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Journal articles on the topic 'Solutions of lanthanide nitrates'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Keskinov, V. A., A. V. Kudrova, O. V. Valueva, and A. K. Pyartman. "Extaction of lanthanide (III) nitrates from aqueous solutions with n-octanol." Russian Journal of Applied Chemistry 77, no. 9 (2004): 1559–60. http://dx.doi.org/10.1007/s11167-005-0072-y.

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2

Kuz’micheva, Galina, Alexander Trigub, Alexander Rogachev, Andrey Dorokhov, and Elena Domoroshchina. "Physicochemical Characterization and Antimicrobial Properties of Lanthanide Nitrates in Dilute Aqueous Solutions." Molecules 29, no. 17 (2024): 4023. http://dx.doi.org/10.3390/molecules29174023.

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This work presents the results of studying dilute aqueous solutions of commercial Ln(NO3)3 · xH2O salts with Ln = Ce-Lu using X-ray diffraction (XRD), IR spectroscopy, X-ray absorption spectroscopy (XAS: EXAFS/XANES), and pH measurements. As a reference point, XRD and XAS measurements for characterized Ln(NO3)3 · xH2O microcrystalline powder samples were performed. The local structure of Ln-nitrate complexes in 20 mM Ln(NO3)3 · xH2O aqueous solution was studied under total external reflection conditions and EXAFS geometry was applied to obtain high-quality EXAFS data for solutions with low con

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3

Coles, Simon, Laura McCormick McPherson, Andrew Platt, and Kuldip Singh. "Solid State and Solution Structures of Lanthanide Nitrate Complexes of Tris-(1-napthylphosphine Oxide)." Molecules 29, no. 11 (2024): 2580. http://dx.doi.org/10.3390/molecules29112580.

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Coordination complexes of lanthanide metals with tris-1-naphthylphosphine oxide (Nap3PO, L) have not been previously reported in the literature. We describe here the formation of lanthanide(III) nitrate complexes Ln(NO3)3L4 (Ln = Eu to Lu) and the structures of [Ln(NO3)3L2]·2L (Ln = Eu, Dy, Ho, Er) and L. The core structure of the complexes is an eight-coordinate [Ln(NO3)3L2] with the third and fourth ligands H-bonded via their oxygen atoms to one of the naphthyl rings. The structures are compared with those of the analogous complexes of triphenylphosphine oxide and show that the Ln-O(P) bond

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4

Safiulina, Alfiya M., Alexey V. Lizunov, Evgenii I. Goryunov, and Valery K. Brel. "Extraction system based on N-diphenylphosphoryl- N’-n-octylurea for the separation of f- elements from multicomponent nitric acid solutions." Vestnik Тomskogo gosudarstvennogo universiteta. Khimiya, no. 35 (2024): 192–200. https://doi.org/10.17223/24135542/35/15.

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The extraction of actinides and lanthanides using phosphorylurea deriva-tives from nitric acid solutions in presence of the background of nitrates Fe(III), Ni(II), Cr(III), Zr(IV), etc. has been studied. The possibility of using N-diphenylphosphoryl-N'-n-octylurea for efficient extraction separation of actinides and lanthanides from SNF reprocessing solutions has been demonstrated. A basic technological scheme is proposed.

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5

M.F.M.EID. "Thermodynamic Stabilities of Lanthanides-2-Thiophenylhydrazodimedone Complexes in Dioxane-Water Media." Journal of Indian Chemical Society Vol. 74, Feb 1997 (1997): 97–102. https://doi.org/10.5281/zenodo.5875123.

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Chemistry Department. Faculty of Educations. Ain Shams University. Roxy, Cairo, Egypt <em>Manuscript received 30 January 1995, revised 12 July 1995, accepted 30 August 1995</em> The thermodynamic parameters for the formation of 1 : 1 and 1 : 2 complexes between lanthanide cations and 2-thiophenylhydrazodimedone(2-TPHD) have been determined by potentiometric titrations in 75% (v/v) dioxane-water solution of 0.1 <em>M</em> (KNO<sub>3</sub>) ionic strength. The stepwise Gibbs energies of metal complexes varied in the sequence, Δ<em>G</em><sub>1</sub> > Δ<em>G</em><sub>2</sub> and t

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6

Bünzli, Jean-Claude G., and Catherine Mabillard. "FT-IR investigation of the interaction between dimethylsulphoxide (DMSO) and some lanthanide nitrates in acetonitrile solutions." Journal of the Less Common Metals 126 (December 1986): 379–88. http://dx.doi.org/10.1016/0022-5088(86)90326-7.

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7

A., S. GAHLAUT, CHATURVEDI BEENA, and C. SHARMA R. "Studies on Quaternary Complexes of some Rare Earth Metals." Journal of Indian Chemical Society Vol. 63, June 1986 (1986): 608–9. https://doi.org/10.5281/zenodo.6272222.

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Department of Chemistry, Agra University, Agra-282 004 <em>Manuscript received 23 September 1986, revised 25 March 1986, accepted 21 </em>April <em>1986</em> Studies on Quaternary Complexes of some Rare Earth Metals.

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8

Belair, S., C. Lamouroux, M. Tabarant, A. Labet, C. Mariet, and P. Dannus. "Modeling of the Extraction of Lanthanide Nitrates from Aqueous Solutions Over a Wide Range of Activities by CMPO." Solvent Extraction and Ion Exchange 22, no. 5 (2004): 791–811. http://dx.doi.org/10.1081/sei-200035602.

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9

Pyartman, A. K., V. A. Keskinov, and A. V. Kudrova. "Extraction of Lanthanide(III) Nitrates from Aqueous Nitrate Solutions with Tri-n-butyl Phosphate in Hexane and Tetradecane (Two- and Three-Phase Systems)." Radiochemistry 47, no. 4 (2005): 382–86. http://dx.doi.org/10.1007/s11137-005-0106-6.

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10

Ohta, A., H. Kagi, H. Tsuno, and M. Nomura. "Coordination study of lanthanide and yttrium in aqueous nitrate solutions." Geochimica et Cosmochimica Acta 70, no. 18 (2006): A454. http://dx.doi.org/10.1016/j.gca.2006.06.914.

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11

Makarevich, A. M., S. V. Kardashev, A. N. Grigor’ev, and N. P. Kuz’mina. "Formation of heterometallic compounds in mixed solutions of nickel(II)-Schiff base complexes and lanthanide nitrates: Electrospray ionization mass spectrometry data." Russian Journal of Inorganic Chemistry 53, no. 9 (2008): 1476–83. http://dx.doi.org/10.1134/s0036023608090210.

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12

Yatsenko, Alexandr V., Igor P. Gloriozov, Nelly I. Zhokhova, Ksenia A. Paseshnichenko, Leonid A. Aslanov, and Yuri A. Ustynyuk. "Structure of lanthanide nitrates in solution and in the solid state: DFT modelling of hydration effects." Journal of Molecular Liquids 323 (February 2021): 115005. http://dx.doi.org/10.1016/j.molliq.2020.115005.

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13

Ustynyuk, Yuri A., Pavel S. Lemport, Vitaly A. Roznyatovsky, et al. "First Trifluoromethylated Phenanthrolinediamides: Synthesis, Structure, Stereodynamics and Complexation with Ln(III)." Molecules 27, no. 10 (2022): 3114. http://dx.doi.org/10.3390/molecules27103114.

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The first examples of 1,10-phenanthroline-2,9-diamides bearing CF3-groups on the side amide substituents were synthesized. Due to stereoisomerism and amide rotation, such complexes have complicated behavior in solutions. Using advanced NMR techniques and X-ray analysis, their structures were completely elucidated. The possibility of the formation of complex compounds with lanthanoids nitrates was shown, and the constants of their stability are quantified. The results obtained are explained in terms of quantum-chemical calculations.

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14

Nosov, Viktor G., Yulia N. Toikka, Anna S. Petrova, et al. "Brightly Luminescent (TbxLu1−x)2bdc3·nH2O MOFs: Effect of Synthesis Conditions on Structure and Luminescent Properties." Molecules 28, no. 5 (2023): 2378. http://dx.doi.org/10.3390/molecules28052378.

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Luminescent, heterometallic terbium(III)–lutetium(III) terephthalate metal-organic frameworks (MOFs) were synthesized via direct reaction between aqueous solutions of disodium terephthalate and nitrates of corresponding lanthanides by using two methods: synthesis from diluted and concentrated solutions. For (TbxLu1−x)2bdc3·nH2O MOFs (bdc = 1,4-benzenedicarboxylate) containing more than 30 at. % of Tb3+, only one crystalline phase was formed: Ln2bdc3·4H2O. At lower Tb3+ concentrations, MOFs crystallized as the mixture of Ln2bdc3·4H2O and Ln2bdc3·10H2O (diluted solutions) or Ln2bdc3 (concentrate

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15

Turanov, A., and V. Karandashevb. "Adsorption of lanthanides(III) from aqueous solutions by fullerene black modified with di(2-ethylhexyl)phosphoric acid." Open Chemistry 7, no. 1 (2009): 54–58. http://dx.doi.org/10.2478/s11532-008-0093-5.

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AbstractFullerene black (FB) - a product of electric arc graphite vaporization after extraction of fullerenes - was modified with the di(2-ethylhexyl)phosphoric acid (D2EHPA). The distribution of D2EHPA between FB and aqueous HNO3 solutions has been studied. The effect of HNO3 concentration in the aqueous phase and that of D2EHPA concentration in the sorbent phase on the adsorption of microquantities of La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and Y nitrates from HNO3 solutions by D2EHPA-modified FB are considered. The stoichiometry of the sorbed complexes has been determined by

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16

Kudrova, A. V., V. A. Keskinov, and A. K. Pyartman. "Extraction of Lanthanide(III) Nitrates from Aqueous Solutions with Mixtures n-Octanol-Decane, Tri-n-butyl Phosphate-n-Octanol, and Diisoamyl Methylphosphonate-n-Octanol." Radiochemistry 47, no. 3 (2005): 270–77. http://dx.doi.org/10.1007/s11137-005-0086-6.

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17

Kieboom, A. P. G., A. Sinnema, J. M. van der Toorn, and H. van Bekkum. "13C NMR study of the complex formation of sorbitol (glucitol) with multivalent cations in aqueous solution using lanthanide(III) nitrates as shift reagents." Recueil des Travaux Chimiques des Pays-Bas 96, no. 2 (2010): 35–37. http://dx.doi.org/10.1002/recl.19770960203.

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18

Guignot, Sylvain, Arnault Lassin, Christomir Christov, Adeline Lach, Laurent André, and Pierre Henocq. "Modeling the Osmotic and Activity Coefficients of Lanthanide Nitrate Aqueous Solutions at 298.15 K from Low Molalities to Supersaturation." Journal of Chemical & Engineering Data 64, no. 1 (2018): 345–59. http://dx.doi.org/10.1021/acs.jced.8b00859.

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19

Yang, Li Dan, Ming Quan Ye, and Ai Jun Han. "Low Temperature Combustion Synthesis and Characterization of Pr-CeO₂ Doped with Zr Red Ceramic Pigments." Advanced Materials Research 399-401 (November 2011): 514–18. http://dx.doi.org/10.4028/www.scientific.net/amr.399-401.514.

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New inorganic pigments Ce0.95ZrxPr0.05-xO2(x = 0, 0.01, 0.02, 0.03, 0.04, 0.05) based on CeO2-ZrO2-Pr6O11solid solutions were synthesized by low-temperature combustion synthesis (LCS) method using citric acid as a reductant and metal nitrate as an oxidant. The pigments are CeO2solid solutions doped with praseodymium and zirconium ions, and display colors ranging from dark brown via brick red to bright cream. The prepared pigments were characterized by X-ray powder diffraction, transmission electron microscopy, ultraviolet-visible absorption spectroscopy and colorimetrical measurements. Results

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20

Matveeva, Anna G., Alexander S. Peregudov, Evgenij I. Matrosov, Zoya A. Starikova, Sergej V. Matveev, and Eduard E. Nifant’ev. "Structure and dynamic behaviour of lanthanide nitrate complexes with bis(diphenylphosphorylmethyl)mesitylene in solutions: The nature of unexpected 31P NMR spectra." Inorganica Chimica Acta 362, no. 10 (2009): 3607–16. http://dx.doi.org/10.1016/j.ica.2009.04.005.

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21

Vul'fson, S. G., V. F. Nikolaev, N. V. Utyaganov, A. N. Vereshchagin, and B. A. Arbuzov. "Phenomenon of magnetic birefringence in solutions of paramagnetic substances. Communication 2. Molar magneto-optic constants of chlorides and nitrates of some lanthanides in water." Bulletin of the Academy of Sciences of the USSR Division of Chemical Science 34, no. 12 (1985): 2472–78. http://dx.doi.org/10.1007/bf00953008.

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22

Majdan, Marek, and Pawel Sadowski. "Complexation of lanthanide nitrates." Monatshefte f�r Chemie Chemical Monthly 123, no. 11 (1992): 987–91. http://dx.doi.org/10.1007/bf00810929.

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23

Sadowski, P., and M. Majdan. "Spectroscopic investigation of lanthanide nitrates." Monatshefte f�r Chemie Chemical Monthly 126, no. 8-9 (1995): 863–70. http://dx.doi.org/10.1007/bf00811005.

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24

Cepeda, Javier, Sonia Pérez-Yáñez, Garikoitz Beobide, et al. "Enhancing luminescence properties of lanthanide(iii)/pyrimidine-4,6-dicarboxylato system by solvent-free approach." Dalton Transactions 44, no. 15 (2015): 6972–86. http://dx.doi.org/10.1039/c4dt03797a.

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Solvent-free reaction between lanthanide nitrates and pyrimidine-4,6-dicarboxylic acid led to 3D frameworks with coordinated nitrates showing a photoluminescence improvement and waveguiding behaviour.

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25

Platt, Andrew W. G. "Reactions of lanthanide nitrates with dimethylbenzoylphosphonate." Polyhedron 12, no. 5 (1993): 467–72. http://dx.doi.org/10.1016/s0277-5387(00)83395-1.

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26

Lokshin, E. P., K. G. Ivlev, and O. A. Tareeva. "Synthesis of Lanthanide Nitrates from Phosphosemihydrate." Russian Journal of Applied Chemistry 78, no. 12 (2005): 1903–12. http://dx.doi.org/10.1007/s11167-006-0001-8.

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27

Bowden, Allen, Simon J. Coles, Mateusz B. Pitak, and Andrew W. G. Platt. "Complexes of lanthanide nitrates with tri-isopropylphosphine oxide." Polyhedron 68 (January 2014): 258–64. http://dx.doi.org/10.1016/j.poly.2013.10.028.

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28

Rajasekar, N., and S. Soundararajan. "Complexes of lanthanide nitrates with 2-n-acetylaminopyrimidine." Bulletin des Sociétés Chimiques Belges 88, no. 10 (2010): 773–80. http://dx.doi.org/10.1002/bscb.19790881004.

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29

Dill, Simone, and Hans-Jürgen Meyer. "Synthese und Untersuchung der Lanthanoidoxidnitrate LnONO3 (Ln = Pr, Nd und Sm-Yb) / Synthesis and Studies of Lanthanide Oxide Nitrates LnONO3 (Ln = Pr, Nd, and Sm-Yb)." Zeitschrift für Naturforschung B 61, no. 1 (2006): 11–16. http://dx.doi.org/10.1515/znb-2006-0103.

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The lanthanide oxide nitrates LnONO3 with Ln = Pr, Nd, and Sm-Yb were synthesised by thermal decomposition of hydrated lanthanide nitrates. The compounds were refined isotypically to YONO3 in the tetragonal space group P4/nmm and the structure is closely related to the PbFCl-type. Because of the orientational disorder of NO3 − in this structure refinement a possible superstructure is discussed. Together with the oxide ions, the metal ions form [Ln2O2]2+ layers, alternating with double (NO3)− layers. Lattice parameters were determined by powder X-ray diffraction, and the structure of HoONO3 was

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30

Zangana, Karzan H., Eufemio Moreno Pineda, and Richard E. P. Winpenny. "Tetrametallic lanthanide(iii) phosphonate cages: synthetic, structural and magnetic studies." Dalton Trans. 43, no. 45 (2014): 17101–7. http://dx.doi.org/10.1039/c4dt02630f.

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31

Bowden, Allen, Kuldip Singh, and Andrew W. G. Platt. "Lanthanide nitrate complexes with triethylphosphine oxide. Solid state and solution properties." Polyhedron 42, no. 1 (2012): 30–35. http://dx.doi.org/10.1016/j.poly.2012.04.021.

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32

Rapko, Brian M., Bruce K. McNamara, Robin D. Rogers, Gregg J. Lumetta, and Benjamin P. Hay. "Coordination of Lanthanide Nitrates withN,N,N‘,N‘-Tetramethylsuccinamide." Inorganic Chemistry 38, no. 20 (1999): 4585–92. http://dx.doi.org/10.1021/ic990535x.

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33

Lees, Anthony M. J., and Andrew W. G. Platt. "Complexes of Lanthanide Nitrates with Bis(diphenylphosphino)methane Dioxide." Inorganic Chemistry 42, no. 15 (2003): 4673–79. http://dx.doi.org/10.1021/ic0342954.

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34

Bowden, Allen, Simon J. Coles, Mateusz B. Pitak, and Andrew W. G. Platt. "Complexes of Lanthanide Nitrates with Tri Tert Butylphosphine Oxide." Inorganic Chemistry 51, no. 7 (2012): 4379–89. http://dx.doi.org/10.1021/ic300142r.

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35

Bartczak, T., R. Kruszynski, and M. Zalewicz. "Study of new complexes of lanthanide nitrates with hexamethylenetetramine." Acta Crystallographica Section A Foundations of Crystallography 58, s1 (2002): c129. http://dx.doi.org/10.1107/s0108767302090207.

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36

Barnes, Francis H., Andrew W. Kelly, Henry Melzer, Howard H. Patterson, and Robert D. Pike. "Triphenylphosphane Oxide Complexes of Lanthanide Nitrates: Polymorphs and Photophysics." Zeitschrift für anorganische und allgemeine Chemie 644, no. 11 (2018): 525–33. http://dx.doi.org/10.1002/zaac.201800096.

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37

Barnes, Francis H., Aaron D. Nicholas, Henry Melzer, et al. "Triphenylarsane Oxide Complexes of Lanthanide Nitrates: Polymorphs and Photophysics." Zeitschrift für anorganische und allgemeine Chemie 645, no. 16 (2019): 1043–51. http://dx.doi.org/10.1002/zaac.201900137.

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38

Zhu, L. Y., Z. F. Wang, H. He, and G. Tian. "Competition between lanthanides in extraction with tri-n-butyl phosphate in supercritical CO2 from solid nitrates." RSC Advances 6, no. 99 (2016): 96531–37. http://dx.doi.org/10.1039/c6ra20687e.

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Competition extraction of lanthanide nitrates with tri-n-butyl phosphate (TBP) in supercritical CO<sub>2</sub> (SC-CO<sub>2</sub>) is investigated by monitoring the absorption spectra of Ln(iii) in UV-Vis region.

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39

Laurikenas, Andrius, Aldona Beganskiene, and Aivaras Kareiva. "On the Synthesis and Characterization of Lanthanide Metal-Organic Frameworks." Ceramics 1, no. 1 (2018): 54–64. http://dx.doi.org/10.3390/ceramics1010006.

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In this study, lanthanide metal-organic frameworks Ln(BTC)(DMF)2(H2O) (LnMOFs) are synthesized using the metal nitrates as lanthanide (Ln = La, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, Yb and Lu) source and 1,3,5-benzenetricarboxylic acid (BTC) as a coordination ligand. X-ray diffraction (XRD) analysis, Fourier-transform infrared spectroscopy (FTIR), thermogravimetric (TG/DTG) analysis fluorescence spectroscopy (FLS), and scanning electron microscopy (SEM) are employed to characterize the newly synthesized LnMOFs.

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40

Platt, David C., Linda M. Ferrence, Faith Breausche, Katelyn Terry, Gregory M. Ferrence, and Marjorie A. Jones. "Lanthanide Exposure In Vitro Differentially Diminishes MTT Cell Viability in Axenic Neuronal or Glial Cell Model Systems." Inorganics 13, no. 4 (2025): 127. https://doi.org/10.3390/inorganics13040127.

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Applications of lanthanide chemistry have been successful in metallics and the petroleum industry. In the medical realm, lanthanides have shown utility in radiotherapy agents, photodynamic therapy agents, and magnetic resonance imaging (MRI) contrast agents. The lanthanide group elements have a few known biological roles, notably among some bacteria and the yeast Saccharomyces cerevisiae, which have been used as models for changes in gene expression. However, the systematic effects of lanthanide nitrates on eukaryotic cell model systems have not yet been reported. This study presents the first

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41

Belova, Vera V., Yulia V. Tsareva, Yulia A. Zakhodyaeva, Vladimir K. Ivanov, and Andrey A. Voshkin. "Solvent Extraction of Lanthanides(III) in the Presence of the Acetate Ion Acting as a Complexing Agent Using Mixtures of Cyanex 272 and Caprylic Acid in Hexane." Processes 9, no. 12 (2021): 2222. http://dx.doi.org/10.3390/pr9122222.

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A new extraction system containing a mixture of Cyanex 272 and caprylic acid is proposed for the extraction and separation of lanthanides(III). It was shown that this system possesses a high level of extraction ability and capacity. The extraction of lanthanides(III) from chloride-acetate and nitrate-acetate media was investigated on an example of La(III). The composition of the extracted species was confirmed, based on the analysis of lanthanum(III) extraction isotherms. In the case of acetic-acetate aqueous solutions, a decrease in lanthanum(III) extraction efficiency was observed, due to th

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42

Rajasekar, N., and S. Soundararajan. "Complexes of lanthanide nitrates with N,N-diethylantipyrine-4-carboxamide." Proceedings / Indian Academy of Sciences 100, no. 1 (1988): 1–6. http://dx.doi.org/10.1007/bf02839520.

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43

Arabadzhiev, Vladislav, Jordanka Petrova, Erhard T. K. Haupt, Jürgen Kopf, and Isabelle Nevoigt. "Complexes of Alkyl Esters of Ethylidenediphosphonic Acids with Lanthanide Nitrates." Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 38, no. 4 (2008): 362–69. http://dx.doi.org/10.1080/15533170802132162.

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44

Arabadzhiev, Vladislav, Galin Petrov, and Erhard T. K. Haupt. "Complexes of Lanthanide Nitrates with Alkyl Esters of Bromomethylenediphosphonic Acid." Phosphorus, Sulfur, and Silicon and the Related Elements 184, no. 10 (2009): 2594–604. http://dx.doi.org/10.1080/10426500802529747.

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45

Vigdorchik, A. G. "Specific features of rare-earth polyhedra in alkali lanthanide nitrates." Acta Crystallographica Section A Foundations of Crystallography 52, a1 (1996): C333. http://dx.doi.org/10.1107/s0108767396086199.

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46

Khol’kin, A. I., A. K. Pyartman, V. V. Belova, N. S. Egorova, and V. A. Keskinov. "Extraction of lanthanide nitrates with trioctylmethylammonium di(2,4,4-trimethylpentyl)phosphinate." Radiochemistry 49, no. 4 (2007): 397–402. http://dx.doi.org/10.1134/s1066362207040133.

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47

Bednarczyk, L., and S. Siekierski. "EXTRACTION OF LIGHT LANTHANIDE NITRATES BY TRI-n-BUTYL PHOSPHATE." Solvent Extraction and Ion Exchange 7, no. 2 (1989): 273–87. http://dx.doi.org/10.1080/07360298908962309.

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48

Boyle, Timothy J., Xavier J. Robinson, Fernando Guerrero, Diana Perales, Joshua A. Hubbard, and Roger E. Cramer. "Organophosphorus-Modified Lanthanide Nitrates as Potential Actinide Oxide Aerosol Surrogates." Inorganic Chemistry 59, no. 23 (2020): 17149–61. http://dx.doi.org/10.1021/acs.inorgchem.0c02428.

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49

Silber, Herbert B., Ferenc Gaizer, Thang Pham, and Max Strozier. "Complexation differences between lanthanide nitrates from spectroscopic measurements in water." Journal of the Less Common Metals 126 (December 1986): 315–21. http://dx.doi.org/10.1016/0022-5088(86)90316-4.

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50

Gansow, Otto A., and A. Rashid Kausar. "Complexes of lanthanide nitrates with the cryptand 2B:2:1." Inorganica Chimica Acta 109, no. 1 (1985): 1–6. http://dx.doi.org/10.1016/s0020-1693(00)86318-5.

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