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Journal articles on the topic 'Spherical top molecule'

Author: Grafiati

Published: 22 February 2025

Last updated: 31 July 2025

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1

Rotger, M., V. Boudon, M. Loëte, et al. "The bending triad of the quasi-spherical top molecule SO2F2 in the 550cm−1 region." Journal of Molecular Spectroscopy 238, no. 2 (2006): 145–57. http://dx.doi.org/10.1016/j.jms.2006.04.014.

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2

Inostroza, Natalia, Ricardo Letelier, and María Luisa Senent. "On the variational solution of the coupled breathing rotation-vibration of a spherical top molecule." Journal of Mathematical Chemistry 45, no. 4 (2008): 1055–59. http://dx.doi.org/10.1007/s10910-008-9392-5.

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3

Chang, Johnny, and Robert E. Wyatt. "Artificial intelligence techniques in the study of multiphoton dynamics: Application to a general vibrating-rotating spherical top molecule." Chemical Physics Letters 121, no. 4-5 (1985): 307–14. http://dx.doi.org/10.1016/0009-2614(85)87184-0.

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4

Paka, I., D. A. Roth, M. Heppa та ін. "High resolution spectroscopy of Ar-CH4 and Kr-CH4 in the 7 μ region (j = 1 ← 0 transition)". Zeitschrift für Naturforschung A 53, № 8 (1998): 725–32. http://dx.doi.org/10.1515/zna-1998-0814.

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Abstract Diode laser spectra of the rare gas - spherical top van der Waals complexes Ar-CH4 and Kr-CH4 were measured in the wavelength region near 1310 cm-1 and assigned. The most prominent lines of both complexes exhibit three dense but well resolved RP0, QR0, and RQ0 branches, correlated to the R(0) transition of the triply degenerate bending vibration v4 of methane, CH4. A model Hamiltonian based on Coriolis coupled states was applied for the assignment, analysis and fitting of the spectra to within the experimental accuracy of ≈ 15 MHz. The rotational B constants of the upper and lower sta

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5

Brot, Claude. "Liquides de toupies symétriques: leur tenseur de polarisabilité optique intrinsèque via deux expériences sous champ statique: CH3CN." Canadian Journal of Chemistry 68, no. 9 (1990): 1490–93. http://dx.doi.org/10.1139/v90-228.

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NMR line splitting under a strong static electric field (EF-NMR) allows one to measure the average alignment (second spherical harmonic) of the molecule studied under the influence of the field. This average alignment (per unit squared field) can be formulated theoretically by an expression involving the permanent dipole moment, the anisotropy of the static polarizability, etc. and possibly orientational intercorrelations within the liquid. On the other hand the Kerr constant per molecule can be represented by the same expression, multiplified by a factor that is independent of any static elec

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6

Kuyliev, B. T., N. D. Orlova, L. A. Pozdnyakova, L. O. Meyliev, M. A. Rahmonova, and Zh N. Huzhamberdieva. "Vibrational-Rotational Interaction in Molecules of the Spherical Top Type." Ukrainian Journal of Physics 59, no. 3 (2014): 222–25. http://dx.doi.org/10.15407/ujpe59.03.0222.

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7

BUNKER, P. R., and PER JENSEN. "Spherical top molecules and the molecular symmetry group." Molecular Physics 97, no. 1-2 (1999): 255–64. http://dx.doi.org/10.1080/00268979909482827.

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8

JENSEN, P. R. BUNKER, PER. "Spherical top molecules and the molecular symmetry group." Molecular Physics 97, no. 1 (1999): 255–64. http://dx.doi.org/10.1080/002689799164090.

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9

McDowell, Robin S. "Rotational partition functions for spherical-top molecules." Journal of Quantitative Spectroscopy and Radiative Transfer 38, no. 5 (1987): 337–46. http://dx.doi.org/10.1016/0022-4073(87)90028-8.

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10

Najafi, Mohsen. "Prediction of Thermophysical Properties of Spherical Top Molecules." Russian Journal of Physical Chemistry A 96, no. 8 (2022): 1658–66. http://dx.doi.org/10.1134/s0036024422080167.

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11

Evans, M. W. "Laboratory-frame cross-correlation functions for spherical-top molecules." Physical Review A 35, no. 7 (1987): 2989–92. http://dx.doi.org/10.1103/physreva.35.2989.

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12

Krohn, Burton J., and James K. G. Watson. "Perturbations of the dominant approximation in spherical-top molecules." Journal of Molecular Spectroscopy 129, no. 2 (1988): 395–435. http://dx.doi.org/10.1016/0022-2852(88)90047-1.

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13

Sadovskii, D. A., and B. I. Zhilinskii. "Qualitative analysis of vibration-rotation hamiltonians for spherical top molecules." Molecular Physics 65, no. 1 (1988): 109–28. http://dx.doi.org/10.1080/00268978800100891.

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14

Millot, G., J. Hetzler, G. Pierre, and J. I. Steinfeld. "Infrared double-resonance lineshapes in strongly pumped spherical-top molecules." Spectrochimica Acta Part A: Molecular Spectroscopy 45, no. 1 (1989): 5–15. http://dx.doi.org/10.1016/0584-8539(89)80021-2.

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15

Ogurtsov, I. Ya, and V. L. Ostrovski. "The quadrupole moments of spherical-top molecules in orbitally degenerate states." Molecular Physics 54, no. 1 (1985): 119–27. http://dx.doi.org/10.1080/00268978500100091.

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16

Papoušek, Dušan. "Forbidden transitions in molecular vibrational-rotational spectroscopy." Collection of Czechoslovak Chemical Communications 54, no. 10 (1989): 2555–630. http://dx.doi.org/10.1135/cccc19892555.

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A review is given of the forbidden ( more precisely: perturbation allowed) transistions between molecular vibrational-rotational states including transistions which are induced by the electric dipole and quadrupole moments and the magnetic dipole moment. The basic theory of these transistions is outlined starting with the overall symmetry selection rules, followed by the discussion of the spin statistics isomers, approximate selection rules for the usual vibrational-rotational transistions, and forbidden transistions induced by the electric quadrupole and magnetic dipole moments. Forbidden tra

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17

Pierre, G., D. A. Sadovskii, and B. I. Zhilinskii. "Organization of Quantum Bifurcations: Crossover of Rovibrational Bands in Spherical Top Molecules." Europhysics Letters (EPL) 10, no. 5 (1989): 409–14. http://dx.doi.org/10.1209/0295-5075/10/5/004.

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18

Bobin, Bernard, and Jacques Moret-Bailly. "Fourier transform spectroscopy and the vibration-rotation spectra of spherical top molecules." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 51, no. 7 (1995): 1231–37. http://dx.doi.org/10.1016/0584-8539(94)00016-5.

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19

Krivtsun, V. M., D. A. Sadovskii, and B. I. Zhilinskii. "Critical phenomena and diabolic points in rovibrational energy spectra of spherical top molecules." Journal of Molecular Spectroscopy 139, no. 1 (1990): 126–46. http://dx.doi.org/10.1016/0022-2852(90)90246-m.

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20

Blokhin, A. P., and M. F. Gelin. "Effect of the intensity of collisions on the orientational relaxation of spherical top molecules." Molecular Physics 87, no. 2 (1996): 455–68. http://dx.doi.org/10.1080/00268979600100301.

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21

Braun, P. A., A. M. Shirokov, and Yu F. Smirnov. "On the level clustering in the spectra of the non-rigid spherical top molecules." Molecular Physics 56, no. 3 (1985): 573–87. http://dx.doi.org/10.1080/00268978500102531.

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22

Wenger, Ch, V. Boudon, J.-P. Champion, and G. Pierre. "Highly-spherical Top Data System (HTDS) software for spectrum simulation of octahedral XY6 molecules." Journal of Quantitative Spectroscopy and Radiative Transfer 66, no. 1 (2000): 1–16. http://dx.doi.org/10.1016/s0022-4073(99)00161-2.

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23

Grygiel, Krzysztof. "Anomalous dielectric relaxation in solutions of rigid, dipolar asymmetric-top molecules in spherical solvent." Chemical Physics 532 (April 2020): 110702. http://dx.doi.org/10.1016/j.chemphys.2020.110702.

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24

Sarychev, Andrey K., Andrey V. Ivanov, Igor V. Bykov, et al. "Giant Raman radiation from molecules in a spherical metal shell." Applied photonics 10, no. 7 (2023): 33–53. http://dx.doi.org/10.15593/2411-4375/2023.7.03.

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The work considers an electrodynamic model of radiation from molecules placed in a metal shell. The model qualitatively describes the enhancement of the surface-enhanced Raman scattering (SERS) signal from spherical nanoparticles coated with a thin silver film. The change in the SERS signal is calculated depending on the thickness of the metal nanolayer on top of the spherical particles. The radiating molecular dipole interacts with the metal shell and excites surface plasmons. Plasmonic oscillations reach a maximum when the frequency of the dipole is close to the plasmon resonance of the meta

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25

Parson, Robert. "A symmetry‐based model for selective rotational energy transfer in collisions of spherical top molecules." Journal of Chemical Physics 93, no. 12 (1990): 8731–38. http://dx.doi.org/10.1063/1.459261.

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26

Tarrago, G., and M. Dang Nhu. "Ground state rotational energies of C3v quasi-spherical top molecules: Applications to 16OPF3 and PH3." Journal of Molecular Spectroscopy 111, no. 2 (1985): 425–39. http://dx.doi.org/10.1016/0022-2852(85)90017-7.

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27

Park, Youngho, Hanbin Pang, and Shoudan Liang. "Continuum Approximations to the Hückel Spectrum of Fullerenes." International Journal of Modern Physics B 11, no. 13 (1997): 1607–17. http://dx.doi.org/10.1142/s0217979297000824.

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We discuss several continuum approximations to the tight-binding spectrum of fullerene molecules at the bottom, top and center of the spectrum. The bottom part of the spectrum can be well fit by spherical harmonics, whereas the top part can be understood as due to an electron moving in the magnetic field of a monopole. The center part of the spectrum is described by the theory of González et al. Comparison with the Hückel spectrum of fullerenes, with up to 2160 atoms, yields excellent agreement with the continuum approximations, especially for larger fullerenes.

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28

Kalmykov, Yuri P., Sergey V. Titov, and William T. Coffey. "Langevin equation method for the rotational Brownian motion and orientational relaxation in liquids: spherical top molecules." Journal of Molecular Liquids 116, no. 3 (2005): 119–23. http://dx.doi.org/10.1016/j.molliq.2004.10.030.

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29

Kim, Jae Gwang, Jae Gyeong Lee, and Jeong Jae Wie. "Confinement-Induced Fabrication of Liquid Crystalline Polymeric Fibers." Molecules 27, no. 17 (2022): 5639. http://dx.doi.org/10.3390/molecules27175639.

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In aqueous media, liquid crystalline droplets typically form spherical shapes in order to minimize surface energy. Recently, non-spherical geometry has been reported using molecular self-assembly of surfactant-stabilized liquid crystalline oligomers, resulting in branched and randomly oriented filamentous networks. In this study, we report a polymerization of liquid crystalline polymeric fibers within a micro-mold. When liquid crystal oligomers are polymerized in freely suspended aqueous media, curvilinear and randomly networked filaments are obtained. When reactive liquid crystalline monomers

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30

Alexiewicz, W., and K. Grygiel. "Kinetic Theory of the Langevin Saturation in Dilute Solution of Dipolar Symmetric-Top Molecules in Spherical Solvents." Acta Physica Polonica A 114, no. 4 (2008): 667–86. http://dx.doi.org/10.12693/aphyspola.114.667.

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31

Chiu, Ying‐Nan. "Four‐photon selection rules and line strengths in symmetric and spherical‐top molecules and time‐reversal invariance." Journal of Chemical Physics 86, no. 4 (1987): 1686–97. http://dx.doi.org/10.1063/1.452167.

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32

Evans, M. W., K. N. Swamy, G. C. Lie, and E. Clementi. "Computer Simulation of the Structures and Cross Correlation Functions of Spherical-top Molecules in the Liquid State." Molecular Simulation 1, no. 3 (1988): 187–206. http://dx.doi.org/10.1080/08927028808080942.

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33

Clodius, William B., and C. Richard Quade. "Internal coordinate formulation for the vibration‐rotation energies of polyatomic molecules. III. Tetrahedral and octahedral spherical top moleculesa)." Journal of Chemical Physics 82, no. 5 (1985): 2365–79. http://dx.doi.org/10.1063/1.448332.

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34

Jain, A. "Effect of gas temperature on the rotational excitation of spherical top molecules (CH4 and SiH4) by low-energy electrons." Zeitschrift f�r Physik D Atoms, Molecules and Clusters 21, no. 2 (1991): 153–61. http://dx.doi.org/10.1007/bf01425594.

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35

Parson, Robert. "Fine‐structure selective collisional energy transfer in spherical top molecules: Evidence for a symmetry‐based mechanism from rovibrational eigenfunctions." Journal of Chemical Physics 95, no. 12 (1991): 8941–61. http://dx.doi.org/10.1063/1.461226.

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36

Losic, Dusan, Ken Short, Justin Gooding, and Joe Shapter. "Scanning probe microscopy characterization of immobilized enzyme molecules on a biosensor surface: Visualisation of individual molecules." Journal of the Serbian Chemical Society 69, no. 2 (2004): 93–106. http://dx.doi.org/10.2298/jsc0402093l.

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Scanning probe microscopy techniques were used to study immobilized enzyme molecules of glucose oxidase (GOD) on a biosensor surface. The study was carried out in order to optimize atomic force microscopy (AFM) imaging and reveal themolecular resolution of individual GOD molecules. Chemically modified AFM tips and the light tapping mode were found to be the optimal conditions for imaging soft biomolecules such as GOD. The information obtained from the AFM images included spatial distribution and organization of the enzyme molecules on the surface, surface coverage and shape, size and orientati

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37

Sano, Ken-Ichi, and Kiyotaka Shiba. "In Aqua Manufacturing of a Three-Dimensional Nanostructure Using a Peptide Aptamer." MRS Bulletin 33, no. 5 (2008): 524–29. http://dx.doi.org/10.1557/mrs2008.105.

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AbstractTBP-1 is a 12-amino-acid peptide aptamer that has been isolated as a Ti binder using a peptide-phage system. Subsequent analyses have shown that TBP1 also binds Si and Ag, and has the ability to enhance the formation of titania and silica as well as nanoparticles of Ag. TBP-1 is thus a bifunctional peptide: a binder that also acts as a mediator of mineralization. These two functions can be grafted onto heterologous molecules. For instance, mutational analysis of the TBP-1 revealed that its N -terminal hexapeptide, RKLPDA (minTBP-1), is sufficient for Ti binding. When the surface of fer

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38

Fan, Kang Qi, Chun Hui Xu, and Feng Bo Chao. "A Model of Adhesive Contact between a Spherical Tip and a Flat Surface." Advanced Materials Research 860-863 (December 2013): 2700–2706. http://dx.doi.org/10.4028/www.scientific.net/amr.860-863.2700.

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There have been increasing research interests in the measurement of the mechanical properties of nanoscale materials by pressing a spherical tip into surfaces of the tested materials. To acquire a better understanding of this process, a model of adhesive contact between a spherical tip and a flat surface is developed by employing the Hamaker hypotheses and molecular dynamics (MD) method. With this model, the deformation characteristics of the tested surface are illustrated by the key snapshots of the deformed surface and the corresponding curves of pressure distribution. The results indicate t

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39

Molet, Pau, Luz Karimé Gil-Herrera, Juan Luis Garcia-Pomar, et al. "Large area metasurfaces made with spherical silicon resonators." Nanophotonics 9, no. 4 (2020): 943–51. http://dx.doi.org/10.1515/nanoph-2020-0035.

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AbstractHigh-index dielectric nanostructures have emerged as an appealing complement to plasmonic nanostructures, offering similar light management capabilities at the nanoscale but free from the inherent optical losses. Despite the great interest in these all-dielectric architectures, their fabrication still requires cumbersome fabrication techniques that limit their implementation in many applications. Hence, the great interest in alternative scalable procedures. Among those, the fabrication of silicon spheres is at the forefront, with several routes available in the literature. However, the

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40

Ritze, H. H. "The Role of “Rotational Freezing” in the Polarisation-Dependent Two-Photon Excitation of Triply Degenerate Vibrations in Spherical-Top-Molecules." Annalen der Physik 498, no. 6-8 (1986): 545–72. http://dx.doi.org/10.1002/andp.19864980616.

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41

Latter, William B., and Joseph L. Hora. "Investigating the near-IR properties of PN: Deep imaging of molecular hydrogen emission." Symposium - International Astronomical Union 180 (1997): 254. http://dx.doi.org/10.1017/s0074180900130724.

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We present the first results of a deep near-infrared narrowband imaging study of several planetary nebulae. The data were acquired using the University of Hawaii 2.2m telescope on Mauna Kea and the “QUIRC” 1024 × 1024 array camera. With these sensitive high spatial resolution imaging data, we are able to explore in detail where H2 is found relative to the ionized region in planetary nebulae at various stages of evolution (See Figure 1, for an example). The objects were selected from previous studies to have evidence for extended emission from H2, and they are at several differing phases of cen

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42

Masir, Amin Nouroozi, Abolfazl Darvizeh, and Asghar Zajkani. "Nanoindentation on the bio-inspired high-performance nature composite by molecular dynamics method." Advanced Composites Letters 28 (January 1, 2019): 096369351986016. http://dx.doi.org/10.1177/0963693519860162.

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The determination of mechanical properties at the nanoscale is of such importance today that researchers pay special attention to it. Discovering the mechanical properties of biological composite structures in the nanoscale is much interesting today. Top neck mollusk shells are among biomaterial nanocomposites that their layered structures are composed of organic and inorganic materials. Since the nanoindentation process is known as an efficient method to determine mechanical properties like elastic modulus and hardness in small scale, therefore, due to some limitations of considering all peri

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43

Alexiewicz, W., and K. Grygiel. "Cole-Cole Plots for Linear and Nonlinear Dielectric Relaxation in Solutions of Rigid Highly Dipolar Symmetric-Top Molecules in Spherical Solvents." Acta Physica Polonica A 114, no. 4 (2008): 687–98. http://dx.doi.org/10.12693/aphyspola.114.687.

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44

Sarka, Kamil, Jean Demaison, Laurent Margulès, et al. "Centrifugal Distortion Analysis of a Near-Spherical Top, SO2F2: The First Determination of All Six Quartic Centrifugal Distortion Constants for an Asymmetric Top." Journal of Molecular Spectroscopy 200, no. 1 (2000): 55–64. http://dx.doi.org/10.1006/jmsp.1999.8018.

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45

XIAO, WENDE, ZHIJUN YAN, SUNIL SINGH KUSHVAHA, MAOJIE XU, and XUE-SEN WANG. "DIFFERENT GROWTH BEHAVIOR OF Ge, Al AND Sb ON GRAPHITE." Surface Review and Letters 13, no. 02n03 (2006): 287–96. http://dx.doi.org/10.1142/s0218625x06008025.

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Growth of Ge , Al and Sb on highly oriented pyrolytic graphite (HOPG) was systematically investigated using in situ scanning tunneling microscopy (STM). At room temperature (RT), three dimensional (3D) clusters of all three elements nucleate and grow at the step edges and defect sites of HOPG. The clusters of Al and Ge form chains, while Sb islands are mostly isolated. With further deposition at RT, Al clusters grow and coarsen into faceted islands with craters on the top (111) facets, whereas ramified single- and double-layer cluster islands are observed for Ge . When deposited or annealed at

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46

Parson, Robert. "Erratum: A symmetry‐based model for selective rotational energy transfer in collisions of spherical top molecules [J. Chem. Phys. 93, 8731 (1990)]." Journal of Chemical Physics 95, no. 7 (1991): 5492. http://dx.doi.org/10.1063/1.461840.

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47

Holmes, Thomas R., and Amy S. Paller. "Gene Regulation Using Spherical Nucleic Acids to Treat Skin Disorders." Pharmaceuticals 13, no. 11 (2020): 360. http://dx.doi.org/10.3390/ph13110360.

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Spherical nucleic acids (SNAs) are nanostructures consisting of nucleic acids in a spherical configuration, often around a nanoparticle core. SNAs are advantageous as gene-regulating agents compared to conventional gene therapy owing to their low toxicity, enhanced stability, uptake by virtually any cell, and ability to penetrate the epidermal barrier. In this review we: (i) describe the production, structure and properties of SNAs; (ii) detail the mechanism of SNA uptake in keratinocytes, regulated by scavenger receptors; and (iii) report how SNAs have been topically applied and intralesional

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48

Busont, Océane, Gaëlle Durambur, Sophie Bernard, et al. "Black Poplar (Populus nigra L.) Root Extracellular Trap, Structural and Molecular Remodeling in Response to Osmotic Stress." Cells 12, no. 6 (2023): 858. http://dx.doi.org/10.3390/cells12060858.

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The root extracellular trap (RET) consists of root-associated, cap-derived cells (root AC-DCs) and their mucilaginous secretions, and forms a structure around the root tip that protects against biotic and abiotic stresses. However, there is little information concerning the changes undergone by the RET during droughts, especially for tree species. Morphological and immunocytochemical approaches were used to study the RET of black poplar (Populus nigra L.) seedlings grown in vitro under optimal conditions (on agar-gelled medium) or when polyethylene glycol-mediated (PEG6000—infused agar-gelled

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49

Nishi, Noriaki, Takahisa Jitsuno, Koji Tsubakimoto, Shinichi Matsuoka, Noriaki Miyanaga, and Masahiro Nakatsuka. "Two-Dimensional Multi-Lens Array with Circular Aperture Spherical Lens for Flat-Top Irradiation of Inertial Confinement Fusion Target." Optical Review 7, no. 3 (2000): 216–20. http://dx.doi.org/10.1007/s10043-000-0216-5.

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50

Dupont, V., and F. Sansoz. "Molecular dynamics study of crystal plasticity during nanoindentation in Ni nanowires." Journal of Materials Research 24, no. 3 (2009): 948–56. http://dx.doi.org/10.1557/jmr.2009.0103.

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Molecular dynamics simulations were performed to gain fundamental insight into crystal plasticity, and its size effects in nanowires deformed by spherical indentation. This work focused on <111>-oriented single-crystal, defect-free Ni nanowires of cylindrical shape with diameters of 12 and 30 nm. The indentation of thin films was also comparatively studied to characterize the influence of free surfaces in the emission and absorption of lattice dislocations in single-crystal Ni. All of the simulations were conducted at 300 K by using a virtual spherical indenter of 18 nm in diameter with

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