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Dissertations / Theses on the topic 'SOLVENT SYSTEMS'

Author: Grafiati

Published: 18 May 2024

Last updated: 31 July 2025

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1

Dakua, Vikas Kumar. "Physico-chemical studies on interactions between ion-solvent, ion-ion and solvent-solvent in aqueous and non-aqueous pure and mixed solvent systems." Thesis, University of North Bengal, 2008. http://hdl.handle.net/123456789/707.

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2

Cheng, Chin-Hwa 1957. "Solubility of diuron in complex solvent systems." Thesis, The University of Arizona, 1989. http://hdl.handle.net/10150/277194.

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The solubility of diuron was determined in binary and ternary cosolvent-water systems. The binary systems were composed of a completely miscible organic solvent (CMOS) and water while the ternary systems incorporate partially miscible organic solvents (PMOS) into the binary systems. Due to the low aqueous solubilities of trichloroethylene and toluene, the PMOS's do not behave as cosolvents and they do not play an important role in altering solubility.

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3

Lunkov, Sergey. "Modelling metal complexation in solvent extraction systems." Thesis, Curtin University, 2013. http://hdl.handle.net/20.500.11937/2018.

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This thesis represents a theoretical investigation of synergistic solvent extraction of transition metal ions based on models for the commercial used components, namely LIX63 and Versatic10 acid. Quantum mechanical studies of oxime isomerisation have been conducted in order to understand the thermodynamic and kinetic properties of the syn/anti interconversion of LIX63, which is found to favour an oligomeric form in non-polar solvents.

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4

Brindle, David. "Lattice models of amphiphile and solvent mixtures." Thesis, Sheffield Hallam University, 1991. http://shura.shu.ac.uk/19397/.

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Materials based on amphiphilic molecules have a wide range of industrial applications and are of fundamental importance in the structure of many biological systems. Their importance derives from their behaviour as surface-active agents in solubilization applications and because of their ability to form systems with varying degrees of structural order such as micelles, bilayers and liquid crystal phases. The nature of the molecular ordering is of importance both during the processing of these materials and in their final application. A Monte Carlo simulation of a three dimensional lattice model

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5

Lesutis, Heather Patrick. "Reaction kinetics in environmentally benign novel solvent systems." Diss., Georgia Institute of Technology, 2000. http://hdl.handle.net/1853/11865.

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6

Bailie, David S. "Homogeneous oxidation catalysis in multiphasic liquid solvent systems." Thesis, Queen's University Belfast, 2014. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.675950.

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Carrying out oxidations on an industrial scale in an environmentally sustainable manner can be challenging with currently available methods. Consequentially, the pharmaceutical industry avoids transformations involving oxidations where possible. Developments over the past few decades have brought catalytic processes to light that can carry out oxidations using simple terminal oxidants, such as O2 and H202• In particular, ligand-promoted Pd(II) complexes have been shown to be capable of oxidising alcohols and olefins to carbonyl compounds, producing water as the principal byproduct. In this the

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7

Payne, Kathryn Elizabeth Ann. "Pigment-dispersant-solvent interactions appropriate to paint systems." Thesis, London South Bank University, 1998. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.267389.

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8

Healy, Mary Rose. "Outer-sphere interactions in metal solvent extraction systems." Thesis, University of Edinburgh, 2017. http://hdl.handle.net/1842/28712.

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This work aims to define the modes of action of a series of metal extraction ligands with particular focus on how these depend on the formation of supramolecular assemblies. Though solvent extraction processes are well established industrially often the understanding, particularly of the metal coordination chemistry, is less so. A greater understanding of a variety of solvent extraction systems can lead to the development of stronger and more specific extractants. Chapter 2 examines the role of inter-ligand interactions in the extraction of copper by phenolic oximes and pyrazoles. Computationa

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9

Cocchi, Giovanni <1984&gt. "Thermodynamic and mechanical properties of polymer-solvent systems." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2013. http://amsdottorato.unibo.it/5782/1/cocchi_giovanni_tesi.pdf.

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This work presents the results of theoretical and experimental characterization of thermodynamic, mechanical and transport properties in polymer solvent systems. The polymer solvent pairs considered ranged to those in which the polymer is rubbery, to those in which the initially glassy polymeric matrix is plasticized by the action of the low molecular weight species. Advanced Equation of State models have been adopted for thermodynamic modeling,along with a rigorous procedure that enables to extend their applicability to the non equilibrium, glassy region. Mass sorption kinetics had been model

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10

Cocchi, Giovanni <1984&gt. "Thermodynamic and mechanical properties of polymer-solvent systems." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2013. http://amsdottorato.unibo.it/5782/.

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This work presents the results of theoretical and experimental characterization of thermodynamic, mechanical and transport properties in polymer solvent systems. The polymer solvent pairs considered ranged to those in which the polymer is rubbery, to those in which the initially glassy polymeric matrix is plasticized by the action of the low molecular weight species. Advanced Equation of State models have been adopted for thermodynamic modeling,along with a rigorous procedure that enables to extend their applicability to the non equilibrium, glassy region. Mass sorption kinetics had been model

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11

Draucker, Laura Christine. "Novel Solvent Systems for the Development of Sustainable Technology." Diss., Georgia Institute of Technology, 2007. http://hdl.handle.net/1853/16188.

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Sustainable development in chemical engineering offers technical, industrially relevant solutions to environmental and economic issues. This work focuses on three specific issues; improving solvent selection and reducing costly experimentation, improving catalyst recovery while reducing reaction time, and producing commercial viable biofuels by cost effective pretreatments and valuable side product extractions. Novel solvent systems are a sustainable solution because they provide the ability to replace costly solvents with cheap, benign, and recyclable systems. Specifically, this work investi

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12

Belhadj, Hamza [Verfasser]. "Solvent isotope effect (D2O) in photocatalytic systems / Hamza Belhadj." Hannover : Technische Informationsbibliothek (TIB), 2017. http://d-nb.info/1150536683/34.

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13

Chen, Zhihong. "Morphology of, and solvent diffusion in, hollow nanoparticle systems." Thesis, University of Sheffield, 2014. http://etheses.whiterose.ac.uk/5019/.

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In this project, we studied the morphology of SiO2/TiO2 hollow nanoparticles (HNPs), the morphology of polymer-embedded HNPs and diffusion of solvents into polymer-embedded HNPs, mainly based on small angle scattering methods. The average outer diameter, average inner diameter and polydispersity of HNPs were characterized by a combination of experimental methods, including light, X-ray and neutron scattering, electron microscopy and N2 adsorption-desorption isotherms. Furthermore, the porosity of the shells of HNPs and the size of intrawall pores were determined by a new method proposed with t

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14

Dreimann, Jens M. [Verfasser]. "Process Intensification in Homogeneous Catalysis - Catalyst Recovery via Thermomorphic Solvent Systems and Organic Solvent Nanofiltration / Jens M. Dreimann." München : Verlag Dr. Hut, 2017. http://d-nb.info/1139538349/34.

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15

Dreimann, Jens [Verfasser]. "Process Intensification in Homogeneous Catalysis - Catalyst Recovery via Thermomorphic Solvent Systems and Organic Solvent Nanofiltration / Jens M. Dreimann." München : Verlag Dr. Hut, 2017. http://d-nb.info/1139538349/34.

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16

Hamilton, Patrick Neal. "The behavior and separation of polystyrene in mixed solvent systems." [College Station, Tex. : Texas A&M University, 2007. http://hdl.handle.net/1969.1/ETD-TAMU-1256.

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17

Baranowski, Roman. "The properties of polymer/solvent systems at surfaces and interfaces." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/nq25767.pdf.

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18

Pitt, Julian Llewellyn. "The behaviour of mineral particles in uranium solvent extraction systems." Thesis, Imperial College London, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.339619.

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19

Rivett, Carl Matthew. "Carbon Dioxide as a Solvent and Antisolvent for Hydrocarbon Systems." Thesis, University of East Anglia, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.518387.

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20

Helal, Hatem Hamdi Ahmed. "Including solvent effects in first-principles simulations of biological systems : development, implementation, and application of an implicit solvent model." Thesis, University of Cambridge, 2011. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.609182.

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21

Husain, Zainul Abideen. "Coupling reactions and separations in propane-organic-aqueous tunable solvent systems." Thesis, Atlanta, Ga. : Georgia Institute of Technology, 2009. http://hdl.handle.net/1853/29719.

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Thesis (M. S.)--Chemical Engineering, Georgia Institute of Technology, 2009.<br>Committee Chair: Eckert, Charles; Committee Co-Chair: Liotta, Charles; Committee Member: Meredith, Carson. Part of the SMARTech Electronic Thesis and Dissertation Collection.

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22

Das, Mousumi. "Physico-chemical investigation of transport and thermodynamic properties of some electrolytes in verious solvent systems." Thesis, University of North Bengal, 2007. http://hdl.handle.net/123456789/817.

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23

Hafner, Kellye Padgett. "Design of solvent systems for supercritical fluid and high pressure applications." Diss., Georgia Institute of Technology, 1996. http://hdl.handle.net/1853/11211.

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24

Theaker, Ian. "A structural and thermodynamic study of non-aqueous solvent/wax systems." Thesis, University of Hull, 1996. http://hydra.hull.ac.uk/resources/hull:4996.

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Non-aqueous wax/solvent systems of industrial relevance for the manufacture of paste polishes have been investigated. These mixtures have been modelled using a paraffin wax of Japanese origin (Nippon Seiro 140/145°F) in a solution of pure heptane to which dopant components are added.The stability of any resulting gel has been assessed via solubility studies and measurement of the solvent vapour pressure. A new technique for the measurement of vapour pressure in these systems has been developed. The operation of the apparatus has been made almost completely automatic by the use of modern contro

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25

Chavez, Krystle J. "Crystallization of pseudopolymorphic forms of sodium naproxen in mixed solvent systems." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2009. http://hdl.handle.net/1853/29759.

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Thesis (Ph.D)--Chemical Engineering, Georgia Institute of Technology, 2009.<br>Committee Chair: Rousseau, Ronald; Committee Member: Meredith, Carson; Committee Member: Prausnitz, Mark; Committee Member: Teja, Amyn; Committee Member: Wilkinson, Angus. Part of the SMARTech Electronic Thesis and Dissertation Collection.

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26

Eckert, Norbert L. "Aspects of phase separation in an experimental mixer-settler using two solvent extraction systems." Thesis, University of British Columbia, 1987. http://hdl.handle.net/2429/26697.

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An experimental investigation was undertaken to study the factors affecting phase separation in a specially constructed, laboratory scale mixer-settler. Two phase systems were used: 1. A laboratory prepared HSLIX64N-copper phase system, similar to that used in commercial copper solvent extraction processes. 2. A phase system obtained directly from the uranium extraction circuit of the Key Lake Mining Corporation, Sask., millsite. A settler scale-up criterion relating dispersion band thickness to specific settler flow of dispersed phase, was found to have considerable merit. Besides being de

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27

Rieck, Daniel C. "MEMS fabricated nanopores and micropores functionalized with chromate-selective solvent polymeric membrane." Pullman, Wash. : Washington State University, 2008. http://www.dissertations.wsu.edu/Thesis/Fall2008/d_rieck_012609.pdf.

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Thesis (M.S. in chemical engineering)--Washington State University, December 2008.<br>Title from PDF title page (viewed on Apr. 10, 2009). "Department of Chemical Engineering." Includes bibliographical references.

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28

Cecconie, Theodore James 1961. "Fundamental studies on the separation of the lanthanides using solvent extraction systems." Thesis, The University of Arizona, 1988. http://hdl.handle.net/10150/276744.

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Fundamental solvent extraction studies on the separation of the lanthanides were carried out by investigating both the hydroxamic acid and phosphinic acid reagent families. In general, the lanthanides were found to extract as self-adducts. It was found that the separation of the individual lanthanides with both of these reagent families was adversely affected by steric hindrance.

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29

Muhuri, Prakash Kumar. "Studies on the ion-solvent interactions of some electrolytes in propylene carbonate and its binary mixtures with other organic solvent systems." Thesis, University of North Bengal, 1993. http://hdl.handle.net/123456789/710.

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30

Sinha, Anuradha. "Investigation on viscous synergy and antagonism of some liquid mixtures and ion-solvent interaction of some compounds in various solvent systems." Thesis, University of North Bengal, 2006. http://hdl.handle.net/123456789/705.

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31

Brunet, Jean-Christophe. "An expert system for solvent-based separation process synthesis." Thesis, Virginia Tech, 1992. http://hdl.handle.net/10919/42949.

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Expert systems are being used more daily in chemical engineering. This work continues the development of an EXpert system for SEParation flowsheet synthesis named EXSEP. Written in Prolog, it can generate flowsheets for four multicomponent separations: distillation, absorption, stripping and liquid-liquid extraction. For these separations, we describe a large collection of heuristics (or rules) that are used for flowsheet synthesis. EXSEP uses several of these heuristics and the Kremser equation to test the thermodynamic feasibility of separation tasks. EXSEP requires only basic input data suc

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32

Horne, Gregory. "An experimental and computational investigation into the radiolysis of PUREX solvent systems." Thesis, University of Manchester, 2016. https://www.research.manchester.ac.uk/portal/en/theses/an-experimental-and-computational-investigation-into-the-radiolysis-of-purex-solvent-systems(a793f6ee-0b49-47ce-ae2b-cd88d94c53a0).html.

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Plutonium Uranium Reduction EXtraction (PUREX) technology is a solvent extraction process used to recover plutonium and uranium from spent nuclear fuel. The solvent system is composed of an aqueous nitric acid phase in contact with an organic phase made up of tributyl phosphate in an organic diluent. During the separation process, the PUREX solvent system is subject to an intense multi-component radiation field (gamma rays, alpha particles, beta particles, neutrons, and fission fragments) rendering it susceptible to radiolytic degradation, which reduces its performance. Despite the PUREX proce

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33

Tian, Olivia Yingnan. "Pigmented and solvent dyed latex systems for ink jet printing on textiles." Thesis, Georgia Institute of Technology, 1998. http://hdl.handle.net/1853/8681.

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34

Nzengung, Valentine Asongu. "Organoclays as sorbents for organic contaminants in aqueous and mixed-solvent systems." Diss., Georgia Institute of Technology, 1993. http://hdl.handle.net/1853/26460.

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35

McGillen, J. G. "Studies on the wet spinning of cellulose fibres from novel solvent systems." Thesis, University of Strathclyde, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.372448.

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36

Gumus, Selahaddin. "Secondary Electronic and Solvent Effects on Regiospecific P-Bromination of Aromatic Systems." TopSCHOLAR®, 2018. https://digitalcommons.wku.edu/theses/3031.

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Bromoarenes are important aromatic building blocks that are commonly used to synthesize various functional compounds in pharmaceutical, agrochemical and related industries.1,2 This great demand for bromoarenes makes their preparation a widely studied area of synthetic organic chemistry. However, further understanding of the reactivity and regiochemistry of aromatic functionalization reactions is still necessary, as much about the secondary substitution and solvent effects remain unknown. Resonance Theory is a widely used theoretical model to predict the regiospecifity and reactivity of the bro

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37

APRAHAMIAN, EDWARD JR. "ROLE OF THE INTERFACE IN THE KINETICS AND MECHANISM OF SOLVENT EXTRACTION SYSTEMS (DITHIZONE, OXINE, INTERFACIAL AREA, DISPERSION)." Diss., The University of Arizona, 1985. http://hdl.handle.net/10150/187968.

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A high speed stirring apparatus was constructed for following the kinetics of metal ion extraction by chelating agents. The semi-automated system is capable of measuring reactions with half lives of 20 seconds or more with data being collected every second. Experimental data obtained with the device are superior to those collected by batch shakers, fixed interface cells, falling drop, or other stirring devices. The use of a microporous Teflon membrane phase separator along with the thermodynamic relation, the Gibbs Equation, enabled the measurement of drop sizes in a two phase liquid-liquid di

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38

Khalid, Muhammad. "Influence of solvent viscosity, polarity and polarizability on the chemiluminescence parameters of inter and intramolecular electron transfer initiated chemiexcitation systems." Universidade de São Paulo, 2015. http://www.teses.usp.br/teses/disponiveis/46/46136/tde-29092015-114251/.

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The cyclic peroxides: diphenoyl peroxide (1), spiro-adamantyl-1,2-dioxetanone (2) and 4-(3-tert-butyldimethylsilyloxyphenyl)-4-methoxyspiro[1.2-dioxetane-3.2\'-adamantane] (3) synthesized, purified and characterized, also their kinetic and chemiluminescence (CL) properties were determined. The influence of solvent polarity on the chemiexcitation parameters of the catalyzed decomposition of 1 and 2, as well as the induced decomposition of 3 were examined in several binary solvent mixtures with different polarity and polarizability parameters, but similar viscosities. For solvents with low polar

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39

Cikalo, Maria Gillian. "Separation and quantification of weakly-absorbing and low-concentration analytes by capillary electrophoresis." Thesis, University of York, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.321675.

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40

Datta, Biswajit. "Exploration of miscellaneous interfaces of some ionic solids and ionic liquids Prevailing in various solvent systems by the process of psysicochemical contrivance." Thesis, University of North Bengal, 2017. http://ir.nbu.ac.in/handle/123456789/2673.

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41

Chunsrivirot, Surasak. "Binding affinity of a small molecule to an amorphous polymer in a solvent." Thesis, Massachusetts Institute of Technology, 2011. http://hdl.handle.net/1721.1/65771.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Computational and Systems Biology Program, 2011.<br>Page 169 blank. Cataloged from PDF version of thesis.<br>Includes bibliographical references (p. 165-168).<br>Crystallization is a commonly used purification process in industrial practice. It usually begins with heterogeneous nucleation on a foreign surface. The complicated mechanism of heterogeneous nucleation is not well understood, but we hypothesize a possible correlation between binding affinity to a surface and nucleation enhancement. Amorphous polymers have been used in controlli

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42

Julien, Grégoire. "Dynamics in polymer blends and polymer-solvent blends close to the glass transition." Thesis, Lyon 1, 2014. http://www.theses.fr/2014LYO10187/document.

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Dans ce travail, nous proposons un modèle qui décrit la dynamique dans les mélanges de polymères et polymère-solvant à l'approche de la transition vitreuse. Le modèle est résolu sur un réseau 2D sur des échelles de 10 nm à plusieurs microns. Ce modèle incorpore l'aspect hétérogène de la dynamique à l'échelle d'une hétérogénéité dynamique (3-5 nm). Dans le cas des mélanges de polymères, nous appliquons ce modèle afin d'étudier la séparation de phase lorsque le système est refroidi proche ou sous Tg, et le rajeunissement lorsque le système est réchauffé dans un état miscible et fondu. Pendant la

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43

Das, Bijan. "Physico - chemical investigations on the ion-solvent interactions of some Tetraalkylammonium and common ions in non-aqueous and mixed binary aqueous solvent systems." Thesis, University of North Bengal, 1992. http://hdl.handle.net/123456789/719.

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44

Adinata, Donni [Verfasser]. "Single-drop based modelling of solvent extraction in high-viscosity systems / Donni Adinata." Aachen : Hochschulbibliothek der Rheinisch-Westfälischen Technischen Hochschule Aachen, 2011. http://d-nb.info/1018200606/34.

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45

Chang, Yun Chea. "Concentration dependent diffusion of solid-solute, liquid-solvent systems in the supersautrated region." Diss., Georgia Institute of Technology, 1985. http://hdl.handle.net/1853/11802.

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46

Gautam, Devaki Nandan. "Molecular dynamics simulation of horse-heart cytochrome c in water-methanol solvent systems." Thesis, Wichita State University, 2014. http://hdl.handle.net/10057/10956.

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Molecular Dynamics simulations have been carried out to investigate the dynamics of horse heart Cytochrome C and associated crystallographic water molecules in different water-methanol systems. The 100 ns simulation predicts that hh-CytC undergoes different dynamical transitions with some common conformations in different solvents. With increase of methanol concentration in solvents, hh-CytC has increased flexibility, fluctuating its hydrophobic solvent accessible surface area (SASA), and number of persistent internal hydrogen bonds with long hydrogen-bond-lifetime. The protein became more liq

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47

Van, Deventer David. "Discrimination of Retained Solvent Levels in Printed Food-Packaging Using Electronic Nose Systems." Thesis, Virginia Tech, 2000. http://hdl.handle.net/10919/9741.

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The expanding role of electronic nose instrumentation, as a quality-monitoring tool for food-packaging materials, is examined and reviewed. The food industry is interested in determining the applicability of using an electronic nose for odor analysis of retained printing solvent levels in packaging. Three electronic nose systems were optimized for this application and their performance assessed. These include the FOX 3000, the Cyranose 320, and the QMB6. Response surface methodology was used to generate 2nd order models of sensor response as a function of system and experimental parameters f

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48

Lin, Tingdong. "On the phase behavior and particle formation in polyimide/solvent/nonsolvent ternary systems." Diss., This resource online, 1993. http://scholar.lib.vt.edu/theses/available/etd-06062008-165916/.

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49

Eser, Hülya Tıhmınlıoğlu Funda. "Diffusion And Equilibrium Measurements In Polymer-Solvent Systems By Inverse Gas Chromatography Method/." [s.l.]: [s.n.], 2004. http://library.iyte.edu.tr/tezler/master/kimya/T000451.pdf.

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50

Kobayashi, Takashi. "Development of Reactor Systems Based on Kinetic Analysis of β-Glucosidase-or Lipase-catalyzed Condensation in Organic Solvent Systems". Kyoto University, 2003. http://hdl.handle.net/2433/148961.

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Kyoto University (京都大学)<br>0048<br>新制・課程博士<br>博士(農学)<br>甲第10232号<br>農博第1304号<br>新制||農||862(附属図書館)<br>学位論文||H15||N3753(農学部図書室)<br>UT51-2003-H653<br>京都大学大学院農学研究科応用生命科学専攻<br>(主査)教授松野隆一, 教授大東肇, 教授井上國世<br>学位規則第4条第1項該当

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