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Journal articles on the topic 'Soluble lead redox flow battery'

Author: Grafiati

Published: 6 September 2023

Last updated: 31 July 2025

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1

Shittu, Emmanuel, Rathod Suman, Musuwathi Krishnamoorthy Ravikumar, et al. "Life cycle assessment of soluble lead redox flow battery." Journal of Cleaner Production 337 (February 2022): 130503. http://dx.doi.org/10.1016/j.jclepro.2022.130503.

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2

An, Sang-Yong, and Eung-Jin Kim. "Characteristics of Redox Flow Battery Using the Soluble Lead Electrolyte." Journal of the Korean Electrochemical Society 14, no. 4 (2011): 214–18. http://dx.doi.org/10.5229/jkes.2011.14.4.214.

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3

Nandanwar, Mahendra, and Sanjeev Kumar. "Charge coup de fouet phenomenon in soluble lead redox flow battery." Chemical Engineering Science 154 (November 2016): 61–71. http://dx.doi.org/10.1016/j.ces.2016.07.001.

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4

Jaiswal, Nandini, Harun Khan, and R. Kothandaraman. "Review—Recent Developments and Challenges in Membrane-Less Soluble Lead Redox Flow Batteries." Journal of The Electrochemical Society 169, no. 4 (2022): 040543. http://dx.doi.org/10.1149/1945-7111/ac662a.

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Soluble lead redox flow battery (SLEFB) is attractive for its undivided cell configuration over other flow battery chemistries, which require an expensive membrane/separator. In the SLRFB, lead metal and lead dioxide are plated on the negative and positive electrodes from a single electrolyte reservoir containing soluble lead(II) species. Although the membrane-less cell configuration bestows SLRFB cost-effectiveness over other flow batteries, there are challenges associated with the plating of PbO2, Pb dendrite formation and the presence of parasitic reactions. This review mainly focuses on th

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5

Rathod, Suman, Nandini Jaiswal, M. K. Ravikumar, Satish Patil, and Ashok Shukla. "Effect of binary additives on performance of the undivided soluble-lead-redox-flow battery." Electrochimica Acta 365 (January 2021): 137361. http://dx.doi.org/10.1016/j.electacta.2020.137361.

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6

Nandanwar, Mahendra N., Kottu Santosh Kumar, S. S. Srinivas, and D. M. Dinesh. "Pump-less, free-convection-driven redox flow batteries: Modelling, simulation, and experimental demonstration for the soluble lead redox flow battery." Journal of Power Sources 454 (April 2020): 227918. http://dx.doi.org/10.1016/j.jpowsour.2020.227918.

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7

Rahbani, Noura, Piotr de Silva, Corentin Bellay, Solène Guihéneuf, Thibault Godet-Bar, and Emmanuel Baudrin. "Screening of First-Row Transition Metal Complexes for Aqueous Redox Flow Batteries: Experimental and Density Functional Theory Approaches." ECS Meeting Abstracts MA2023-02, no. 59 (2023): 2862. http://dx.doi.org/10.1149/ma2023-02592862mtgabs.

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The development of redox flow batteries took new directions in the last decades. From initial metal-based systems, it evolved towards organic and hybrid approaches in aqueous media. Furthermore, redox targeting flow batteries are an emerging alternative to the traditional redox flow battery architecture which offer improved energy density via an added electroactive solid ‘booster’. Whatever the system, there is a need of soluble electroactive species with potentials allowing large cell potentials within the water stability window or imperative redox potentials matching between soluble redox me

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8

Srivastava, Shaswat, and Sanjeev Kumar. "Role of Side Reaction Involving PbO_x in Soluble Lead Redox Flow Battery: Effect on Cyclability." ECS Meeting Abstracts MA2024-01, no. 3 (2024): 584. http://dx.doi.org/10.1149/ma2024-013584mtgabs.

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Soluble lead redox flow battery (SLRFB) has been an active subject of investigation in the past two decades because of its high energy efficiency (~70%) and charge efficiency (~90%) [1]. During charging, Pb2+ ions deposit as solid lead dioxide (PbO2 ) on anode and solid lead (Pb) on cathode, respectively. These features permit a membrane-less single-compartment design, making SLRFB a cost-effective electrochemical energy storage device. Discharge occurs by electro-dissolution of these solids, regenerating the electrolyte. The limited cycle-life of SLRFB is its current deployment challenge (bes

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9

Nandanwar, Mahendra, and Sanjeev Kumar. "A modelling and simulation study of soluble lead redox flow battery: Effect of presence of free convection on the battery characteristics." Journal of Power Sources 412 (February 2019): 536–44. http://dx.doi.org/10.1016/j.jpowsour.2018.11.070.

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10

Chaurasia, Shabdiki B., Andrew Boules, Juan Pablo Trelles, and Ertan Agar. "Exploring Redox Mediated Water Electrolysis Using Mn – V Redox Flow Batteries." ECS Meeting Abstracts MA2025-01, no. 4 (2025): 471. https://doi.org/10.1149/ma2025-014471mtgabs.

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Hydrogen gas is widely regarded as a key energy carrier for achieving net-zero carbon emissions by 2050, with green hydrogen, produced via electrochemical water splitting, being central to this goal. However, the production of green hydrogen from renewable sources remains limited, accounting for ~4% of global hydrogen production in 2021 [1]. Water electrolysis systems, while theoretically operating at 1.23 V, require higher voltages in practice due to membrane gas crossover, which reduces efficiency and raises costs [2]. This study explores a novel approach to supplement green hydrogen generat

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11

Debiais, Alizée, Calvine Lai, Thomas Boulanger, et al. "Pegylated Viologen Derivatives to Improve Performance of Aqueous Organic Redox Flow Battery." ECS Meeting Abstracts MA2024-01, no. 3 (2024): 544. http://dx.doi.org/10.1149/ma2024-013544mtgabs.

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Renewable energy sources like wind and solar power are great alternatives for a clean way to produce electricity but have the inconvenience to fluctuate1. To address this issue and promote the implementation of renewables sources, scientists are developing new ways to store energy while production is at a maximum for a subsequent release when there is demand. Redox flow batteries (RFBs) are the most appropriate solution and are increasingly gaining attention for stationary, large scale electrochemical energy storage2,3. One variation of RFBs are aqueous organic redox flow batteries (AORFBs), w

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12

Sarigamala, Karthik Kiran, Yu-Hsiu Lin, Kai Rui Pan, and Hsun-Yi Chen. "Life span enhancement of low cost soluble-lead-redox-flow battery using high performance meso-graphite spherules/AC anode." Journal of Energy Storage 70 (October 2023): 107957. http://dx.doi.org/10.1016/j.est.2023.107957.

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13

BANERJEE, A., D. SAHA, T. N. GURU Row, and A. K. SHUKLA. "A soluble-lead redox flow battery with corrugated graphite sheet and reticulated vitreous carbon as positive and negative current collectors." Bulletin of Materials Science 36, no. 1 (2013): 163–70. http://dx.doi.org/10.1007/s12034-013-0426-7.

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14

Nandanwar, Mahendra N. "Effect of porous nature of anode on the performance of the soluble lead redox flow battery: A modeling and simulation study." Journal of Power Sources 571 (July 2023): 233029. http://dx.doi.org/10.1016/j.jpowsour.2023.233029.

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15

Khan, Harun, Nandini Jaiswal, Nikhil C., M. S. Ramachandra Rao, and Kothandaraman R. "Conformal coating of PbO2 around boron doped diamond coated carbon felt positive electrode for stable and high-capacity operation of soluble lead redox flow battery." Journal of Energy Storage 99 (October 2024): 113304. http://dx.doi.org/10.1016/j.est.2024.113304.

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16

Romadina, Elena, and Keith J. Stevenson. "(Digital Presentation) Novel Organic Materials for Non-Aqueous Redox Flow Batteries: Implementation of Triarylamine and Phenazine Core Structures." ECS Meeting Abstracts MA2022-01, no. 48 (2022): 2039. http://dx.doi.org/10.1149/ma2022-01482039mtgabs.

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The rapid growth of the role of renewable energy sources dictates new requirements for the efficiency, stability and scales of electrochemical energy storage devices for stationary applications [1]. Among the storage systems, redox flow batteries (RFBs) are regarded as a promising technology, since their advantages of excellent scalability, low cost, easy fabrication and operation, long lifetime, and safety. Today inorganic RFBs are penetrating the market, however, low specific capacity in conjunction with low electrochemical stability window of aqueous electrolytes (≈1.5 V) and safety issues,

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17

Jung, Min Soo, Sungjin Yang, and Xiulei (David) Ji. "Concentrated Chloride Electrolyte Enabling SEI for Fe Metal Anode." ECS Meeting Abstracts MA2024-01, no. 3 (2024): 622. http://dx.doi.org/10.1149/ma2024-013622mtgabs.

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Iron is one of the most abundant metal elements in the Earth’s crust and has been widely used worldwide since ancient times. Due to this natural abundance and well-established mass production methods, iron is a promising candidate as a battery electrode for cost-effective large-scale energy storage systems. Edison’s Ni-Fe battery, invented in 1900, used an alkaline electrolyte without ferrous or ferric ions that eventually limited its anode design using iron oxide. More recent Fe redox flow batteries and the newly suggested Fe-ion batteries that use an acidic electrolyte containing ferrous ion

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18

Claus, Ana, Alexandra Berkova, Osama Awadallah, and Bilal El-Zahab. "Seawater Battery: Strategies to Enable High Performance." ECS Meeting Abstracts MA2022-02, no. 64 (2022): 2330. http://dx.doi.org/10.1149/ma2022-02642330mtgabs.

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Renewable energy sources such as solar, wind, and tide energy have been implemented to decrease air pollution due to common fossil fuel-generated electricity [1]. However, those systems are intermittent; creating the need for an energy storage system (ESS) that stores over-generated energy for later use and effectively matches the power fluctuation generated because of the sporadic demand throughout the day [2]. A possible solution to this problem is to couple renewable sources with rechargeable batteries. The most widespread electrochemical battery in the market is Lithium-ion, owing to its h

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19

Gong, Ke, Fei Xu, Jonathan B. Grunewald, et al. "All-Soluble All-Iron Aqueous Redox-Flow Battery." ACS Energy Letters 1, no. 1 (2016): 89–93. http://dx.doi.org/10.1021/acsenergylett.6b00049.

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20

Koenig, Gary, Devanshi Gupta, Jing Wang, and Yuxuan Zhang. "Assessing Mediated Redox Flow Battery Reaction Progression." ECS Meeting Abstracts MA2022-02, no. 4 (2022): 549. http://dx.doi.org/10.1149/ma2022-024549mtgabs.

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One potential next generation battery system is mediated redox flow batteries (RFBs). With mediated RFBs, soluble electroactive species (redox shuttles) deliver power via electrochemical reactions in a flow-through stack reactor much like a conventional RFB. However, the redox shuttles then undergo chemical redox in a coupled chemical reactor system with solid electroactive materials. The use of solid electroactive material for chemical energy storage results in substantial increases in volumetric energy density for the system. Mediated RFBs with different configurations for the chemical redox

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21

Krishna, M., R. G. A. Wills, A. A. Shah, D. Hall, and J. Collins. "The separator-divided soluble lead flow battery." Journal of Applied Electrochemistry 48, no. 9 (2018): 1031–41. http://dx.doi.org/10.1007/s10800-018-1230-2.

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22

Wang, Hao, Sayed Youssef Sayed, Yuqiao Zhou, Brian C. Olsen, Erik J. Luber, and Jillian M. Buriak. "Water-soluble pH-switchable cobalt complexes for aqueous symmetric redox flow batteries." Chemical Communications 56, no. 25 (2020): 3605–8. http://dx.doi.org/10.1039/d0cc00383b.

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23

Wang, Wei. "Proton Activity and Pathway in Aqueous Organic Redox Flow Battery Electrolyte." ECS Meeting Abstracts MA2024-01, no. 3 (2024): 542. http://dx.doi.org/10.1149/ma2024-013542mtgabs.

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Aqueous soluble organic (ASO) redox-active materials have recently shown great promise as alternatives to transition metal ions employed as energy-bearing active materials in redox flow batteries for large-scale energy storage because of their structural tunability, cost-effectiveness, availability, and safety features. However, development so far has been limited to a small palette of organics that are aqueous soluble. This presentation will use fluorenone as an example to showcase how a natively redox-inactive molecule can be tuned to possess two-electron redox reversibility through hydrogen

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24

Lei, Jiafeng, and Yi-Chun Lu. "Aqueous Polysulfide-Based Redox Flow Battery with Soluble Molecular Catalysts." ECS Meeting Abstracts MA2024-01, no. 3 (2024): 576. http://dx.doi.org/10.1149/ma2024-013576mtgabs.

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Aqueous polysulfide-based redox flow batteries (RFBs) are promising for large-scale energy storage applications due to their low cost and high safety1. However, polysulfide negolyte suffers from poor kinetics, resulting in low operating current density and low energy efficiency2-5. Herein, we proposed a molecular catalyst strategy to transfer the sluggish electrochemical polysulfide reduction reaction to a fast chemical reaction via homogeneous catalysis. Inspired by the electron transport chain in the respiratory process, we selected riboflavin sodium phosphate (FMN-Na) as the molecular catal

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25

Weller, Jon Mark, Gabriel Nambafu, Aaron Hollas, et al. "In Operando Raman Spectroscopy – a Powerful Tool for Understanding the Chemistry and Electrochemistry of Aqueous Redox Flow Batteries." ECS Meeting Abstracts MA2024-02, no. 4 (2024): 502. https://doi.org/10.1149/ma2024-024502mtgabs.

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Of the many emerging technologies for low-cost, grid-scale energy storage, redox flow batteries have been an area of active investigation for decades. More recently, a focus on lower cost alternatives to the foundational Vanadium-based redox flow batteries has been a major focus of the flow battery research community. Specifically, there is great interest in redox active species based on Earth-abundant materials suitable for aqueous systems such that the overall cost per kWh of energy storage can be minimized to enable economical and reliable grid storage to utilize energy generated from inter

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26

Wills, R. G. A., J. Collins, D. Stratton-Campbell, C. T. J. Low, D. Pletcher, and Frank C. Walsh. "Developments in the soluble lead-acid flow battery." Journal of Applied Electrochemistry 40, no. 5 (2009): 955–65. http://dx.doi.org/10.1007/s10800-009-9815-4.

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27

Freeman, Matthew B., Le Wang, Daniel S. Jones, and Christopher M. Bejger. "A cobalt sulfide cluster-based catholyte for aqueous flow battery applications." Journal of Materials Chemistry A 6, no. 44 (2018): 21927–32. http://dx.doi.org/10.1039/c8ta05788e.

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28

Ziegler, Christopher J. "(Keynote) Zwitterionic Ferrocenes As Redox Flow Battery Components." ECS Meeting Abstracts MA2022-01, no. 48 (2022): 2021. http://dx.doi.org/10.1149/ma2022-01482021mtgabs.

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Ferrocenes play increasingly important roles as cathodic components in redox flow battery designs. Peripheral functionalization has become an key tool in the development of ferrocenes as catholytes, as they can impart significant aqueous solubility. In this talk, two new aqueous soluble ferrocene compounds will be introduced that have zwitterionic functional groups pendant to the cyclopentadienyl ring. These compounds can be produced in one step from commercially available reagents and exhibit good stability and reversible electrochemistry in aqueous solution. We tested two such compounds in r

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29

Wang, Wei. "(Invited) Accelerating Material Design for Aqueous Organic Redox Flow Batteries." ECS Meeting Abstracts MA2022-02, no. 46 (2022): 1701. http://dx.doi.org/10.1149/ma2022-02461701mtgabs.

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Aqueous soluble organic (ASO) redox-active materials have recently shown great promise as alternatives to transition metal ions to be employed as energy-bearing active materials in redox flow batteries for large-scale energy storage because of their structural tunability, cost-effectiveness, availability, and safety features. Development so far however has been limited to a small palette of organics that are aqueous soluble. How to quickly identify and design organic molecules for the targeted properties became a critical challenge in accelerating the aqueous organic flow battery development.

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30

Wang, Wei. "(Invited) Accelerating Material Design for Aqueous Organic Redox Flow Batteries." ECS Meeting Abstracts MA2022-01, no. 3 (2022): 487. http://dx.doi.org/10.1149/ma2022-013487mtgabs.

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Aqueous soluble organic (ASO) redox-active materials have recently shown great promise as alternatives to transition metal ions to be employed as energy-bearing active materials in redox flow batteries for large-scale energy storage because of their structural tunability, cost-effectiveness, availability, and safety features. Development so far however has been limited to a small palette of organics that are aqueous soluble. How to quickly identify and design organic molecules for the targeted properties became a critical challenge in accelerating the aqueous organic flow battery development.

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31

Suman, Rathod, Satya Prakash Yadav, M. K. Ravikumar, Satish Patil, and A. K. Shukla. "Developing Shunt-Current Minimized Soluble-Lead-Redox-Flow-Batteries." Journal of The Electrochemical Society 168, no. 12 (2021): 120552. http://dx.doi.org/10.1149/1945-7111/ac436c.

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Shunt currents in membrane-less soluble-lead-redox-flow-batteries (SLRFB) are observed in open-circuit condition and found to depend on size of the stack, manifolds, flow rates and charge/discharge parameters. Ramifications of shunt currents on the performance of membrane-less SLRFB stacks with internal and external manifolds are reported. In the case of stacks with 3, 5 and 7-cells and internal manifold design, the charge current for the middle cell decreases by 3.3%, 6%, and 8.5%, while the discharge current increases by 2.6%, 5.5%, and 6.6%, respectively, for 3 A charge/discharge current. B

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32

Stracensky, Thomas, Sandip Maurya, Rangachary Mukundan, and Sanjeev Mukerjee. "Novel Anolyte Redox Active Organic Molecules for Redox Flow Battery Applications." ECS Meeting Abstracts MA2022-02, no. 1 (2022): 47. http://dx.doi.org/10.1149/ma2022-02147mtgabs.

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Non-aqueous redox flow batteries (NARFBs) offer several advantages over traditional aqueous electrolyte-based redox flow batteries, such as higher cell voltage, potentially higher energy density, and flexible operating temperatures. However, the current aqueous chemistries use toxic metals such as Vanadium and Chromium and highly acidic and oxidative acid mixtures. The efforts to develop metal-ligand based chemistries to tap the benefits of NARFBs have met with mixed success and only V(acac)3 based symmetric NARFBs have shown potential for long term operations. Even so, the solubility of V(aca

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33

Pahari, Shyam K., Tugba Ceren Gokoglan, Jennifer Nina Bolibok, Patrick J. Cappillino, and Ertan Agar. "Cation Modified Highly Soluble Active Materials for Redox Flow Batteries." ECS Meeting Abstracts MA2023-01, no. 3 (2023): 770. http://dx.doi.org/10.1149/ma2023-013770mtgabs.

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Renewables such as solar and wind energy are making increased penetration into modern electrical grids.1 However, the reliability of such grids is challenged by the intermittent nature of renewable sources and variable atmospheric conditions, posing a major roadblock in transition toward carbon-neutral energy sources. Grid level energy storage has long been seen as a solution to the intermittency problem.2 Among various storage technologies, redox flow batteries (RFBs) stand out, due to their ability to accommodate various needs of renewable-powered grids.3 RFBs based on non-aqueous chemistry

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34

Dong-Yang, LIU, CHENG Jie, PAN Jun-Qing, WEN Yue-Hua, CAO Gao-Ping, and YANG Yu-Sheng. "All-Lead Redox Flow Battery in a Fluoroboric Acid Electrolyte." Acta Physico-Chimica Sinica 27, no. 11 (2011): 2571–76. http://dx.doi.org/10.3866/pku.whxb20111105.

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35

Modestov, Alexander D., Oleg V. Tripachev, and Vladimir N. Andreev. "New electrochemical power source: Lead-iodine hybrid redox flow battery." Journal of Energy Storage 120 (June 2025): 116550. https://doi.org/10.1016/j.est.2025.116550.

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36

Mouron, Spencer T., and Trung Van Nguyen. "(Invited) A Non-Stabilized Supersaturated High-Energy-Density Storage Concept for the Redox Flow Battery and Its Demonstration in an H₂-V System." ECS Meeting Abstracts MA2024-02, no. 69 (2024): 4835. https://doi.org/10.1149/ma2024-02694835mtgabs.

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Redox flow battery (RFB)-based storage systems have the unique feature of separating power generation from energy storage, allowing individually sized systems uncoupling power from capacity. RFBs can be used for days-long energy storage, but because of the low solubility of most ions and molecules in both aqueous and non-aqueous solvents,[1,2] scaling these RFB systems for days-long applications requires significant storage tanks and floor area. Our team has been working on a new storage method for Vanadium electrolytes that significantly increases the energy storage density while still mainta

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37

Schrage, Briana R., Baosen Zhang, Stephen C. Petrochko, et al. "Highly Soluble Imidazolium Ferrocene Bis(sulfonate) Salts for Redox Flow Battery Applications." Inorganic Chemistry 60, no. 14 (2021): 10764–71. http://dx.doi.org/10.1021/acs.inorgchem.1c01473.

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38

Shah, A. A., X. Li, R. G. A. Wills, and F. C. Walsh. "A Mathematical Model for the Soluble Lead-Acid Flow Battery." Journal of The Electrochemical Society 157, no. 5 (2010): A589. http://dx.doi.org/10.1149/1.3328520.

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39

Hazza, Ahmed, Derek Pletcher, and Richard Wills. "A novel flow battery: A lead acid battery based on an electrolyte with soluble lead(ii)." Physical Chemistry Chemical Physics 6, no. 8 (2004): 1773. http://dx.doi.org/10.1039/b401115e.

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40

Pletcher, Derek, and Richard Wills. "A novel flow battery: A lead acid battery based on an electrolyte with soluble lead(ii)." Physical Chemistry Chemical Physics 6, no. 8 (2004): 1779. http://dx.doi.org/10.1039/b401116c.

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41

Pletcher, Derek, Hantao Zhou, Gareth Kear, C. T. John Low, Frank C. Walsh, and Richard G. A. Wills. "A novel flow battery—A lead-acid battery based on an electrolyte with soluble lead(II)." Journal of Power Sources 180, no. 1 (2008): 621–29. http://dx.doi.org/10.1016/j.jpowsour.2008.02.024.

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Pletcher, Derek, Hantao Zhou, Gareth Kear, C. T. John Low, Frank C. Walsh, and Richard G. A. Wills. "A novel flow battery—A lead-acid battery based on an electrolyte with soluble lead(II)." Journal of Power Sources 180, no. 1 (2008): 630–34. http://dx.doi.org/10.1016/j.jpowsour.2008.02.025.

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43

Pletcher, Derek, and Richard Wills. "A novel flow battery—A lead acid battery based on an electrolyte with soluble lead(II)." Journal of Power Sources 149 (September 2005): 96–102. http://dx.doi.org/10.1016/j.jpowsour.2005.01.048.

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44

Hazza, Ahmed, Derek Pletcher, and Richard Wills. "A novel flow battery—A lead acid battery based on an electrolyte with soluble lead(II)." Journal of Power Sources 149 (September 2005): 103–11. http://dx.doi.org/10.1016/j.jpowsour.2005.01.049.

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45

Li, Xiaohong, Derek Pletcher, and Frank C. Walsh. "A novel flow battery: A lead acid battery based on an electrolyte with soluble lead(II)." Electrochimica Acta 54, no. 20 (2009): 4688–95. http://dx.doi.org/10.1016/j.electacta.2009.03.075.

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46

Li, Bin, and Jun Liu. "Progress and directions in low-cost redox-flow batteries for large-scale energy storage." National Science Review 4, no. 1 (2017): 91–105. http://dx.doi.org/10.1093/nsr/nww098.

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Abstract Compared to lithium-ion batteries, redox-flow batteries have attracted widespread attention for long-duration, large-scale energy-storage applications. This review focuses on current and future directions to address one of the most significant challenges in energy storage: reducing the cost of redox-flow battery systems. A high priority is developing aqueous systems with low-cost materials and high-solubility redox chemistries. Highly water-soluble inorganic redox couples are important for developing technologies that can provide high energy densities and low-cost storage. There is al

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47

Hengesbach, Charley, Jessica Scott, Sharmila Samaroo, Chase Bruggeman, David Hickey, and Thomas F. Guarr. "Nonaqueous Redox Flow Batteries Incorporating Novel Pyridinium Anolytes." ECS Meeting Abstracts MA2022-01, no. 3 (2022): 480. http://dx.doi.org/10.1149/ma2022-013480mtgabs.

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While the use of nonaqueous solvents in redox flow batteries (RFBs) offers the promise of higher cell voltages than can typically be obtained in aqueous electrolytes, suitable compounds that are sufficiently soluble and stable to permit extended operation has proven challenging. Viologen anolytes have been successfully employed in aqueous systems, but their first reduction occurs at very modest potentials, thus limiting their advantage in nonaqueous systems. We have previously reported flow battery chemistry employing a series of extended bis(pyridinium) species with reduction potentials ca. 3

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48

Fischer, Peter, Petr Mazúr, and Joanna Krakowiak. "Family Tree for Aqueous Organic Redox Couples for Redox Flow Battery Electrolytes: A Conceptual Review." Molecules 27, no. 2 (2022): 560. http://dx.doi.org/10.3390/molecules27020560.

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Redox flow batteries (RFBs) are an increasingly attractive option for renewable energy storage, thus providing flexibility for the supply of electrical energy. In recent years, research in this type of battery storage has been shifted from metal-ion based electrolytes to soluble organic redox-active compounds. Aqueous-based organic electrolytes are considered as more promising electrolytes to achieve “green”, safe, and low-cost energy storage. Many organic compounds and their derivatives have recently been intensively examined for application to redox flow batteries. This work presents an up-t

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49

Koenig, Gary M., Charles R. Leroux, Thomas Lam, and Geoffrey M. Geise. "Selective Cation Exchange Membrane for Nonaqueous Flow Battery Separator." ECS Meeting Abstracts MA2025-01, no. 45 (2025): 2389. https://doi.org/10.1149/ma2025-01452389mtgabs.

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Membranes are a critical component for redox flow battery (RFB) systems. Ideal RFB membranes must be stable in the electrolyte and process environment, while facilitating transport of the charge compensating ion and minimizing crossover of the dissolved electroactive species (e.g., redox shuttles). More established aqueous RFB systems often leverage commercial membranes, such as sulfonated fluoropolymers, and have been demonstrated in RFB power stacks at industrial scales. Recently, there has been in pursuing RFB systems moving beyond the more established vanadium RFBs. One route is to develop

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Sun, Hong, Feiyang Hu, Zirui Jiang, et al. "Advancements of non-viologen-based anolytes for pH-neutral aqueous organic redox flow batteries." Chemical Synthesis 3, no. 4 (2023): 33. http://dx.doi.org/10.20517/cs.2023.07.

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Abstract:

Aqueous organic redox flow battery (AORFB) is regarded as the most promising next-generation technology for energy storage that stores electricity in redox-active organics lysed in mild salt-electrolytes. Composed of abundant elements such as C, H, O, and N, the adapted organics have a high degree of structural diversity and tunability, endowing it possible to modulate the physicochemical properties of water solubility, redox potential, and stability, and resulting in potential cost-effectiveness, ecological and environmental safety. Therefore, the designable organics consumedly expand the dis

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