Academic literature on the topic 'Solid base catalysis'

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Journal articles on the topic "Solid base catalysis"

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Dwulet, Gregory E., Benjamin J. Coscia, Michael R. Shirts, and Douglas L. Gin. "A nanostructured bifunctional acid–base catalyst resin formed by lyotropic liquid crystal monomers." Canadian Journal of Chemistry 98, no. 7 (2020): 332–36. http://dx.doi.org/10.1139/cjc-2019-0408.

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An ordered, nanoporous polymer resin was prepared from the self-assembly of lyotropic liquid crystal monomers and employed as a heterogeneous, bifunctional catalyst. This material contains antagonistic acid and base sites in the periodic nanopores and efficiently catalyzes a model tandem reaction (i.e., the deacetalization–nitroaldol reaction between benzaldehyde dimethyl acetal and nitromethane to yield β-nitrostyrene) with excellent product selectivity. This lyotropic liquid crystal-based solid catalyst represents one of the few examples of polymeric tandem catalysts synthesized by a “bottom
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Shi, Huancong, Min Huang, Qiming Wu, et al. "Study of Catalytic CO2 Absorption and Desorption with Tertiary Amine DEEA and 1DMA-2P with the Aid of Solid Acid and Solid Alkaline Chemicals." Molecules 24, no. 6 (2019): 1009. http://dx.doi.org/10.3390/molecules24061009.

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Studies of catalytic CO2 absorption and desorption were completed in two well-performed tertiary amines: diethylmonoethanolamine (DEEA) and 1-dimethylamino-2-propanol (1DMA-2P), with the aid of CaCO3 and MgCO3 in the absorption process, and with the aid of γ-Al2O3 and H-ZSM-5 in the desorption process. The batch process was used for CO2 absorption with solid alkalis, and the recirculation process was used for CO2 desorption with solid acid catalysts. The CO2 equilibrium solubility and pKa were also measured at 293 K with results comparable to the literature. The catalytic tests discovered that
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Kikkawa, Soichi, Mio Tsukada, Kanako Shibata, et al. "Base Catalysis of Sodium Salts of [Ta6−xNbxO19]8− Mixed-Oxide Clusters." Symmetry 13, no. 7 (2021): 1267. http://dx.doi.org/10.3390/sym13071267.

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The solid base catalysis of sodium salts of Lindqvist-type metal oxide clusters was investigated using a Knoevenagel condensation reaction. We successfully synthesized the sodium salts of Ta and Nb mixed-oxide clusters Na8−nHn[(Ta6−xNbx)O19]·15H2O (Na-Ta6−xNbx, n = 0, 1, x = 0–6) and found them to exhibit activity for proton abstraction from nitrile substrates with a pKa value of 23.8, which is comparable to that of the conventional solid base MgO. The Ta-rich Na-Ta6 and Na-Ta4Nb2 exhibited high activity among Ta and Nb mixed-oxide clusters. Synchrotron X-ray diffraction (SXRD) measurements, F
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Onaka, Makoto, Tsunetake Seki, and Yoich Masui. "Recent Studies on Solid Acid Catalysis and Solid Base Catalysis for Fine Chemicals Synthesis." Journal of Synthetic Organic Chemistry, Japan 63, no. 5 (2005): 492–502. http://dx.doi.org/10.5059/yukigoseikyokaishi.63.492.

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Alcaraz, J. "Solid base catalysts for mercaptan oxidation." Catalysis Today 43, no. 1-2 (1998): 89–99. http://dx.doi.org/10.1016/s0920-5861(98)00137-0.

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Zhang, Chen-Yang, Wen-Li Shao, Wei-Xia Zhou, et al. "Biodiesel Production by Esterification Reaction on K+ Modified MgAl-Hydrotalcites Catalysts." Catalysts 9, no. 9 (2019): 742. http://dx.doi.org/10.3390/catal9090742.

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K+ modified hydrotalcites and its activity as a solid base catalyst for ultrasonic wave- assisted biodiesel conversion was investigated. The solid alkaline catalysts of the MgAl-hydrotalcites (HT) was prepared by co-precipitation and modified with K+ by impregnation. The influence of K+ incorporation on the performance of Mg-Al hydrotalcites catalysts was investigated by SmartLab X-ray powder diffractometer (XRD), infrared spectrum (IR), thermogravimetric-differential thermal analysis (TG–DTA), CO2 temperature programmed desorption (CO2-TPD), scanning electron microscopy (SEM), and N2 adsorpti
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Auriemma, Finizia, and Claudio De Rosa. "Theoretical investigation of (MgCl2)xpolynuclear species formed during preparation of MgCl2-supported Ziegler–Natta catalysts from solid solvates." Journal of Applied Crystallography 41, no. 1 (2008): 68–82. http://dx.doi.org/10.1107/s0021889807054453.

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A novel approach for the study of the nature of the active species in Ziegler–Natta catalysis is described. This approach is based on the study of reliable structural models for disordered (MgCl2)xpolynuclear species which develop during the preparation of MgCl2-supported catalysts starting from MgCl2–Lewis-base adducts, and the calculation of X-ray diffraction patterns of these models. A method for the calculation of the X-ray powder diffraction patterns of the model structures is devised. This diffraction modelling method may be useful for the correct interpretation of the nature of some dif
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Dai, Yong-Ming, Cheng-Hsuan Hsieh, Jia-Hao Lin, Fu-Hsuan Chen, and Chiing-Chang Chen. "Biodiesel Production Using Bauxite in Low-Cost Solid Base Catalyst Precursors." Catalysts 9, no. 12 (2019): 1064. http://dx.doi.org/10.3390/catal9121064.

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Investigation was conducted on bauxite mixed with Li2CO3 as alkali metal catalysts for biodiesel production. Bauxite contains a high percentage of Si and Al compounds among products. Because of the high expense of commercial materials (SiO2, Al2O3) that makes them not economical, the method was very recently improved by replacing commercial materials with Si and Al from bauxite. This is one of the easiest methods for preparing heterogeneous transesterification catalysts, through one-pot blending, grinding bauxite with Li2CO3, and heating at 800 °C for 4 h. The prepared solid-base alkali metal
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Vakros, John. "Biochars and Their Use as Transesterification Catalysts for Biodiesel Production: A Short Review." Catalysts 8, no. 11 (2018): 562. http://dx.doi.org/10.3390/catal8110562.

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Biodiesel can be a significant alternative for diesel. Usually, it is produced through transesterification with a base catalyst. Using heterogeneous catalysts for transesterification, the process can be more efficient. Among the possible catalysts that can be used, biochars combine high performance for transesterification and valorization of waste biomass. Biochars are cheap materials, and are easy to activate through chemical treatment with acid or base solutions. In this short review, the application of biochar as solid heterogeneous catalysts for transesterification of lipids to produce bio
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Purnamasari, Amalia Putri, Meyga E. F. Sari, Desy T. Kusumaningtyas, Suprapto Suprapto, Abdul Hamid, and Didik Prasetyoko. "The Effect of Mesoporous H-ZSM-5 Crystallinity as a CaO Support on the Transesterification of Used Cooking Oil." Bulletin of Chemical Reaction Engineering & Catalysis 12, no. 3 (2017): 329. http://dx.doi.org/10.9767/bcrec.12.3.802.329-336.

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Transesterification of used cooking oil was carried out over calcium oxide supported on mesoporous H-ZSM-5 prepared from kaolin as solid base catalysts. Solid basic catalysts investigated in this study were characterized by XRD, FTIR spectroscopy, and N2 adsorption-desorption techniques. The XRD pattern showed peaks corresponding to the CaO and mesoporous ZSM-5 in the sample. The peak intensity of the CaO increased as CaO loading in ZSM-5 was increased. The characterization based on FTIR spectroscopy revealed that CaO/H-ZSM-5 solids have functional groups characteristics of both CaO and mesopo
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Dissertations / Theses on the topic "Solid base catalysis"

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Li, Zhijian. "Novel solid base catalysts for Michael additions." Doctoral thesis, [S.l.] : [s.n.], 2005. http://deposit.ddb.de/cgi-bin/dokserv?idn=976576759.

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Wight, Andrea P. Davis Mark E. "I. Synthesis, characterization, and base catalysis of organic-functionalized molecular sieves. : II. Selective oxidation of ethane via heteropolyanion-containing solid catalysts /." Diss., Pasadena, Calif. : California Institute of Technology, 2004. http://resolver.caltech.edu/CaltechETD:etd-05252004-102344.

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Woodford, Julia Jane. "Hierarchical nanoporous solid base catalysts for biodiesel synthesis." Thesis, Cardiff University, 2013. http://orca.cf.ac.uk/51927/.

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The discovery of alternative solid base catalysts to replace homogeneous catalysts currently used in the industrial synthesis of biodiesel could remove the need for atom and energy inefficient routes to the desired biofuel product, and allow for the possibility of a continuous production process. Hydrotalcites have shown promise as catalysts in the transesterification of triglycerides with methanol to form biodiesel; however their activity is hampered by slow diffusion of the bulky triglycerides through the microporous hydrotalcite structure and poor accessibility of the active sites. This the
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Abdoullah, Mohamad. "Supported transition metal oxides as solid base catalysts." Thesis, University of Huddersfield, 2016. http://eprints.hud.ac.uk/id/eprint/28325/.

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The initial objective of the work studied here was to investigate the effects of isomorphously-substituted transition metals in lattice sites in Layered Double Hydroxides (LDHs) in terms of basicity and catalytic activity in base-catalysed reactions and oxidation reactions. Experiments in which copper(II), nickel(II), cobalt(II), zinc(II) and iron(III) were substituted in the lattice of synthetic hydrotalcites showed that, on calcination, the resultant mixed oxides arising from hydrotalcites containing copper(II) exhibited the greatest enhancement of catalytic activity. Test reactions were the
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Patil, Pratap Tukaram. "Nanoscopic metal fluoride based novel solid catalysts." Doctoral thesis, Humboldt-Universität zu Berlin, Mathematisch-Naturwissenschaftliche Fakultät I, 2009. http://dx.doi.org/10.18452/16021.

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Metallfluoride sind dank ihrer hohen chemischen und thermischen Stabilität, insbesondere bei Reaktionen unter Beteiligung von hoch korrosiven Gasen (HF, HCl, Cl2, F2) den entsprechenden Oxiden überlegen. Über den Sol-Gel Prozess synthetisierte Produkte weisen oft spezifische, zum Teil sehr unterschiedliche Eigenschaften im Vergleich zu klassisch hergestellten Verbindungen auf. In dieser Arbeit wurde der Sol-Gel Prozess zur Herstellung von binären Fluoriden (AlF3, MgF2, CaF2, CuF2 und FeF3) genutzt und zum Teil weiter entwickelt sowie das Synthesepotential dieser Methode als Zugang für komplex
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Al-Haq, Nazli. "Novel organo-bridged polysilsesquioxanes towards environmentally friendly solid acid and base catalysts." Thesis, Queen Mary, University of London, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.420569.

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Elbakush, Mohamed Mostafa. "Structure and function relationship in novel solid organic-inorganic hybrid base catalysts." Thesis, University of Huddersfield, 2016. http://eprints.hud.ac.uk/id/eprint/30285/.

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The overall objective of this study was to prepare and optimise solid base catalysts for liquid phase reactions, based on silica support materials functionalised with alkyl amine groups. The study included an investigation of the effect of the pore volume, surface area and the surface chemical characteristics of the silica support on the catalyst performance. The role of surface silanol groups remaining on the silica surface after functionalisation working cooperatively with basic amine groups was also studied. A series of silica gel supports, together with a commercially-available ordered mes
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Hooper, Thomas J. N. "Solid state nuclear magnetic resonance on quadrupolar nuclei in disordered catalysis based materials." Thesis, University of Warwick, 2017. http://wrap.warwick.ac.uk/101212/.

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The behaviour of a catalyst is intrinsically linked to its structure and, therefore, accurate structural refinements are desired to tune their overall function. Higher functional demands on catalysts systems, require more complex disordered materials which are inherently difficult to characterise with conventional analytical techniques. Solid state NMR is an excellent probe of local order and, hence, is utilised in this thesis for the structural determination of several catalytic related materials. The first direct105 Pd solid state NMR measurements of diamagnetic (K2PdCl6, (NH4)2PdCl6 and K2P
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Coe, Neil J. "A study of Ni based fuel reforming anodes for solid oxide fuel cells." Thesis, Keele University, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.343244.

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The anode material in a conventional design of solid oxide fuel cell (SOFC) operating above 1123 K is typically made from NiO/Zirconia. NiO/Zirconia anodes are known to perform well in hydrogen but exhibit difficulties when natural gas is used as a fuel. Natural gas is much cheaper than hydrogen and widely available but causes carbon deposition and deactivation of the NiO/Zirconia SOFC anode. One objective of this work was to prepare and characterize NiO/Zirconia anodes both as powders and as applied to extruded zirconia tubes. The problem of carbon deposition when NiO/Zirconia anodes operate
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Guzman, Montanez Felipe. "SAMARIUM-BASED INTERMEDIATE TEMPERATURE SOLID OXIDE FUEL CELLS." University of Akron / OhioLINK, 2005. http://rave.ohiolink.edu/etdc/view?acc_num=akron1134056820.

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Books on the topic "Solid base catalysis"

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Hideshi, Hattori, and SpringerLink (Online service), eds. Solid Base Catalysis. Springer Berlin Heidelberg, 2011.

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Ono, Yoshio, and Hideshi Hattori. Solid Base Catalysis. Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/978-3-642-18339-3.

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Hattori, Hideshi, and Yoshio Ono. Solid Base Catalysis. Springer, 2012.

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Hattori, Hideshi, and Yoshio Ono. Solid Base Catalysis. Springer, 2016.

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Solid Base Catalysis Springer Series in Chemical Physics. Springer, 2011.

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New solid acids and bases: Their catalytic properties (Studies in surface science and catalysis). [Distributors] for the U.S.A. and Canada, Elsevier Science Pub. Co, 1989.

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United States. National Aeronautics and Space Administration., ed. Active sites and roles of solid acid base catalysts. National Aeronautics and Space Administration, 1988.

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Kōzō, Tanabe, ed. New solid acids and bases: Their catalytic properties. Kodansha, 1989.

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New Solid Acids and Bases - Their Catalytic Properties. Elsevier, 1989. http://dx.doi.org/10.1016/s0167-2991(08)x6021-5.

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K, Tanaabe, and United States. National Aeronautics and Space Administration., eds. A new method of determining acid base strength distribution and a new acidity-basicity scale for solid catalysts: The strongest point, Ho. National Aeronautics and Space Administration, 1988.

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Book chapters on the topic "Solid base catalysis"

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Ono, Yoshio, and Hideshi Hattori. "Preparation and Catalytic Properties of Solid Base Catalysts — I. Metal Oxides." In Solid Base Catalysis. Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/978-3-642-18339-3_3.

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Ono, Yoshio, and Hideshi Hattori. "Preparation and Catalytic Properties of Solid Base Catalysts — II. Specific Materials for Solid Bases." In Solid Base Catalysis. Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/978-3-642-18339-3_4.

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Ono, Yoshio, and Hideshi Hattori. "Introduction." In Solid Base Catalysis. Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/978-3-642-18339-3_1.

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Ono, Yoshio, and Hideshi Hattori. "Characterization of Solid Base Catalysts." In Solid Base Catalysis. Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/978-3-642-18339-3_2.

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Ono, Yoshio, and Hideshi Hattori. "Reactions Catalyzed by Solid Bases." In Solid Base Catalysis. Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/978-3-642-18339-3_5.

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Ono, Yoshio, and Hideshi Hattori. "Solid Base Catalysts for Specific Subjects." In Solid Base Catalysis. Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/978-3-642-18339-3_6.

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Motokura, Ken, Toshihide Baba, and Yasuhiro Iwasawa. "Acid-Base Cooperative Catalysis for Organic Reactions by Designed Solid Surfaces with Organofunctional Groups." In Bridging Heterogeneous and Homogeneous Catalysis. Wiley-VCH Verlag GmbH & Co. KGaA, 2014. http://dx.doi.org/10.1002/9783527675906.ch1.

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Tanabe, Kozo. "Acid-Base Bifunctional Catalysis." In Acidity and Basicity of Solids. Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-011-0986-4_16.

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Kouzu, Masato. "Eco-Friendly Production of Biodiesel by Utilizing Solid Base Catalysis of Calcium Oxide for Reaction to Convert Vegetable Oil into Its Methyl Esters." In Zero-Carbon Energy Kyoto 2009. Springer Japan, 2010. http://dx.doi.org/10.1007/978-4-431-99779-5_3.

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Campbell, Ian M. "Industrial processes based on solid catalysts." In Catalysis at Surfaces. Springer Netherlands, 1988. http://dx.doi.org/10.1007/978-94-009-1205-2_8.

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Conference papers on the topic "Solid base catalysis"

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Brus, Grzegorz, Zygmunt Kolenda, Shinji Kimijima, and Janusz S. Szmyd. "An Analysis of Heat Transfer Processes in an Internal Indirect Reforming Type Solid Oxide Fuel Cell." In 2010 14th International Heat Transfer Conference. ASMEDC, 2010. http://dx.doi.org/10.1115/ihtc14-22785.

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This paper presents experimental and numerical studies on the fuel reforming process on an Ni/YSZ catalyst. Nickel is widely known as a catalyst material for Solid Oxide Fuel Cells. Because of its prices and catalytic properties, Ni is used in both electrodes and internal reforming reactors. However, using Ni as a catalyst carries some disadvantages. Carbon formation is a major problem during a methane/steam reforming reaction based on Ni catalysis. Carbon formation occurs between nickel and metal-support, creating fibers which damage the catalytic property of the reactor. To prevent carbon de
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O’Hern, T. J., S. M. Trujillo, J. B. Oelfke, P. R. Tortora, and S. L. Ceccio. "Solids-Loading Measurements in a Gas-Solid Riser." In ASME 2004 Heat Transfer/Fluids Engineering Summer Conference. ASMEDC, 2004. http://dx.doi.org/10.1115/ht-fed2004-56602.

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Gas-solid multiphase flows are commonly used in chemical processing, petroleum fluid catalytic cracking, and other industrial applications. The distribution of the solid phase in gas-solid flows (generally in the form of small particles) is seldom uniform, but more commonly involves clusters, streamers, and core-annular distributions, depending on the flow orientation and the overall gas and solid flowrates and their ratio. For this reason, tomographic techniques are of great interest for measurement of cross-sectional solids distributions in such flows. The cross-sectional profiles of solids
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LI, XIANCAI, LAITAO LUO, KANGQIANG LIU, and ZHIHUA LAI. "THE STUDIES ON PREPARATION AND CATALYSTIC PERFORMANCE OF SUPERFINE BaTiO3-SUPPORTED Ni-BASED CATALYST." In Proceedings of the International Symposium on Solid State Chemistry in China. WORLD SCIENTIFIC, 2002. http://dx.doi.org/10.1142/9789812776846_0029.

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Brauns, E., E. Morsbach, M. Baumer, and W. Lang. "A fast and sensitive catalytic hydrogen sensor based on a stabilized nanoparticle catalyst." In 2013 Transducers & Eurosensors XXVII: The 17th International Conference on Solid-State Sensors, Actuators and Microsystems (TRANSDUCERS & EUROSENSORS XXVII). IEEE, 2013. http://dx.doi.org/10.1109/transducers.2013.6626983.

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Leem, Sungkwang, and Joongmyeon Bae. "Autothermal Reforming of Natural Gas for High-Temperature Fuel Cells." In ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology. ASMEDC, 2005. http://dx.doi.org/10.1115/fuelcell2005-74062.

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Hydrogen production using current fueling facilities is essential for near- term applications of fuel cells. A preliminary process for developing natural gas autothermal reforming (ATR) reactor for solid oxide fuel cell (SOFC) was performed in this study. Catalyst scanning was performed for three catalysts and Pt based catalyst selected for further study. Using Pt catalyst we determined feeding conditions for the thermal neutrality by varying O2/CH4 with selected temperatures and feeding conditions. Temperature profiles of a reactor were observed and reformed gas composition was analyzed to ev
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Kafuku, Gerald, Makme Mbarawa, Man Kee Lam, and Keat Teong Lee. "Optimized Preparation of Moringa Oleifera Methyl Esters Using Sulfated Tin Oxide as Heterogenous Catalyst." In ASME 2010 4th International Conference on Energy Sustainability. ASMEDC, 2010. http://dx.doi.org/10.1115/es2010-90503.

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Fatty acid methyl esters (biodiesel), prepared from transesterification of vegetable oils or animal fats, have gained great importance in substituting petroleum based diesel for combating environmental problems and higher diesel prices. Moringa oleifera fatty acids are among the newly investigated potentials for biodiesel production in recent years. In getting rid of soap formation and thus large waste washing water from biodiesel produced from homogenous catalysts, the use of heterogeneous catalysts is currently preferred due to easily separation and purification of the final products. In thi
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Czernichowski, Albin, Mieczyslaw Czernichowski, and Krystyna Wesolowska. "GlidArc-Assisted Production of Synthesis Gas Through Propane Partial Oxidation." In ASME 2003 1st International Conference on Fuel Cell Science, Engineering and Technology. ASMEDC, 2003. http://dx.doi.org/10.1115/fuelcell2003-1716.

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Commercial propane can contain up to 300 ppm of Sulfur so that reforming technologies based on catalytic processes can not be directly applied without prior cleaning of such a feed in order to avoid the reformer’s catalyst poisoning (while some Solid Oxide Fuel Cells can accept Sulfur-polluted syngas). We run our reforming process in a presence of high-voltage discharges (called GlidArc) that assist the Partial Oxidation of pure or polluted propane. Electric consumption for this non-catalytic reformer is less than 2% of a Fuel Cell electric output. Recycling such a small portion of the electri
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Perdana, Indra, Agnes Martha Lisa Dolok Saribu, and I. Made Bendiyasa. "Solubility of sodium silicates as solid base catalyst in methanol." In THE 11TH REGIONAL CONFERENCE ON CHEMICAL ENGINEERING (RCChE 2018). Author(s), 2019. http://dx.doi.org/10.1063/1.5095031.

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Feng, Bo, Cheng-Yang Wang, and Bin Zhu. "Novel AC-M-SCC Anode Materials for Solid Oxide Fuel Cells Using Methanol at Intermediate or Low Temperature." In ASME 2005 3rd International Conference on Fuel Cell Science, Engineering and Technology. ASMEDC, 2005. http://dx.doi.org/10.1115/fuelcell2005-74140.

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In this paper, novel anode materials for solid oxide fuel cells which can directly operate liquid fuels at intermediate or low temperature were investigated. These materials were based on the activated carbons supported transition metal catalysts (AC-M) and the solid carbonate-ceria composite (SCC) materials, which were prepared via the sol-gel route. The SCCs possess both oxide-ion and proton conductivity, being used as multi-ion conductors. Activated carbons supported transition metals were used to improve the characters of anode materials and especially to enhance the anode catalyst functio
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Peres, Sérgio, and Alex Green. "Catalytic Indirectly Heated Gasification of Bagasse." In ASME 1998 International Gas Turbine and Aeroengine Congress and Exhibition. American Society of Mechanical Engineers, 1998. http://dx.doi.org/10.1115/98-gt-161.

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The catalytic indirectly heated gasification of bagasse was investigated in this study. The quality of the gaseous fuel was assessed using the total energy analysis of the gas, in which both heat content and total yields of the gas produced from the gasification of bagasse are analyzed at temperatures ranging from 700 to 1000°C. Untreated bagasse gasification was used as a baseline for the investigation of the effect of catalysts on the gasification process. The total energy analysis showed a significant improvement of gas quality due to increase of temperature and due to the use of alumina-zi
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