Academic literature on the topic 'Stable and clumped isotope'

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Dissertations / Theses on the topic "Stable and clumped isotope"

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Methner, Katharina [Verfasser], Andreas [Gutachter] Mulch, and C. Page [Gutachter] Chamberlain. "Recovering Eocene paleotopography and paleoclimate of the North American Cordillera through integrated stable isotope and clumped isotope analyses / Katharina Methner ; Gutachter: Andreas Mulch, C. Page Chamberlain." Frankfurt am Main : Universitätsbibliothek Johann Christian Senckenberg, 2016. http://d-nb.info/1115250353/34.

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Li, Shanying. "Petrological and stable isotopic study of lacustrine and paleosol carbonates: Implications for paleoelevation and tectonic evolution of the Tibetan Plateau." Miami University / OhioLINK, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=miami1461562459.

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Peral, Marion. "Calibration of the clumped-isotope thermometer in foraminifera and its application to paleoclimatic reconstructions of the mid-Pleistocene in the Gulf of Taranto." Thesis, Université Paris-Saclay (ComUE), 2018. http://www.theses.fr/2018SACLS382/document.

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Quantifier les variations de température océanique du passé est nécessaire pour comprendre les mécanismes qui régissent l’évolution climatique. Les méthodes de paléo-thermométrie classiques peuvent souffrir de limitation inhérente à l’écologie des organismes et/ou à cause de l’influence d'effets physico-chimiques (salinité, acidité de l’eau de mer…). Ce travail se focalise sur la technique de paléothermométrie Δ47, qui repose sur la mesure du « clumping isotopique » dans les carbonates. Il vise d’abord à établir une calibration appliquée aux foraminifères et ensuite à mettre en œuvre cette calibration pour l’étude des variations climatiques au cours de la transition du Pléistocène moyen (MPT). Notre calibration Δ47-température des foraminifères planctoniques et benthiques, prélevés dans des sédiments modernes, couvre une gamme de température de -2 à 25°C. Les valeurs de Δ47 sur 9 espèces de foraminifères présentent une excellente corrélation avec la température de calcification des organismes, estimée à partir des mesures isotopiques de l’oxygène. Les résultats obtenus confirment l’absence d’effets liés à l’écologie des foraminifères (effets vitaux et de taille des organismes) et démontrent que la salinité n’affecte pas les mesures de Δ47. Cette étude constitue une avancée méthodologique importante pour les futures études paléocéanographiques sur les foraminifères. La MPT correspond à une transition climatique marquée par un changement de fréquence des cycles glaciaires-interglaciaires (de 41 000 à 100 000 ans). La compréhension de cette période est un enjeu scientifique majeur pour appréhender la mise en place du climat actuel. Notre calibration Δ47-température a permis de quantifier les variations de températures au cours de la MPT en mer méditerranée (Section de Montalbano Jonico, sud de l’Italie) et particulièrement des stades isotopiques marins 31 et 19, considérés comme des analogues à l’Holocène. Les résultats indiquent que (i) les températures (Δ47) obtenues sont en adéquation avec les températures obtenues par d’autres paléothermomètres, (2) les températures permettent de retracer les changements de régime océanographique et hydrologique, et (3) la mesure du Δ47 est complément prometteur pour les études multi-méthodes en paléocéanographie<br>The quantification of past oceanic temperature changes is a critical requirement for understanding the mechanisms which regulate climate variations. Classical methods of paleothermometry could suffer from well-known limitations related to ecology and/or to physico-chemical biases (sea water salinity, acidity…). This work focuses on clumped-isotope carbonate thermometry (Δ47). It aims to establish a calibration of Δ47 foraminifera and use it to study past climatic variations through the Mid-Pleistocene Transition (MPT). Our Δ47 calibration in planktonic and benthic foraminifera collected from modern marine sediment covers a temperature range of -2 to 25 °C. The clumped-isotope compositions of 9 species of foraminifera show a robust correlation with the calcification temperature, estimated from the measurements of oxygen-18. These results confirm the absence of bias linked to foraminifer ecology (species-specific and foraminifer size effects) and provide evidence that salinity does not affect the Δ47 thermometer. This study constitutes significant methodological progress for future paleoceanographic applications in foraminifera.The MPT is a climatic transition characterized by a shift in the frequencies of glacial-interglacial cycles (from 41 000 to 100 000 years). Understanding the MPT is a major scientific objective, which underlies our effort to study the establishment of our present climate. Our Δ47 calibration was used to quantify temperature changes through the MPT in the Mediterranea Sea (Montalbano Jonico section, south of Italy), and in particular the marine isotopic stages 31 and 19, which may be described as Holocene analogues. We find that (1) Δ47 temperatures are in good agreement with temperatures reconstructed from other paleothermometers, (2) these results allow reconstructing changes in past oceanographic and hydrologic regime, and (3) Δ47 measurement are a promising component of multi-proxy paleoceanographic studies
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Guo, Weifu Blake Geoffrey A. Eiler John. "Carbonate clumped isotope thermometry : application to carbonaceous chondrites and effects of kinetic isotope fractionation /." Diss., Pasadena, Calif. : California Institute of Technology, 2009. http://resolver.caltech.edu/CaltechETD:etd-12182008-115035.

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Kirk, Ruth. "Development of clumped isotope techniques and their application to palaeoclimate studies." Thesis, University of East Anglia, 2017. https://ueaeprints.uea.ac.uk/63690/.

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The aims of this research were to firstly help development of clumped isotope measurements of carbonate samples at UEA, and to then explore whether the technique could be used to retrieve robust environmental signals from geological material. This specifically looks at the Hirnantian glaciation at the boundary between the Ordovician and Silurian periods. Using the MIRA instrument, it is possible to make high precision measurements to enable the assessment of Earth surface temperatures. Long term precision of standard material is comparable to existing studies. MIRA is also absent of any non-linearity issues. Removal of contaminants and the identification of samples displaying contamination is stringent, as we find contamination has a serious effect on the Δ47 signal. Using modern biogenic carbonates and controlled temperature precipitates, the relationship between the clumped isotope signatures represented by the Δ47 value and temperature is: Δ47(ARF) = 3.5 x 10⁴/ T² + 0.2416. The relationship lies within measurement error of the theoretical estimate of temperature sensitivity. Applying this temperature calibration to fossil material collected from across the Ordovician/Silurian boundary found that the clumped isotope signal had been overprinted during diagenesis, and it has not been possible to extract an original Earth Surface temperature. However, the isotopic signal does show how the basin has developed during diagenesis under closed system conditions. As a result, the bulk δ¹⁸O and δ¹³C values have not been altered and record an original environmental signal.
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Laycock, Adam John. "Stable isotope tracing of engineered nanoparticles." Thesis, Imperial College London, 2014. http://hdl.handle.net/10044/1/43853.

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Engineered nanoparticles (NPs) are increasingly being used in consumer products due to their novel properties. Consequently, concerns have been raised over the potential hazards that these materials may present as a result of their release into the natural environment. This has prompted numerous investigations into the environmental behavior, transport and fate of engineered NPs. Importantly the predicted environmental concentrations of these materials is often x10 to x100 lower than the natural background levels of the element. Many studies overcome this problem with the use of high dosing concentrations, however this raises concerns regarding environmental relevance. The work presented in this thesis demonstrates how stable isotope tracing enables the accurate detection and quantification of engineered NPs in complex biological samples even when exposures are performed at low and environmentally relevant concentrations. This thesis focuses on three of the most prominent commercially available NPs; ZnO, CeO2 and Ag, and covers all aspects of the application of stable isotope labeling and tracing for these materials. This includes; (i) an assessment and evaluation of the technique for application with CeO2 NPs, including the development of chemical separation and mass spectrometric methods for an environmental tracer study, (ii) the assessment of a synthesis protocol for the production of isotopically labeled Ag NPs, and (iii) two environmental tracer studies to assess the uptake and loss of Zn from ZnO NPs by an estuarine snail and earthworm.
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Nelson, Michael Eric. "Nonactin biosynthesis : stable isotope precursor studies /." The Ohio State University, 2001. http://rave.ohiolink.edu/etdc/view?acc_num=osu1486399451962492.

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8

FRANZOI, ALESSANDRO. "ANIMAL ECOLOGY THROUGH STABLE ISOTOPE ANALYSIS." Doctoral thesis, Università degli studi di Pavia, 2016. http://hdl.handle.net/11571/1203350.

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Stable Isotope Ratios techniques raised in the last thirty years as a novel approach very useful for researchers and ecologists that intend to deepen into manifold aspects of animal ecology. In particular, isotopic ratios in animal tissues ultimately reflect diet, and the isotopic composition of diet reflects biogeochemical attributes of environments that may, in turn, show spatial structure and pattern, both at local and continental scale. Here, SIRs techniques were applied to birds, and, in particular, the stable isotope ratios of hydrogen, carbon, nitrogen, oxygen and sulfur were determined in bird feathers. The study was articulated in three different case studies. In the first two studies, SIRs technique was applied to migratory birds, sampled during post-breeding migration on Italian Alps. In particular, feathers were sampled on juvenile Passerines captured in some ringing stations of ‘Progetto Alpi’ long-term monitoring project. The focus was put both on commonly and less commonly observed species (more than 800 individuals of 48 species). The first study aimed to determine the geographical breeding origin of migrants using the stable isotope ratios of hydrogen and oxygen. The study allowed 1) to perform an analyses on the relationship between hydrogen and oxygen isotope ratios of several species, 2) to verify whether migratory populations have distinct geographical origins, different timing of passage and a comparison between species. To achieve the aims, a recovery data set was also used. The second study focused on the application of stable isotope ratios of carbon, nitrogen and sulfur to infer the trophic attitudes of different passerine species during the breeding season. In this study more species were analyzed, aiming to understand if isotopic variability of carbon, nitrogen and sulfur were able to distinguish trophic relationships between species which have similar diets. It was found that species are isotopically different grouping them for migratory phenology. These first two studies want to be a start point to better understand migrant trends across the Alps and Europe, and to improve knowledge in using stable isotopes in European continent. The third case study focused on lesser kestrel breeding ecology in the Gela Plain, in Sicily. In particular the stable isotope ratios of hydrogen, carbon, nitrogen, oxygen and sulfur were measured in feathers of nestlings. The aim of this study was to delineate the isotopic fingerprint of the hunting areas of their parents, making possible to distinguish different spatial uses of adults within and between colonies, and verifying if different habitat selected may be translated into distinct isotopic composition in keratinous tissues. Findings underlined the potential that a multi-isotope approach has in studying animal ecology, especially in detecting trophic partitioning and habitat selection at local and regional scale.<br>Stable Isotope Ratios techniques raised in the last thirty years as a novel approach very useful for researchers and ecologists that intend to deepen into manifold aspects of animal ecology. In particular, isotopic ratios in animal tissues ultimately reflect diet, and the isotopic composition of diet reflects biogeochemical attributes of environments that may, in turn, show spatial structure and pattern, both at local and continental scale. Here, SIRs techniques were applied to birds, and, in particular, the stable isotope ratios of hydrogen, carbon, nitrogen, oxygen and sulfur were determined in bird feathers. The study was articulated in three different case studies. In the first two studies, SIRs technique was applied to migratory birds, sampled during post-breeding migration on Italian Alps. In particular, feathers were sampled on juvenile Passerines captured in some ringing stations of ‘Progetto Alpi’ long-term monitoring project. The focus was put both on commonly and less commonly observed species (more than 800 individuals of 48 species). The first study aimed to determine the geographical breeding origin of migrants using the stable isotope ratios of hydrogen and oxygen. The study allowed 1) to perform an analyses on the relationship between hydrogen and oxygen isotope ratios of several species, 2) to verify whether migratory populations have distinct geographical origins, different timing of passage and a comparison between species. To achieve the aims, a recovery data set was also used. The second study focused on the application of stable isotope ratios of carbon, nitrogen and sulfur to infer the trophic attitudes of different passerine species during the breeding season. In this study more species were analyzed, aiming to understand if isotopic variability of carbon, nitrogen and sulfur were able to distinguish trophic relationships between species which have similar diets. It was found that species are isotopically different grouping them for migratory phenology. These first two studies want to be a start point to better understand migrant trends across the Alps and Europe, and to improve knowledge in using stable isotopes in European continent. The third case study focused on lesser kestrel breeding ecology in the Gela Plain, in Sicily. In particular the stable isotope ratios of hydrogen, carbon, nitrogen, oxygen and sulfur were measured in feathers of nestlings. The aim of this study was to delineate the isotopic fingerprint of the hunting areas of their parents, making possible to distinguish different spatial uses of adults within and between colonies, and verifying if different habitat selected may be translated into distinct isotopic composition in keratinous tissues. Findings underlined the potential that a multi-isotope approach has in studying animal ecology, especially in detecting trophic partitioning and habitat selection at local and regional scale.
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9

Howland, Mark Roger. "Compound-specific stable isotope investigations of the influence of diet on the stable isotope composition of body tissues." Thesis, University of Bristol, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.274604.

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10

Kaiser, Jan. "Stable isotope investigations of atmospheric nitrous oxide." [S.l. : s.n.], 2002. http://ArchiMeD.uni-mainz.de/pub/2003/0004/diss.pdf.

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