Relevant bibliographies by topics / Solid acid catalyst

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  1. Journal articles
  2. Dissertations / Theses
  3. Books
  4. Book chapters
  5. Conference papers
  6. Reports

Academic literature on the topic 'Solid acid catalyst'

Author: Grafiati
Published: 4 June 2021
Last updated: 5 February 2022

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Journal articles on the topic "Solid acid catalyst"

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Hidayati, Nur, Rahmah Puspita Sari, and Herry Purnama. "Catalysis of glycerol acetylation on solid acid catalyst: a review." Jurnal Kimia Sains dan Aplikasi 23, no. 12 (2021): 414–23. http://dx.doi.org/10.14710/jksa.23.12.414-423.

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Biodiesel is a substitute fuel that is environmentally friendly, biodegradable, and sustainable. The need for biodiesel continues to increase. Biodiesel is made through the process of transesterification of triglycerides and alcohol. Glycerol is a side-effect of biodiesel products with a capacity of 10% of the total weight of its production. Glycerol is the simplest glyceride compound and has several functions as a primary ingredient in chemical production. Through acetylation, glycerol is converted to a material that has a higher sale value. Both homogeneous and heterogeneous catalysts are the acetylation approach to achieve the desired product, namely acetyl glycerol esters (mono-, di- and triacetin). However, in the process, the catalyst’s type and characteristics significantly affect the yield and conversion of the product and the deactivation or reusability of the catalyst, which can inhibit the catalyst’s utilization and effectiveness; therefore, it must be studied further. Besides, the parameters that affect the reaction will also be assessed.
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Mohan Kumar T. E, Mohan Kumar T. E., and S. Z. Mohamed Shamshuddin. "O-acetylation of salicylic acid over Zirconium phosphate (ZPO) solid acid catalyst." International Journal of Scientific Research 2, no. 3 (2012): 39–43. http://dx.doi.org/10.15373/22778179/mar2013/14.

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Yarmo, Mohd Ambar, Raja Saadiah Raja Shariff, Siti Rohaya Omar, Juan Joon Ching, and Roziana Haron. "New Perspective in Recent Solid Acid Catalyst." Materials Science Forum 517 (June 2006): 117–22. http://dx.doi.org/10.4028/www.scientific.net/msf.517.117.

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This paper will review on the latest development on solid acid catalysts used in industries as well in research activities. Application of heterogeneous acid catalysis becomes current trend for many industries due to world wide environmental concern. Conventional synthetic or natural zeolites widely used for petrochemical processing, has some limitation because its pore size is normally smaller than reactant molecules. To overcome this challenge new delaminated zeolite process was introduced. In this process specific synthetic zeolite (i.e. ferrierite) was swelled up using specific surfactant followed by sonification to produce the delaminated zeolite. Further modification of this material such as sulfonification reaction to its surface has been found to improve the catalytic activity and selectivity for esterification reaction. Other acid catalyst systems based on mesoporous molecular sieves and Keggin heteropolyacids (HPA) are also discussed in this paper.
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Sharma, Anita, Stuti Katara, Sakshi Kabra, and Ashu Rani. "Acid Activated fly Ash, as a Novel Solid Acid Catalyst for Esterification of Acetic Acid." Indian Journal of Applied Research 3, no. 4 (2011): 37–39. http://dx.doi.org/10.15373/2249555x/apr2013/12.

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Jiang, Qimeng, Guihua Yang, Fangong Kong, Pedram Fatehi, and Xiaoying Wang. "High Acid Biochar-Based Solid Acid Catalyst from Corn Stalk for Lignin Hydrothermal Degradation." Polymers 12, no. 7 (2020): 1623. http://dx.doi.org/10.3390/polym12071623.

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Solid acid catalysts generally show the disadvantage of low acid amount and low recycling rate. To solve these problems, corn stalk-based solid acid catalysts were synthesized through carbonization and sulfonation processes in this work. The results showed that besides the rod-like structure inherited from raw corn stalk, the catalysts contained some small broken pieces on the surface, and the specific surface area varied from 1120 to 1640 m2/g. The functional groups (-SO3H) were successfully introduced onto the surface of the obtained solid acid catalysts. The acid amount varied between 1.2 and 2.4 mmol/g, which was higher than most of solid acid catalysts. The catalyst produced at 800 °C for 6 h in carbonation and then at 150 °C for 8 h in sulfonation had larger specific surface area and more sulfonate groups. In the degradation of lignin, the use of catalyst led to the generation of more aromatic compounds (65.6 wt. %) compared to that without using the catalyst (40.5 wt. %). In addition, a stable yield of reaction (85%) was obtained after four reuses. Therefore, corn stalk is suitable for high-value utilization to prepare high-acid amount biochar-based catalyst.
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Lotfi, Samira, Daria C. Boffito, and Gregory S. Patience. "Gas–solid conversion of lignin to carboxylic acids." Reaction Chemistry & Engineering 1, no. 4 (2016): 397–408. http://dx.doi.org/10.1039/c6re00053c.

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Hidayati, Nur, Titik Pujiati, Elfrida B. Prihandini, and Herry Purnama. "Synthesis of Solid Acid Catalyst from Fly Ash for Eugenol Esterification." Bulletin of Chemical Reaction Engineering & Catalysis 14, no. 3 (2019): 683. http://dx.doi.org/10.9767/bcrec.14.3.4254.683-688.

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A series of fly ash-based heterogeneous acid catalysts were prepared by chemical and thermal treatment. Fly ash was chemically activated using sulfuric acid and followed by thermal activation. Characterization methods of XRD, BET, SEM-EDX, and the performance in esterification of eugenyl acetate production was carried out to reveal the physical and chemical characteristics of prepared catalysts. Activated catalyst showed high silica content (96.5%) and high BET surface area of 70 m2.g-1. The catalyst was proven to be highly active solid acid catalyst for liquid phase esterification of eugenol with acetic acid yielding eugenyl acetate. A yield of 43-48% was obtained with activated fly ash catalysts for 90 minutes reaction. These catalysts may replace beneficially the conventional homogenous liquid acid to the eco-friendly heterogeneous one. Copyright © 2019 BCREC Group. All rights reserved
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Ansanay, Yane, Praveen Kolar, Ratna Sharma-Shivappa, Jay Cheng, Sunkyu Park, and Consuelo Arellano. "Pre-treatment of biomasses using magnetised sulfonic acid catalysts." Journal of Agricultural Engineering 48, no. 2 (2017): 117. http://dx.doi.org/10.4081/jae.2017.594.

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There is a significant interest in employing solid acid catalysts for pre-treatment of biomasses for subsequent hydrolysis into sugars, because solid acid catalysts facilitate reusability, high activity, and easier separation. Hence the present research investigated pretreatment of four lignocellulosic biomasses, namely Switchgrass (Panicum virgatum L ‘Alamo’), Gamagrass (Tripsacum dactyloides), Miscanthus (Miscanthus × giganteus) and Triticale hay (Triticale hexaploide Lart.) at 90°C for 2 h using three carbon-supported sulfonic acid catalysts. The catalysts were synthesized via impregnating p-Toluenesulfonic acid on carbon (regular) and further impregnated with iron nitrate via two methods to obtain magnetic A and magnetic B catalysts. When tested as pre-treatment agents, a maximum total lignin reduction of 17.73±0.63% was observed for Triticale hay treated with magnetic A catalyst. Furthermore, maximum glucose yield after enzymatic hydrolysis was observed to be 203.47±5.09 mg g–1 (conversion of 65.07±1.63%) from Switchgrass treated with magnetic A catalyst. When reusability of magnetised catalysts were tested, it was observed that magnetic A catalyst was consistent for Gamagrass, Miscanthus × Giganteus and Triticale hay, while magnetic B catalyst was found to maintain consistent yield for switchgrass feedstock. Our results suggested that magnetised solid acid catalyst could pre-treat various biomass stocks and also can potentially reduce the use of harsh chemicals and make bioenergy processes environment friendly.
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Zhuang, Jun Ping, Xue Ping Li, and Ying Liu. "Optimal Process Conditions for Levulinic Acid Synthesis from Glucose Using ZSM-5 Supported SO42-/ZrO2 Catalysts." Advanced Materials Research 538-541 (June 2012): 2256–59. http://dx.doi.org/10.4028/www.scientific.net/amr.538-541.2256.

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Levulinic acid has been identified as a promising green, biomass derived platform chemical. Since the availability of fossil resources diminishes, the conversion of carbohydrates to Levulinic acid has become increasingly important. ZSM-5 supported SO42-/ZrO2 solid acid catalyst have been applied for the dehydration of glucose to Levulinic acid. With ZSM-5 supported SO42-/ZrO2 solid acid as the catalyst, an optimized Levulinic acid yield was obtained at 180 °C for 2.5 h with 3 g ZSM-5 supported SO42-/ZrO2 catalyst solid acid catalys and the highest Levulinic acid yield was 55.035%.
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Manayil, Jinesh, Adam Lee, and Karen Wilson. "Functionalized Periodic Mesoporous Organosilicas: Tunable Hydrophobic Solid Acids for Biomass Conversion." Molecules 24, no. 2 (2019): 239. http://dx.doi.org/10.3390/molecules24020239.

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The catalytic deoxygenation of bio-based feedstocks to fuels and chemicals presents new challenges to the catalytic scientist, with many transformations either performed in or liberating water as a byproduct during reaction. The design of catalysts with tunable hydrophobicity to aid product and reactant adsorption or desorption, respectively, is vital for processes including (trans)esterification and condensation reactions employed in sustainable biodiesel production and bio-oil upgrading processes. Increasing surface hydrophobicity of catalyst materials offers a means to displace water from the catalyst active site, and minimizes potential deactivation or hydrolysis side reactions. Hybrid organic–inorganic porous solids offer exciting opportunities to tune surface polarity and hydrophobicity, as well as critical parameters in controlling adsorption, reactant activation, and product selectivity in liquid and vapor phase catalysis. Here, we review advances in the synthesis and application of sulfonic-acid-functionalized periodic mesoporous organosilicas (PMO) as tunable hydrophobic solid acid catalysts in reactions relevant to biorefining and biofuel production.
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Dissertations / Theses on the topic "Solid acid catalyst"

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Ahmad, Husan. "Synthesis of Diazonium Perfluoroalkyl(Aryl) Sufonimide (PFSI) Zwitterions for Solid Acid Alkylation Catalysts." Digital Commons @ East Tennessee State University, 2015. https://dc.etsu.edu/honors/314.

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The final objective of this project is to create an environmentally friendly solid alkylation catalyst to replace the commercially available liquid acid catalysts, such as hydrofluoric acid and sulfuric acid, which are used in the petroleum industry. My research target is to synthesize the diazonium PFSI zwitterions, which can be chemically grafted on the silica as the solid alkylation catalyst. A 4-steps synthesis is designed to prepare the diazonium PFSI zwitterions. The first two steps were successfully completed in the lab. The first one is to prepare the starting material of 4-nitrobenzenesulfonamide from an ammonolysis reaction between 4-nitrobenzene sulfonyl chloride and ammonium hydroxide. And next, a base catalyzed coupling reaction was carried out with 4-nitrobenzenesulfonamide and commercially available perfluorobutane sulfonyl fluoride with nitrogen gas (N2) protection. The coupling product (I in Figure 1) was then purified by extraction and recrystallization. All chemicals in the synthesis procedure were characterized with proton NMR, fluorine NMR, Infrared (IR) spectroscopy and melting points.
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Missengue-Na-Moutoula, Roland. "Synthesis of ZSM-5 zeolite from South African fly ash and its application as solid catalyst." University of the Western cape, 2016. http://hdl.handle.net/11394/5431.

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Philosophiae Doctor - PhD<br>Zeolites are widely used as environmentally friendly solid catalysts or catalyst supports in the refining and petrochemical industries. ZSM-5 zeolite is composed of a three-dimensional medium pore structure (openings of 5-5.5 Å) with high silica content, high temperature stability and strong acidity making it a well-known and an established catalyst for several petroleum derived chemical processes such as cracking, aromatic alkylation, disproportionation, Methanol-to-Gasoline, isomerisation, etc. Nowadays, the synthesis of ZSM-5 zeolite from silica, alumina sources and structure directing agents (templates) is well known. Its synthesis is possible from fly ash, which is a low cost source of both silica and alumina. Fly ash is an inorganic residue resulting from the combustion of coal in electricity generating plants, consisting mostly of SiO₂ and Al₂O₃. ZSM-5 zeolite has not been synthesised from South African coal fly ash and the literature reports that fly ash-based ZSM-5 zeolite was synthesised only with tetrapropylammonium (TPA+) as structure directing agent and required an excessive amount of additional silica. The final ZSM-5 product was reported to still contain fly ash mineral phases after synthesis. This prevents the use of fly ash as a ZSM-5 zeolite precursor. Moreover, the synthesis of a high purity ZSM-5 zeolite from fly ash without additional silica has not been yet reported. This study aimed to synthesise high purity ZSM-5 zeolite from South African coal fly ash without additional silica, and with tetrapropylammonium bromide (TPABr), 1,6- hexanediamine (HDA) or 1-propylamine (PA) as structure directing agent. This aim was achieved by first optimising the synthesis of ZSM-5 zeolite from South African coal fly ash based on a formulation reported in the literature with fumed silica and TPABr as additional source of silica and structure directing agent respectively. Thereafter, the obtained optimum conditions were used to synthesise other fly ash-based ZSM-5 zeolite products by substituting TPABr with HDA or PA. Two routes of treating the as-received fly ash prior to the hydrothermal synthesis were applied in order to improve the quality of the final products or reduce the amount of the fumed silica that was used. The first route consisted of treating the as-received fly ash with concentrated H₂SO₄ in order to remove a certain amount of aluminium and increase the Si/Al in the acid treated fly ash solid residue but also remove some other elements such as Fe, Ca, Mg, and Ti which might have an undesirable effect on the product quality. The acid treated fly ash solid residue was used as ZSM-5 precursor with fumed silica as additional silica source and TPABr, HDA or PA as structure directing agent. The ZSM-5 zeolite products that were synthesised from the as-received fly ash as well as from the H₂SO₄ treated fly ash were treated with oxalic acid solution in order to reduce the aluminium content in the final products. The second route consisted of fusing the as-received fly ash with NaOH and treating the powder fused fly ash extract with oxalic acid solution. The obtained fused and oxalic acid treated fly ash extracts were used as ZSM-5 precursors without additional fumed silica and with TPABr, HDA or PA as structure directing agent. ZSM-5 zeolite was synthesised from the as-received South African coal fly ash not only with the commonly used structure directing agent TPABr but also with two other, lower cost structure directing agents, HDA and PA. The synthesis process did not generate any solid waste as fly ash was used as bulk, which could be a way of valorising South African coal fly ash. However, the final products contained some fly ash mineral phases such as mullite and quartz, and had poor physical and chemical properties compared to a commercial H-ZSM-5 zeolite. The treatment of the as-received fly ash with H₂SO4 resulted in fly ash-based ZSM-5 zeolite products with better physical and chemical properties than those of ZSM-5 zeolite products that were synthesised from the as-received fly ash. Moreover, the post-synthesis treatment of the fly ash-based ZSM-5 zeolite products with oxalic acid resulted in an increase in the Si/Al ratio, offering a post-synthesis route to adjust the acidity of the catalysts. However, mullite and quartz phases were still present in the synthesised products. Alternatively, high purity ZSM-5 zeolite was synthesised from the fused and oxalic treated fly ash extracts without additional silica and with TPABr, HDA or PA as structure directing agent. Moreover, these synthesised fly ash-based ZSM-5 zeolite products had similar physical and chemical properties to the commercial H-ZSM-5 zeolite. The synthesised fly ash-based ZSM-5 zeolite products were used as solid catalysts in the Methanol-to-Olefins (MTO) and Nazarov reactions. The ZSM-5 zeolite products that were synthesised from the H₂SO4 treated fly ash as well as fused and oxalic treated fly ash were successfully used as solid catalysts in the MTO and Nazarov reactions. The ZSM-5 zeolite products that were synthesised from the H₂SO₄ treated fly ash presented a similar trend in MTO and Nazarov reactions depending on the structure directing agent that was used, and the ZSM-5 zeolite that was synthesised with HDA as structure directing agent had the highest MTO and Nazarov conversion. However these catalysts deactivated more quickly compared to the commercial H-ZSM-5 zeolite. On the other hand, the zeolites that were synthesised from the fused and oxalic acid treated fly ash had a high initial MTO conversion equivalent to the commercial H-ZSM-5 zeolite. However, they deactivated after 5 h of time on stream due to diffusional constraints, because of their large crystal sizes. This study developed novel routes in the synthesis of high value zeolites from fly ash. ZSM-5 zeolite was synthesised from fly ash with structure directing agents other that TPA+ cation and had acceptable Brønsted acidity and high initial conversion in MTO and Nazarov reactions. This has not been yet reported in the literature. Moreover, for the first time a high purity ZSM-5 zeolite was synthesised from fly ash without additional silica and had similar properties to a commercial H-ZSM-5 zeolite. This constituted a breakthrough in the fly ash-based ZSM-5 zeolite synthesis procedure, which will promote the valorisation of fly ash through ZSM-5 synthesis due to avoiding the addition of silica source in the hydrothermal gel and preventing the presence of fly ash mineral phases in the final products. This study can have a significant economic and environmental impact in South Africa if the synthesis process is scaled up as it provides a potentially cheap and innovative way of using waste for making a high value green and acid catalyst, namely ZSM-5 zeolite that has several catalytic applications; and it promotes the valorisation of South African coal fly ash that is considered by many as waste material.<br>National Research Foundation (NRF)
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McIntosh, Debra Joy. "Synthesis and characterization of mesoporous sulfated zirconia and its use as a solid acid catalyst." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape7/PQDD_0019/MQ48026.pdf.

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Lemoine, Gaetan. "Comparison of different types of Zeolites used as Solid Acid Catalysts in the Transesterification reaction of Jatropha-type oil for Biodiesel production." Digital WPI, 2013. https://digitalcommons.wpi.edu/etd-theses/268.

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Sustainable energy management has become a high priority for many countries. A great majority of our energy stocks comes from non-renewable fossil fuels, which are currently dwindling. Biofuels are one of the most promising solutions being researched to address this urgent problem. In particular, using transesterified Jatropha curcas L. oil appears to be a promising method of producing biofuels due to several properties of the plant, such as the high oil yield of its seeds and the fact that it does not compete with food crops. The literature mentions many attempts of using zeolites as solid acid catalysts in transesterification reactions of vegetable oils with high free fatty acid (FFA) content. The acid catalysis prevents soap formation and emulsification, which can be observed in the basic process. The use of a solid catalyst makes the separation and purification of the final products steps easier to implement in comparison to catalysis in homogeneous conditions. However, the efficiency of the zeolite in the heterogeneous transesterification reaction of vegetable oil is not well-known yet and varies on the structure of the catalyst used. This project aims at better understanding the relationship between the type of zeolite used and the yield of this particular reaction using reconstituted Jatropha oil from Sesame seed oil, which has a similar composition. Five different types of zeolites were compared: Y, X, Beta, Mordenite & ZSM-5. Non-catalyzed reactions as well as homogeneously catalyzed - with H2SO4 - reactions were also implemented. Since we take advantage of the catalytic properties of different zeolites, the one that were not already in hydrogen form were ion-exchanged and the ion-exchanged species were then analyzed by Energy-Dispersive X-Ray spectroscopy (EDX). Three alcohol-to-oil ratios were tested at atmospheric pressure and at T=115°C for each catalyst in order to determine the influence of this ratio. All experiments were conducted in an airtight autoclave with butan-1-ol in order to obtain a biofuel whose cetane index is higher than regular petroleum-based diesels.
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Ikenberry, Myles. "Acid monolayer functionalized iron oxide nanoparticle catalysts." Diss., Kansas State University, 2014. http://hdl.handle.net/2097/17060.

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Doctor of Philosophy<br>Department of Chemical Engineering<br>Keith L. Hohn<br>Superparamagnetic iron oxide nanoparticle functionalization is an area of intensely active research, with applications across disciplines such as biomedical science and heterogeneous catalysis. This work demonstrates the functionalization of iron oxide nanoparticles with a quasi-monolayer of 11-sulfoundecanoic acid, 10-phosphono-1-decanesulfonic acid, and 11-aminoundecanoic acid. The carboxylic and phosphonic moieties form bonds to the iron oxide particle core, while the sulfonic acid groups face outward where they are available for catalysis. The particles were characterized by thermogravimetric analysis (TGA), transmission electron microscopy (TEM), potentiometric titration, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), inductively coupled plasma optical emission spectrometry (ICP-OES), X-ray photoelectron spectrometry (XPS), and dynamic light scattering (DLS). The sulfonic acid functionalized particles were used to catalyze the hydrolysis of sucrose at 80˚C and starch at 130˚C, showing a higher activity per acid site than the traditional solid acid catalyst Amberlyst-15, and comparing well against results reported in the literature for sulfonic acid functionalized mesoporous silicas. In sucrose catalysis reactions, the phosphonic-sulfonic nanoparticles (PSNPs) were seen to be incompletely recovered by an external magnetic field, while the carboxylic-sulfonic nanoparticles (CSNPs) showed a trend of increasing activity over the first four recycle runs. Between the two sulfonic ligands, the phosphonates produced a more tightly packed monolayer, which corresponded to a higher sulfonic acid loading, lower agglomeration, lower recoverability through application of an external magnetic field, and higher activity per acid site for the hydrolysis of starch. Functionalizations with 11-aminoundecanoic acid resulted in some amine groups binding to the surfaces of iron oxide nanoparticles. This amine binding is commonly ignored in iron oxide nanoparticle syntheses and functionalizations for biomedical and catalytic applications, affecting understandings of surface charge and other material properties.
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Martinis, Coll Jorge Maximiliano. "Single event kinetic modeling of solid acid alkylation of isobutane with butenes over proton-exchanged Y-Zeolites." Diss., Texas A&M University, 2004. http://hdl.handle.net/1969.1/3232.

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Complex reaction kinetics of the solid acid alkylation of isobutane with butenes over a proton-exchanged Y-zeolite has been modeled at the elementary step level. Starting with a computer algorithm that generated the reaction network based on the fundamentals of the carbenium ion chemistry, the formation of over 100+ product species has been modeled in order to gain understanding of the underlying phenomena leading to rapid catalyst deactivation and product selectivity shifts observed in experimental runs. An experimental investigation of the solid acid alkylation process was carried out in a fixed bed catalytic reactor operating with an excess of isobutane under isothermal conditions at moderate temperatures (353-393 K) in liquid phase. Experimental data varying with run-time for a set of butene space-times and reaction temperatures were collected for parameter estimation purposes. A kinetic model was formulated in terms of rate expressions at the elementary step level including a rigorous modeling of deactivation through site coverage. The single event concept was applied to each rate coefficient at the elementary step level to achieve a significant reduction in the number of model parameters. Based on the identification of structural changes leading to the creation or destruction of symmetry axes and chiral centers in an elementary step, formulae have been developed for the calculation of the number of single events. The Evans-Polanyi relationship and the concept of stabilization energy were introduced to account for energy levels in surface-bonded carbenium ions. A novel functional dependency of the stabilization energy with the nature of the carbenium ion and the carbon number was proposed to account for energy effects from the acid sites on the catalyst. Further reductions in the number of parameters and simplification of the equations for the transient pseudohomogeneous one-dimensional plug-flow model of the reactor were achieved by means of thermodynamic constraints. Altogether, the single event concept, the Evans-Polanyi relationship, the stabilization energy approach and the thermodynamic constraints led to a set of 14 parameters necessary for a complete description of solid acid alkylation at the elementary step level.
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Iwase, Yukari. "Application of Metal Nanoparticles and Polyoxometalates for Efficient Photocatalysis and Catalysis." Kyoto University, 2018. http://hdl.handle.net/2433/232051.

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Li, Zhijian. "Novel solid base catalysts for Michael additions." Doctoral thesis, [S.l.] : [s.n.], 2005. http://deposit.ddb.de/cgi-bin/dokserv?idn=976576759.

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Long, Wei. "Designing immobilized catalysts for chemical transformations: new platforms to tune the accessibility of active sites." Diss., Georgia Institute of Technology, 2012. http://hdl.handle.net/1853/49017.

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Chemical catalysts are divided into two traditional categories: homogeneous and heterogeneous catalysts. Although homogeneous (molecular) catalysts tend to have high activity and selectivity, their wide application is hampered by the difficulties in catalyst separation. In contrast, the vast majority of industrial scale catalysts are heterogeneous catalysts based on solid materials. Immobilized catalysts, combining the advantages of homogeneous and heterogeneous catalysts, have developed into an important field in catalysis research. This dissertation presents synthesis, characterization and evaluation of several novel immobilized catalysts. In the first part, MNP supported aluminum isoproxide was developed for ROP of Є-caprolactone to achieve facile magnetic separation of catalysts from polymerization system and reduce toxic metal residues in the poly(caprolactone) product. Chapter 3 presents a silica coated MNP supported DMAP catalyst that was synthesized and displayed good activity and regio-selectivity in epoxide ring opening reactions. In Chapter 4, hybrid sulfonic acid catalysts based on polymer brush materials have been developed. The unique polymer brush architecture permits high catalyst loadings as well as easy accessibility of the active sites to be achieved in this catalytic system. In Chapter 5, aminopolymer-silica composite supported Pd catalysts with good activity and selectivity were developed for the selective hydrogenation of alkynes. In this case, the aminopolymer composite works as a stabilizer for palladium nanoparticles, as well as a modifier to tune the catalyst selectivity. All in all, the general theme of the thesis is developing new immobilized catalysts with improved activity/selectivity as well as easy separation via rational catalyst design.
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Yamamoto, Takashi. "Studies on the Catalysis by New Solid Acid Catalysts and the Characterization." Kyoto University, 1999. http://hdl.handle.net/2433/77922.

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Books on the topic "Solid acid catalyst"

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Elings, Jacob Antonius. Solid-acid catalysed reactions with epoxides and allyl aryl ethers. Delft University Press, 1997.

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Li, Xiaohong. Preparation and characterization of sulfated ZrO₂ solid acid catalysts. 1994.

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Solid Acid Catalysis From Fundamentals To Applications. Pan Stanford Publishing Pte Ltd, 2014.

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United States. National Aeronautics and Space Administration., ed. Active sites and roles of solid acid base catalysts. National Aeronautics and Space Administration, 1988.

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Kōzō, Tanabe, ed. New solid acids and bases: Their catalytic properties. Kodansha, 1989.

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New solid acids and bases: Their catalytic properties (Studies in surface science and catalysis). [Distributors] for the U.S.A. and Canada, Elsevier Science Pub. Co, 1989.

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K, Tanaabe, and United States. National Aeronautics and Space Administration., eds. A new method of determining acid base strength distribution and a new acidity-basicity scale for solid catalysts: The strongest point, Ho. National Aeronautics and Space Administration, 1988.

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Book chapters on the topic "Solid acid catalyst"

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Pai, Shivanand M., Raj Kumar Das, S. A. Kishore Kumar, Lalit Kumar, Ashvin L. Karemore, and Bharat L. Newalkar. "Emerging Trends in Solid Acid Catalyst Alkylation Processes." In Catalysis for Clean Energy and Environmental Sustainability. Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-65021-6_4.

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Ngaosuwan, Kanokwan. "Solid Acid Catalyst Derived from Coffee Residue for Biodiesel Production." In Renewable Energy in the Service of Mankind Vol I. Springer International Publishing, 2015. http://dx.doi.org/10.1007/978-3-319-17777-9_5.

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Petkovic, Lucia M., Daniel M. Ginosar, David N. Thompson, and Kyle C. Burch. "Application of Supercritical Fluids to Solid Acid Catalyst Alkylation and Regeneration." In ACS Symposium Series. American Chemical Society, 2007. http://dx.doi.org/10.1021/bk-2007-0959.ch013.

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Li, Jia, Yan Li, and Hua Zhao. "Production of Ethyl Acetate Catalyzed by Activated Carbon-Based Solid Acid Catalyst." In Lecture Notes in Electrical Engineering. Springer Singapore, 2017. http://dx.doi.org/10.1007/978-981-10-4801-2_66.

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Lu, Pengmei, Lianhua Li, Weiwei Liu, and Zhenhong Yuan. "Biodiesel Production from High Acidified Oil Through Solid Acid Catalyst and Plug Flow Reactor." In Proceedings of ISES World Congress 2007 (Vol. I – Vol. V). Springer Berlin Heidelberg, 2008. http://dx.doi.org/10.1007/978-3-540-75997-3_486.

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Witono, Judy R. B., Ken Hashigata, Herry Santoso, and Inge W. Noordergraaf. "Exploration of Carbon Based Solid Acid Catalyst Derived from Corn Starch for Conversion of Non-edible Oil into Biodiesel." In Springer Proceedings in Physics. Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-46601-9_19.

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Cho, Hyejin, Christian Schäfer, and Béla Török. "Microwave-Assisted Solid Acid Catalysis." In Microwaves in Catalysis. Wiley-VCH Verlag GmbH & Co. KGaA, 2015. http://dx.doi.org/10.1002/9783527688111.ch10.

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Tanabe, Kozo. "Acid-Base Bifunctional Catalysis." In Acidity and Basicity of Solids. Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-011-0986-4_16.

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Toba, Makoto, Atsuhiko Katayama, Genki Takeuchi, Shu-ichi Niwa, Fujio Mizukami, and Shuichi Mitamura. "Isopropylation of Naphthalene over Solid Acid Catalysts." In ACS Symposium Series. American Chemical Society, 1999. http://dx.doi.org/10.1021/bk-2000-0738.ch021.

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Xu, Jun, Qiang Wang, Shenhui Li, and Feng Deng. "Solid-State NMR Characterization of Acid Properties of Zeolites and Solid Acid Catalysts." In Lecture Notes in Chemistry. Springer Singapore, 2019. http://dx.doi.org/10.1007/978-981-13-6967-4_5.

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Conference papers on the topic "Solid acid catalyst"

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Yang, Liao, Li Yan, Tong Peijie, Zhao Shilin, and Liao Xuepin. "A Novel Fibrous Zirconium Sulfate Solid Acid Catalyst for Esterification Reaction." In 2011 International Conference on Computer Distributed Control and Intelligent Environmental Monitoring (CDCIEM). IEEE, 2011. http://dx.doi.org/10.1109/cdciem.2011.114.

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"Esterification of Free Fatty Acids in Waste Oil Using a Carbon-based Solid Acid Catalyst." In 2nd International Conference on Emerging Trends in Engineering and Technology. International Institute of Engineers, 2014. http://dx.doi.org/10.15242/iie.e0514546.

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Kafuku, Gerald, Makme Mbarawa, Man Kee Lam, and Keat Teong Lee. "Optimized Preparation of Moringa Oleifera Methyl Esters Using Sulfated Tin Oxide as Heterogenous Catalyst." In ASME 2010 4th International Conference on Energy Sustainability. ASMEDC, 2010. http://dx.doi.org/10.1115/es2010-90503.

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Abstract:
Fatty acid methyl esters (biodiesel), prepared from transesterification of vegetable oils or animal fats, have gained great importance in substituting petroleum based diesel for combating environmental problems and higher diesel prices. Moringa oleifera fatty acids are among the newly investigated potentials for biodiesel production in recent years. In getting rid of soap formation and thus large waste washing water from biodiesel produced from homogenous catalysts, the use of heterogeneous catalysts is currently preferred due to easily separation and purification of the final products. In this study, biodiesel was produced from moringa oleifera oil using sulfated tin oxide enhanced with SiO2 (SO42−/SnO2−SiO2) as super acid solid catalyst. The experimental design was done using design of experiment (DoE), specifically, response surface methodology based on three-variable central composite design (CCD) with alpha (α) = 2. The reaction parameters in the optimization process were reaction temperature (60°C to 180°C), reaction period (1 to 3 hrs) and methanol to oil ratio (1:6 to 1:24 mol/mol). It was observed that the yield up to 84wt% of moringa oleifera methyl esters can be obtained with reaction conditions of 150°C temperature, 150 minutes reaction time and 1:19.5 methanol to oil ratio, while catalyst concentration and agitation speed are kept at 3wt% and 350 rpm respectively.
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Lim, Steven, Pang Yean Ling, and Leong Weng Jun. "Synthesis and characterisation of carbon-based solid acid catalyst from Jatropha biomass for biodiesel production." In INTERNATIONAL SYMPOSIUM ON GREEN AND SUSTAINABLE TECHNOLOGY (ISGST2019). AIP Publishing, 2019. http://dx.doi.org/10.1063/1.5126587.

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Krishnan, Shamala Gowri, Fei Ling Pua, Kumaran Palanisamy, and Sharifah Nabihah Syed Jaafar. "Oil palm EFB supported solid acid catalyst for esterification reaction: Optimization and parametric effects study." In PROCEEDINGS OF THE 3RD INTERNATIONAL CONFERENCE ON AUTOMOTIVE INNOVATION GREEN ENERGY VEHICLE: AIGEV 2018. Author(s), 2019. http://dx.doi.org/10.1063/1.5085990.

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Jenie, S. N. Aisyiyah, Anis Kristiani, Kustomo, Sabar Simanungkalit, and Dieni Mansur. "Preparation of nanobiochar as magnetic solid acid catalyst by pyrolysis-carbonization from oil palm empty fruit bunches." In PROCEEDINGS OF THE 3RD INTERNATIONAL SYMPOSIUM ON APPLIED CHEMISTRY 2017. Author(s), 2017. http://dx.doi.org/10.1063/1.5011875.

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Diana, Nur Indah Fajar Mukti, and Arif Hidayat. "Performance of Indion ion exchange resin as solid catalyst for the esterification of oleic acid with glycerol." In THE 11TH REGIONAL CONFERENCE ON CHEMICAL ENGINEERING (RCChE 2018). Author(s), 2019. http://dx.doi.org/10.1063/1.5095045.

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ZHANG, SHI-HONG, XUE-YAN TU, ZHONG-MIN YANG, et al. "A STUDY ON CATALYTIC WET OXIDATION OF SIMULATED WASTEWATER SUCCINIC ACID AQUEOUS SOLUTION WITH Ru/TiO2 CATALYST." In Proceedings of the International Symposium on Solid State Chemistry in China. WORLD SCIENTIFIC, 2002. http://dx.doi.org/10.1142/9789812776846_0036.

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Dekamin, Mohammad, M. Reza Naimi-Jamal, and Narges Ghadaksaz. "A Facile Biginelli Reaction on Grinding Using Nano-Ordered MCM-41-SO3H as an Efficient Solid Acid Catalyst." In The 15th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2011. http://dx.doi.org/10.3390/ecsoc-15-00772.

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Le, Son Dinh, Shun Nishimura, and Kohki Ebitani. "Synthesis of N-hydroxysuccinimide from succinic acid and hydroxylammonium chloride using Amberlyst A21 as reusable solid base catalyst." In THE IRAGO CONFERENCE 2017: A 360-degree Outlook on Critical Scientific and Technological Challenges for a Sustainable Society. Author(s), 2018. http://dx.doi.org/10.1063/1.5021930.

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Reports on the topic "Solid acid catalyst"

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Williamson, R., J. Holladay, M. Jaffe, and D. Brunelle. Continuous Isosorbide Production From Sorbitol Using Solid Acid Catalysis. Office of Scientific and Technical Information (OSTI), 2006. http://dx.doi.org/10.2172/892556.

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Allenger, V. M. Synthesis of liquid fuels by reacting acetylene over solid acid catalysts. Natural Resources Canada/ESS/Scientific and Technical Publishing Services, 1985. http://dx.doi.org/10.4095/302609.

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Haw, James F. NMR Computational Studies of Solid Acidity/Fundamental Studies of Catalysis by Solid Acids. Office of Scientific and Technical Information (OSTI), 2008. http://dx.doi.org/10.2172/1049372.

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