represent critical source areas of the catchment, need careful management. The high proportions of TDP as DOP in runoff, throughflow and soil solution suggest DOP was the major form of P loss from soil. Phosphorus losses from the catchments are also likely in the form of PP in clay and loam soil but leaching losses are more likely in sand. High exchangeable Na in the subsoil of loam and clay soils increases dispersion of clay particles resulting in low permeability of subsoil and greater lateral P mobility as throughflow at the interface of sand and clay textured horizons. In general, soils of Fitzgerald River catchment had low soil P, but nevertheless significant risk of P loss at Colwell-P > 15 mg/kg. This study provides baseline information for P loss risks in the wheatbelt of WA. Stream water quality monitoring instruments were installed in the upper Fitzgerald River Catchment at 5 stream locations by CSIRO to measure base line concentrations of P. The measured P concentrations were higher than ANZECC trigger values (> 0.05 mg P/l) for management response over the three-year monitoring period (2005-07). Hence this and many other catchments on the south coast and wheatbelt of south west Western Australia need assessment for P loss risks. Previous emphasis in south west Western Australia on P losses from sandy coastal soils under pasture may need to be reconsidered. In the South coast region, cropping land in the medium rainfall zone may still represent a risk of P loss to waterways and risk to water quality. The present study evaluated the risk of P loss based on soil P forms and their mobility. It suggests greater attention needs to be given to the difference between clay and loam soils with dispersive or non-dispersive sub-soils, and to the composition and mobility of DOP. However, a more complete understanding of P loss risks depends on follow-up studies on hydrological flow and connectivity in the upper Fitzgerald River catchment and similar landscapes of south west Western Australia.

Following over 100 years of agriculture and continuous phosphorus (P) fertilizer application in the south west of Western Australia, there is a growing risk of P transport from cropping and pasture land to streams. However, soil and landscape factors affecting the likelihood of P losses and of stream water contamination have not yet been assessed for the South coast region of Western Australia. The present investigation was conducted in the Fitzgerald River catchment located ~ 400 km south east of Perth, to identify risk of P losses from agricultural land to streams, through an understanding of how P is retained within complex landscapes and released via surface and subsurface flow paths. The 104,000 ha catchment is in a moderately dissected landscape (average annual rainfall 450 mm) and discharges into the World Heritage listed Fitzgerald Biosphere. The main use of cleared land in the catchment is broad-scale agriculture, primarily winter grain cropping and pasture for livestock. The aim of an initial study was to identify the areas with high soil P concentrations and their relationship to factors such as soil type, topography, management (e.g. fertilizer and manure inputs, and uptake by crops or forage) and how variations in soil P concentrations were related to soil physico-chemical properties, P fertilizer management and landscape position. A wide variation in P concentrations was observed across the catchment, but few of the samples exceeded Colwell extractable P levels of 30 mg/kg in the 0-10 cm layer which is regarded as a critical level for crop and pasture productivity. The western area of the catchment, which was cleared earlier (before 1966) than the eastern area had a greater prevalence of loam soils, and higher Colwell-extractable P concentrations (average)22 mg/kg vs. 13 mg P/kg) due to soil type effects and higher P accumulation over time. Risk of P loss from the east and west of the catchment is expected to vary due to textural and topographic differences and P history (P fertilizer input and uptake by crops). The CaCl2-extractable P in the catchment was negatively correlated with oxalate extractable Fe (Feox) in soils. This suggests that P may be transported as particulate P (PP) on loam and clay soils due to sorption of P on oxides surfaces, while on sand soil leaching losses may be more likely. On loam and clay soils, higher sodicity and the dispersive nature of subsoils may increase the risk of both dissolved P (DP) and PP loss due to the effects on hydraulic conductivity of the profile. Hedley's fractionation scheme was used to quantify P fractions in the order of decreasing lability, viz: resin-P > NaOH-Pi > NaOH-Po > acid-P (H2SO4-P) > residual-P. Surface soil had higher resin and NaOH-Pi, which are regarded as water-soluble and readily exchangeable P forms, respectively and expected to contribute to DP in the runoff losses. The residual P was the largest fraction followed by the hydroxide extractable organic-P fraction (NaOH-Po): the former was positively correlated (r) with clay content, organic carbon (OC) and pyrophosphate extractable Fe and Al (0.48**, 0.61**, 0.69** and 0.58**, P < 0.01). A relatively higher value of NaOH-Po in the subsurface layer and positive correlation with OC (r = 0.45**, P < 0.01) suggests potential mobility of P as soluble organic P in run-off, throughflow and leachate. Phosphorus sorption and its relationship to soil properties was used to assess the potential P release from the catchment soils. Values of P sorption maxima varied from 1111-3333 mg/kg for surface soils and 1010-2917 mg/kg for subsoils. The P sorption isotherms conformed better to the Freundlich equation than the Langmuir equation. A highly significant negative correlation between CaCl2 extractable P and Feox in surface soils (r = -0.65**, P < 0.01) suggests that P was bound to hydrated Fe oxide surfaces and this may determine the concentration and dynamics of loosely bound P equilibrating with leachates and eroded particulate materials. On the other hand, high surface organic matter and the high proportion of total dissolved P in organically bound form may inhibit P sorption on clays and sesquioxides, which would increase P mobility through leaching or runoff losses. The relationship between soil P concentration and degree of P stratification in the top 0-10 cm of soils along five toposequences was examined to predict the effect on runoff P losses. The total Colwell-P content of the 0-10 cm layer of soils in the catchment was very low in comparison to other studies on P losses from agricultural soils, but soils showed higher P concentration at 0-1 cm depth compared to 5-10 cm (average 37 mg/kg vs. 19 mg/kg). The higher extractable P concentration in the 0-1 cm layer will create a greater P mobilization risk in surface runoff and leachate than analysis of the 0-10 cm layer might suggest. Assessment of P risk using the 0-10 cm data would still be reliable as P concentration in the 0-1 cm layer was linearly related (R2 = 0.59) with concentration in the 0-10 cm layer. The sampling at varied soil depths will result in different critical P levels for estimating the risk of P enrichment in runoff. In a glasshouse study with intact soil columns, initial high P concentrations in leachate decreased with leaching events suggesting that macropore flow dominated in initial leaching events changing later to matrix flow. The hydraulic behavior of clay and loam soil below 10 cm depends largely on structure and the type of clay minerals and exchangeable Na. Higher levels of exchangeable Na in the subsoil might increase dispersion of clay particles resulting in low permeability leading to ponding of surface water or lateral movement of water at the interface of sand A and clay B horizons. Lateral water movements increase the risk of P losses in the form of DP, dissolved organic P (DOP) or PP. The P concentration in all the P forms (DRP, DOP and TDP) increased significantly with P rates of application (P < 0.01). The DRP concentration was < 2 mg/l in unfertilized columns but an increase to 11 mg/l was observed with P application at 40 kg P/ha. The higher proportion of DOP relative to DRP and its correlation with TDP indicates that the DOP was the major form of P in leachate. However, the estimation of DOP which was by subtraction of DRP from TDP generally overestimates OP concentration. The TDP load from unfertilized soil was < 0.20 mg/l in runoff and < 2.40 mg/l in throughflow but increased with P application (20, 40 kg P/ha) for both packed box and field studies. Under field conditions, higher P loss was found with broadcast P application compared to drill placement. The higher load of DOP as a proportion of TDP and its significant relationship with TDP in runoff (R2sand = 0.81; R2clay = 0.79) and throughflow (R2sand = 0.94; R2clay = 0.98) in field and box studies also suggests DOP was the major form of P loss from soil. Dissolved OP concentration increased significantly with increase in soluble organic carbon (SOC) in soil solution at 5 cm depth (P < 0.05). Consequently, the amount of organic matter dissolved in soil solution may influence P sorption and mobility. Relatively higher affinity of soil for sorption of DRP compared to DOP might allow DOP to be more mobile through the profile. Higher PP load in clay soil in throughflow indicates subsurface lateral flow along the interface with the horizon of dispersive clay might be an additional risk factor regarding P mobility in clay soils of the catchment. The runoff, throughflow and leachate were dominated by eroded particles of clay and colloidal organic materials. However, the soil solution collected though 0.1 m pores in the Rhizon samplers had a similar dominance of DOP to the < 0.45 jum filtered samples in runoff and throughflow. This reduces the likelihood that the so-called DOP fraction was mostly P associated with PP in the 0.1 to 0.45 jum size fraction. The composition of DOP in soil solution collected through Rhizon samplers (< 0.1 jum) might provide important insights for P mobility since this more effectively excluded PP than in the < 0.45 jum filtrate used for runoff and throughflow samples. The DOP in soil solution (< 0.1 jum) might be associated with fine colloidal compound such as silicates, metallic hydroxides, humic acids, polysaccharides, fulvic acids and proteins. If so, then most, but not all of the DOP fraction would be organically bound. However, this requires verification. In conclusion, soil P levels across the catchment were never very high when assessed in the 0-10 cm layer, but levels in the 0-1 cm layer were more than twice as high. Overall, < 1 % of land area of the upper Fitzgerald River catchment had Colwell-P levels > 30 mg/kg (0-10 cm) and hydrological connection to streams. In addition, another 7 % of land had Colwell-P levels > 15 mg/kg, which appears to be a change point in soils for the release of CaCl2 extractable P. These areas, which are predicted to represent critical source areas of the catchment, need careful management. The high proportions of TDP as DOP in runoff, throughflow and soil solution suggest DOP was the major form of P loss from soil. Phosphorus losses from the catchments are also likely in the form of PP in clay and loam soil but leaching losses are more likely in sand. High exchangeable Na in the subsoil of loam and clay soils increases dispersion of clay particles resulting in low permeability of subsoil and greater lateral P mobility as throughflow at the interface of sand and clay textured horizons. In general, soils of Fitzgerald River catchment had low soil P, but nevertheless significant risk of P loss at Colwell-P > 15 mg/kg. This study provides baseline information for P loss risks in the wheatbelt of WA. Stream water quality monitoring instruments were installed in the upper Fitzgerald River Catchment at 5 stream locations by CSIRO to measure base line concentrations of P. The measured P concentrations were higher than ANZECC trigger values (> 0.05 mg P/l) for management response over the three-year monitoring period (2005-07). Hence this and many other catchments on the south coast and wheatbelt of south west Western Australia need assessment for P loss risks. Previous emphasis in south west Western Australia on P losses from sandy coastal soils under pasture may need to be reconsidered. In the South coast region, cropping land in the medium rainfall zone may still represent a risk of P loss to waterways and risk to water quality. The present study evaluated the risk of P loss based on soil P forms and their mobility. It suggests greater attention needs to be given to the difference between clay and loam soils with dispersive or non-dispersive sub-soils, and to the composition and mobility of DOP. However, a more complete understanding of P loss risks depends on follow-up studies on hydrological flow and connectivity in the upper Fitzgerald River catchment and similar landscapes of south west Western Australia.

Following over 100 years of agriculture and continuous phosphorus (P) fertilizer application in the south west of Western Australia, there is a growing risk of P transport from cropping and pasture land to streams. However, soil and landscape factors affecting the likelihood of P losses and of stream water contamination have not yet been assessed for the South coast region of Western Australia. The present investigation was conducted in the Fitzgerald River catchment located ~ 400 km south east of Perth, to identify risk of P losses from agricultural land to streams, through an understanding of how P is retained within complex landscapes and released via surface and subsurface flow paths. The 104,000 ha catchment is in a moderately dissected landscape (average annual rainfall 450 mm) and discharges into the World Heritage listed Fitzgerald Biosphere. The main use of cleared land in the catchment is broad-scale agriculture, primarily winter grain cropping and pasture for livestock. The aim of an initial study was to identify the areas with high soil P concentrations and their relationship to factors such as soil type, topography, management (e.g. fertilizer and manure inputs, and uptake by crops or forage) and how variations in soil P concentrations were related to soil physico-chemical properties, P fertilizer management and landscape position. A wide variation in P concentrations was observed across the catchment, but few of the samples exceeded Colwell extractable P levels of 30 mg/kg in the 0-10 cm layer which is regarded as a critical level for crop and pasture productivity. The western area of the catchment, which was cleared earlier (before 1966) than the eastern area had a greater prevalence of loam soils, and higher Colwell-extractable P concentrations (average)22 mg/kg vs. 13 mg P/kg) due to soil type effects and higher P accumulation over time. Risk of P loss from the east and west of the catchment is expected to vary due to textural and topographic differences and P history (P fertilizer input and uptake by crops). The CaCl2-extractable P in the catchment was negatively correlated with oxalate extractable Fe (Feox) in soils. This suggests that P may be transported as particulate P (PP) on loam and clay soils due to sorption of P on oxides surfaces, while on sand soil leaching losses may be more likely. On loam and clay soils, higher sodicity and the dispersive nature of subsoils may increase the risk of both dissolved P (DP) and PP loss due to the effects on hydraulic conductivity of the profile. Hedley's fractionation scheme was used to quantify P fractions in the order of decreasing lability, viz: resin-P > NaOH-Pi > NaOH-Po > acid-P (H2SO4-P) > residual-P. Surface soil had higher resin and NaOH-Pi, which are regarded as water-soluble and readily exchangeable P forms, respectively and expected to contribute to DP in the runoff losses. The residual P was the largest fraction followed by the hydroxide extractable organic-P fraction (NaOH-Po): the former was positively correlated (r) with clay content, organic carbon (OC) and pyrophosphate extractable Fe and Al (0.48**, 0.61**, 0.69** and 0.58**, P < 0.01). A relatively higher value of NaOH-Po in the subsurface layer and positive correlation with OC (r = 0.45**, P < 0.01) suggests potential mobility of P as soluble organic P in run-off, throughflow and leachate. Phosphorus sorption and its relationship to soil properties was used to assess the potential P release from the catchment soils. Values of P sorption maxima varied from 1111-3333 mg/kg for surface soils and 1010-2917 mg/kg for subsoils. The P sorption isotherms conformed better to the Freundlich equation than the Langmuir equation. A highly significant negative correlation between CaCl2 extractable P and Feox in surface soils (r = -0.65**, P < 0.01) suggests that P was bound to hydrated Fe oxide surfaces and this may determine the concentration and dynamics of loosely bound P equilibrating with leachates and eroded particulate materials. On the other hand, high surface organic matter and the high proportion of total dissolved P in organically bound form may inhibit P sorption on clays and sesquioxides, which would increase P mobility through leaching or runoff losses. The relationship between soil P concentration and degree of P stratification in the top 0-10 cm of soils along five toposequences was examined to predict the effect on runoff P losses. The total Colwell-P content of the 0-10 cm layer of soils in the catchment was very low in comparison to other studies on P losses from agricultural soils, but soils showed higher P concentration at 0-1 cm depth compared to 5-10 cm (average 37 mg/kg vs. 19 mg/kg). The higher extractable P concentration in the 0-1 cm layer will create a greater P mobilization risk in surface runoff and leachate than analysis of the 0-10 cm layer might suggest. Assessment of P risk using the 0-10 cm data would still be reliable as P concentration in the 0-1 cm layer was linearly related (R2 = 0.59) with concentration in the 0-10 cm layer. The sampling at varied soil depths will result in different critical P levels for estimating the risk of P enrichment in runoff. In a glasshouse study with intact soil columns, initial high P concentrations in leachate decreased with leaching events suggesting that macropore flow dominated in initial leaching events changing later to matrix flow. The hydraulic behavior of clay and loam soil below 10 cm depends largely on structure and the type of clay minerals and exchangeable Na. Higher levels of exchangeable Na in the subsoil might increase dispersion of clay particles resulting in low permeability leading to ponding of surface water or lateral movement of water at the interface of sand A and clay B horizons. Lateral water movements increase the risk of P losses in the form of DP, dissolved organic P (DOP) or PP. The P concentration in all the P forms (DRP, DOP and TDP) increased significantly with P rates of application (P < 0.01). The DRP concentration was < 2 mg/l in unfertilized columns but an increase to 11 mg/l was observed with P application at 40 kg P/ha. The higher proportion of DOP relative to DRP and its correlation with TDP indicates that the DOP was the major form of P in leachate. However, the estimation of DOP which was by subtraction of DRP from TDP generally overestimates OP concentration. The TDP load from unfertilized soil was < 0.20 mg/l in runoff and < 2.40 mg/l in throughflow but increased with P application (20, 40 kg P/ha) for both packed box and field studies. Under field conditions, higher P loss was found with broadcast P application compared to drill placement. The higher load of DOP as a proportion of TDP and its significant relationship with TDP in runoff (R2sand = 0.81; R2clay = 0.79) and throughflow (R2sand = 0.94; R2clay = 0.98) in field and box studies also suggests DOP was the major form of P loss from soil. Dissolved OP concentration increased significantly with increase in soluble organic carbon (SOC) in soil solution at 5 cm depth (P < 0.05). Consequently, the amount of organic matter dissolved in soil solution may influence P sorption and mobility. Relatively higher affinity of soil for sorption of DRP compared to DOP might allow DOP to be more mobile through the profile. Higher PP load in clay soil in throughflow indicates subsurface lateral flow along the interface with the horizon of dispersive clay might be an additional risk factor regarding P mobility in clay soils of the catchment. The runoff, throughflow and leachate were dominated by eroded particles of clay and colloidal organic materials. However, the soil solution collected though 0.1 m pores in the Rhizon samplers had a similar dominance of DOP to the < 0.45 jum filtered samples in runoff and throughflow. This reduces the likelihood that the so-called DOP fraction was mostly P associated with PP in the 0.1 to 0.45 jum size fraction. The composition of DOP in soil solution collected through Rhizon samplers (< 0.1 jum) might provide important insights for P mobility since this more effectively excluded PP than in the < 0.45 jum filtrate used for runoff and throughflow samples. The DOP in soil solution (< 0.1 jum) might be associated with fine colloidal compound such as silicates, metallic hydroxides, humic acids, polysaccharides, fulvic acids and proteins. If so, then most, but not all of the DOP fraction would be organically bound. However, this requires verification. In conclusion, soil P levels across the catchment were never very high when assessed in the 0-10 cm layer, but levels in the 0-1 cm layer were more than twice as high. Overall, < 1 % of land area of the upper Fitzgerald River catchment had Colwell-P levels > 30 mg/kg (0-10 cm) and hydrological connection to streams. In addition, another 7 % of land had Colwell-P levels > 15 mg/kg, which appears to be a change point in soils for the release of CaCl2 extractable P. These areas, which are predicted to represent critical source areas of the catchment, need careful management. The high proportions of TDP as DOP in runoff, throughflow and soil solution suggest DOP was the major form of P loss from soil. Phosphorus losses from the catchments are also likely in the form of PP in clay and loam soil but leaching losses are more likely in sand. High exchangeable Na in the subsoil of loam and clay soils increases dispersion of clay particles resulting in low permeability of subsoil and greater lateral P mobility as throughflow at the interface of sand and clay textured horizons. In general, soils of Fitzgerald River catchment had low soil P, but nevertheless significant risk of P loss at Colwell-P > 15 mg/kg. This study provides baseline information for P loss risks in the wheatbelt of WA. Stream water quality monitoring instruments were installed in the upper Fitzgerald River Catchment at 5 stream locations by CSIRO to measure base line concentrations of P. The measured P concentrations were higher than ANZECC trigger values (> 0.05 mg P/l) for management response over the three-year monitoring period (2005-07). Hence this and many other catchments on the south coast and wheatbelt of south west Western Australia need assessment for P loss risks. Previous emphasis in south west Western Australia on P losses from sandy coastal soils under pasture may need to be reconsidered. In the South coast region, cropping land in the medium rainfall zone may still represent a risk of P loss to waterways and risk to water quality. The present study evaluated the risk of P loss based on soil P forms and their mobility. It suggests greater attention needs to be given to the difference between clay and loam soils with dispersive or non-dispersive sub-soils, and to the composition and mobility of DOP. However, a more complete understanding of P loss risks depends on follow-up studies on hydrological flow and connectivity in the upper Fitzgerald River catchment and similar landscapes of south west Western Australia.

Accelerated soil erosion holds strong links to excessive land degradation, socioeconomic problems and accelerated climate change, particularly in developing countries such as South Africa. An analysis of the properties of severely eroded soils is undertaken to determine which characteristic properties influence the erodibility of the soils at several gully and badland sites in three catchments of the Ngqushwa rural municipality, which is tagged as one of the area’s most severely affected by soil erosion and degradation in the Eastern Cape. Physical, biological and chemical properties of the soils were analysed, including aggregate stability, soil texture, organic matter- and carbon content, clay mineralogy, sesquioxide content as Fe2O3 and cation composition. The distribution of a number of these properties was also determined, particularly between erosion sites, along hillslope profiles and with depth. The study area comprises three catchments, namely Mgwalana, Bira and Gqora which share common soil parent materials, land use history, exhibit similar topography and advanced degree of erosion. A total of 63 soil samples were strategically collected from identified erosion zones and site controls devoid of active erosion; where stability was evident by means of vegetation cover and soil surface condition. Surface samples were collected above 30cm depth and subsurface samples at depths greater than 30cm. To determine the fate of carbon additional samples were collected from runon and sink zones at the Mgwalana catchment along a transect from top to bottom slope. Laboratory analyses was performed to determine the soil properties, whereby C content was measured by the dry combustion method, Fe2O3- and cation content by Atomic Absorption (AA) Spectrometer, texture by the separation method described by Schlichting, Blume & Stahr (1995), clay mineralogy by X-Ray Diffraction and organic matter content by conversion of total C. In addition to these properties being used to infer aggregate stability, the wet sieving method was also used for this purpose and for validation of the other soil properties. The results revealed that no one soil property has a greater influence on aggregate stability than the others, but rather that the stability of the soil is dependent on the combinations of these properties in the soil and the interactions that occur between them. Based on this, the results indicated greater stability for runon, sink and control samples, mainly in the topsoil, which were characterised by a relatively higher C- and organic matter content, loam texture and higher concentrations of Ca2+. Furthermore, the less stable eroded samples were characterised by a more clay rich texture particularly in the subsoil, relatively lower C- and organic matter contents and a greater sodicity due to higher concentrations of Na+. The least stable soils belonged to the Gqora catchment, which were found to consist of higher silt content in the topsoil and a higher Fe2O3 content in the subsoil. The clay mineralogy was relatively uniform across all catchments, comprising of primarily illite and secondly kaolinite. The sample with the highest sodicity in terms of ESP contained smectite clay in addition to illite and kaolinite which is assumed to contribute to this increased Na+ concentration. These findings aid in the conclusion that the chemical characteristics of the soils, in association with biological and, to a less extent, physical properties of the soil exacerbate the erosion problem initiated by the extrinsic contributors, such as climate and topography. Investigation into the fate of carbon on eroded lands revealed a topographically driven dynamic whereby the total carbon content was found to be greater at the top and middle slope positions as well as in the sink zone. These hillslope sections were found to have a lower slope gradient and slightly more pronounced concave shape to those sections with lower C values. These topographic variables influence the degree of gully erosion taking place at different hillslope sections, which tends to be greater where slope angle is increased and convexity exists, resulting in the removal of soil C at these positions and its deposition in areas of accumulation, namely the runon and sink zones of low angle concave slope sections. The findings of this research may be used to develop restoration and management strategies with the ultimate goal to reduce the soils vulnerability to erosion by enhancing those soil properties conducive to greater aggregate stability as determined in the present study.

The forests of south-eastern Australia, having evolved in one of the most fire-prone environments in the world, are characterized by many adaptations to recovery following burning. Thus forest ecosystems are characterized by rapid regenerative capacity, from either seed or re-sprouting, and mechanisms to recover nutrients volatilized, including an abundance of N2 fixing plants in natural assemblages. Soil physical, chemical and biological properties are directly altered during fire due to heating and oxidation of soil organic matter, and after fire due to changes in heat, light and moisture inputs. In natural ecosystems, carbon (C) and nitrogen (N) lost from soil due to fires are recovered through photosynthesis and biological N2 fixation (BNF) by regenerating vegetation and soil microbes.<br>This study investigated post-fire recovery of soil C and N in four structurally different sub-alpine plant communities (grassland, heathland, Snowgum and Alpine ash) of south-eastern Australia which were extensively burnt by landscape-scale fires in 2003. The amount and isotopic concentration of C and N in soils to a depth of 20 cm from Alpine ash forest were assessed five years after fire in 2008 and results were integrated with measurements taken immediately prior to burning (2002) and annually afterwards.<br>Because the historical data set, comprised of three soil samplings over the years 2002 to 2005, consisted of soil total C and N values which were determined as an adjunct to 13C and 15N isotopic studies, it was necessary to establish the accuracy of these IRMS-derived measurements prior to further analysis of the dataset. Two well-established and robust methods for determining soil C (total C by LECO and oxidizable C by the Walkley-Black method) were compared with the IRMS total C measurement in a one-off sampling to establish equivalence prior to assembling a time-course change in soil C from immediately pre-fire to five years post-fire. The LECO and IRMS dry combustion measurements were essentially the same (r2 >0.99), while soil oxidizable C recovery by the Walkley-Black method (wet digestion) was 68% compared to the LECO/IRMS measurements of total C. Thus the total C measurement derived from the much smaller sample size (approximately 15 mg) combusted during IRMS are equivalent to LECO measurement which require about 150 mg of sample.<br>Both total C and N in the soil of Alpine ash forests were significantly higher than soils from Snowgum, heathland and grassland communities. The ratio of soil NH4+ to NO3- concentration was greater for Alpine ash forest and Snow gum woodland but both N-fractions were similar for heathland and grassland soils. The abundance of soil 15N and 13C was significantly depleted in Alpine ash but both isotopes were enriched in the heathland compared to the other ecosystems. Abundance of both 15N and 13C increased with soil depth.<br>The natural abundance of 15N and 13C in the foliage of a subset of non-N2 fixing and N2 fixing plants was measured as a guide to estimate BNF inputs. Foliage N concentration was significantly greater in N2 fixers than non-N2 fixers while C content and 13C abundance were similar in both functional groups. Abundance of 15N was depleted in the N2 fixing species but was not significantly different from the non-N2 fixers to confidently calculate BNF inputs based on the 15N abundance in the leaves.<br>The total C pool in soil (to 20 cm depth) had not yet returned to the pre-fire levels in 2008 and it was estimated that such levels of C would be reached in another 6-7 years (about 12 years after the fire). The C and N of soil organic matter were significantly enriched in 15N and 13C isotopes after fire and had not returned to the pre-fire levels five years after the fire. It is concluded that the soil organic N pool can recover faster than the total C pool after the fire in the Alpine ash forests.

Intensive tillage and monoculture cropping practices reduce soil C accumulation hence increasing soil vulnerability to chemical, physical and biological degradation. This study focussed on enhancing biomass production of wheat and oat winter cover crops as a means of increasing C sequestration in the low organic C soils of the central part of Eastern Cape Province. The specific objectives were (i) to evaluate the short-term effects of no till and cereal-fallow based crop rotations on; soil organic matter related parameters, pH and electrical conductivity, (ii) soil bulk density, water retention and aggregate stability, (iii) soil microbial biomass C and N, mineralizable N, soil respiration, and dehydrogenase enzyme activity, (iv) grain yield, soil nutrient concentration (N, P and K) and their uptake by maize, and (v) to identify soil parameters with high sensitivity to tillage under maize-fallow-maize, maize-wheat-maize and maize-oat-maize rotational cover cropping practices. The experiment was laid out as a split-plot arrangement in a randomized complete block design with 4 replicates. Tillage treatments (CT and NT) were applied on the main plots which measured 8 × 18 m while crop rotation treatments were applied in the subplots which measured 8 × 6 m. The rotation treatments were maize-fallow-maize (MFM), maize-wheat-maize (MWM) and maize-oat-maize (MOM). Weed control in NT plots involved preplant application of glyphosate to control mainly the grass weeds while post emergence weed management was done using Atrazine (485 atrazine and 15 g l-1 triazines). Initial weed control in CT plots was achieved through ploughing to a depth of 20 cm followed by disking while post emergence weed iii management was done by hand hoeing. Soil parameters measured were; (i) particulate organic matter (POM), soil organic carbon (SOC), total nitrogen (TN), pH and electrical conductivity (EC), (ii) soil bulk density (b), moisture at field capacity (FC), aggregate mean weight diameter (MWD) determined by fast wetting (FW), slow wetting (SW), mechanical breakdown by shaking (MB) and the stability index (SI), (iii) soil microbial biomass C (MBC) and N (MBN), mineralizable N (MN), soil respiration (SR), and dehydrogenase enzyme activity (DHEA). No-till increased POM and TN compared to CT in Lenye and Burnshill, respectively. The MWM and the MOM rotations increased TN relative to the MFM rotation in Lenye. The MWM and MOM rotations enhanced SOC relative to MFM in all sampled soil depths at Burnshill and similar observations were made under MOM rotation in the 5-20 cm depth in Lenye. The MWM and MOM rotations tended to depress soil pH relative to the MFM rotation in both sampled soil depths in Lenye while NT reduced soil pH relative to CT on the surface soil layer in Burnshill. Soil EC and pH varied with depth across tillage practices but both parameters remained within the ideal range for successful crop production over the study period. Soil stability index (SI) and aggregate MWD determined by FW, SW and MB were higher in Lenye compared to Burnshill. The MOM rotation enhanced the SI relative to MFM and MWM rotations at both sites. Scanning electron microscope (SEM) showed that more organic C was incorporated into the soil under NT and MOM rotation compared to CT and MFM rotation which had few organic coatings on the soil particles. Microbial properties varied with plant biomass input as influenced by tillage and type of rotational cover crop at both sites. Like in other past studies, NT showed higher levels of MBC, MBN, NM and SR at the soil surface layer compared to CT in Burnshill. No till increased MN iv relative to CT in both sampled soil depths in Lenye and resulted in higher DHEA compared to CT in Burnshill. The MOM rotation increased MBC, MBN, MN relative to MFM rotation especially within surface soil layer. Similar observations were made with respect to MN and SR in both sampled soil layers at Lenye. By contrast, the DHEA was higher under the MFM relative to the MWM and MOM rotations in Lenye but similar under the MFM and MOM rotations in Burnshill. Maize grain yield was not affected by both tillage and crop rotations but varied with cropping season. Comparable grain yields observed under the two tillage practices with similar fertilizer application rates indicated the advantage of NT over CT in saving on labour costs in maize production without compromising yields. High plant biomass retention under NT relative to CT contributed to high soil N and P levels under the former compared to the latter tillage practice especially on soil surface layer at both study sites. Principal component analysis (PCA) revealed that soil chemical and biological parameters closely linked to organic matter, namely SOC, MN, MBC and MBN showed the highest sensitivity to tillage and crop rotation treatments. Soil aggregate MWD determined by SW and b were the physical parameters which were highly altered by agronomic management practice. The MWM and MOM rotations were clustered together and clearly separated from the MFM rotation and this observed trend only applied to the 0-5 and 5-20 cm depths in Lenye site only. No till, MWM and MOM rotations enhanced POM, SOC and TN relative to CT and MFM rotation suggesting these practices have greater potential to improve soil chemical properties compared to intensive tillage and maize monoculture based production practices. Reduced soil b under MOM rotation and improved SI under NT compared to MFM and CT, respectively v indicate that these practices have the potential to improve degraded soils. Although not significantly different, NT values for MBC, MBN, MN, SR and DHEA were higher compared to CT indicating the potential of the practice to improve soil biotic activity relative to conventional tillage practices. No till enhanced surface soil nitrate N and extractable P compared to CT at both sites revealing the long-term potential of NT in improving the supply of these essential plant nutrients compared to CT. Principal component analysis showed that SOC, MN, K, P, MBC, MBN, soil aggregate MWD determined by SW and b were the most sensitive parameters to tillage and crop rotations. Therefore, these parameters could constitute the minimum data set for assessments of the impact of selected CA practices on soil quality attributes.

A field-based project was undertaken to develop and test a mechanism which would allow for the correlation of the health of vegetation surrounding playa lakes in south-west Australia with the natural variation in salinity and waterlogging that occurs spatially and temporally in natural systems. The study was designed to determine threshold ranges of vegetation communities using moderately extensive data over short temporal periods which will guide the design of potential engineering solutions that manipulate hydrological regimes to ultimately conserve and protect native vegetation. A pair of playa lake ecosystems, surrounded by primary production land, was modelled with hydro-geological data collected from March 2006 to March 2007. The data was used to determine the hydroperiods of vegetation communities fringing playa lakes and provide insight into the areas and species that are most affected by extreme rainfall events which are hypothesised to have a significant, rapid deleterious effect on the ecosystems. The methodology was multi-faceted and included; a detailed topographical survey; vegetation surveys; hydrological and hydro-geological monitoring over a 12 month period. 4 The hydro-geological data and vegetation data was linked with the topographical survey at a high resolution for spatial analysis in a Geographic Information System (GIS) to determine the degree of waterlogging experienced by vegetation communities over the monitoring period. The study has found that the spatial and temporal variability of hydroperiods has been reduced by rising groundwater levels, a result of extensive clearing of native vegetation. Consequently populations are becoming extinct locally resulting in a shift in community composition. Extreme summer rainfall events also have a significant impact on the health of vegetation communities by increasing the duration of waterlogging over an annual cycle and in some areas expanding the littoral zone. Vegetation is most degraded at lower positions in the landscape where communities are becoming less diverse and dominated by salt tolerant halophytic species as a result of altered hydrological regimes. Some species appear to be able to tolerate groundwater depths of less than 2.0 m from the surface, however there are thresholds related to the duration at which groundwater is maintained at this depth. Potential engineering solutions include groundwater pumping and diverting water through drains to maintain sustainable hydroperiods for vegetation in areas with conservation value. The effectiveness and efficiency of the engineering solutions can be maximised by quantifying thresholds for vegetation that include sustainable durations of waterlogging. The study has quantified tolerance ranges to salinity and waterlogging with data collected over 12 months but species may be experiencing a transition period where they have 5 sustained irreversible damage that will result in their eventual mortality. With long-term monitoring, the methodology developed and tested in the study can be used to quantify the long-term tolerance ranges that are important for the application of conservation approaches that include engineering solutions.

Includes bibliographical references (leaves 78-86) In the Herrmanns sub-catchment in the Mt. Lofty Ranges (near Mt. Torrens) soil sodicity was the dominant factor in causing clay to disperse in the eroded area along the foot slopes, wheras in non-eroded areas of the mid-slopes and on the stream banks, the dispersive power of sodicity was attenuated by the flocculative power of other soil properties.

With the increased planting of E. globulus monoculture plantations, concerns surround the impact these mass plantings will have on the soil environment and wider ecosystem. Soil and litter mites are the dominant saprophages of terrestrial ecosystems, contributing to decomposition processes through their comminution and grazing activities. Despite the importance of mites to decomposition processes, there have been no investigations to date of the litter and soil communities under these plantations within Australia. This study investigated the impact of Eucalyptus globulus subsp. globulus (Tasmanian bluegum) monoculture plantations on the diversity and abundance of the soil and litter acarine (mite) fauna. Mite communities under three 8 year-old E. globulus plantations sited on reclaimed pastureland were compared with an adjacent native E. marginata (jarrah) forest and a grazed pasture in the mediterranean-type region of southwest Western Australia. Sites were sampled in spring 1997 and new sites randomly selected in autumn 1998. Large seasona1 variations in abundance and diversity were found between the sampling periods of spring 1997 and autumn 1998, influenced considerably by soil moisture. Species richness was consistently higher in both the soil and litter layers under native jarrah forest, with the E. globulus plantations intermediate in species richness between the native forest and grazed pasture. A total of 114 mite species/morphospecies was recognized; 16 Mesostigmata, 52 Prostigmata, 45 Oribatida (Cryptostigmata) and 1Astigmata. Species diversity in the surface litter was higher under the native forest, reflecting the greater heterogeneity of the litter. Diversity in the underlying soil was similar for the native forest and E. globulus plantation, although there were considerable differences in species richness. Soil diversity in the pasture was very poor in comparison to the two forest systems, reflecting the absence of a litter layer and reduced niche dimensions. The monospecific E. globulus litter possibly reduced niche variety by simplifying the physical habitat and reducing the variety of resources available for the saprophagous fauna, of which the oribatid mites are a major component. Consequently, the number of families represented in the microphytophagous, phytophagous and predator functional groups under the E. globulus plantation may have been reduced. The most common oribatid families under the plantation were those often reported from disturbed habitats, Oppiidae and Tectocepheidae, and those common in many habitats, Oppiinae and Oppiellinae. An important management implication arising from this study is that these plantations would harbour a more diverse mite fauna if planted as a mixed tree stratum.

Winter rotational cover crops (WRCC) are often used to boost soil fertility and plant nutrition. However, selection and use of WRCC for soil physical improvement is usually overlooked. The objective of this study was to determine the effects of WRCC on soil strength, aggregate stability and water conservation of a hardsetting soil. The soil physical properties were determined after four rotations of growing monocultures of vetch (Vicia dasycarpa cv. Max), lupin (Lupinus angustifolius cv. Tanjil) and oats (Avena sativa cv. Sederberg) and after two rotations of growing bicultures of oats (Avena sativa cv. Pallinup) and vetch (Vicia dasycarpa cv. Max) across two soil layers, 0 to 15 cm and 15 to 30 cm. The individual WRCC and a weedy fallow constituted the treatments in the monoculture study whilst in the biculture study the various combinations of WRCC namely; 90% oat plus 10% vetch (O90V10); 70% oat plus 30% vetch (O70V30) and 50% oat plus 50% vetch (O50V50) and a weedy fallow constituted the treatments. After four rotations with cover crop monocultures, oats significantly (P ≤ 0.05) reduced penetration resistance (PR) whilst vetch increased PR in both soil layers compared to the weedy fallow control. The effect of the biculture treatments was only experienced within the 15 to 30 cm depth. The treatments O50V50 and O70V30 increased the PR compared to the control. The WRCC in monoculture significantly increased the soil aggregate stability relative to the control in both soil layers. Vetch, lupin and oats resulted in a 41.7%; 20.4% and 15.7% increase in MWD in the 0 to 15 cm soil layer and 47.2%; 44.2% and 39.7% in the 15 to 30 cm depth, respectively. An increase in aggregate stability was associated with increased macro-aggregation. Under the biculture, WRCC slightly increased, non- significantly, the aggregate stability. Both hot water and dilute acid extractable polysaccharides showed no significant correlation with aggregate stability in the two studies. Oats monoculture resulted in a significant difference (P ≤ 0.05) on cumulative infiltration compared to the control. However, after 2 h vetch and lupin showed no significant difference from the control on cumulative infiltration. Oats resulted in a 7.8% increase in final infiltration rate (FIR) whilst vetch and lupin reduced FIR by 9% and 16.7% respectively, compared to the control. Bicultures of oats and vetch significantly (P ≤ 0.05) increased cumulative infiltration compared to the weedy fallow control. A similar significant increase in FIR was also observed under bicultures. The treatments O50V50; O90V10 and O70V30 resulted in a 163.3%; 113.3% and 105.4% increase in FIR respectively, compared to the control. Cover crop monocultures significantly (P ≤ 0.05) increased plant available water (PAW) compared to the weedy fallow, with vetch, oats and lupin resulting in a 28.3%; 22% and 23.9% increase respectively, in PAW. However, no significant differences were observed on PAW after two rotations with bicultures. Compared with winter weedy fallow, WRCC improved most of the soil physical properties under study, with the most suitable results expected under bicultures compared to monocultures. Under CA, selection of WRCC like oats, vetch and lupin, one should therefore take into consideration their effects on soil physical properties as a selection criterion and not biomass and fertility alone.

Soil microbial communities play and essential role in nutrient cycling and influence functioning of the ecosystems though taking part in feedback mechanisms that shape plant communities. Anthropogenic influences on vegetation can result in changes in the activity of soil microbes, which is reflected in soil chemical and biochemical properties, for example nutrient content, enzymatic activity or respiration. Such information about microbial function in soils can enhance research focusing on land use change, degradation and restoration. Large-scale deforestation of land for agricultural use in the south west of Western Australia (SWWA) and subsequent artificial afforestation of resulting pastureland with Eucalyptus globulus plantations created a mosaic of native vegetation remnants, exotic forest and pastures. Remnants of native woodland in such a fragmented landscape are prone to decline, often as a result of the legacy of pastoral uses of the neighbouring land, such as grazing by livestock. Degradation of the remnants undermines the efforts to preserve native biodiversity of the region. Restoration undertaken to improve their condition is usually by herbicide application and planting of native understorey species. To date, little research is available to guide these efforts towards efficient and successful use of scarce resources allocated to rehabilitation in land management projects. The main objective of this study was to determine the usefulness of soil biochemical properties in assessing land degradation and restoration treatments in native vegetation remnants enclosed in E. globulus plantations in SWWA. It was hypothesised that differences in soil biochemical properties detected using microplate assays would allow assessment and monitoring of soil following land use change and potential of restoration treatments. A second objective was to determine which out of the restoration or degradation treatments had the most influence on soil chemical properties as well as on weed cover, native vegetation growth and regeneration in remnant vegetation. The hypotheses tested were that: a) soil nutrient enrichment would be a more influential factor contributing to degradation than clearing and incursion of exotic ryegrass in the remnants with native understorey and b) herbicide application and mulching with plantation harvest residue would improve survival and growth of seedlings planted for revegetation in remnants with exotic understorey. This information is important for informing the plantation companies responsible for managing remnant woodland in their estates, particularly those with forest product certification. A third objective was to find chemical and biochemical properties of soil that were both descriptors and predictors of processes involved in disturbance and restoration to investigate the possibility of developing an inexpensive tool for monitoring the condition of remnant vegetation and assessing the suitability of putative restoration treatments. It was hypothesised that soil functional diversity based on soil chemical and biochemical properties could be used as an indicator of land condition. The first study revealed that while soils from five land conditions common in the landscapes of SWWA differed in their chemical and biochemical properties, soil physical properties were more influential than soil chemical and biochemical properties. The second study showed that addition of fertilizer, but not clearing of native vegetation or incursion of exotic ryegrass, altered the soil biochemistry in remnant vegetation with native understorey. It also revealed that soil alkaline phosphomonoesterase and β-glucosidase activity and soil respiration in response to succinic, cinnamic and α-ketoglutaric acids were related to the outcomes of disturbance of both native and exotic vegetation. The results of subsequent studies showed, contrary to the expectations, that mulching with plantation harvest residue increased soil nutrient levels, especially potassium and nitrate concentration. Herbicide application and mulching improved the growth and survival of native seedlings planted for revegetation; however, there were species-specific responses to each treatment. Analysis of the relationships among soil chemical and biochemical properties revealed that soil nitrogen pools and pH were most influential on soil biochemistry. Functional diversity varied among soils from different land condition, but not among the experimental treatments applied. Soil nitrate, ammonium, potassium and sulphur, alkaline phosphomonoesterase activity and N-mineralization potential together with respiration in response to imidazole, thiamine and the organic acids: succinic, cinnamic and α-ketoglutaric, were useful in discerning land conditions and experimental treatments. Microplate assays for soil biochemical properties provided information useful in discriminating among land conditions; however, they were not sensitive enough to clearly detect the effects of all experimental interventions. The usefulness of a soil functional diversity approach as an index for disturbance was tentatively confirmed; however, more work is required to assure its’ robustness and wider applicability. The importance of soil nitrogen and pH in altering soil biochemical properties found in this study is consistent with previous research. Soil nitrogen was more important than soil phosphorus in maintaining exotic plant incursion in remnant vegetation with native understorey, suggesting that managing nitrogen pools by avoiding excess fertilizer application and encouraging denitrification could be a useful strategy to minimise the weed load in remnant vegetation, one of the biggest impediments to restoration. Mulching with plantation harvest residue with occasional application of glyphosate controlled exotic weeds as effectively as the herbicide-only treatment, while benefiting the survival and growth of the native plant seedlings more, probably through increasing moisture retention and providing nutrients. The choice of restoration treatments have to be considered in conjunction with the choice of plant species used for revegetation. The usefulness of microplate tests for soil biochemical properties in assessing land condition, including that of remnant vegetation with native and exotic understorey was confirmed. This assay format was used with promising results to show the effects of several treatments simulating degradation and restoration on soils and vegetation, which is of practical importance in management of remnant patches of native vegetation. In addition, it provided preliminary insights into the relationships among soil chemical and biochemical properties, which could contribute to the development of a high through-put, inexpensive and reliable tool for assessing and monitoring land condition and restoration efforts.

[Truncated abstract] Perth is the capital city of Western Australia (WA) and the home of more than three quarters of the population in the state. It is located in the southwest WA (SWWA), a low to moderate seismic region but the seismically most active region in Australia. The 1968 ML6.9 Meckering earthquake, which was about 130 km from the Perth Metropolitan Area (PMA), caused only minor to moderate damage in PMA. With the rapid increase in population in PMA, compared to 1968, many new structures including some high-rise buildings have been constructed in PMA. Moreover, increased seismic activities and a few strong ground motions have been recorded in the SWWA. Therefore it is necessary to evaluate the seismic risk of PMA under the current conditions. This thesis presents results from a comprehensive study of seismic risk of PMA. This includes development of ground motion attenuation relations, ground motion time history simulation, site characterization and response analysis, and structural response analysis. As only a very limited number of earthquake strong ground motion records are available in SWWA, it is difficult to derive a reliable and unbiased strong ground motion attenuation model based on these data. To overcome this, in this study a combined approach is used to simulate ground motions. First, the stochastic approach is used to simulate ground motion time histories at various epicentral distances from small earthquake events. Then, the Green's function method, with the stochastically simulated time histories as input, is used to generate large event ground motion time histories. Comparing the Fourier spectra of the simulated motions with the recorded motions of a ML6.2 event in Cadoux in June 1979 and a ML5.5 event in Meckering in January 1990, provides good evidence in support of this method. This approach is then used to simulate a series of ground motion time histories from earthquakes of varying magnitudes and distances. ... The responses of three typical Perth structures, namely a masonry house, a middle-rise reinforced concrete frame structure, and a high-rise building of reinforced concrete frame with core wall on various soil sites subjected to the predicted earthquake ground motions of different return periods are calculated. Numerical results indicate that the one-storey unreinforced masonry wall (UMW) building is unlikely to be damaged when subjected to the 475-year return period earthquake ground motion. However, it will suffer slight damage during the 2475-return period earthquake ground motion at some sites. The six-storey RC frame with masonry infill wall is also safe under the 475-year return period ground motion. However, the infill masonry wall will suffer severe damage under the 2475-year return period earthquake ground motion at some sites. The 34-storey RC frame with core wall will not experience any damage to the 475-year return period ground motion. The building will, however, suffer light to moderate damage during the 2475-year return period ground motion, but it might not be life threatening.

[Truncated abstract] A functional ecosystem is increasingly being recognised as a requirement for health and well being of resident human populations. Clearing of native vegetation for agriculture has left 1.047 million hectares of south-west Western Australia affected by a severe form of environmental degradation, dryland salinity, characterised by secondary soil salinisation and waterlogging. This area may expand by a further 1.7-3.4 million hectares if current trends continue. Ecosystems in saline affected regions display many of the classic characteristics of Ecosystem Distress Syndrome (EDS). One outcome of EDS that has not yet been investigated in relation to dryland salinity is adverse human health implications. This thesis focuses on one such potential adverse health outcome: increased incidence of Ross River virus (RRV), the most common mosquito-borne disease in Australia. Spatial analysis of RRV notifications did not reveal a significant association with dryland salinity. To overcome inherent limitations with notification data, serological RRV antibody prevalence was also investigated, and again no significant association with dryland salinity was detected. However, the spatial scale imposed limited the sensitivity of both studies. ... This thesis represents the first attempt to prospectively investigate the influence of secondary soil salinity on mosquito-borne disease by combining entomological, environmental and epidemiological data. The evidence collected indicates that RRV disease incidence is not currently a significant population health priority in areas affected by dryland salinity despite the dominant presence of Ae. camptorhynchus. Potential limiting factors include; local climatic impact on the seasonal mosquito population dynamics; vertebrate host distribution and feeding behaviour of Ae. camptorhynchus; and the scarce and uneven human population distribution across the region. However, the potential for increased disease risk in dryland salinity affected areas to become apparent in the future cannot be discounted, particularly in light of the increasing extent predicted to develop over coming decades before any benefits of amelioration strategies are observed. Finally, it is important to note that both dryland salinity and salinity induced by irrigation are important forms of environmental degradation in arid and semi-arid worldwide, with a total population of over 400 million people. Potential health risks will of course vary widely across different regions depending on a range of factors specific to the local region and the complex interactions between them. It is therefore not possible to make broad generalisations. The need is highlighted for similar research in other regions and it is contended that an ecosystem health framework provides the necessary basis for such investigations.

This thesis outlines findings from a series of field experiments measuring the efficiency with which wheat and barley crops grown in south eastern Australia utilise nitrogen (N) fertiliser, with particular focus on loss of N as emissions of the greenhouse gas: nitrous oxide. N use efficiency varied significantly across regions, seasons and management strategies, while nitrous oxide emissions were highest in high rainfall environments or under irrigation compared with lower rainfall environments. Strategies which match the rate and timing of fertiliser application to crop demand resulted in greater efficiency, offering opportunities to reduce the greenhouse footprint of crop production.

Puccinellia (puccinellia ciliata) and tall wheatgrass (Thinopyrum ponticum) often show ecological zonation in saline landscapes, with puccinellia occurring in less elevated more saline/waterlogged locations, and tall wheatgrass occurring in more elevated less saline/waterlogged locations. The aims of this study were to: (a) characterize the observed ecological zonation at a field site, (b) quantify the effects of variables likely to explain growth differences of the two plants in glasshouse experiments, and (c) identify and compare anatomical and physiological mechanisms that explain these zonation patterns. At an experiment in the field near Kojonup (0522824E, 6244579N), puccinellia was found to colonise the lower more severely salinised and waterlogged zones of the landscape, with tall wheatgrass occupying the higher less affected zones. These differences in zonation were clearly associated with variance in soil salinity and water-table depth. Glasshouse experiments in soil revealed that low pH values, low calcium concentrations and variation in salinity alone did not explain the ecological zonation observed in the field. However, there was a substantial difference in the responses of the two plant species to waterlogging in combination with salinity. Puccinellia grew better under saline waterlogged conditions than tall wheatgrass, which was associated with better regulation of Na+ and K+ under saline/waterlogged conditions than in tall wheatgrass. Under non-saline conditions, waterlogging (hypoxia) decreased shoot weights in puccinellia by 15% and in tall wheatgrass by 20%. Similar growth results were obtained in nutrient solution culture, where waterlogging was simulated by lowering the oxygen in solutions through bubbling with N2 gas. Under saline hypoxic conditions, puccinellia, compared to tall wheatgrass, showed increased growth and maintenance of selectivity of K+ over Na+ across adventitious roots. Solution experiments revealed adaptive traits responsible for conveying better growth and ion maintenance present in puccinellia, but not tall wheatgrass, such as inducement of a barrier to radial oxygen loss in the basal regions of adventitious roots (not previously reported in the literature for puccinellia), formation of root aerenchyma and packing of cortical cells and suberin deposition in hypodermal and endodermal root cell layers. These results should assist in targeting pasture species, and predicting their growth response, in saline and waterlogged landscapes. Further work on examining the genetic material of puccinellia is warranted in order to identify genes that could be transferred into crop plants to convey salt and waterlogging tolerance.

[Truncated abstract. Please see the pdf format for the complete text. Also, formulae and special characters can only be approximated here. Please see the pdf version for an accurate reproduction.] This thesis examines the water use, ecophysiology and hydraulic architecture of Eucalyptus marginata (jarrah) growing on bauxite mine rehabilitation sites in the jarrah forest of south-western Australia. The principal objective was to characterise the key environment and plant-based influences on tree water use, and to better understand the dynamics of water use over a range of spatial and temporal scales in this drought-prone ecosystem. A novel sap flow measurement system (based on the use of the heat pulse method) was developed so that a large number of trees could be monitored concurrently in the field. A validation experiment using potted jarrah saplings showed that rates of sap flow (transpiration) obtained using this system agreed with those obtained gravimetrically. Notably, diurnal patterns of transpiration were measured accurately and with precision using the newly developed heat ratio method. Field studies showed that water stress and water use by jarrah saplings on rehabilitation sites were strongly seasonal: being greatest in summer when it was warm and dry, and least in winter when it was cool and wet. At different times, water use was influenced by soil water availability, vapour pressure deficit (VPD) and plant hydraulic conductance. In some areas, there was evidence of a rapid decline in transpiration in response to dry soil conditions. At the end of summer, most saplings on rehabilitation sites were not water stressed, whereas water status in the forest was poor for small saplings but improved with increasing size. It has been recognised that mature jarrah trees avoid drought by having deep root systems, however, it appears that saplings on rehabilitation sites may have not yet developed functional deep roots, and as such, they may be heavily reliant on moisture stored in surface soil horizons. Simple predictive models of tree water use revealed that stand water use was 74 % of annual rainfall at a high density (leaf area index, LAI = 3.1), high rainfall (1200 mm yr-1) site, and 12 % of rainfall at a low density (LAI = 0.4), low rainfall (600 mm yr-1) site, and that water use increased with stand growth. A controlled field experiment confirmed that: (1) sapling transpiration was restricted as root-zone water availability declined, irrespective of VPD; (2) transpiration was correlated with VPD when water was abundant; and (3) transpiration was limited by soil-to-leaf hydraulic conductance when water was abundant and VPD was high (> 2 kPa). Specifically, transpiration was regulated by stomatal conductance. Large stomatal apertures could sustain high transpiration rates, but stomata were sensitive to hydraulic perturbations caused by soil water deficits and/or high evaporative demand. No other physiological mechanisms conferred immediate resistance to drought. Empirical observations were agreeably linked with a current theory suggesting that stomata regulate transpiration and plant water potential in order to prevent hydraulic dysfunction following a reduction in soil-to-leaf hydraulic conductance. Moreover, it was clear that plant hydraulic capacity determined the pattern and extent of stomatal regulation. Differences in hydraulic capacity across a gradient in water availability were a reflection of differences in root-to-leaf hydraulic conductance, and were possibly related to differences in xylem structure. Saplings on rehabilitation sites had greater hydraulic conductance (by 50 %) and greater leaf-specific rates of transpiration at the high rainfall site (1.5 kg m-2 day1) than at the low rainfall site (0.8 kg m-2 day1) under near optimal conditions. Also, rehabilitation-grown saplings had significantly greater leaf area, leaf area to sapwood area ratios and hydraulic conductance (by 30-50 %) compared to forest-grown saplings, a strong indication that soils in rehabilitation sites contained more water than soils in the forest. Results suggested that: (1) the hydraulic structure and function of saplings growing under the same climatic conditions was determined by soil water availability; (2) drought reduced stomatal conductance and transpiration by reducing whole-tree hydraulic conductance; and (3) saplings growing on open rehabilitation sites utilised more abundant water, light and nutrients than saplings growing in the forest understorey. These findings support a paradigm that trees evolve hydraulic equipment and physiological characteristics suited to the most efficient use of water from a particular spatial and temporal niche in the soil environment.

The Azeri, Chirag, Gunashli (ACG) field is located offshore Azerbaijan. The reservoirs are multilayered sandstones forming traps within a major anticlinal structure. Proven crude oil reserves are estimated to contain 5.4 billion barrels of oil. In the past this area has been studied in regional detail but not at the reservoir scale with respect to the fluvio-deltaic sediments filling the northern shore of the ancient South Caspian Sea. The aim of this study is carried out the sedimentological, cyclostratigraphical analysis and reservoir characterization of Balakhany X Formation within the Productive Series which is considered to be one of the significant producing horizons. To be able to achieve this objective, a 30m thick section, which is mainly composed of siliciclastics, has been studied in detail on Balakhany X cores from C01 well Azeri field. In this study, detailed lithofacies analyses were performed and sandstone, mudstone, siltstone facies were recognized in the studied interval of the Balakhany X Formation. Litharenites and sublitharenites sandstones are the most abundant in the succession. Sedimentological analysis such as grain-size sphericity, provenance, XRD, SEM and grain surface texture were performed and their relationship with depositional environment were discussed. The grain size distribution of the samples along the succession shows distribution of fine to very fine sands. Sorting of sandstones ranges between moderately well to very well sorted. The provenance analysis of sandstones based on modal analysis of thin sections related to recycled orogen. According to interpretation of grain size parameters and grain surface textures analysis the main transporting agent of sands observed as wind, wave and river agents. High resolution cyclostratigraphy studies based on cm-m scaled cyclic occurrences of lithofacies along the measured section were performed. Milankovitch, sub-Milankovitch and millennial cycles were determined along the studied section. The petrophysical analysis revealed good to very good (18 to 24%) porosity and good permeability (10 to 538mD) in Balakhany X Formation. The porosity and permeability are affected by both textural and compositional controls. Grain size distribution along the reservoir section is fine to very fine sands. Influence of compaction was observed by the fractures and dissolutions on the sand grains. The calcite cement, grain-size variation, sorting and compaction are the main factors controlling porosity and permeability.

Comprised of the author's previously published works<br>Includes bibliographical references<br>1 v. (various pagings) :<br>Thesis (D. Sc.)--University of Adelaide, Dept. of Soil Science, Waite Agricultural Research Institute, 1988

Drip irrigation is the most common method of water application used in Australian vineyards. However it places physical and chemical stress upon soil structure, which may affect soil physical properties, soil water availability and grapevine functioning. Common soil types within Australian vineyards appear vulnerable to soil degradation and there is emerging evidence of such degradation occurring. Two South Australian vineyards (one located at Nuriootpa in the Barossa Valley, the other in the McLaren Vale winegrowing region) were used to examine evidence of altered soil physical properties due to irrigation. Significantly higher soil strength and lower permeability was found under or near the dripper in irrigated soils. There was also evidence that irrigation increased subsoil bulk density at Nuriootpa. It was uncertain how irrigation caused these changes. While sodicity was present at Nuriootpa, it appeared the physical pressures exerted by irrigation, such as rapid wetting and prolonged wetness, also contributed. To gauge the severity of the degradation at Nuriootpa, a modelling study assessed the impact of higher soil strength and salinity on grapevine transpiration. The SWAP model (Soil- Water-Atmosphere-Plant) was modified and then calibrated using soil moisture data from Nuriootpa. Simulations were conducted for different irrigation regimes and the model output indicated that degradation led to a reduction in cumulative transpiration, which was almost entirely due to higher soil strength. However the reduction was relatively minor and there was evidence of water extraction by roots in all soil layers. Hence the degradation, in terms of higher soil strength and salinity, was not considered a significant management problem in the short - term. Evidence of increased waterlogging and its consequences require further investigation. Roots were observed in soils at Nuriootpa with penetration resistance (PR) much greater than 2 MPa, which was thought to completely impede grapevine root growth. It was hypothesised that roots avoided the physically hostile matrix by using biopores or structural cracks. A pot experiment tested this hypothesis and examined the relationship between soil strength, biopores and root growth for grapevines. Grapevine rootlings (cv. Cabernet Sauvignon) were grown into pots with varying degrees of soil compaction, with and without artificial biopores. No root growth occurred when PR>2 MPa unless biopores were present. Pores also improved root growth in non-compacted soil when PR approached 1 MPa, which suggested biopores influence root growth in soils regardless of compaction levels. Therefore PR should not be the only tool used to examine the rooting-potential of a vineyard soil. An assessment of soil structure, such as biopore density and size, should be incorporated. In drip-irrigated vineyards, there is a possibility that degraded clayey subsoils could be ameliorated by manipulating zones of soil drying. At distances away from the dripper, drying events could generate shrinkage cracks that improve drainage and provide opportunities for root growth. From a practical perspective, drying events could be manipulated by moving the dripper laterally or by changing the irrigation frequency and intensity. The potential of this simple, non-invasive, ameliorative approach was investigated. Large, intact cores were sampled from Nuriootpa subsoil where degradation had been identified. Individual core bulk density was calculated using a formula that was derived by solving two common soil physics equations simultaneously. This proved to be an accurate and non - invasive method. Half the cores were leached with a calcium solution, and the saturated hydraulic conductivity (K [subscript s] ) was measured on all cores before and after drying to a matric potential of -1500 kPa. Soil drying led to a significant increase in K [subscript s], which indicated an improvement in structure through the creation of shrinkage cracks and heaving. Calcium treatment had no impact on K [subscript s], but that could change with more wetting and drying cycles. Results indicated the need for further investigation in the field, where different compressive and tensile forces operate. Harnessing this mechanism may provide an attractive soil management option for growers. The soil physical degradation identified is concerning for sustainable production in irrigated vineyards. Given the sites were representative of typical irrigation practices, such degradation may be widespread. While modelling suggested the impact of higher soil strength and salinity was minimal, these properties should be monitored because they may worsen with continuing irrigation. Furthermore, the impact of irrigation on subsoil permeability needs to be defined more accurately. An increased incidence of waterlogging could significantly restrict production, which was evident when overly wet growing seasons were modelled. If subsoil permeability was found to be significantly lower in irrigated soils, amelioration may be required. In this instance, the use of drying events to generate structure provides an option. Ultimately, the impact of drip irrigation on soil physical quality warrants further attention, and it is imperative to monitor the physical quality of vineyard soils to ensure sustainable production.<br>Thesis (Ph.D.) -- University of Adelaide, School of Earth and Environmental Sciences, 2007.

Bibliography: leaves 131-153.<br>xiii, 153 leaves : ill. (some col.) ; 30 cm.<br>This thesis investigates the mechanisms of manganese (Mn) efficiency (genetic tolerance to Mn-deficient soils) in barley (Hordeum vulgare L.) at both physiological and molecular levels.<br>Thesis (Ph.D.)--University of Adelaide, Dept. of Plant Science, 1996

Includes bibliographies<br>1 v. (various pagings) :<br>Title page, contents and abstract only. The complete thesis in print form is available from the University Library.<br>Thesis (D.E.)--University of Adelaide, 1991

The definition of the principle of effective stress and its implications have been examined for saturated and partly saturated soils. The results of a series of oedometer and all round compression tests of partly saturated and fully saturated soils are presented. These results together with additional experimental data indicate that most soils, from sands right through to clays, exhibit behaviour which, below a critical degree of saturation, cannot be accounted for by the effective stress principle. In sands the critioal degree of saturation appears to be below 50%. In clays, however, the critical degree of saturation is upwards of 85%. An explanation for the observed behaviour of partly saturated soils is offered. It is apparent that structural changes resulting from a change of pressure deficiency in a soil are very different from those resulting from an equivalent change in applied stress. The investigation as a whole indicates that, below the critical degree of saturation, the concept of effective stress in a partly saturated soil is not valid. It is suggested that the term 'intergranular stress' is more suitable than the term 'effective stress' since its use does not imply the validity of the principle of effective stress. The practical significance of the investigation is discussed briefly and the lines along which further research would prove profitable are indicated.

A significant proportion of Australia's sugarcane crop is grown on east-coast estuarine floodplains underlain by pyritic gel-clay subsoils. At the current study site these agricultural acid sulfate soils are typically characterised by a topsoil horizon of river alluvium, a subsoil of oxidised actual acid sulfate soil (AASS), a zone of partially oxidised AASS and a deep sulfidic horizon of pyritic potential acid sulfate soil (PASS). Addition of nitrogenous fertiliser at key points in the sugarcane cropping cycle can create soil nitrogen levels in excess of immediate soil flora/fauna and crop requirements. In high rainfall tropical and sub-tropical regions conditions are thus suitable for nitrate, a strong oxidising agent, to leach down to the sulfidic soil layers with the consequent risk of pyrite oxidation. Little information is available on the fate of nitrogenous fertilisers in these pyritic subsoils. The purpose of this field and laboratory study was to evaluate the potential for nitrate reduction to occur in the presence of pyrite in sugarcane soils in the Tweed River valley, northern NSW, Australia. The study focus was on examining the soil profile hydrology including leaching mechanisms and nitrate concentrations down the profile to the AASS/PASS interface, as well as evaluating the potential for nitrate to increase the rate of pyrite oxidation in this generally anoxic soil zone. Following an investigative nitrogen field trial to gather initial data, a second replicated urea fertiliser treatment trial with a nil-treatment control plot and three nitrogen (N) treatments was set up on a plant-cane-block in collaboration with a Tweed region cane grower, Robert Quirk. Installed loggers recorded rainfall, air and soil temperature, soil moisture and watertable data. Separate surveys and analytical work characterised selected soil physical, morphological and geochemical aspects. Soil profile sampling on four occasions over the twelve month crop cycle was analysed for N-species, NH{u2084}{u207A} and N0{u2083}{u207B}. Hydraulic data analysis showed the watertable generally varying between 0.2 and 1.4 m below ground level with observed strong and rapid responses to rainfall events greater than approximately 15 mm per day. This and associated data supports the postulate that soil nitrate could move down the profile under even moderate precipitation events in these soils. Temperature, pH, redox potential and biological substrate soil data demonstrated the biogeochemical suitability of these subsoil zones to support nitrate reduction. Soil-N analysis revealed significant differences between N-trial treatments using urea fertiliser and also significant nitrogen transformation and movement within the soil profile. Over a period of weeks, the urea fertiliser was rapidly transformed and appeared in the upper profile as elevated levels of ammonium and nitrate ions. The initial high ammonium levels quickly declined to be replaced almost completely by nitrate in the upper layers of the cane soil. Subsequently, increasing soil nitrate concentrations were evident deeper in the soil profile on higher nitrogen treatment plots during the middle phase of the crop cycle. In no instances were significant levels of nitrate detected below the soil redoxcline (the oxic-anoxic boundary) at around 1.0 m depth, nor was nitrate pooling evident anywhere in the AASS transition zone. Laboratory experimental work was undertaken to evaluate nitrate reduction coupled with pyrite oxidation under the biogeochemical conditions existing in the AASS transition zone. Results indicated that nitrate reduction associated with pyrite oxidation does take place in pyritic gel clay from the field site.