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Dissertations / Theses on the topic 'Solvent effects'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 July 2025

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1

Barry, Justin. "The Solvent Cage Effect: Using Microviscosity to Predict the Recombination Efficiency of Geminate Radicals Formed by the Photolysis of the Mo-Mo Bond of Cpʹ2Mo2(CO)6". Thesis, University of Oregon, 2018. http://hdl.handle.net/1794/23713.

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Radicals are core reactive species that occur in almost every subfield of chemistry. In particular, solution phase radicals find their way into biochemistry (e.g. vitamin B12), and in polymer chemistry (e.g. radical polymerizations) just to name a few. Yet, given the proliferation of radical chemistry, there are still fundamental aspects of it that are poorly understood. This dissertation probed factors that influence the solvent cage effect. The solvent cage effect is where two radicals are held in close proximity to one another and prevented from easily escaping (to form free radicals)

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2

Mack, Chris Alan. "Modeling solvent effects in optical lithography /." Digital version accessible at:, 1998. http://wwwlib.umi.com/cr/utexas/main.

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3

Macák, Peter. "Solvent and vibrational effects on nonlinear optical properties." Doctoral thesis, KTH, Biotechnology, 2002. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-3330.

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4

Norman, S. J. "Solvent and structural effects in solvolytic reactions." Thesis, Swansea University, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.638338.

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Rate Constants for the solvolysis of standard compounds have been used as a measure of solvent polarity. The Grunwald and Winstein equation utilized <i>tert</i>-butyl chloride for the Y scale. Y<SUB>X</SUB> scales for the 1- and 2-adamantyl derivatives have been established to correlate various substrates with different leaving groups. This thesis presents Y<SUB>OMs</SUB> results for binary aqueous mixtures of acetonitrile and dioxane which are classified as dipolar aprotic solvents. Y<SUB>Cl</SUB> values have also been obtained. When compounds containing one aromatic ring such as <i>p</i>-met

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5

Ranieri, Giuseppe. "Solvent Effects on Nucleophiles in Ionic Liquids." Thesis, Imperial College London, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.511816.

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6

Barnett, Christopher Bevan. "Electronic and solvent effects on monosaccharide conformations." Master's thesis, University of Cape Town, 2007. http://hdl.handle.net/11427/7487.

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The hydroxymethyl group rotational preferences of the monosaccharides glucose and galactose are different from each other and non-intuitive (from a steric point of view) in their preferences for gauche conformers. These molecules exhibit very different biological and thermodynamic properties in, for example their binding to glycosides or their liquid crystalline phases in glycolipids. The preference for gauche conformations has been attributed to solvent effects, stereo-electronic effects and hydrogen bonding; yet the experimentally obtained hydroxymethyl rotational populations have not yet be

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7

Oesterle, Matthew John. "Silver ion and solvent effects on polystyrene photochemistry." Thesis, Georgia Institute of Technology, 1998. http://hdl.handle.net/1853/27565.

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8

McEvoy, James P. "Temperature and solvent effects in protein film voltammetry." Thesis, University of Oxford, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.249424.

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9

Dalgleish, John Richard. "The effects of paint solvent exposure on submariners." Thesis, University of Newcastle Upon Tyne, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.240861.

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10

Steiger, Adam. "Effects of solvent composition on hydrogen bonding equilibria." Thesis, University of Sheffield, 2015. http://etheses.whiterose.ac.uk/8823/.

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11

Clifton, A. Paige. "Solvent induced microcracking in high performance polymeric composites." Thesis, This resource online, 1996. http://scholar.lib.vt.edu/theses/available/etd-11182008-063245/.

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12

Adhikari, Sajag. "Solvent Effects and Bioconcentration Patterns of Antimicrobial Compounds in Wetland Plants." Thesis, University of North Texas, 2011. https://digital.library.unt.edu/ark:/67531/metadc67953/.

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This study looked at effects of organic solvents dimethylsulfoxide, dimethylformamide and acetone at 0.01%, 0.05% and 0.1% concentration on germination and seedling development wetland plants. Even at 0.01% level, all solvents affected some aspect of seed germination or seedling growth. Acetone at 0.01% was least toxic. Root morphological characteristics were most sensitive compared to shoot morphological characteristics. This study also looked at bioconcentration patterns of antimicrobial compounds triclosan, triclocarban and methyl-triclosan in wetland plants exposed to Denton Municipal Wast

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13

Thompson, Robert Lee. "Supercritical fluid solvent effects on a diels-alder reaction." Thesis, Georgia Institute of Technology, 1996. http://hdl.handle.net/1853/10021.

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14

Crehan, Gabriel. "Friedel-crafts catalysis with zeolites and solid solvent effects." Thesis, University of Liverpool, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.367807.

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15

Samsonov, Sergey. "Protein-protein interactions: impact of solvent and effects of fluorination." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2009. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-25194.

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Proteins have an indispensable role in the cell. They carry out a wide variety of structural, catalytic and signaling functions in all known biological systems. To perform their biological functions, proteins establish interactions with other bioorganic molecules including other proteins. Therefore, protein-protein interactions is one of the central topics in molecular biology. My thesis is devoted to three different topics in the field of protein-protein interactions. The first one focuses on solvent contribution to protein interfaces as it is an important component of protein complexes. The

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16

Erp, Titus Sebastiaan van. "Solvent effects on chemistry with alcohols an ab initio study /." [S.l. : Amsterdam : s.n.] ; Universiteit van Amsterdam [Host], 2003. http://dare.uva.nl/document/70635.

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17

Al-Alousy, Ahmad. "Solvent effects on solubility, reactivity and spectroscopy of inorganic complexes." Thesis, University of Leicester, 1990. http://hdl.handle.net/2381/33763.

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Transfer chemical potential trends have been determined from solubility measurements for uncharged encapsulated and semi-encapsulated iron(II) complexes, and for series of ?-diketonate metal complexes, in water-alcohol and water- dimethyl sulphoxide mixtures. These solubilities were obtained by spectrophotometry and atomic absorption spectrometry. The transfer chemical potentials are discussed in terms of ligand periphery and solvent nature. Reactivities for base hydrolysis of series of iron(II) diimine complexes, containing diazabutadiene, pyridine- derived Schiff base, terdentate, linear hex

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18

Xue, Yuan. "Co-Solvent Effects on Metal-Ligand Interactions in the Environment /." The Ohio State University, 1995. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487931512620735.

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19

Chen, Ruoling. "Health effects of solvent exposure : a study of dockyard painters." Thesis, University of Aberdeen, 1997. http://digitool.abdn.ac.uk/R?func=search-advanced-go&find_code1=WSN&request1=AAIU100432.

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A cohort study was carried out to investigate mortality of 1292 male painters who had worked in a Royal Naval dockyard in Scotland for at least one year during 1950 and 1992. The mortality of the painters were compared to that of general male population of Scotland in 5-year ages and 5-year periods. Among the cohort there were 205 deaths, 58 from cancer. Proportionate mortality ratios suggested elevated risks of death from all cancers (PMR=110, 95%CI 84-143), prostate cancer (225, 83-489), bladder cancer (219, 60-560) and lymphosarcoma and reticulosarcoma (769, 93-2780). Excess deaths also wer

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20

Cubberley, Mark Stull. "Investigation of solvent effects in aromatic electron donor-acceptor interactions /." Digital version accessible at:, 2000. http://wwwlib.umi.com/cr/utexas/main.

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21

Helal, Hatem Hamdi Ahmed. "Including solvent effects in first-principles simulations of biological systems : development, implementation, and application of an implicit solvent model." Thesis, University of Cambridge, 2011. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.609182.

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22

Olmon, Eric Daniel. "Solvent effects on photodegradation of the 18-mer of thymidylic acid." Connect to this title online, 2005. http://hdl.handle.net/1811/364.

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Thesis (Honors)--Ohio State University, 2005.<br>Title from first page of PDF file. Document formattted into pages: contains, 49 p.; also includes graphics. Includes bibliographical references (p. 46-49). Available online via Ohio State University's Knowledge Bank.

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23

Mayo, Dennis H. "Solvent and protonation effects on a resorcin[4]arene based cavitand." Connect to resource, 2006. http://hdl.handle.net/1811/6456.

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Thesis (Honors)--Ohio State University, 2006.<br>Title from first page of PDF file. Document formatted into pages: contains 29 p.; also includes graphics. Includes bibliographical references (p. 28-29). Available online via Ohio State University's Knowledge Bank.

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24

Clayton, C. "Magnetic resonance as a probe of solvent effects in heterogeneous catalysis." Thesis, University of Cambridge, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.597760.

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The first experimental work discussed in this thesis is a series of reaction studies to look at the effect of four solvents - methanol, propan-1-ol, propan-2-ol and octanol - on the hydrogenation of 4-tertiary butyl phenol (TBP). Experiments are first done in a stirred pot-type reactor with two different sized catalyst particles and the rate and selectivity were compared. The same reaction was also performed in a small trickle bed reactor so that the effect of the reactor could be considered along with the effect of particle size and solvent. The next three areas of experimental work, use NMR

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25

Riechert, Ole [Verfasser]. "Phase Equilibria and Solvent Effects in Liquid-Phase Reactions / Ole Riechert." München : Verlag Dr. Hut, 2016. http://d-nb.info/108438633X/34.

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26

Fujisawa, Tomotsumi. "Raman spectroscopic study on the solvent effects in new-generation solvents : supercritical water, supercritical alcohols, and room temperature ionic liquids." 京都大学 (Kyoto University), 2008. http://hdl.handle.net/2433/136916.

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27

Perez, Arlandis Juan Manuel. "The solvent properties of ionic liquids and their effects on amination reactions." Thesis, Imperial College London, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.440461.

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28

Moor, H. "Understanding Solvent Effects on the Liquid Phase Heterogeneously Catalysed Hyrogenation of Ketoisophorone." Thesis, Queen's University Belfast, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.527878.

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29

Longin, Teresa L. Lewis Nathan Saul Lewis Nathan Saul. "Measurements of solvent effects on local barrier heights in scanning tunneling microscopy /." Diss., Pasadena, Calif. : California Institute of Technology, 1995. http://resolver.caltech.edu/CaltechETD:etd-10172007-085145.

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30

Gumus, Selahaddin. "Secondary Electronic and Solvent Effects on Regiospecific P-Bromination of Aromatic Systems." TopSCHOLAR®, 2018. https://digitalcommons.wku.edu/theses/3031.

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Bromoarenes are important aromatic building blocks that are commonly used to synthesize various functional compounds in pharmaceutical, agrochemical and related industries.1,2 This great demand for bromoarenes makes their preparation a widely studied area of synthetic organic chemistry. However, further understanding of the reactivity and regiochemistry of aromatic functionalization reactions is still necessary, as much about the secondary substitution and solvent effects remain unknown. Resonance Theory is a widely used theoretical model to predict the regiospecifity and reactivity of the bro

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31

Ransdell, Robert Arthur. "Solvent and Substituent Effects on the Redox Potentials of Several Substituted Tetraphenylporphyrins." PDXScholar, 1991. https://pdxscholar.library.pdx.edu/open_access_etds/1230.

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Tetraphenylporphyrins can be used to absorb visible light and pass on their excitation energy to electron transfer agents. The purpose of this research has been to investigate our ability to understand and control the energetics of porphyrin derivatives in order to use their electron transfer ability to harness the energy of sunlight. Shifts in the redox (reduction and oxidation) potentials of tetraphenylporphyrins result from variations in the substituents attached at the para- position of the phenyl rings of tetraphenylporphyrins, as well as variations in the state of ionization of those sub

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32

Black, James. "Solvent and additive effects on the appearance of polymorphs of p-aminobenzoic acid." Thesis, University of Manchester, 2016. https://www.research.manchester.ac.uk/portal/en/theses/solvent-and-additive-effects-on-the-appearance-of-polymorphs-of-paminobenzoic-acid(8357c4cc-12e9-49a0-a9bf-9cab9b5349a1).html.

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P-aminobenzoic acid (PABA) is a polymorphic compound with two known polymorphs - alpha with a needle morphology and β with a rhombic morphology. It is an enantiotropic compound with a transition temperature at 13.8oC, where alpha is more thermodynamically stable above transition temperature and β is more thermodynamically stable below. At the beginning of this project, crash-cooling crystallisation experiments were conducted to determine the effect of solvent, temperature and supersaturation on the nucleating polymorphs of PABA. Three solvents were tested (water, ethanol and isopropyl alcohol)

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33

Cockrill, Nathaniel S. "The infrared spectroscopic study of the effects of solvent exposure on polyimide films." CardinalScholar 1.0, 2009. http://liblink.bsu.edu/uhtbin/catkey/1538081.

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The goal of this research was to observe the changes in thickness and chemical characteristics that occur in Kapton® , a type of polyimide film, when exposed to heated solvents commonly used in cleaning and processing of these materials. Interference fringes present in transmission infrared spectra were used to calculate the thickness changes of the film, and attenuated total reflection infrared spectroscopy (ATR) was used to observe spectral shifts of the polymer film. Pieces of Kapton® film were immersed in heated solvents of n-methyl pyrrolidinone (NMP) and dimethylsulfoxide (DMSO) resultin

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34

Schaefer, Thomas Gerard. "Effects of varying ethanol and water concentrations as a gold nanoparticle gel solvent." Thesis, Massachusetts Institute of Technology, 2009. http://hdl.handle.net/1721.1/58072.

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Thesis (S.B.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, 2009.<br>Cataloged from PDF version of thesis.<br>Includes bibliographical references (p. 25).<br>Striped gold nanoparticles are unique in several of their characteristics and applications. Recent experiments have determined a new medium with which contain the nanoparticles is that of a chemical gel. The nanoparticles for use in these studies do not require a polymer base in order to form a gel phase. However, a concrete analysis of the transition temperature between the gel and liquid phases had

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35

McCleary, Keith Alan. "Sample introduction and solvent effects in an argon and helium microwave induced plasma." Diss., Virginia Tech, 1992. http://hdl.handle.net/10919/40444.

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36

Petretto, Emanuele <1989&gt. "Computational Study of Solvent Effects on the Stability of Native Structures in Proteins." Master's Degree Thesis, Università Ca' Foscari Venezia, 2018. http://hdl.handle.net/10579/12078.

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The commonly accepted protein folding mechanism hinges upon the idea that all the information required for a protein to reach the native conformation are encoded in its primary sequence. However, an equally important role is played by the interaction with the solvent, as recent both experimental and computational studies have clarified. The present thesis will build upon these study to investigate the stability of few representative proteins in the presence of solvents of different nature, ranging from highly polar, as water, to highly non-polar, as ciclohexane. This task will be pursued usi

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37

Hedong, Zhang, Yasunaga Mitsuya, Yosuke Fujikawa, Akira Fuwa, and Kenji Fukuzawa. "Solvent Effects on Friction Properties of Monolayer Perfluoropolyether Films Coated on Magnetic Disk Surfaces." IEEE, 2009. http://hdl.handle.net/2237/13956.

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38

HESS, JEFFREY E. "A PILOT STUDY OF OCCUPATIONAL EXPOSURE TO 1-BROMOPROPANE LOOKING FOR NEUROLOGICAL AND HEMATOLOGICAL EFFECTS." University of Cincinnati / OhioLINK, 2002. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1022098837.

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39

Chacha, Joseph S. "Solvent, anion and temperature effects in UPD lead adatom array formation at gold electrodes." Thesis, University of Ottawa (Canada), 1989. http://hdl.handle.net/10393/5727.

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40

Basu, Sukanta. "Effects of humidity on the adsorption of coating solvent, m-xylene, on activated carbon." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2000. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape3/PQDD_0025/MQ62186.pdf.

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41

Crane, Cynthia E. "Sorption of pentachlorophenol to humic acids and subsequent effects on biodegradation and solvent extraction." Thesis, This resource online, 1992. http://scholar.lib.vt.edu/theses/available/etd-03172010-020652/.

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42

Broering, James M. "Quantification of Hofmeister Effects on Enzyme Deactivation and Amyloid Protein Stability." Diss., Georgia Institute of Technology, 2006. http://hdl.handle.net/1853/14077.

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Protein stability plays an important role in a wide variety of settings ranging from industrial processes where proteins are used as biocatalysts to medical settings where misfolded proteins are implicated in disease. Understanding protein stability will allow design of improved bioprocess and pharmaceutical formulations as well as aid in the development of therapies for protein-based diseases. The effects of dissolved salts on protein kinetic stability are studied here. We find that ion-solvent interactions, characterized by the Jones-Dole B-viscosity coefficient, are strong indicators of s

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43

Adam, Catherine. "Molecular balances for measuring non-covalent interactions in solution." Thesis, University of Edinburgh, 2015. http://hdl.handle.net/1842/16466.

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Non-covalent interactions in solution are subject to modulation by surrounding solvent molecules. This thesis presents two experimental molecular balances that have been used to quantify solvent effects on non-covalent interactions, including electrostatic and dispersion interactions. The first chapter introduces literature where non-covalent interactions have been studied in a range of solvents, particularly those where the effects of aqueous or fluorous solvents have been investigated. These solvents are of particular interest as they both invoke solvophobic effects on organic molecules, but

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44

Muchowska, Kamila Barbara. "Molecular balances." Thesis, University of Edinburgh, 2015. http://hdl.handle.net/1842/17880.

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Predicting and quantifying solvent effects on non-covalent interactions is often very challenging, as they are influenced and modulated by multiple factors. In this thesis, a series of molecular torsion balances is used as a tool to tackle the complexities of noncovalent interactions in solution. Chapter 1 presents an up-to-date literature review on solvent effects on non-covalent interactions, with a particular focus on solvent effects on conformational equilibria and molecular torsion balances. Chapter 2 demonstrates the use of molecular torsion balances and a simple explicit solvation compu

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45

Das, Koyeli. "Physicochemical investigation of assorted interactions of some imperative compounds with the manifestation of solvation effects prevalent in diverse solvent systems." Thesis, University of North Bengal, 2018. http://ir.nbu.ac.in/handle/123456789/2684.

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46

Alquist, Erik James. "The Effects of High Hydrostatic Pressures on NADH Conformation." Miami University / OhioLINK, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=miami1281640692.

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47

Wang, Hongfeng. "Optimisation de matériaux moléculaires bistables." Phd thesis, Université Sciences et Technologies - Bordeaux I, 2012. http://tel.archives-ouvertes.fr/tel-01059793.

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Les complexes à transition de spin sont des molécules qui peuvent être commutées entre deux états, l'un diamagnétique et l'autre paramagnétique. Cette commutation peut s'effectuer, entre autre, à l'aide d'une excitation lumineuse, ouvrant la voie vers un possible stockage de l'information au niveau d'une molécule unique. Toutefois, l'information photo-inscrite n'est stable qu'au-dessous d'une certaine température appelée T(LIESST). L'objectif principal de cette thèse a constitué en des modifications chimiques (modification du ligand organique, désolvatation, modifications d'anion,...) d'un com

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48

Schweitzer, Benjamin. "Modélisation d’effets de solvant pour des réseaux réactionnels étendus de la biomasse en catalyse hétérogène." Thesis, Lyon, 2018. http://www.theses.fr/2018LYSEN019.

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Cette thèse porte sur la modélisation multi-échelle des réactions en catalyse hétérogène de polyols sur une surface de platine 111, en phase aqueuse. Ce travail s’inscrit dans l’utilisation de la biomasse lignocellulosique. Les réseaux réactionnels issus du traitement de cette matière première sont très grands en taille, et en complexité. D’autre part, la nature même des molécules la composant impose une chimie en phase aqueuse. Il n’est donc pas possible de cartographier l’ensemble des ces chemins réactionnels avec des méthodes de calcul ab initio, tant les conditions aqueuses et le grand nom

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49

Dickson, Nicole M. "Solute/Solvent Interactions And Excited State Photophysics Of 1,4-Diphenyl-1,3-Butadiene And 1,4-Diphenyl-1,3-Cyclopentadiene." The Ohio State University, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=osu1206119352.

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50

D'Ascanio, Anna M. "A study of solvent and metal effects on the formation of phthalocyanines at room temperature." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp03/MQ39184.pdf.

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