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Journal articles on the topic 'Solvolytic rearrangement'

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Published: 5 June 2025

Last updated: 1 August 2025

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1

Popsavin, Velimir, Mirjana Popsavin, and Dusan Miljkovic. "S-O acetyl rearrangement in 6-thio-D-glucose derivatives." Journal of the Serbian Chemical Society 83, no. 12 (2018): 1297–303. http://dx.doi.org/10.2298/jsc180811075p.

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The solvolytic reaction of 1,2-O-isopropylidene-3,6-di-O-(p-toluenesulphonyl)- ?-D-glucofuranose (2), as well as that of 6-chloro-6-deoxy-1,2-O-isopropylidene-3-O-(p-toluenesulphonyl)-?-D-glucofuranose (3), in the presence of potassium thioacetate unexpectedly gave the 6-S-acetyl-5-O-acetyl derivative 5 as the main reaction product. A possible mechanism of these transformations was postulated whereby the main role was ascribed to a neighbouring group participation process, involving hydrogen thio-orthoester formation as an intermediate. The regiospecific monosubstitution of the 6-tosyloxy grou

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2

Ronald, Robert C., Suzanne M. Ruder, and Thomas S. Lillie. "Solvolytic hydroperoxide rearrangements IV. Selective rearrangement of spiro[5,2]octan-4-ol." Tetrahedron Letters 28, no. 2 (1987): 131–34. http://dx.doi.org/10.1016/s0040-4039(00)95667-3.

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3

Della, EW, GM Elsey, and G. Skouroumounis. "Rearrangement of Substituted Bicyclo[2.1.1]hex-2-yl Mesylates Under Solvolytic Conditions." Australian Journal of Chemistry 43, no. 7 (1990): 1231. http://dx.doi.org/10.1071/ch9901231.

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When heated in formic acid, methyl 2-mesyloxybicyclo[2.1.1]hexane-2-carboxylate (3) ionizes significantly faster than expected and yields the rearranged isomer (6) essentially quantitatively. The latter, on the other hand, solvolyses at a much reduced rate. These data are interpreted as evidence for the presence in the ester of a favourable mesomeric interaction which largely offsets an otherwise destabilizing inductive effect when the ester is attached to a carbocationic centre. The corresponding cyano mesylates (8) and (29) were found to behave in an analogous manner when exposed to the solv

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4

Jarvis, Bruce B., M. Estela Alvarez, G. Wang, and Herman L. Ammon. "Solvolytic cyclization of 4,15-anhydroverrucarol. A facile trichothecene-10,13-cyclotrichothecene rearrangement." Journal of Organic Chemistry 54, no. 19 (1989): 4493–94. http://dx.doi.org/10.1021/jo00280a008.

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5

Kruper, William J., and Albert H. Emmons. "Synthesis of .alpha.-halocinnamate esters via solvolytic rearrangement of trichloroallyl alcohols." Journal of Organic Chemistry 56, no. 10 (1991): 3323–29. http://dx.doi.org/10.1021/jo00010a027.

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6

KRUPER, W. J. JUN, та A. H. EMMONS. "ChemInform Abstract: Synthesis of α-Halocinnamate Esters via Solvolytic Rearrangement of Trichloroallyl Alcohols." ChemInform 22, № 39 (2010): no. http://dx.doi.org/10.1002/chin.199139087.

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7

Lee, Choi Chuck, and Dave Wanigasekera. "Solvolytic rearrangement studies with (E)- and (Z)-2-anisyl-1,2-ditolyl[2-13C]vinyl bromides." Canadian Journal of Chemistry 65, no. 5 (1987): 933–40. http://dx.doi.org/10.1139/v87-158.

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Reaction of (E,Z)-or (E)-2-anisyl-1,2-ditolyl[2-13C]vinyl bromides ((E,Z)- or (E)-6-Br-2-13C) with HOAc–AgOAc gave a 1:1 mixture of (E)- and (Z)-2-anisyl-1,2-ditolyl[1,2-13C]vinyl acetates ((E,Z)-6-OAc-1,2-13C), with about 37.4% scrambling of the label from C-2 to C-1 arising from degenerate 1,2-anisyl shifts in the 2-anisyl-1,2-ditolyl[2-13C]vinyl cation (6-2-13C). No detectable amount of 1-anisyl-2,2-ditolylvinyl acetate was formed, indicating no nondegenerate 1,2-tolyl shift in cation 6 to give the more stable 1 -anisyl-2,2-ditolylvinyl cation (10) in the reaction with HOAc–AgOAc. Reaction

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8

THIBBLIN, A. "ChemInform Abstract: Ion Pairs and Ion-Molecule Pairs in Solvolytic Substitution, Elimination and Rearrangement Reactions." ChemInform 26, no. 46 (2010): no. http://dx.doi.org/10.1002/chin.199546281.

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9

Lee, Choi Chuck, and Dave Wanigasekera. "Solvolytic rearrangement studies with 14C or 13C labeled (E)- and (Z)-1,2-diphenyl-2-tolylvinyl bromides." Canadian Journal of Chemistry 64, no. 6 (1986): 1228–34. http://dx.doi.org/10.1139/v86-204.

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The reaction of (E)-, (Z)-, or a 2:3 mixture of (E)- and (Z)-1,2-diphenyl-2-tolyl[2-14C]vinyl bromide ((E)-, (Z)-, or (E,Z)-3-Br-2-14C) in HOAc–AgOAc gave a 1:1 mixture of the structurally unrearranged but isotopically scrambled (E)- and (Z)-1,2-diphenyl-2-tolyl[1,2-14C]vinyl acetates ((E,Z)-3-OAc-1,2-14C), with an average of 18.3% scrambling of the 14C label from C-2 to C-1 arising from 1,2-tolyl shifts in the 1,2-diphenyl-2-tolylvinyl cation (3). No detectable amount of the structurally rearranged 2,2-diphenyl-1-tolylvinyl acetate (4-OAc) was formed. Solvolysis of (E,Z)-3-Br-2-14C in TFE-2,6

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10

Ue, Masaki, Teruhisa Nagashima, Masahiko Kinugawa, et al. "Solvolytic Rearrangement of 5,6-Polymethylenebicyclo[4.2.0]octan-2-cl Derivatives to Functionalized Polymethylenebicyclo[3.2.1]- and [3.3.0]octanes." Chemistry Letters 17, no. 9 (1988): 1521–22. http://dx.doi.org/10.1246/cl.1988.1521.

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11

Kitagawa, Toshikazu, Takao Okazaki, Koichi Komatsu, and Kenichi Takeuchi. "Solvolysis of [3-13C]-4-homoadamantyl tosylate. Limited degeneracy of 4-homoadamantyl cation via multiple Wagner-Meerwein rearrangement and vicinal hydride shifts under solvolytic conditions." Journal of Organic Chemistry 58, no. 27 (1993): 7891–98. http://dx.doi.org/10.1021/jo00079a039.

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12

Klobus, Michael, Lijuan Zhu, and Robert M. Coates. "Solvolytic rearrangement of silphin-2.alpha.-yl methanesulfonate to .alpha.-terrecyclene: a probable biogenetic relationship between silphinene and quadrone." Journal of Organic Chemistry 57, no. 16 (1992): 4327–29. http://dx.doi.org/10.1021/jo00042a001.

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13

Sasaki, Michiko, Misato Fujiwara, Yuri Kotomori, Masatoshi Kawahata, Kentaro Yamaguchi та Kei Takeda. "Chirality transfer in Brook rearrangement-mediated SE2′ solvolytic protonation and its use in estimation of the propensity for racemization of the α-lithiocarbanions of the substituents". Tetrahedron 69, № 29 (2013): 5823–28. http://dx.doi.org/10.1016/j.tet.2013.05.043.

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14

Kasal, Alexander, and Jaroslav Zajíček. "Solvolysis of Westphalen-type compounds." Collection of Czechoslovak Chemical Communications 51, no. 7 (1986): 1462–75. http://dx.doi.org/10.1135/cccc19861462.

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Action of some nucleophilic reagents (CH3COOAg, CH3COOK, LiAlH4) on 6β-chloro- and 6β-methanesulfonyloxy-5-methyl-19-nor-5β-cholest-9-enes VIII - XII affords predominantly A-homo-B,19-dinor-5β-cholest-9-ene derivatives, arising by rearrangement and substitution (XIII, XXIV) or rearrangement and elimination (e.g. XX). Hydrogenolysis of compounds of the type VIII with lithium aluminium hydride gives, in addition, a product of rearrangement, fragmentation and further reduction (XXVI), and 5-methyl-6α,10-cyclo-19-nor-5β,9β,10α-cholestan-3β-ol (XXX).

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15

Ronald, Robert C., and Thomas S. Lillie. "Solvolytic hydroperoxide rearrangements III. Stereoselective Rearrangements of Methylated Cyclopropyl Carbinols." Tetrahedron Letters 27, no. 48 (1986): 5787–90. http://dx.doi.org/10.1016/s0040-4039(00)85327-7.

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16

Kaválek, Jaromír, Josef Jirman, and Vojeslav Štěrba. "Kinetics and mechanism of rearrangement and methanolysis of acylphenylthioureas." Collection of Czechoslovak Chemical Communications 50, no. 3 (1985): 766–78. http://dx.doi.org/10.1135/cccc19850766.

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S-Acyl-1-phenylthioureas and their 3-methyl derivatives are rearranged to 1-acyl derivatives of thiourea in methanolic solution. The rearrangement of the 1-acyl-1-phenyl derivative to the thermodynamically more stable 3-acyl derivative is subject to specific base catalysis. The rearrangement of acetyl group is about 2 orders of magnitude slower than that of benzoyl group. 1-Acetyl-l-phenylthiourea undergoes base-catalyzed methanolysis (giving phenylthiourea and methyl acetate) instead of the rearrangement. The methanolysis rates of l-acyl-3-phenylthioureas and their N-methyl derivatives have b

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17

Hanessian, Stephen, and René Roy. "Chemistry of spectinomycin: its total synthesis, stereocontrolled rearrangement, and analogs." Canadian Journal of Chemistry 63, no. 1 (1985): 163–72. http://dx.doi.org/10.1139/v85-026.

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The total stereocontrolled synthesis of the antibiotic spectinomycin is described, based on the regiospecific functionalization and manipulation of appropriate starting materials. The tertiary ketol rearrangement of the antibiotic and its derivatives was studied and the stereochemical identity of spectinoic acid was established by chemical correlation. Dihydrospectinomycin derivatives undergo unusual solvolysis reactions.

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18

Della, Ernest W., Gordon M. Elsey, and George Skouroumounis. "Solvolytic rearrangements of bicyclo[2.1.1]hex-2-yl mesylates." Tetrahedron Letters 27, no. 49 (1986): 5993–96. http://dx.doi.org/10.1016/s0040-4039(00)85381-2.

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19

Conner, John K., Johanna Haider, MN Stuart Hill, Howard Maskill, and Monique Pestman. "The mechanism of solvolysis of 2-adamantyl azoxytosylate: isotopic labelling, medium effect, and attempted deoxygenation studies." Canadian Journal of Chemistry 76, no. 6 (1998): 862–68. http://dx.doi.org/10.1139/v98-071.

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Rates of solvolysis of 2-adamantyl azoxytosylate (1) have been measured over a range of temperatures in ethanoic acid, methanoic acid, 50:50 (v/v) trifluoroethanol:water, 80:20 (v/v) trifluoroethanol:water, 97:3 (w/w) trifluoroethanol:water, and 70:30 (v/v) ethanol:water. For comparison, rates of solvolysis of 2-adamantyl tosylate (2) have also been measured in 50:50, 80:20, and 90:10 (v/v) trifluoroethanol:water, and for both compounds, activation parameters have been determined. These and results published earlier allow a correlation of the two reactions and indicate that the m value for 2-a

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20

Saunders, James, Chris Adamson, Yumeela Ganga-Sah, Andrew R. Lewis, and Andrew J. Bennet. "Rearrangement and nucleophilic trapping of bicyclo[4.1.0]hept-2-yl derived nonclassical bicyclobutenium ions." Canadian Journal of Chemistry 96, no. 2 (2018): 235–40. http://dx.doi.org/10.1139/cjc-2017-0569.

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Here we describe the synthesis of two specifically labelled 13C isotopologues of cis-2-(4-nitrophenoxy)bicyclo[4.1.0]heptane and their solvolysis reactions in trifluoroethanol. By using one- and two-dimensional 1H- and 13C-NMR spectroscopy, we characterized the pathways for the rearrangement of these isotopologues to give 13C-labelled 4-(2,2,2-trifluoroethoxy)cycloheptene. We show that the initially formed cationic intermediate undergoes a degenerate rearrangement, which does not reach equilibrium before nucleophilic capture of the cation. Moreover, we show that the nonclassical carbocation, c

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21

Braverman, Samuel, and Haim Manor. "THE SYNTHESIS, SOLVOLYSIS AND REARRANGEMENT OF BENZYL TRIFLUOROMETHANESULFINATES." Phosphorus, Sulfur, and Silicon and the Related Elements 53, no. 1-4 (1990): 357–65. http://dx.doi.org/10.1080/10426509008038045.

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22

Ruder, Suzanne M., and Robert C. Ronald. "Solvolytic hydroperoxide rearrangements V. A stereoselective synthesis of trans-fused butyrolactones." Tetrahedron Letters 28, no. 2 (1987): 135–38. http://dx.doi.org/10.1016/s0040-4039(00)95668-5.

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23

Joska, Jiří, Jan Fajkoš та František Tureček. "Solvolytic rearrangements in 3-acetoxy-4β,5β-cyclopropanocholestane-19-p-toluenesulfonates". Tetrahedron Letters 28, № 25 (1987): 2901–4. http://dx.doi.org/10.1016/s0040-4039(00)96240-3.

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24

Braverman, Samuel, Tatiana Pechenick, and Yossi Zafrani. "Synthesis, rearrangement and solvolysis of propargylic and allylic trifluoromethanesulfinates." Arkivoc 2004, no. 2 (2003): 51–63. http://dx.doi.org/10.3998/ark.5550190.0005.204.

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25

Cherton, Jean-Claude, Marc Bazinet, Marie-Madeleine Bolze, Marc Lanson та Paul-Louis Desbene. "Réactivité du nucléophile azoture vis-à-vis de cations hétérocycliques aromatiques. VIII. Réarrangement de β-tétrazolo-trans-benzalacétophénones". Canadian Journal of Chemistry 63, № 10 (1985): 2601–7. http://dx.doi.org/10.1139/v85-432.

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β-Tetrazolyl-trans-benzalacetophenones (T) isomerize upon heating into the corresponding azido-azomethines (A). These non-isolable products undergo various transformations depending on the reaction conditions. With organic bases such as triphenylphosphine or pyridine, their interception can occur. In aromatic solvents, a rearrangement involving loss of nitrogen leads to five-membered diazoted heterocycles:-N-benzoyl imidazoles and pyrazoles, via intermediate diazirines and oxazepines. Protic solvents have been found to facilitate the isomerisation of tetrazoles into azidoazomethines. Solvolysi

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26

Bennet, Andrew James. "ChemInform Abstract: Solvolysis and Rearrangement in Unsaturated Carbon Cage Compounds." ChemInform 30, no. 50 (2010): no. http://dx.doi.org/10.1002/chin.199950260.

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27

Lillie, Thomas S., and Robert C. Ronald. "Solvolytic hydroperoxide rearrangements. 2. Oxa bicyclic hemiketal peroxides from homoallylic and cyclopropylcarbinyl precursors." Journal of Organic Chemistry 50, no. 25 (1985): 5084–88. http://dx.doi.org/10.1021/jo00225a018.

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28

Braverman, Samuel, and Ytzhak Duar. "Highly reactive sulfinates. The synthesis, solvolysis and rearrangement of benzyl trichloromethanesulfinates." Tetrahedron 46, no. 8 (1990): 2975–90. http://dx.doi.org/10.1016/s0040-4020(01)88389-7.

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29

Joska, Jiří, Jan Fajkoš та František Tureček. "Solvolytic rearrangements in 4β,5-cyclopropano-5β-cholestane-3β,19-diol 3-acetate 19-p-toluenesulphonate". Collection of Czechoslovak Chemical Communications 52, № 12 (1987): 2991–3012. http://dx.doi.org/10.1135/cccc19872991.

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Acetolysis of the tosylate VIII proceeded under participation of the cyclopropane ring at the electron-deficient center formed during the reaction to yield three products all having modified steroid skeletons. They were the diene XXIII, the unsaturated acetate XI, and the saturated 4β,10β-cycloderivative XIII carrying two acetoxy groups in the molecule. For the purpose of spectral studies and structure elucidation the acetolysis has been carried out with the labelled tosylate XXXII the synthesis of which is described and analogous three labelled products were isolated. The structures of these

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30

Nevill, S. M., and J. A. Pincock. "The design of radical clocks to probe the reactivity of the intermediates in arylmethyl ester photochemistry." Canadian Journal of Chemistry 75, no. 2 (1997): 232–47. http://dx.doi.org/10.1139/v97-027.

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The photochemistry in methanol of the esters 1–6was examined. These reactions normally proceed through radical pairs that result from homolytic cleavage of the carbon–oxygen bond in the excited singlet state. Each of the esters was designed to probe the intervention and reactivity of the substituted arylmethyl radical by incorporating a potential radical clock at the carbon of the reactive bond. For esters 1–5, the products isolated indicated that the radical clock was not reactive enough to compete with the very rapid alternate processes of the radical pair, namely, electron transfer to form

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31

Creary, Xavier. "The cyclopropylcarbinyl route to γ-silyl carbocations". Beilstein Journal of Organic Chemistry 15 (24 липня 2019): 1769–80. http://dx.doi.org/10.3762/bjoc.15.170.

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The mesylate derivative of cis-1-hydroxymethyl-2-trimethylsilylcyclopropane has been prepared, along with a number of related mesylates and triflates with substituents on the 1-position. These substrates all solvolyze in CD3CO2D to give products derived from cyclopropylcarbinyl cations that undergo further rearrangement to give 3-trimethylsilylcyclobutyl cations. These 3-trimethylsilylcyclobutyl cations are stabilized by a long-range rear lobe interaction with the γ-trimethylsilyl group. When the substituent is electron-withdrawing (CF3, CN, or CO2CH3), significant amounts of bicyclobutane pro

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32

Cristol, Stanley J., George C. Schloemer, Dieter Braun, and Gwendolyn O. Mayo. "Bridged polycyclic compounds. 88. Multiple intermediates in solvolysis of certain bridged bicyclic and tricyclic compounds." Canadian Journal of Chemistry 64, no. 6 (1986): 1077–80. http://dx.doi.org/10.1139/v86-180.

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Acetolyses of 7-chloromethyl- and 7-bromomethyldibenzobicyclo[2.2.2]octatrienes, 8-chloro- and 8-bromo-7-methylenedibenzobicyclo[2.2.2]octa-2,5-dienes, 4-bromo-8-methylenedibenzobicyclo[3.2.1]octa-2,6-diene, and 2-chlorodibenzotricyclo[3.2.2.02,4]nonadiene were carried out. The results observed were consistent with the involvement of two carbocations interconverting by a Wagner–Meerwein rearrangement, and with the absence of the 1-dibenzosemibullvalenylcarbinyl cation, which is the cyclopropylcarbinyl isomer of one of the cations produced. The preparations of the reactants and products are des

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33

Nge, Thi Thi, Yuki Tobimatsu, Masaomi Yamamura, et al. "Effect of Heat Treatment on the Chemical Structure and Thermal Properties of Softwood-Derived Glycol Lignin." Molecules 25, no. 5 (2020): 1167. http://dx.doi.org/10.3390/molecules25051167.

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A large-scale glycol lignin (GL) production process (50 kg wood meal per batch) based on acid-catalyzed polyethylene glycol (PEG) solvolysis of Japanese cedar (JC) was developed at the Forestry and Forest Products Research Institute (FFPRI), Tsukuba, Japan. JC wood meal with various particle size distributions (JC-S < JC-M < JC-L) (average meal size, JC-S (0.4 mm) < JC-M (0.8 mm) < JC-L (1.6 mm)) and liquid PEG with various molecular masses are used as starting materials to produce PEG-modified lignin derivatives, namely, GLs, with various physicochemical and thermal properties. Be

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34

Kocovsky, Pavel, Frantisek Turecek, Vratislav Langer, Jana Podlahova, and Jaroslav Podlaha. "A stereospecific tandem Wagner-Meerwein rearrangement in the solvolysis of 19-mesyloxy steroids." Journal of Organic Chemistry 51, no. 25 (1986): 4888–91. http://dx.doi.org/10.1021/jo00375a024.

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35

Poulter, C. Dale, and Douglas S. Mautz. "Solvolysis of allylic isoprene phosphorothioate esters. A mechanistic study of the thiono .fwdarw. thiolo rearrangement." Journal of the American Chemical Society 113, no. 13 (1991): 4895–903. http://dx.doi.org/10.1021/ja00013a027.

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36

Fajkoš, Jan, та Jiří Joska. "Solvolytic rearrangements in 4β,5-cyclopropano-5β-androstane-3β,17β,19-triol 3-acetate 17-benzoate 19-p-toluenesulfonate". Collection of Czechoslovak Chemical Communications 54, № 3 (1989): 751–59. http://dx.doi.org/10.1135/cccc19890751.

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The title tosylate V was prepared from the tosylate III by Simmons-Smith methylenation. Its acetolysis afforded three products with modified steroid skeletons: The diene VIII, the olefin XI, and the pentacyclic diacetate XIII. The 3-oxo derivatives XIV, XVI, XVII, and XIX-compounds of potentional biological interest-were prepared as follows: Oxidation of the monoacetate X followed by hydrolysis yielded the testosterone analogue XIV and oxidation of the diol IX gave the dione XVI. Using similar reaction sequence the triol diester XII afforded the oxo compounds XVII and XIX.

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37

Shankar, Sriram, та Robert M. Coates. "Solvolysis of Caryophyllen-8β-yl Derivatives: Biomimetic Rearrangement−Cyclization to 12-Nor-8α-presilphiperfolan-9β-ol". Journal of Organic Chemistry 63, № 25 (1998): 9177–82. http://dx.doi.org/10.1021/jo971984m.

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38

Inomata, Kohei, and Sanami Narita. "Novel stereoselective 1,2-rearrangement of Swaminathan ketone derivatives bearing a 7-membered ring under solvolysis conditions." Tetrahedron Letters 61, no. 9 (2020): 151542. http://dx.doi.org/10.1016/j.tetlet.2019.151542.

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39

POULTER, C. D., and D. S. MAUTZ. "ChemInform Abstract: Solvolysis of Allylic Isoprene Phosphorothioate Esters. A Mechanistic Study of the Thiono → Thiolo Rearrangement." ChemInform 22, no. 40 (2010): no. http://dx.doi.org/10.1002/chin.199140071.

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40

Cristol, Stanley J., Ellen O. Aeling, S. J. Strickler, and Robert D. Ito. "Photochemical transformations. 46. Photophysics and photochemistry of some compounds undergoing light-induced solvolysis and Wagner-Meerwein rearrangement." Journal of the American Chemical Society 109, no. 23 (1987): 7101–4. http://dx.doi.org/10.1021/ja00257a032.

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41

Jasti, Ramesh, and Scott D. Rychnovsky. "Solvolysis of a Tetrahydropyranyl Mesylate: Mechanistic Implications for the Prins Cyclization, 2-Oxonia-Cope Rearrangement, and Grob Fragmentation." Organic Letters 8, no. 10 (2006): 2175–78. http://dx.doi.org/10.1021/ol0606738.

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42

Anulewicz-Ostrowska, Romana, Izabella Jastrzȩbska, Jacek W. Morzycki, and Jacek Wójcik. "An Assisted Solvolysis of 23-Spirostanyl Bromides and Tosylates. A New Rearrangement of Spirostanes to the Bisfuran Systems." Journal of Organic Chemistry 67, no. 20 (2002): 6916–24. http://dx.doi.org/10.1021/jo020231j.

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43

Biali, Silvio E., and Zvi Rappoport. "Vinylic cations from solvolysis. 42. Cyclization on methyl, capture by solvent, and degenerate rearrangement of the trimesitylvinyl cation." Journal of Organic Chemistry 51, no. 7 (1986): 964–70. http://dx.doi.org/10.1021/jo00357a002.

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44

Asokan, Chitoorthekkathil V., Hiriyakkanavar Ila, and Hiriyakkanavar Junjappa. "ketendithioacetals 39. Novel solvolytic rearrangements of 1,1-bis-(methylthio)-2,4-dimethyl-5-aryl (or styryl)-1,4-pentadien-3-ols to cyclopentenone derivative." Tetrahedron Letters 26, no. 8 (1985): 1087–90. http://dx.doi.org/10.1016/s0040-4039(00)98519-8.

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45

Durrant, Michael L., and John R. Malpass. "Solvolysis of N-chloro-1,4-dihydro-1,4-iminonaphthalenes (7-azabenzonorbornadienes); dependence of the rearrangement pathway on the configuration at nitrogen." Tetrahedron 51, no. 25 (1995): 7063–76. http://dx.doi.org/10.1016/0040-4020(95)00336-7.

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46

Ghigo, Giovanni, Andrea Maranzana, and Glauco Tonachini. "Memory Effects in Carbocation Rearrangements: Structural and Dynamic Study of the Norborn-2-en-7-ylmethyl-X Solvolysis Case." Journal of Organic Chemistry 78, no. 18 (2013): 9041–50. http://dx.doi.org/10.1021/jo401188e.

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47

Thibblin, Alf. "Acid-catalysed intramolecular allylic rearrangement of methyl ethers in aqueous solvent. Evidence for the intermediacy of ion–molecule pairs in solvolysis." J. Chem. Soc., Perkin Trans. 2, no. 11 (1987): 1629–32. http://dx.doi.org/10.1039/p29870001629.

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Clark, Benjamin C., Theresa S. Chamblee, and Guillermo A. Iacobucci. "Micellar-induced selectivity and rate enhancement in the acid-catalyzed cyclization and rearrangement of monoterpenes. The solvolysis of linalyl and geranyl acetates." Journal of Organic Chemistry 54, no. 5 (1989): 1032–36. http://dx.doi.org/10.1021/jo00266a007.

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DURRANT, M. L., and J. R. MALPASS. "ChemInform Abstract: Solvolysis of N-Chloro-1,4-dihydro-1,4-iminonaphthalenes (7- Azabenzonorbornadienes); Dependence of the Rearrangement Pathway on the Configuration at Nitrogen." ChemInform 26, no. 40 (2010): no. http://dx.doi.org/10.1002/chin.199540064.

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Mbianda, Xavier Y., та Petrus H. Van Rooyen. "Solvolysis of 1-oxo-2,8-diphenyl-2,5,8-triaza-1λ5-phosphabicyclo[3.3.0]octane: new rearrangement of an eight- to a five-membered phosphodiamidate system". Chemical Communications, № 7 (1998): 741–42. http://dx.doi.org/10.1039/a800836a.

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