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Journal articles on the topic 'Stabilité de la SEI'

Author: Grafiati

Published: 25 May 2024

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1

Ali, Yasir, Noman Iqbal, Imran Shah, and Seungjun Lee. "Mechanical Stability of the Heterogenous Bilayer Solid Electrolyte Interphase in the Electrodes of Lithium–Ion Batteries." Mathematics 11, no. 3 (2023): 543. http://dx.doi.org/10.3390/math11030543.

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Mechanical stability of the solid electrolyte interphase (SEI) is crucial to mitigate the capacity fade of lithium–ion batteries because the rupture of the SEI layer results in further consumption of lithium ions in newly generated SEI layers. The SEI is known as a heterogeneous bilayer and consists of an inner inorganic layer connecting the particle and an outer organic layer facing the electrolyte. The growth of the bilayer SEI over cycles alters the stress generation and failure possibility of both the organic and inorganic layers. To investigate the probability of mechanical failure of the

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2

Lucht, Brett L. "(Invited) Optimization of Carbonate Electrolytes for Lithium Metal Anodes." ECS Meeting Abstracts MA2023-02, no. 5 (2023): 830. http://dx.doi.org/10.1149/ma2023-025830mtgabs.

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A solid electrolyte interphase (SEI) is generated on the anode of lithium ion batteries during the first few charging cycles. While the SEI generated for LiPF6/carbonate based electrolytes is stable on graphite anodes, the stability of the SEI is poor for LiPF6/carbonate based electrolytes with lithium metal anodes. However, modification of the carbonate based electrolytes via incorporation of alternative salts and/or electrolyte additives significantly improves the stability of the SEI and the cycle life of lithium metal anodes. Investigations of the SEI structure have been conducted via a co

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3

Yao, Koffi, Rownak Jahan Mou, Sattajit Barua, and Daniel P. Abraham. "(Digital Presentation) Unraveling of the Morphology and Chemistry Dynamics in the FEC-Generated Silicon Anode SEI across Delithiated and Lithiated States." ECS Meeting Abstracts MA2023-02, no. 8 (2023): 3289. http://dx.doi.org/10.1149/ma2023-0283289mtgabs.

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The silicon solid electrolyte interphase (SEI) faces cyclical cracking and reconstruction due to the ~350% volume expansion of Si which leads to shortened cell life during electrochemical cycling. Understanding the SEI morphology/chemistry and more importantly its dynamic evolution from delithiated and lithiated states is paramount to engineering a stable Si anode. Fluoroethylene carbonate (FEC) is a preferred additive with widely demonstrated enhancement of the Si cycling. Thus, insights into the effects of FEC on the dynamics of the resulting SEI may provide hints toward engineering the Si i

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4

Mesmin, C., and J. ‐O Liljenzin. "Determination of H2TPTZ22+Stability Constant by TPTZ Solubility in Nitric Acid." Solvent Extraction and Ion Exchange 21, no. 6 (2003): 783–95. http://dx.doi.org/10.1081/sei-120025922.

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5

Ji, Yuchen, Luyi Yang, and Feng Pan. "In-Situ Probing the Origin of Interfacial Instability of Na Metal Anode." ECS Meeting Abstracts MA2023-02, no. 5 (2023): 832. http://dx.doi.org/10.1149/ma2023-025832mtgabs.

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The chemical-mechanical stability of solid–electrolyte interphase (SEI) is probably the most critical factor determining the performance of alkali metal anode (Li, Na, etc.) in secondary batteries. Although extensive advanced characterization methods have been carried out to study SEI layers of Na metal anode, including solid state nuclear magnetic resonance1, 2, cryogenic transmission electron microscopy3, etc., the structural/componential evolution of SEI is still an uncharted territory due to its transient formation process and complicated components. In this work, we systematically analyze

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6

Swallow, Jack E. N., Michael Fraser, Nis-Julian Kneusels, et al. "Operando X-Ray Absorption Spectroscopy of Solid Electrolyte Interphase Formation on Silicon Anodes." ECS Meeting Abstracts MA2023-02, no. 5 (2023): 825. http://dx.doi.org/10.1149/ma2023-025825mtgabs.

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Lithium-ion batteries (LIBs) are key to the transition from fossil fuels towards increased use of renewable energy sources. However, more widespread deployment requires improvements in energy density, cost and cycle-lifetime. Various cathode and anode materials are under consideration for next-generation LIBs, and the interfacial stability of these materials in contact with the electrolyte is a critical consideration. Interface-sensitive operando characterization techniques are thus urgently needed to reveal the reactions occurring in working batteries.1,2 The solid electrolyte interphase (SEI

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7

Westhead, Olivia, Matthew Spry, Zonghao Shen, et al. "Solvation and Stability in Lithium-Mediated Nitrogen Reduction." ECS Meeting Abstracts MA2022-02, no. 49 (2022): 1929. http://dx.doi.org/10.1149/ma2022-02491929mtgabs.

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The lithium-mediated method of electrochemical nitrogen reduction, pioneered by Tsuneto et al1 then verified by Andersen et al2, is currently the sole paradigm capable of unequivocal electrochemical ammonia synthesis. Such a system could allow the production of green, distributed ammonia for use as fertiliser or a carbon-free fuel. However, despite great improvements in Faradaic efficiency and stability since just 20193, fundamental understanding of the mechanisms governing nitrogen reduction and other parasitic reactions is lacking. Lithium Ion Battery (LIB) research can provide insight; sinc

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8

Alexandratos, Spiro D., and Stephanie D. Smith. "High Stability Solvent Impregnated Resins: Metal Ion Complexation as a Function of Time." Solvent Extraction and Ion Exchange 22, no. 4 (2004): 713–20. http://dx.doi.org/10.1081/sei-120038701.

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9

Wang, Menghao. "In Situ Formation of Dense Polymers as Artificial Protective Layers for Lithium Metal Anodes." Journal of Physics: Conference Series 2578, no. 1 (2023): 012034. http://dx.doi.org/10.1088/1742-6596/2578/1/012034.

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Abstract In order to improve the stability and safety of lithium (Li) metal anodes, an innovative artificial solid electrolyte interface (SEI) film of Li Poly (tert-butyl acrylate-co-ethyl acrylate-co-methacrylic acid) (LiPTBEM) has been designed. This thin and uniformly artificial SEI is stable, which can suppress the continuous side reactions between the electrolyte and Li metal, improve the stability of modified Li metal anodes, and achieve better electrochemical performance. Symmetric batteries with LiPTBEM exhibit significantly improved cycling stability, indicating that LiPTBEM is a prom

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10

Guo, Xuyun, Xiaoqiong DU, Valeria Nicolosi, Biao Zhang, and Ye Zhu. "Tailoring Breathing Behaviour of Solid Electrolyte Interphases (SEIs) Unraveled by Cryo-TEM." ECS Meeting Abstracts MA2023-02, no. 5 (2023): 882. http://dx.doi.org/10.1149/ma2023-025882mtgabs.

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The cycling stability of batteries is closely related to the dynamic evolution of solid electrolyte interphases (SEIs) in response to the discharging/charging processes. Here we utilize the state-of-the-art cryogenic transmission electron microscopy (cryo-TEM) and spectroscopy to probe the SEI breathing behaviour induced by discharging/charging on the conversion-type anode made of Fe2O3 quasi-cubes. The incorporation of the identical-location strategy allows us to track the evolution of same SEIs at different charge states, which unequivocally unravels SEI breathing featured by swelling (contr

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11

Morasch, Robert, Hubert A. Gasteiger, and Bharatkumar Suthar. "Li-Ion Battery Material Impedance Analysis II: Graphite and Solid Electrolyte Interphase Kinetics." Journal of The Electrochemical Society 171, no. 5 (2024): 050548. http://dx.doi.org/10.1149/1945-7111/ad48c0.

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Li-ion battery graphite electrodes form a solid-electrolyte-interphase (SEI) which is vital in protecting the stability and efficiency of the cell. The SEI properties have been studied extensively in the context of formation and additives, however studying its kinetic features after formation have been neglected. In this study we show the dynamic resistive behavior of the SEI after formation. Via electrochemical impedance spectroscopy measurements on Cu-foil after SEI formation we show how the SEI shows a potential-dependent resistance which can be explained by a change in charge carriers (Li+

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12

Guihua, Li, and Jin Zhen. "Global stability of an SEI epidemic model." Chaos, Solitons & Fractals 21, no. 4 (2004): 925–31. http://dx.doi.org/10.1016/j.chaos.2003.12.031.

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13

Kim, Ji-Wan, Myung-Keun Oh, Yeona Kim, et al. "Enhancing Cycle Life of Lithium Metal Batteries By Regulating Solid-Electrolyte Interphase Using Gel Polymer Electrolyte." ECS Meeting Abstracts MA2023-02, no. 4 (2023): 698. http://dx.doi.org/10.1149/ma2023-024698mtgabs.

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Lithium metal with high theoretical capacity and low redox potential is one of the promising anode materials for high energy density batteries. However, the lithium metal has safety problems and poor cycling performance, due to the growth of Li dendrite and side reactions between Li and electrolytes. One of the most effective strategies to stabilize Li metal is forming robust solid-electrolyte interphase (SEI). Recently, anion-derived and inorganic-rich SEI is known to be stable and ionic conductive, leading to good cycling stability. One of the most popular strategies to form durable SEI is t

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14

Lim, Kyungmi, Marion Hagel, Kathrin Küster, et al. "Chemical stability and functionality of Al₂O₃ artificial solid electrolyte interphases on alkali metals under open circuit voltage conditions." Applied Physics Letters 122, no. 9 (2023): 093902. http://dx.doi.org/10.1063/5.0123535.

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We studied chemical stability of atomic layer deposition-grown Al2O3 artificial solid electrolyte interphases (SEIs) on lithium and sodium upon contact with liquid electrolyte by electrochemical impedance spectroscopy (EIS) and in the case of Li also by x-ray photoelectron spectroscopy. Both methods show that the formed Al2O3 is porous for all nominal thicknesses, and that the natural SEI grows in its pores and cracks. EIS shows that the porosity of the SEI on Na is higher than the one observed on Li, in particular at higher nominal thicknesses of Al2O3. The observed values of activation energ

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15

Modolo, Giuseppe, and Stefan Seekamp. "HYDROLYSIS AND RADIATION STABILITY OF THE ALINA SOLVENT FOR ACTINIDE(III)/LANTHANIDE(III) SEPARATION DURING THE PARTITIONING OF MINOR ACTINIDES." Solvent Extraction and Ion Exchange 20, no. 2 (2002): 195–210. http://dx.doi.org/10.1081/sei-120003021.

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16

Song, Xiaosheng, Shiyu Li, Xifei Li, et al. "A lattice-matched interface between in situ/artificial SEIs inhibiting SEI decomposition for enhanced lithium storage." Journal of Materials Chemistry A 8, no. 22 (2020): 11165–76. http://dx.doi.org/10.1039/d0ta00448k.

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Lattice-matched interfaces are introduced between the in situ SEI and the artificial LiAlO<sub>2</sub> layer and demonstrated their substantial advantages in inhibiting the decomposition of the in situ SEI and boosting the cycling stability of LIBs.

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17

Xue, Yakui, Xinpeng Yuan, and Maoxing Liu. "Global stability of a multi-group SEI model." Applied Mathematics and Computation 226 (January 2014): 51–60. http://dx.doi.org/10.1016/j.amc.2013.09.050.

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18

Lahiri, Abhishek, Natalia Borisenko, Andriy Borodin, Mark Olschewski, and Frank Endres. "Characterisation of the solid electrolyte interface during lithiation/delithiation of germanium in an ionic liquid." Physical Chemistry Chemical Physics 18, no. 7 (2016): 5630–37. http://dx.doi.org/10.1039/c5cp06184a.

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The characterisation of the SEI layer revealed that LiTFSI–[Py<sub>1,4</sub>] is a relatively good ionic liquid based electrolyte for lithium batteries. However modifications in the electrolyte or a different anion might be necessary to improve the stability and composition of the SEI layer.

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19

Fan, Lishuang, Zhikun Guo, Yu Zhang, et al. "Stable artificial solid electrolyte interphase films for lithium metal anode via metal–organic frameworks cemented by polyvinyl alcohol." Journal of Materials Chemistry A 8, no. 1 (2020): 251–58. http://dx.doi.org/10.1039/c9ta10405d.

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Polyvinyl alcohol (PVA) as a “glue” to cement the metal organic framework (Zn-MOF) sheet as a reasonable artificial SEI film. The artificial SEI film can efficiently adapt to the changes of the volume during the cycle, significantly improve the stability of the Li metal anode.

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20

Beheshti, S. Hamidreza, Mehran Javanbakht, Hamid Omidvar, et al. "Effects of Structural Substituents on the Electrochemical Decomposition of Carbonyl Derivatives and Formation of the Solid–Electrolyte Interphase in Lithium-Ion Batteries." Energies 14, no. 21 (2021): 7352. http://dx.doi.org/10.3390/en14217352.

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The solid–electrolyte interphase (SEI), the passivation layer formed on anode particles during the initial cycles, affects the performance of lithium-ion batteries (LIBs) in terms of capacity, power output, and cycle life. SEI features are dependent on the electrolyte content, as this complex layer originates from electrolyte decomposition products. Despite a variety of studies devoted to understanding SEI formation, the complexity of this process has caused uncertainty in its chemistry. In order to clarify the role of the substituted functional groups of the SEI-forming compounds in their eff

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21

Schlaier, Jonas, Roman Fedorov, Shixian Huang, et al. "Electrochemical Characterization of Artificial Solid Electrolyte Interphase Developed on Graphite Via ALD." ECS Meeting Abstracts MA2023-02, no. 60 (2023): 2909. http://dx.doi.org/10.1149/ma2023-02602909mtgabs.

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During formation of Li-ion batteries, a ‘natural’ solid electrolyte interphase (SEI) is formed at the anode side by decomposition products of the electrolyte. The properties of the SEI are extremely decisive for the overall battery properties, such as rate capability and cycling stability. However, the SEI formation consumes Li, leading to so called ‘formation losses’ that can make up to 15% of the theoretical energy density of the battery. Several approaches have been presented to overcome formation losses while preserving excellent overall battery properties. Particularly, electrochemical pr

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22

Shen, B. H., S. Wang, and W. E. Tenhaeff. "Ultrathin conformal polycyclosiloxane films to improve silicon cycling stability." Science Advances 5, no. 7 (2019): eaaw4856. http://dx.doi.org/10.1126/sciadv.aaw4856.

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Electrochemical reduction of lithium ion battery electrolyte on Si anodes was mitigated by synthesizing nanoscale, conformal polymer films as artificial solid electrolyte interface (SEI) layers. Initiated chemical vapor deposition (iCVD) was used to deposit poly(1,3,5,7-tetravinyl-1,3,5,7-tetramethylcyclotetrasiloxane) (pV4D4) onto silicon thin film electrodes. pV4D4 films (25 nm) on Si electrodes improved initial coulombic efficiency by 12.9% and capacity retention over 100 cycles by 64.9% relative to untreated electrodes. pV4D4 coatings improved rate capabilities, enabling higher lithiation

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23

Yu, Yikang, Hyeongjun Koh, Zhenzhen Yang, Eric A. Stach, and Jian Xie. "Revisiting Anode Fast-Charging Capability with Solid Electrolyte Interface Using Cryogenic Transmission Electron Microscopy." ECS Meeting Abstracts MA2023-01, no. 2 (2023): 476. http://dx.doi.org/10.1149/ma2023-012476mtgabs.

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The Li+ ion diffusion through the solid electrolyte interphase (SEI) has been widely considered as one of the limiting steps for the Li fast (de)intercalation process. However, a comprehensive understanding of the kinetic limitation of SEI on anode fast-charging remains elusive. Using H-phase (monoclinic) Nb2O5 (H-Nb2O5) as the anode material, we comprehensively studied the fast charging behaviors on both “inorganic SEI free” and “inorganic-rich SEI” anodes with cryogenic transmission electron microscopy (cryo-TEM) and X-ray photoelectron spectroscopy (XPS). The results reveal that there is a

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24

Lucht, Brett L. "(Invited) Electrolyte Oxidation and the Role of Crossover Species in Capacity Loss for Lithium Ion Batteries." ECS Meeting Abstracts MA2022-01, no. 2 (2022): 195. http://dx.doi.org/10.1149/ma2022-012195mtgabs.

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Cycling lithiated metal oxides to high potential (>4.5 V vs Li) is of significant interest for the next generation of lithium ion batteries. Cathodes cycled to high potential suffer from rapid capacity fade due to a combination of thickening of the anode solid electrolyte interphase (SEI) and impedance growth on the cathode. While transition metal catalyzed degradation of the anode SEI has been widely proposed as a primary source of capacity loss, we propose a related acid induced degradation of the anode SEI. A systematic investigation of LiMn2O4, LiNi0.5Mn1.5O4, LiNi0.6Mn0.2Co0.2O2, and L

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25

Shi, Pengcheng, Xu Wang, Xiaolong Cheng, and Yu Jiang. "Progress on Designing Artificial Solid Electrolyte Interphases for Dendrite-Free Sodium Metal Anodes." Batteries 9, no. 7 (2023): 345. http://dx.doi.org/10.3390/batteries9070345.

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Nature-abundant sodium metal is regarded as ideal anode material for advanced batteries due to its high specific capacity of 1166 mAh g−1 and low redox potential of −2.71 V. However, the uncontrollable dendritic Na formation and low coulombic efficiency remain major obstacles to its application. Notably, the unstable and inhomogeneous solid electrolyte interphase (SEI) is recognized to be the root cause. As the SEI layer plays a critical role in regulating uniform Na deposition and improving cycling stability, SEI modification, especially artificial SEI modification, has been extensively inves

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26

Cheng, Xin-Bing, and Qiang Zhang. "Dendrite-free lithium metal anodes: stable solid electrolyte interphases for high-efficiency batteries." Journal of Materials Chemistry A 3, no. 14 (2015): 7207–9. http://dx.doi.org/10.1039/c5ta00689a.

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A more superior cycling stability and a higher utilization ratio of the Li metal anode have been achieved by additive- and nanostructure-stabilized SEI layers. A profound understanding of the composition, internal structure, and evolution of the SEI film sheds new light on dendrite-free high-efficiency lithium metal batteries.

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27

Lenarcik, Beniamin, and Agnieszka Kierzkowska. "The Influence of Alkyl Chain Length on Stability Constants of Zn(II) Complexes with 1‐Alkylimidazoles in Aqueous Solutions and Their Partition Between Aqueous Phase and Organic Solvent." Solvent Extraction and Ion Exchange 22, no. 3 (2004): 449–71. http://dx.doi.org/10.1081/sei-120030398.

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28

Clarke-Hannaford, Jonathan, Michael Breedon, Thomas Rüther, and Michelle J. S. Spencer. "Fluorinated Boron-Based Anions for Higher Voltage Li Metal Battery Electrolytes." Nanomaterials 11, no. 9 (2021): 2391. http://dx.doi.org/10.3390/nano11092391.

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Lithium metal batteries (LMBs) require an electrolyte with high ionic conductivity as well as high thermal and electrochemical stability that can maintain a stable solid electrolyte interphase (SEI) layer on the lithium metal anode surface. The borate anions tetrakis(trifluoromethyl)borate ([B(CF3)4]−), pentafluoroethyltrifluoroborate ([(C2F5)BF3]−), and pentafluoroethyldifluorocyanoborate ([(C2F5)BF2(CN)]−) have shown excellent physicochemical properties and electrochemical stability windows; however, the suitability of these anions as high-voltage LMB electrolytes components that can stabili

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29

Wu, Zhan-Yu, Li Deng, Jun-Tao Li, et al. "Solid Electrolyte Interphase Layer Formation on the Si-Based Electrodes with and without Binder Studied by XPS and ToF-SIMS Analysis." Batteries 8, no. 12 (2022): 271. http://dx.doi.org/10.3390/batteries8120271.

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The formation and evolution of the solid electrolyte interphase (SEI) layer as a function of electrolyte and electrolyte additives has been extensively studied on simple and model pure Si thin film or Si nanowire electrodes inversely to complex composite Si-based electrodes with binders and/or conductive carbon. It has been recently demonstrated that a binder-free Si@C-network electrode had superior electrochemical properties to the Si electrode with a xanthan gum binder (Si-XG-AB), which can be principally related to a reductive decomposition of electrolytes and formation of an SEI layer. Thu

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30

Zhao, Xvtong, Ying Chen, Hao Sun, et al. "Impact of Surface Structure on SEI for Carbon Materials in Alkali Ion Batteries: A Review." Batteries 9, no. 4 (2023): 226. http://dx.doi.org/10.3390/batteries9040226.

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Due to their low cost, suitable working potential and high stability, carbon materials have become an irreplaceable anode material for alkali ion batteries, such as lithium ion batteries, sodium ion batteries and potassium ion batteries. During the initial charge, electrolyte is reduced to form a solid electrolyte interphase (SEI) on the carbon anode surface, which is an electron insulator but a good ion conductor. Thus, a stable surface passivation is obtained, preventing the decomposition of electrolyte in the following cycles. It has been widely accepted that SEI is essential for the long-t

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31

Wang, Donghai. "(Invited) Development of Interfacial Materials for High-Performance Battery Materials." ECS Meeting Abstracts MA2023-02, no. 1 (2023): 71. http://dx.doi.org/10.1149/ma2023-02171mtgabs.

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Metal and alloy anode materials are the most promising anode for next-generation batteries. The interfacial instability in the electrochemical energy storage devices has been the primary issue hindering their practical application. In this talk, I will present approaches on de novo designing and architecting stable interphases on electrode materials using chemically and electrochemically active materials. The strategy works by introducing multiple functional components into the polymer composite which can bond to the Li-based material surface to participate in the formation of the SEI. The rei

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32

Tranter, T. J., R. D. Tillotson, and T. A. Todd. "Laboratory‐Scale Column Testing Using Crystalline Silicotitanate (IONSIV™ IE‐911) for Removing Cesium from Acidic Tank Waste Simulant. 1: Cesium Exchange Capacity of a 15‐cm3Column and Dynamic Stability of the Exchange Media*." Solvent Extraction and Ion Exchange 23, no. 4 (2005): 583–93. http://dx.doi.org/10.1081/sei-200062611.

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33

Kung, Yu-Ruei, Cheng-Yao Li, Panitat Hasin, Chia-Hung Su, and Jeng-Yu Lin. "Effects of Butadiene Sulfone as an Electrolyte Additive on the Formation of Solid Electrolyte Interphase in Lithium-Ion Batteries Based on Li4Ti5O12 Anode Materials." Polymers 15, no. 8 (2023): 1965. http://dx.doi.org/10.3390/polym15081965.

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In this study, butadiene sulfone (BS) was selected as an efficient electrolyte additive to stabilize the solid electrolyte interface (SEI) film on the lithium titanium oxide (LTO) electrodes in Li-ion batteries (LIBs). It was found that the use of BS as an additive could accelerate the growth of stable SEI film on the LTO surface, leading to the improved electrochemical stability of LTO electrodes. It can be supported by the BS additive to effectively reduce the thickness of SEI film, and it significantly enhances the electron migration in the SEI film. Consequently, the LIB-based LTO anode in

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Sarkar, Susmita, and Partha P. Mukherjee. "Electrolytes and Interfaces Driven Thermal Stability of Sodium-Ion Batteries." ECS Meeting Abstracts MA2022-02, no. 4 (2022): 501. http://dx.doi.org/10.1149/ma2022-024501mtgabs.

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Recognizing the mandates in sustainability and material abundance, sodium-ion batteries hold great potential in being alternate chemistry for applications such as grid storage systems. Along with other performance matrices, the safety problem known as “thermal runaway” must be understood and overcome for the practical realization of sodium-ion batteries in countless applications. While the physiochemical properties of the model electrode materials play a major role in determining overall thermal stability, electrolyte-derived unstable solid electrolyte interphases (SEI) can also trigger early

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King, Laura J., Xu Hou, Erik J. Berg, and Maria Hahlin. "Investigating the Reaction Mechanism of Vinylene Carbonate Additive in Lithium Ion Batteries Using X-Ray Photoelectron Spectroscopy." ECS Meeting Abstracts MA2023-02, no. 65 (2023): 3070. http://dx.doi.org/10.1149/ma2023-02653070mtgabs.

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The rechargeable Li-ion battery is an enabling technology which facilitates the electrification of the automotive industry and reduces the demand for fossil fuels. During the charge and discharge of a battery, a solid-electrolyte interphase (SEI) forms between the liquid electrolyte and the solid negative electrode as a result of electrolyte degradation. The chemical and physical stability and the functionality of the SEI is a key determining factor of battery performance. The chemical composition of the SEI is mainly controlled by the choice of solvent and salt used, but can be manipulated by

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DeCaluwe, Steven C. "(Invited, Digital Presentation) Detailed Chemical Modeling of Solid Electrolyte Interphase Growth and Evolution." ECS Meeting Abstracts MA2022-01, no. 38 (2022): 1660. http://dx.doi.org/10.1149/ma2022-01381660mtgabs.

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The solid electrolyte interphase (SEI) is a layer that forms at the anode-electrolyte interphase in lithium ion batteries. The layer forms due to voltage instability of the electrolyte at low anode potentials, but serves to passivate the electrolyte to protect against further uncontrolled decomposition. In theory, the SEI is self-limiting, but in reality, continued growth over the battery’s lifetime leads to capacity fade, poor rate capability, and eventually cell death. Though significant progress in recent years has improved the SEI’s function and stability, poor understanding of its most ba

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Abioye, A. I., O. J. Peter, F. A. Oguntolu, A. F. Adebisi, and T. F. Aminu. "GLOBAL STABILITY OF SEIR-SEI MODEL OF MALARIA TRANSMISSION." Advances in Mathematics: Scientific Journal 9, no. 8 (2020): 5305–17. http://dx.doi.org/10.37418/amsj.9.8.2.

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38

Fan, Xiulin, Xiao Ji, Fudong Han, et al. "Fluorinated solid electrolyte interphase enables highly reversible solid-state Li metal battery." Science Advances 4, no. 12 (2018): eaau9245. http://dx.doi.org/10.1126/sciadv.aau9245.

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Solid-state electrolytes (SSEs) are receiving great interest because their high mechanical strength and transference number could potentially suppress Li dendrites and their high electrochemical stability allows the use of high-voltage cathodes, which enhances the energy density and safety of batteries. However, the much lower critical current density and easier Li dendrite propagation in SSEs than in nonaqueous liquid electrolytes hindered their possible applications. Herein, we successfully suppressed Li dendrite growth in SSEs by in situ forming an LiF-rich solid electrolyte interphase (SEI

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39

Kumar, Mukesh, and Tharamani C. Nagaiah. "Tuning the Interfacial Chemistry for Stable and High Energy Density Aqueous Sodium-Ion/Sulfur Batteries." ECS Meeting Abstracts MA2023-02, no. 4 (2023): 612. http://dx.doi.org/10.1149/ma2023-024612mtgabs.

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The environmental-related issues arising from the fossil fuel assorted industrial revolution and worldwide development have prompted the quest for rechargeable batteries. In these predicaments, lithium-ion batteries (LIBs) took ownership to reshape our lives. However, the limited abundance, non-uniform geographical distribution and severe flammability of organic electrolytes, increase the uncertainty over their large-scale application. Recently, aqueous rechargeable sodium-ion batteries (ARSIBs) have gained considerable curiosity for large-scale energy storage due to their much-assured safety,

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Kang, Hyeonmuk, Taehee Kim, GyuSeong Hwang, GeunHyeong Shin, Junho Lee, and EunAe Cho. "Sustained Release of AgNO₃ Additive in Carbonate Electrolytes for Stable Lithium Metal Anodes." ECS Meeting Abstracts MA2022-01, no. 4 (2022): 526. http://dx.doi.org/10.1149/ma2022-014526mtgabs.

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With increasing energy storage demand, research on high energy density and stable battery became essential. Among different anode materials for lithium batteries, lithium metal is an ideal anode material as it has low redox potential and high specific capacity. Therefore, for post-lithium ion battery with high energy density cannot avoid using lithium metal as an anode. However, lithium metal anode has stability and safety issues due to dendritic growth. Lithium metal in contact with organic electrolyte reacts with the electrolyte to form solid electrolyte interface (SEI). SEI prevents further

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Guo, Juchen. "(Invited) Designing Interphase in Rechargeable Lithium Metal Batteries Via Liquid Electrolyte Additives." ECS Meeting Abstracts MA2022-01, no. 2 (2022): 197. http://dx.doi.org/10.1149/ma2022-012197mtgabs.

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The goal of reaching specific energy at 500 Wh kg-1 resurrects Li metal anode in recent years due to its high capacity (3860 mAh g-1) and low reductive potential (-3.04 V vs. standard hydrogen electrode). However, the reductive decomposition and chemical instability of the liquid electrolytes against Li metal result to unstable solid-electrolyte interphase (SEI) formation and porous Li deposition with low coulombic efficiency and severe volume expansion. Therefore, one strategy to enhance the cycle life of Li metal anode is to design robust SEI to improve the interfacial stability. Herein, we

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del Olmo, Diego, Maria Elzaurdi, Giorgio Baraldi, Maria Echeverria, and Elixabete Ayerbe. "Unraveling the Interplay between Degradation Mechanisms during Battery Cycling Conditions: Influence on SEI Growth." ECS Meeting Abstracts MA2023-02, no. 2 (2023): 241. http://dx.doi.org/10.1149/ma2023-022241mtgabs.

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Although the solid electrolyte interphase (SEI) is integral for the operation and stability of Li-ion batteries, its continuous growth over the battery life leads to in loss of cyclable material and overall degradation which results in capacity face. Therefore, a proper understanding of the mechanisms and factors involved in the SEI evolution during battery operation is integral for both reliable ageing models, allowing proper prognosis of the state of health (SoH), and improvement of battery lifetime. Generally, studies of SEI growth have focused on calendar ageing experiments, in which the b

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Zhao, Yunhao, Yueyue Wang, Rui Liang, Guobin Zhu, Weixing Xiong, and Honghe Zheng. "Building Polymeric Framework Layer for Stable Solid Electrolyte Interphase on Natural Graphite Anode." Molecules 27, no. 22 (2022): 7827. http://dx.doi.org/10.3390/molecules27227827.

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The overall electrochemical performance of natural graphite is intimately associated with the solid electrolyte interphase (SEI) layer developed on its surface. To suppress the interfacial electrolyte decomposition reactions and the high irreversible capacity loss relating to the SEI formation on a natural graphite (NG) surface, we propose a new design of the artificial SEI by the functional molecular cross-linking framework layer, which was synthesized by grafting acrylic acid (AA) and N,N′−methylenebisacrylamide (MBAA) via an in situ polymerization reaction. The functional polymeric framewor

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Chen, Yue-Sheng, and Yu-Sheng Su. "Lithium Silicates as an Artificial SEI for Rechargeable Lithium Metal Batteries." ECS Meeting Abstracts MA2023-02, no. 4 (2023): 680. http://dx.doi.org/10.1149/ma2023-024680mtgabs.

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The major motivation of replacing lithium-ion batteries with lithium metal batteries is to obtain higher energy density by adopting the metallic lithium anode (3860 mAh g-1, theoretically), which means they can store more energy in the same volume or weight. One of the main challenges of rechargeable lithium metal batteries is the formation of lithium dendrites during the charging process.1 Lithium dendrites are tiny needle-like structures that can grow from the surface of the lithium metal electrode and penetrate the separator, causing battery short-circuiting. This can lead to safety issues,

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Kim, Jeongmin, Taeho Yoon, and Oh B. Chae. "Behavior of NO3−-Based Electrolytes Additive in Lithium Metal Batteries." Batteries 10, no. 4 (2024): 135. http://dx.doi.org/10.3390/batteries10040135.

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While lithium metal is highly desired as a next-generation battery material due to its theoretically highest capacity and lowest electrode potential, its practical application has been impeded by stability issues such as dendrite formation and short cycle life. Ongoing research aims to enhance the stability of lithium metal batteries for commercialization. Among the studies, research on N-based electrolyte additives, which can stabilize the solid electrolyte interface (SEI) layer and provide stability to the lithium metal surface, holds great promise. The NO3− anion in the N-based electrolyte

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Ma, Yue, Feng Wu, Nan Chen, et al. "A Dual Functional Artificial SEI Layer Based on a Facile Surface Chemistry for Stable Lithium Metal Anode." Molecules 27, no. 16 (2022): 5199. http://dx.doi.org/10.3390/molecules27165199.

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Solid electrolyte interphase (SEI) on a Li anode is critical to the interface stability and cycle life of Li metal batteries. On the one hand, components of SEI with the passivation effect can effectively hinder the interfacial side reactions to promote long-term cycling stability. On the other hand, SEI species that exhibit the active site effect can reduce the Li nucleation barrier and guide Li deposition homogeneously. However, strategies that only focus on a separated effect make it difficult to realize an ideal overall performance of a Li anode. Herein, a dual functional artificial SEI la

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Wang, Xinyu, Xiaomin Li, Huiqing Fan, and Longtao Ma. "Solid Electrolyte Interface in Zn-Based Battery Systems." Nano-Micro Letters 14, no. 1 (2022). http://dx.doi.org/10.1007/s40820-022-00939-w.

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AbstractDue to its high theoretical capacity (820 mAh g−1), low standard electrode potential (− 0.76 V vs. SHE), excellent stability in aqueous solutions, low cost, environmental friendliness and intrinsically high safety, zinc (Zn)-based batteries have attracted much attention in developing new energy storage devices. In Zn battery system, the battery performance is significantly affected by the solid electrolyte interface (SEI), which is controlled by electrode and electrolyte, and attracts dendrite growth, electrochemical stability window range, metallic Zn anode corrosion and passivation,

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Jiang, Chunlei, Jiaxiao Yan, Doufeng Wang, et al. "Significant Strain Dissipation via Stiff‐Tough Solid Electrolyte Interphase Design for Highly Stable Alloying Anodes." Angewandte Chemie, October 26, 2023. http://dx.doi.org/10.1002/ange.202314509.

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The pulverization of alloying anodes significantly restricts their use in lithium‐ion batteries (LIBs). This study presents a dual‐phase solid electrolyte interphase (SEI) design that incorporates finely dispersed Al nanoparticles within the LiPON matrix. This distinctive dual‐phase structure imparts high stiffness and toughness to the integrated SEI film. In comparison to single‐phase LiPON film, the optimized Al/LiPON dual‐phase SEI film demonstrates a remarkable increase in fracture toughness by 317.8%, while maintaining stiffness, achieved through the substantial dissipation of strain ener

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Jiang, Chunlei, Jiaxiao Yan, Doufeng Wang, et al. "Significant Strain Dissipation via Stiff‐Tough Solid Electrolyte Interphase Design for Highly Stable Alloying Anodes." Angewandte Chemie International Edition, October 26, 2023. http://dx.doi.org/10.1002/anie.202314509.

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The pulverization of alloying anodes significantly restricts their use in lithium‐ion batteries (LIBs). This study presents a dual‐phase solid electrolyte interphase (SEI) design that incorporates finely dispersed Al nanoparticles within the LiPON matrix. This distinctive dual‐phase structure imparts high stiffness and toughness to the integrated SEI film. In comparison to single‐phase LiPON film, the optimized Al/LiPON dual‐phase SEI film demonstrates a remarkable increase in fracture toughness by 317.8%, while maintaining stiffness, achieved through the substantial dissipation of strain ener

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Tripathi, Rashmi, Göktug Yesilbas, Xaver Lamprecht, et al. "Understanding the Electrolyte Chemistry Induced Enhanced Stability of Si Anodes in Li-Ion Batteries based on Physico-Chemical Changes, Impedance, and Stress Evolution during SEI Formation." Journal of The Electrochemical Society, September 19, 2023. http://dx.doi.org/10.1149/1945-7111/acfb3f.

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Abstract Volume expansion/contraction of Si-based anodes during electrochemical lithiation/delithiation cycles causes loss in mechanical integrity and accrued instability of the solid electrolyte interphase (SEI) layer, culminating into capacity fade. Electrolyte additives like fluoroethylene carbonate (FEC) improve SEI stability, but the associated causes remain under debate. This work reveals some of the roles of FEC via post-mortem observations/analyses, operando stress measurements, and a comprehensive study of the impedance associated with the formation/evolution of SEI during lithiation/

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