Academic literature on the topic 'Square-pyramidal geometry'

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Journal articles on the topic "Square-pyramidal geometry"

1

Dolai, Malay, Abhishake Mondal, Jun-Liang Liu, and Mahammad Ali. "Three novel mononuclear Mn(iii)-based magnetic materials with square pyramidal versus octahedral geometries." New Journal of Chemistry 41, no. 19 (2017): 10890–98. http://dx.doi.org/10.1039/c7nj02919e.

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Single crystal X-ray diffraction studies reveal that complexes 1 and 2 have square pyramidal geometry and 3 has octahedral geometry, which showed a dependence of negative anisotropy (D) values on the electronic, geometry and packing effects.
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2

Asok, Nayanthara, Joshua R. Gaffen, Ekadashi Pradhan, Tao Zeng, and Thomas Baumgartner. "Structure-reactivity studies on hypervalent square-pyramidal dithieno[3,2-b:2′,3′-d]phospholes." Dalton Transactions 50, no. 6 (2021): 2243–52. http://dx.doi.org/10.1039/d1dt00062d.

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Magrì, Antonio, Giovanni Tabbì, Raffaella Breglia, et al. "Copper ion interaction with the RNase catalytic site fragment of the angiogenin protein: an experimental and theoretical investigation." Dalton Transactions 46, no. 26 (2017): 8524–38. http://dx.doi.org/10.1039/c7dt01209h.

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Chen, Lei, Jingbo Song, Wen Zhao, et al. "A mononuclear five-coordinate Co(ii) single molecule magnet with a spin crossover between the S = 1/2 and 3/2 states." Dalton Transactions 47, no. 46 (2018): 16596–602. http://dx.doi.org/10.1039/c8dt03783c.

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5

Liu, Shou-Heng, Sheng-Wei Yang, and Shih-Che Chen. "Iron nanoparticles with a square pyramidal structure in mesoporous carbons as an effective catalyst toward oxygen reduction." RSC Advances 6, no. 112 (2016): 111366–73. http://dx.doi.org/10.1039/c6ra22549g.

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6

Sulekh, Chandra, Bansal Usha, Gupta Sunita, and Dutta Sharma Sunil. "Synthesis and EPR spectral studies on oxovanadium(IV) complexes of some oximes." Journal of Indian Chemical Society Vol. 79, Feb 2002 (2002): 129–31. https://doi.org/10.5281/zenodo.5840902.

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Department of Chemistry, Zakir Husain College, JLN Marg, New Delhi-1 10 002, India <em>E-mail: </em>amit1984@mantraonline.com <em>Manuscript received 21 August 2000, revised 16 April 2001, accepted 16 June 2001</em> Oxovanadium(IV) complexes with some oximes, viz. 2-hydroxyacetophenone (hapo), 2-hydroxypropiophenone (hppo), 2-hydroxybutyro- phenone (hbpo) and o-vanilin (ov) have been synthesized. Spectral evidence support a five-coordinate square-pyramidal geometry&nbsp;around vanadium. EPR spectra of the complexes have been recorded. The bonding coefficients have been calculated and discussed
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Chakraborty, Avijit, Saswata Rabi, Snehashis Roy, et al. "Alkali Metal Complexes of an Octamethyl Isomeric Macrocycle: Synthesis, Characterization and Antimicrobial Studies." Asian Journal of Chemistry 35, no. 7 (2023): 1697–701. http://dx.doi.org/10.14233/ajchem.2023.27923.

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Fourteen membered octamethyl tetraazamacrocyclic ligand salt, Me8[14]diene·2HClO4 and three isomeric ligands (LA, LB and LC) of its saturated analog have been synthesized as per literature. Interaction between the isomeric ligand LB and KX (X = SCN, NO3, Cl, Br and I) afforded white-coloured five coordinated square pyramidal potassium complexes [KLBX]. Moreover, the reaction between RbCl and LB produced five coordinated [RbLBCl] having square pyramidal geometry. Then, the axial substitution reaction on [RbLBCl] furnished a substituted rubidium complex with the same geometry of the mother compl
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8

Ellis, Carol A., Seik Weng Ng, Edward R. T. Tiekink та James L. Wardell. "μ-1,4-Diazabicyclo[2.2.2]octane-κ2 N:N′-bis[bis(O,O′-dicyclohexyl dithiophosphato-κ2 S,S′)cadmium(II)]". Acta Crystallographica Section E Structure Reports Online 63, № 3 (2007): m806—m807. http://dx.doi.org/10.1107/s1600536807007155.

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The dinuclear title molecule, [Cd2(C12H22O2PS2)4(C6H12N2)], is disordered and located on a centre of inversion, and features a coordination geometry intermediate between square-pyramidal and trigonal-bipyramidal.
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Kumar, Manish, Gyanendra Kumar, and Dhanraj T. Masram. "Copper(ii) complexes containing enoxacin and heterocyclic ligands: synthesis, crystal structures and their biological perspectives." New Journal of Chemistry 44, no. 20 (2020): 8595–613. http://dx.doi.org/10.1039/d0nj01192d.

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Two copper-based complexes with a distorted square pyramidal geometry show excellent binding and cleavage affinity towards DNA and proteins. Also, these complexes have potential cytotoxicity against MCF-7 cancer cells.
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10

He, Hong-Shan, and Seik Weng Ng. "Dichloro[tris(3-methyl-5-phenylpyrazol-1-yl)methane]copper(II) acetonitrile hemisolvate." Acta Crystallographica Section E Structure Reports Online 63, no. 3 (2007): m685—m686. http://dx.doi.org/10.1107/s1600536807005508.

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In the title complex, [CuCl2(C31H28N6)]·0.5C2H3N, the Cu2+ atom is coordinated in a distorted square-pyramidal geometry by three N atoms from the pyrazolyl groups of the tripodal ligand, and by two chloride anions.
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