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Dissertations / Theses on the topic 'Solid-liquid interface'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 July 2025

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1

Denk, Matthias. "Structural investigation of solid liquid interfaces metal semiconductor interface /." [S.l. : s.n.], 2006. http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-29148.

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2

McDermott, D. C. "Adsorption at the solid/liquid interface." Thesis, University of Oxford, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.317917.

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3

Marsh, Richard James. "Protein adsorption at the solid/liquid interface." Thesis, University of Cambridge, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.624796.

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4

Sun, Chen-guang. "Non-covalent bonding at the solid-liquid interface." Thesis, University of Cambridge, 2012. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.610589.

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5

Curwen, Thomas Daniel. "Kinetics of surfactant adsorption at the solid-liquid interface." Thesis, University of Oxford, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.442388.

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6

Xu, Dan. "The adsorption of nanoparticles at the solid-liquid interface." Thesis, University of Leeds, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.577526.

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This study aims to investigate the adsorption of nanoparticles at the solid-water interface. Surface treatments with nanoparticles have been increasingly explored for a broad range of potential applications. However, the adsorption behaviour of inorganic nanoparticles has not been well studied to-date. Nanoparticle adsorption can be affected by several factors, such as the type of solid substrate, nanoparticle shape, nanoparticle concentration and salt concentration in the nanoparticle suspension, Two types of nanoparticles are used in this thesis: spherical Ludox silica (20 nm) and disk-like

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7

Patel, Asha. "Adsorption studies of polysiloxanes at the solid/liquid interface." Thesis, University of York, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.304063.

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8

Hjalmarsson, Nicklas. "Ionic liquids : The solid-liquid interface and surface forces." Doctoral thesis, KTH, Yt- och korrosionsvetenskap, 2016. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-186267.

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Ionic liquids (ILs) present new approaches for controlling interactions at the solid-liquid interface. ILs are defined as liquids consisting of bulky and asymmetric ions, with a melting point below 373 K. Owing to their amphiphilic character they are powerful solvents but also possess other interesting properties. For example, ILs can self-assemble and are attracted to surfaces due to their charged nature. As a result, they are capable of forming nanostructures both in bulk and at interfaces. This thesis describes how the solid-IL interface responds to external influences such as elevated temp

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9

Stocker, Isabella Natalie. "Adsorption at the calcite-liquid interface." Thesis, University of Cambridge, 2013. https://www.repository.cam.ac.uk/handle/1810/252293.

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10

Brügger, Georges. "Evanescent wave techniques for nanoparticle deposition at liquid-solid interface /." [S.l.] : [s.n.], 2009. http://opac.nebis.ch/cgi-bin/showAbstract.pl?sys=000288123.

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11

Zettner, Claudia Margaret. "Visualization of colloidal particle dynamics at a solid-liquid interface." Diss., Georgia Institute of Technology, 2001. http://hdl.handle.net/1853/17532.

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12

Chabala, Evans David. "Structural x-ray diffraction study of the solid-liquid interface." Thesis, University of Cambridge, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.260614.

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13

Fragneto, Giovanna. "Neutron reflection from surfactants adsorbed at the solid/liquid interface." Thesis, University of Oxford, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.308619.

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14

Ramadan, Adham Ramzi. "An X-ray diffraction study of the solid-liquid interface." Thesis, University of Cambridge, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.627584.

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15

Bowfield, Andrew. "Spectroscopic considerations on molecular adsorption at the solid/liquid interface." Thesis, University of Liverpool, 2009. http://livrepository.liverpool.ac.uk/1225/.

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This thesis mainly focuses on the adsorption behaviour of various molecules at the solid/liquid interface. The variation in adsorption kinetics are studied as a function of concentration, pH, applied electrode potential and surrounding environment by the surface sensitive analytical techniques of Reflection Anisotropy Spectroscopy and X-ray Photoelectron Spectroscopy. An electrochemical investigation into the surface reconstructions of Au(110) and their associated RA profiles is undertaken. The spectral profiles of Au(110) in 0.1 M H2SO4/Na2SO4, NaClO4/HClO4 and NaClO4 electrolytes were observ

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16

Nania, Samantha Lynn. "Spectroscopic analysis of molecular fluids at the solid-liquid interface." Diss., University of Iowa, 2017. https://ir.uiowa.edu/etd/5972.

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Chemical and physical interactions play important roles in surface film formation and fluid slip at the fluid-solid interface. It has been shown that the fluid molecules at this solid interface behave differently than the molecules in the bulk. To investigate fluid film formation and the fluid’s transition between bulk and interfacial regions, a dynamic wetting technique is utilized. This technique allows the formation of variable thickness fluid films. When used in conjunction with vibrational spectroscopy and ellipsometry, direct analysis of variable thicknesses films, spanning the bulk to i

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17

Phipps, Jonathan Stuart. "A neutron reflection study of adsorption at liquid interfaces." Thesis, University of Bristol, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.284248.

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18

Monga, Tanya. "Surface stress at the solid-liquid interface : alkanethiol monolayers on gold." Thesis, McGill University, 2006. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=101628.

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Defective alkanethiol monolayers were studied as a model system to understand the stress changes observed in microcantilever-based DNA hybridization experiments. An exponential relationship between defect density and surface stress was found by performing simultaneous electrochemical/stress-sensing experiments. Microcantilevers with a range of defective alkylthiol self assembled monolayers were prepared and stress change/electrochemical data were collected in perchlorate, chloride, and bromide-containing electrolytes. Defects were probed using a ferrocene-thiol labeling technique which provide

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19

Kampschulte, Lorenz. "Nanoscale Ordering at the Liquid-Solid Interface using Self-Assembly Principles." Diss., lmu, 2007. http://nbn-resolving.de/urn:nbn:de:bvb:19-68432.

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20

Fröberg, Johan C. "On the behaviour of globular proteins at the solid/liquid interface /." Stockholm : Tekniska högsk, 1998. http://www.lib.kth.se/abs98/frob0529.pdf.

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21

Brunt, T. A. "Stress measurements at the solid-liquid interface using a micromechanical sensor." Thesis, University of Cambridge, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.597031.

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This dissertation describes the development of atomic force microscope cantilevers as surface stress sensors for monitoring surface processes at the solid-liquid interface. Micromechanical bending-beams are highly sensitive stress sensors; stress changes as small as 10<SUP>-4</SUP>Nm<SUP>-1</SUP> can be detected using this type of bending-beam, whereas typical stress changes associated with monolayer processes are 0.1-1Nm<SUP>-1</SUP>. As well as offering high sensitivity, micromechanical cantilevers have a fast response time (0.5ms in liquids) which means they are ideally suited for fast st

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22

Kottmann, Stephen Thomas. "Molecular simulation of biomaterials and biomolecules at the solid-liquid interface." Thesis, Massachusetts Institute of Technology, 2008. http://hdl.handle.net/1721.1/43088.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2008.<br>Includes bibliographical references (p. 141-153).<br>Biomaterials and biomineralization have been successfully utilized in a broad variety of technical applications. Properties of natural biopolymers, such as the ability to control the nucleation, growth, and organization of crystals, have been extended to a much wider array of technologically applicable materials through combinatorial selection techniques. However, detailed mechanisms of peptide adsorption on inorganic surfaces have largely escaped characteri

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23

Johal, Malkiat Singh. "Sum-frequency spectroscopy of monomolecular films at the solid-liquid interface." Thesis, University of Cambridge, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.627102.

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24

Lee, Dongil. "Structural studies of the solid-liquid interface using real-time diffraction." Thesis, University of Cambridge, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.621521.

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25

Arechabaleta, Rafael. "AFM and SPR studies of protein adsorption at solid/liquid interface." FIU Digital Commons, 1999. http://digitalcommons.fiu.edu/etd/1054.

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Membrane-like structure formed by surfactant molecules of didodecyldimethylammonium bromide (DDAB) on both HOPG and gold electrodes were studied with AFM and SPR techniques. The study shows that the thickness of the adsorbed layer of DDAB is strongly dependent on the concentration of the vesicle solution. We have also investigated the adsorption of redox protein, Cytochrome c, on graphite electrode with in situ tapping mode AFM. The protein adsorbs spontaneously onto the electrode covered with an adsorbed phosphate layer and forms a uniform monolayer. The adsorbed protein exhibits a reversible

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26

Blom, Annabelle. "Structure and physical properties of surfactant and mixed surfactant films at the solid-liquid interface." Thesis, The University of Sydney, 2005. http://hdl.handle.net/2123/649.

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The adsorbed layer morphology of a series of surfactants under different conditions has been examined primarily using atomic force microscopy (AFM). The morphologies of single and double chained quaternary ammonium surfactants adsorbed to mica have been characterised using AFM at concentrations below the cmc. Mixing these different types of surfactants systematically allowed a detailed examination of the change in adsorbed film curvature from the least curved bilayers through to most curved globules. From this study a novel mesh structure was discovered at curvatures intermediate to bil

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27

Blom, Annabelle. "Structure and physical properties of surfactant and mixed surfactant films at the solid-liquid interface." University of Sydney. Chemistry, 2005. http://hdl.handle.net/2123/649.

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The adsorbed layer morphology of a series of surfactants under different conditions has been examined primarily using atomic force microscopy (AFM). The morphologies of single and double chained quaternary ammonium surfactants adsorbed to mica have been characterised using AFM at concentrations below the cmc. Mixing these different types of surfactants systematically allowed a detailed examination of the change in adsorbed film curvature from the least curved bilayers through to most curved globules. From this study a novel mesh structure was discovered at curvatures intermediate to bil

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28

Brown, Christopher A. "Aspects of the calcium carbonate-water interface." Thesis, University of Oxford, 1992. http://ora.ox.ac.uk/objects/uuid:0d9222b6-2d2a-4f3d-a0f9-61f91433dd02.

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The channel flow method has established the net dissolution kinetics of calcite single crystals at high pH (7.7-9.7) and varying bulk Ca<sup>2+</sup> concentrations (0-10 mM), using wide ranges of solution flow rates (10<sup>-3</sup>-0.3 cm<sup>3</sup> s<sup>-1</sup>). Literature rate equations were in poor agreement with experiment. Modelling with the following mechanism, where Ca<sup>2+</sup> and CO<sub>3</sub><sup>2-</sup> undergo Langmuirian adsorption: Ca<sup>2+</sup><sub>(aq)</sub> ⇄ Ca<sup>2+</sup><sub>(ads)</sub> CO<sup>2-</sup></sub>3 (aq)</sub> ⇄ CO<sup>2-</sup><sub>3 (ads)</sub> Ca(

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29

Di, Nardo Silvio. "Fluctuations during freezing and melting at the solid-liquid interface of xenon /." [S.l.] : [s.n.], 1994. http://e-collection.ethbib.ethz.ch/show?type=diss&nr=10764.

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30

Haschke, Heiko. "Force spectroscopy and microscopy of single molecules at the solid-liquid interface." Thesis, University of Bristol, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.288334.

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31

Prestidge, Clive A. "The chemisorption of cyclic and linear polymers at the solid-liquid interface." Thesis, University of Bristol, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.282888.

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32

Tsang, Man Hong. "The calculation of solid-liquid interface free energies from biased atomistic simulations." Thesis, Imperial College London, 2015. http://hdl.handle.net/10044/1/55870.

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The orientation dependence of the solid-liquid interface (SLI) free energy is an important parameter which determines orientation selection and the evolution of dendritic morphologies during the solidification of metallic melts. Atomistic simulations complemented with well-tempered metadynamics has been carried out to compute SLI free energies for the (100), (110) and (111) crystal interfaces of pure aluminium modelling using the empirical potential model of Mendelev and coworkers. The orientation dependence of the SLI free energy is known to be small, on the order of about 2%, and therefore g

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33

Redeker, Christian. "Lipopolysaccharides in solution and at the solid-liquid interface : structure and interactions." Thesis, University of Bristol, 2017. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.752719.

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34

Abbas, Zareen. "Leaching behavior of MSW combustion ashes and modeling of solid-liquid interface /." Göteborg : Göteborg university, 2002. http://catalogue.bnf.fr/ark:/12148/cb401112568.

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35

Wahlgren, Marie. "Adsorption of proteins and interactions with surfactants at the solid/liquid interface." [Lund : Dept. of Food Technology, Lund University], 1992. http://books.google.com/books?id=zfxqAAAAMAAJ.

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36

Trenkmann, Ines, Jörg Schuster, Shubhra Gangopadhyay, and Christian von Borczyskowski. "Investigation of solid liquid interface in ultra-thin liquid films via single particle tracking of colloidal particles." Universitätsbibliothek Leipzig, 2015. http://nbn-resolving.de/urn:nbn:de:bsz:15-qucosa-191812.

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37

Trenkmann, Ines, Jörg Schuster, Shubhra Gangopadhyay, and Christian von Borczyskowski. "Investigation of solid liquid interface in ultra-thin liquid films via single particle tracking of colloidal particles." Diffusion fundamentals 11 (2009) 115, S. 1-2, 2009. https://ul.qucosa.de/id/qucosa%3A14089.

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38

Stålgren, Johan Jim Roger. "Adsorption of Surfactants at the Solid-Liquid Interface : A Quartz Crystal Microbalance Study." Doctoral thesis, KTH, Chemistry, 2002. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-3291.

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39

Strandh, Jenny. "A study of solid and liquid inclusion separation at the steel-slag interface." Licentiate thesis, Stockholm, 2005. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-307.

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40

Frost, Daniel Wayne. "Study of adsorption of biological and nanoparticle solutions at the solid-liquid interface." Manhattan, Kan. : Kansas State University, 2007. http://hdl.handle.net/2097/411.

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41

Labuda, Aleksander. "Adventures in atomic force microscopy towards the study of the solid-liquid interface." Thesis, McGill University, 2012. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=110355.

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This thesis presents the design and development of an electrochemical atomic force microscope (AFM) equipped with photothermal excitation for actuation of the cantilever for the study of the solid-liquid interface. A rigorous analysis of noise in the optical beam deflection method is presented and leads to innovative techniques for the reduction of the detection noise to levels well below the thermal noise of the cantilever. An AFM stochastic simulation demonstrates that thermal noise fundamentally limits the measurement of hydration structures at the mica-water interface, whereas tip-sample v

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42

Rhodes, Trevor Ian. "Neutron reflection used to investigate polymers and surfactants at the solid-liquid interface." Thesis, University of Oxford, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.275249.

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43

Duclairoir, Florence. "Electrochemical control of supramolecular structures in solution and at the solid/liquid interface." Thesis, Heriot-Watt University, 2003. http://hdl.handle.net/10399/313.

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44

Gorse, Joseph III. "CHARACTERIZATION OF THE SOLID-LIQUID INTERFACE ON CHEMICALLY MODIFIED PARTICULATE SURFACES (CHROMATOGRAPHY, ISOTHERM)." Diss., The University of Arizona, 1985. http://hdl.handle.net/10150/188088.

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A method for representing solid-liquid sorption behavior of solutes by a two step equilibrium is shown to correlate well with observed sorption behavior. By fitting a three term expression to isotherm plots of solute surface concentration vs. the concentration in the bulk solvent the two distribution constants as well as the maximum sorption capacity are determined. Isotherms for hydrocarbon-modified silica are determined for various solvents and solutes. Interpretation of sorption behavior is presented in terms of values determined for sorption capacity and the distribution coefficients. The

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45

Clark, Spencer C. "ATR-FTIR Measurements of Cationic Surfactant Exchange Rates at the Solid-Liquid Interface." Thesis, Virginia Tech, 2003. http://hdl.handle.net/10919/34116.

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In many experiments, surfactant adsorption and desorption at solid-liquid interfaces is found to be quite slow, considering that surfactants are small molecules. Attenuated total reflectance Fourier transform infrared spectroscopy was used to study the adsorption, desorption, and exchange of tetradecyltrimethylammonium bromide (C<sub>14</sub>TABr) at the silicon oxide surface. The exchange of surfactant was monitored using protonated and perdeuterated C<sub>14</sub>TABr. The data show that exchange of C<sub>14</sub>TABr between the surface and the bulk solution is very fast, complete exchang

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46

Dhopatkar, Nishad. "UNDERSTANDING THE ADSORPTION AT SOLID-LIQUID INTERFACE AND ITS CONSEQUENCES ON INTERFACIAL PHENOMENA." University of Akron / OhioLINK, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=akron149944490923674.

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47

Kio, Michael Tamuno Elekima. "Molecular dynamics of Kapitza resistance at the solid-liquid interface of nanofluidic channels." Thesis, Cranfield University, 2014. http://dspace.lib.cranfield.ac.uk/handle/1826/9283.

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This project sought to study the heat transfer and Kapitza resistance of fluids across interfaces, nanopores and nanochannels with varying sti.ness constants, mass and energy intermolecular in- teraction strength of wall and fluid particles. An Einstein-Maxwell molecular dynamics thermal wall model is developed. The developed modeling approach is shown to provide dual energy and momentum transport exchange across solid-liquid interfaces and nanofluidic channels. Cont/d.

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48

Panduwinata, Dwi. "Scanning Tunneling Microscopy Investigation of Porphyrin Self-Assembled Monolayers at Solid/Liquid Interface." Thesis, The University of Sydney, 2013. http://hdl.handle.net/2123/10012.

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In this thesis the author presents Scanning Tunneling Microscopy (STM) study on the self-assembly of tetra-alkyl porphyrin (TAP) series at solid/liquid interface of highly-ordered pyrolytic graphite (HOPG) and 1-phenyloctane. This study determines whether altering the alkyl chain lengths and porphyrin concentrations in solution affects the molecular conformation of the SAMs. It also investigates whether the presence of axial chloride ligand on cobalt porphyrin metal centre can be detected using the STM technique. Porphyrins with long-alkyl chain lengths (i.e. C19-TAP, C17-TAP, and C15-TAP) for

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49

Clements, Patricia J. "Critical point behaviour in binary and ternary liquid mixtures with particular reference to rheological and interfacial properties in model mixtures for microemulsions." Thesis, University of Sheffield, 1997. http://etheses.whiterose.ac.uk/10187/.

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The phase behaviour, rheological effects and interfacial properties of binary and ternary liquid mixtures have been studied near critical points. In particular, measurements have been made of the viscosity-at the bulk macroscopic level by capillary viscometry and at the microscopic level by fluorescence depolarisatiorr-and of critical-point wetting and adsorptiorr-at the solid-liquid interface using evanescent-wave-generated fluorescence spectroscopy and at the liquid-vapour interface using specular neutron reflection. The systems investigated have been mostly alkane + perfluoroalkane mixtures

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50

Sood, Nitin. "The Study of Sonar for Imaging of the Solid-Liquid Interface Inside Large Tanks." FIU Digital Commons, 2005. http://digitalcommons.fiu.edu/etd/30.

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Retrieval, treatment, and disposal of high-level radioactive waste (HLW) is expected to cost between 100 and 300 billion dollars. The risk to workers, public health, and the environment are also a major area of concern for HLW. Visualization of the interface between settled solids and the optically opaque liquid is needed for retrieval of the waste from underground storage tanks. A Profiling sonar selected for this research generates 2-D image of the interface. Multiple experiments were performed to demonstrate the effectiveness of sonar in real-time monitoring the interface inside HLW tanks.

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