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Relevant bibliographies by topics / Steric effects

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Academic literature on the topic 'Steric effects'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 July 2025

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Journal articles on the topic "Steric effects"

1

Adams, Kerry J., Jill Cowie, Steven G. D. Henderson, Gillian J. McCormick, and Alan J. Welch. "Steric effects in heteroboranes." Journal of Organometallic Chemistry 481, no. 2 (1994): C9—C11. http://dx.doi.org/10.1016/0022-328x(94)85038-0.

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Tenner, M. G., E. W. Kuipers, A. W. Kleyn, and S. Stolte. "Steric effects in molecular adsorption." Journal of Chemical Physics 89, no. 10 (1988): 6552–53. http://dx.doi.org/10.1063/1.455376.

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Tobisu, M., and N. Chatani. "Remote Control by Steric Effects." Science 343, no. 6173 (2014): 850–51. http://dx.doi.org/10.1126/science.1250335.

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Mainos, Constantin. "Steric effects in multiphoton excitation." Physical Review A 50, no. 4 (1994): 3216–33. http://dx.doi.org/10.1103/physreva.50.3216.

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Traylor, Teddy G., Douglas J. Taube, Karen A. Jongeward, and Douglas Magde. "Steric effects on geminate recombinations." Journal of the American Chemical Society 112, no. 19 (1990): 6875–80. http://dx.doi.org/10.1021/ja00175a022.

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Ziemkowska, Wanda, Sylwia Kwaśniewska, Rafał Wróblewski, and Romana Anulewicz-Ostrowska. "Steric effects in alkylalane dioldiates." Journal of Organometallic Chemistry 651, no. 1-2 (2002): 72–79. http://dx.doi.org/10.1016/s0022-328x(02)01256-1.

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Novak, Igor. "Substituent effects on steric strain." Chemical Physics Letters 380, no. 3-4 (2003): 258–62. http://dx.doi.org/10.1016/j.cplett.2003.08.109.

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Muszalska, Elżbieta, Waldemar Górski, and Zbigniew Galus. "Steric effects in electrode processes." Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 294, no. 1-2 (1990): 87–95. http://dx.doi.org/10.1016/0022-0728(90)87137-9.

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Ishiguro, Shin-ichi, Yasuhiro Umebayashi, Kenta Fujii, and Ryo Kanzaki. "Solvent conformation and ion solvation: From molecular to ionic liquids." Pure and Applied Chemistry 78, no. 8 (2006): 1595–609. http://dx.doi.org/10.1351/pac200678081595.

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Metal ions are solvated in solution, and, in a sterically congested organic solvent, those solvent molecules that are simultaneously bound to the metal ion will be subject to consequential steric interactions through space. The molecular structure of a solvent, particularly that of any functional groups in the vicinity of the coordinating atom to the metal ion, plays a key role in the solvation steric effect. Weak solvation steric effects lead to a distorted octahedral structure for six-coordinate transition-metal(II) ions, whereas strong steric effects lead to a decreased solvation number. In

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Wepster, B. M., and P. E. Verkade. "Steric effects on mesomerism. IV. Steric effects on mesomerism in derivatives of ortho-nitro-acetanilide." Recueil des Travaux Chimiques des Pays-Bas 68, no. 1 (2010): 88–110. http://dx.doi.org/10.1002/recl.19490680110.

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Dissertations / Theses on the topic "Steric effects"

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Liu, Sung Ying. "Steric effects in Lanthanide pyrazolylborate chemistry." Thesis, University College London (University of London), 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.561271.

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Laitinen, R. (Riitta). "New heterodonor phosphine and bipyridine ligands." Doctoral thesis, University of Oulu, 1999. http://urn.fi/urn:isbn:9514252292.

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Abstract Twenty-seven phosphine and six bipyridine ligands were synthesised and characterized. Additionally, a new route to the family of phosphine ligands via o-thioanisyldichlorophosphine was found. The phosphine ligands contain thiomethylphenyl, methoxyphenyl, dimethylaminophenyl, pyridyl, naphthyl and anthracenyl groups, and the bipyridine ligands thiomorpholine and piperidine groups. Metal complexes of 3-pyridyldiphenylphosphine, 6,6'-bis(methylthiomorpholine)-2,2'-bipyridine and 4,4'-dimethyl-6,6'-bis(methylthiomorpholine)-2,2'-bipyridine were prepared. Ligands and complexes were charac

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McLachlan, Lorna J. "Steric and electronic effects on the structures of substituted silicon compounds." Thesis, University of Edinburgh, 2004. http://hdl.handle.net/1842/15345.

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This thesis is concerned with the application of the SARACEN method to a range of molecules with interesting structural properties and applications in industry. The gas-phase structures of a series of compounds have been obtained, combining gas-phase electron diffraction and <i>ab initio </i>molecular orbital theory. For each compound a series of the potential energy surface was carried out to investigate the number of conformational minima and to locate the global energy minimum. The gas-phase structures of <i>trans-</i>1,2-dichloro-1,2-disilylethene (1), 1,1-bromosilylethene (2) and 1,1,1,4,

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Smith, Adam C. R. "The Effects of Carrier Ligands on Cisplatin Binding to Cysteine and Methionine." TopSCHOLAR®, 2017. http://digitalcommons.wku.edu/theses/1969.

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We have reacted several derivatives of the anticancer drug cisplatin with N-acetyl-Lcysteine (N-AcCys) and N-acetyl-L-methionine (N-AcMet), which are two of the primary amino acid targets of platinum. NMR spectroscopy was used to monitor the reactions and determine the effect the different ligands would have on the platinum reactivity. Several of the platinum compounds were tested at pH of 4 and 7, and with platinum:amino acid ratios of 1:1, 2:1 and 1:2. Competition reactions between cysteine and methionine were done to confirm which would react with the platinum compound first. [Pt(dien)(NO3)

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Bachir, Alexia. "Characterization of quantum dot blinking and steric effects on fluorescence-based biophysical techniques." Thesis, McGill University, 2008. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=19293.

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Semiconductor nanoparticles, or quantum dots (QDs) are being increasingly applied as luminescent labels in optical studies for biophysical and cell biological applications due to their unique spectroscopic properties as compared to traditional organic fluorescent probes. However, the intermittency in the fluorescence emission of QDs, commonly referred to as 'blinking', is suggested to affect transport studies using fluctuation correlation techniques. The QD size has also been suggested to be sterically limiting for some st

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Yang, Shaoguang. "Design and Investigation of Polyurethane End-Capped Polyesters with Controlled Hydrolytic Stability." University of Akron / OhioLINK, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=akron1407971721.

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Ramirez-Huerta, Mayela Cristina. "Steric and Anchimeric Effects on the Hydrolysis of Oligoesters and their Influence on End-Use Polyurethane Coatings." University of Akron / OhioLINK, 2009. http://rave.ohiolink.edu/etdc/view?acc_num=akron1258662846.

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Desai, Salil Dileep. "Ortho substitution effects on the acidic and alkaline hydrolyses of formanilides." Diss., University of Iowa, 2009. https://ir.uiowa.edu/etd/353.

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The objectives of this project were to determine the reaction schemes of formanilide and substituted formanilides in acidic and alkaline solutions, to quantiate the kinetics of hydrolysis, to propose reaction mechanisms, and to assess the role of ortho words substitution in formanilide hydrolysis kinetics. A set of thirty substituted formanilides were synthesized and characterized. Hydrolysis of the formanilides was carried out under first order conditions in hydrochloric acid (0.01-8 M, 40°C) and in hydroxide solutions (0.01-3 M, 25°C and 40°C). Hydrolysis kinetics were evaluated in terms of

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Kahan, Rachel Jennifer. "Investigating the steric and electronic effects of low-valent uranium complexes on the activation of small molecules." Thesis, University of Sussex, 2015. http://sro.sussex.ac.uk/id/eprint/54170/.

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In the last decade substantial progress has been made in our understanding of uranium organometallic chemistry, specifically regarding the activation of small molecules by uranium(III) complexes. Research by Cloke and colleagues has employed dianionic eight- and monoanionic five-membered aromatic ligands around a uranium(III) centre to make mixed-sandwich systems, which have demonstrated novel reactivity with carbon monoxide and carbon dioxide. This thesis continues this work and furthers our understanding of the properties and reactivity of these complexes. The first part of this thesis descr

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Djomgoue, Paul. "N3, N4/(N3S, N3O) and N6 Phenanthroline Bases and their Spin Crossover Iron(II) Complexes." Doctoral thesis, Universitätsbibliothek Chemnitz, 2016. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-207498.

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The present dissertation focuses on the synthesis of iron(II) complexes and the study of their SCO behavior. The equilibrium between the HS and the LS states gives to the SCO systems large potential applications for molecular electronics. However, today there is not a single molecular device from SCO compounds in the market. This is due to the fact that the SCO systems discovered up to now were unable (e.g. TLIESST « 300 K) for these applications. The aim of this thesis is to synthesize new SCO compounds with sustainable properties for applications. In the beginning of the thesis, [Fe(rac-22a)

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Books on the topic "Steric effects"

1

Yadav, Veejendra K. Steric and Stereoelectronic Effects in Organic Chemistry. Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-75622-2.

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Yadav, Veejendra K. Steric and Stereoelectronic Effects in Organic Chemistry. Springer Singapore, 2016. http://dx.doi.org/10.1007/978-981-10-1139-9.

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D, Peyerimhoff Sigrid, Deutsche Forschungsgemeinschaft, and Collaborative Research Centre 334 "Wechselwirkung in Molekülen: Synthese, spektroskopische Analyse und quatentheoretische Behandlung charakteristischer Strukturen.", eds. Interactions in molecules: Electronic and steric effects. Wiley-VCH, 2003.

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Allinger, Norman L. Molecular structure: Understanding steric and electronic effects from molecular mechanics. Wiley, 2010.

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Yoder, Bruce L. Steric Effects in the Chemisorption of Vibrationally Excited Methane on Nickel. Springer Berlin Heidelberg, 2012. http://dx.doi.org/10.1007/978-3-642-27679-8.

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Barucki, Hubert. New fluorinated reagents for functional group transfer: The enlistment of steric and electronic effects of bulky perfluoroalkyl groups in synthesis. University of Birmingham, 1998.

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Wehman-Ooyevaar, Ingrid C. M. Organometallic complexes of rhodium, iridium and platinum: Steric and electronic effects of chelating nitrogen ligands ... : proefschrift ter verkrijging van de graad van doctor ... 1992. [Rijksuniversiteit te Utrecht?], 1992.

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8

E, Micevych Paul, and Hammer Ronald P, eds. Neurobiological effects of sex steroid hormones. Cambridge University Press, 1995.

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Martin, Wehling, ed. Genomic and non-genomic effects of aldosterone. CRC Press, 1995.

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Robert, Morfin, ed. DHEA and the brain. Taylor & Francis, 2002.

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Book chapters on the topic "Steric effects"

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Gallo, Roger. "Treatment of Steric Effects." In Progress in Physical Organic Chemistry. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470171936.ch3.

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Carey, Francis A., and Richard J. Sundberg. "Conformational, Steric, and Stereoelectronic Effects." In Advanced Organic Chemistry. Springer US, 1990. http://dx.doi.org/10.1007/978-1-4613-9795-3_3.

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Unger, S. H., and Corwin Hansch. "Quantitative Models of Steric Effects." In Progress in Physical Organic Chemistry. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470171912.ch4.

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Grote, W., M. Hoffmeister, R. Schleysing, H. Zerhau-Dreihöfer, and H. J. Loesch. "Rotational and Steric Effects in Three Centre Reactions." In Selectivity in Chemical Reactions. Springer Netherlands, 1988. http://dx.doi.org/10.1007/978-94-009-3047-6_3.

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Caldin, E. F., and A. Queen. "Diffusion and Steric Effects in Very Fast Reactions." In Reactions in Compartmentalized Liquids. Springer Berlin Heidelberg, 1989. http://dx.doi.org/10.1007/978-3-642-74787-8_23.

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Buckingham, D. A., and A. M. Sargeson. "Conformational Analysis and Steric Effects in Metal Chelates." In Topics in Stereochemistry. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470147153.ch5.

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Yadav, Veejendra K. "Steric and Stereoelectronic Control of Organic Molecular Structures and Organic Reactions." In Steric and Stereoelectronic Effects in Organic Chemistry. Springer Singapore, 2016. http://dx.doi.org/10.1007/978-981-10-1139-9_1.

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Yadav, Veejendra K. "Reactions at Saturated and Unsaturated Carbons." In Steric and Stereoelectronic Effects in Organic Chemistry. Springer Singapore, 2016. http://dx.doi.org/10.1007/978-981-10-1139-9_2.

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Yadav, Veejendra K. "Diastereoselectivity in Organic Reactions." In Steric and Stereoelectronic Effects in Organic Chemistry. Springer Singapore, 2016. http://dx.doi.org/10.1007/978-981-10-1139-9_3.

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Yadav, Veejendra K. "A(1,2) and A(1,3) Strains." In Steric and Stereoelectronic Effects in Organic Chemistry. Springer Singapore, 2016. http://dx.doi.org/10.1007/978-981-10-1139-9_4.

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Conference papers on the topic "Steric effects"

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Hirano, Susumu, and Tatsuya Sei. "Influence of Hydrocarbon on Stearic Acid as Corrosion Inhibitor in Synthetic Brine." In CONFERENCE 2023. AMPP, 2023. https://doi.org/10.5006/c2023-19330.

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Abstract The role of corrosion inhibitor is explained by the function of surfactant, i.e., partition from oil to water, dispersion in water and adsorption on metal surface. This study selected stearic acid as a surfactant and paid attention to the effect of oil on corrosion inhibition. Stearic acid was treated as a single component corrosion inhibitor. The corrosion inhibitor efficiency of stearic acid was observed in a metal-oil-water system. An acyclic saturated hydrocarbon, i.e., an alkane was tested as oil because it has a simple chemical structure. Stearic acid was dissolved in alkanes an

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Zanotti, Alex, Martino Ermacora, Gabriele Campanardi, and Giuseppe Gibertini. "Experimental Investigation of Perpendicular Vortex Interaction by Stereo Particle Image Velocimetry." In Vertical Flight Society 71st Annual Forum & Technology Display. The Vertical Flight Society, 2015. http://dx.doi.org/10.4050/f-0071-2015-10103.

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The aerodynamic effect of a stream-wise vortex impacting on an oscillating airfoil was experimentally studied in the present work by means of a stereo particle image velocimetry. The experimental rig had enabled the study of the aerodynamic effects induced by the vortex during the blade pitching motion. In particular, the resultant effect of the impacting vortex and airfoil oscillation was highlighted comparing a light dynamic stall regime with equivalent steady conditions. A stereoscopic particle image velocimetry technique was applied to a measurement volume close to the airfoil upper surfac

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Alikhanifaradonbeh, Razieh, Reza Jafari, Jarkko Lehti, Anssi Metsähonkala,, and Heli Koivuluoto. "Nonfluorinated Superhydrophobic TiO2-Based Coatings by Suspension Flame Spraying." In ITSC 2025. ASM International, 2025. https://doi.org/10.31399/asm.cp.itsc2025p0165.

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Abstract This study focuses on the development of three TiO2-based coatings using suspension flame spray process. Superhydrophobic properties were achieved by creating surface roughness and reducing energy with stearic acid. The effects of polydimethylsiloxane and epoxy on these properties and durability were tested under UV light and low temperatures.

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Martin, Sue, Joanne Horn, and Celena Carrillo. "Micron-Scale MIC of Alloy 22 after Long Term Incubation in Saturated Nuclear Waste Repository Microcosms." In CORROSION 2004. NACE International, 2004. https://doi.org/10.5006/c2004-04596.

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Abstract The effects of potential microbiologically influenced corrosion (MIC) on candidate packaging materials for nuclear waste containment are being assessed. Coupons of Alloy 22, the outer barrier candidate for waste packaging, were exposed to a simulated, saturated repository environment consisting of crushed rock from the repository site and a continual flow of simulated ground water for periods up to five years. Coupons were incubated with YM tuff under both sterile and non-sterile conditions. Surfacial analysis of the biotically-incubated coupons shows development of both submicron-siz

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Ocando, Lisseth, Matilde F. de Romero, Oladis T. de Rincón, et al. "Comparative Study of the Effect of Sulfate-Reducing Bacteria on Cathodic Protection under Simulated Blisters." In CONFERENCE 2023. AMPP, 2023. https://doi.org/10.5006/c2023-19465.

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Abstract This work presents a comparison of the effect generated by a mixed culture of sulfate-reducing bacteria (SRB) isolated from a natural estuary in western Venezuela, on the cathodic protection (CP) of carbon steel under simulated blisters. The laboratory study was carried out simultaneously measuring attack morphology, polarized potential, pH, and sessile growth, inside a simulated blister in a special cell arrangement, using two types of coatings: one 100% solids epoxy, and the other one, a tape type, which consists of the combination of a geo mesh-polypropylene textile and tarred rubb

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Ocando, Lisseth, Oladis Troconis de Rincón, Matilde F. de Romero, and Antonio De Turris. "Comparative Study of the Effect of Sulfate-Reducing Bacteria on Cathodic Protection under Simulated Blisters." In CONFERENCE 2024. AMPP, 2024. https://doi.org/10.5006/c2024-21195.

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Abstract This work presents a comparison of the effect generated by a mixed culture of sulfate-reducing bacteria (SRB) isolated from a natural estuary in western Venezuela, on the cathodic protection (CP) of carbon steel under simulated blisters. The laboratory study was carried out simultaneously measuring attack morphology, polarized potential, pH, and sessile growth, inside a simulated blister in a special cell arrangement, using two types of coatings: one 100% solids epoxy, and the other one, a tape type, which consists of the combination of a geo mesh-polypropylene textile and tarred rubb

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Jeffrey, Robert J., and Robert E. Melchers. "The Effect of Microbiological Involvement on the Topography of Corroding Mild Steel in Coastal Seawater." In CORROSION 2010. NACE International, 2010. https://doi.org/10.5006/c2010-10224.

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Abstract Microbiological factors have been implicated in the accelerated corrosion of mild steel in seawater for many years. To date few successful medium-term trials have been carried out to quantify the effect of micro-organisms on the surface of steel exposed to seawater. Presented herein are the results of a two and a half year investigation in which natural seawater was taken from a tributary of Port Stephens, Australia, and split into two streams; natural (raw) seawater and sterile seawater. The waters were pumped directly into tanks in which 25 mm x 25 mm polished steel coupons were sus

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Arie, Ady. "The All-Optical Stern-Gerlach Effect in Space and in Time." In CLEO: Science and Innovations. Optica Publishing Group, 2024. http://dx.doi.org/10.1364/cleo_si.2024.sth3p.5.

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Lightwaves can be split into two beams or two pulses, each comprising a frequency-bin superposition, in the presence of a nonlinear coupling gradient, representing the nonlinear optics analog of the celebrated Stern-Gerlach effect for atoms.

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Willis, Eric R., and Daniel W. Walsh. "The Effect of Inclusion Composition and Morphology on Microbiologically Influenced Corrosion in Low Alloy Steels." In CORROSION 1995. NACE International, 1995. https://doi.org/10.5006/c1995-95220.

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Abstract Micro structure is a key, yet often overlooked variable in micro-biologically influenced corrosion (MIC). A designed experiment was carried out to examine the effects of minor element content (Si, S, and Ce) on the susceptibility of low alloy steels to MIC in anaerobic aqueous systems. A two level, three factor full factorial experiment, using AISI 8630 as the master composition, was used to relate inclusion size, shape, chemical stability and spatial distribution to MIC susceptibility. Significant correlation between MIC susceptibility, measured as pit nucleation frequency and maximu

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Guo, Renzhi, and Jonas Braasch. "Influence of Recording Technique and Ensemble Size on Apparent Source Width." In ICAD 2024: The 29th International Conference on Auditory Display. International Community for Auditory Display, 2024. http://dx.doi.org/10.21785/icad2024.009.

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Previous studies have looked at how different concert halls with different lateral reflections affect apparent source width. Yet, the perceptual effects of different source distributions with different recording techniques on apparent source width are not well understood. This study explores how listeners perceive the width of an orchestra by using four stereo and one binaural recording techniques and three wave field synthesis ensemble settings. Subjective experiments were conducted using stereo loudspeakers and headphone to play back the recording clips asking the listeners to rate the perce

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Reports on the topic "Steric effects"

1

Jacobs, Dennis C. Energetic and Steric Effects in Ion/Surface Reactive Scattering. Defense Technical Information Center, 1998. http://dx.doi.org/10.21236/ada341374.

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Sofield, Chadwick Dean. Steric and electronic effects of 1,3-disubstituted cyclopentadienyl ligands on metallocene derivatives of Cerium, Titanium, Manganese, and Iron. Office of Scientific and Technical Information (OSTI), 2000. http://dx.doi.org/10.2172/764394.

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Hsueh, S. Y. Repetitive Stern-Gerlach effect. Office of Scientific and Technical Information (OSTI), 1990. http://dx.doi.org/10.2172/6988634.

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Cusanelli, Dominic S. Scaling Effects on Stern Flap Performance. Progress Report. Defense Technical Information Center, 2009. http://dx.doi.org/10.21236/ada507858.

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Conte, M., R. Parodi, and W. W. MacKay. An overview on the longitudinal Stern-Gerlach effect. Office of Scientific and Technical Information (OSTI), 1997. http://dx.doi.org/10.2172/573337.

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Perrels, Adriaan, and Kaisa Juhanko. Socio-economic Benefits of the EPS Sterna constellation at high latitudes. Finnish Meteorological Institute, 2023. http://dx.doi.org/10.35614/isbn.9789523361836.

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This report presents a combined meteorological and economic study commissioned by EUMETSAT as part of the planning trajectory for the EPS-Sterna polar-orbiting satellite constellation. The focus of the study is on the foreseeable effects of EPS Sterna on meteorological forecasts and the resulting socioeconomic benefits, particularly regarding application at high latitudes, with emphasis on the Nordic countries. The study has an explorative character, hence the quantified estimates of benefits only indicate orders of magnitude for selected sectors. A more comprehensive assessment of expected be

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Fields, Michael, Mordechai Shemesh, Philip A. Fields, Anna-Riitta Fuchs, and Michael Diskin. Bovine Relaxin: A Placental Source and Effects on Prostaglandin and Steroid Metabolism. United States Department of Agriculture, 1988. http://dx.doi.org/10.32747/1988.7568097.bard.

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Fields, Michael, Mordechai Shemesh, and Phillip A. Fields. Bovine Relaxin: A Placental Source and Effects on Prostaglandin and Steroid Metabolism. United States Department of Agriculture, 1991. http://dx.doi.org/10.32747/1991.7594379.bard.

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Leblanc, Gerald A. Steroid Hydroxylase Activities as Noninvasive Biomarkers of Toxicant Exposure and Effect. Defense Technical Information Center, 1997. http://dx.doi.org/10.21236/ada334730.

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Cuesta, José A., and Fidel Jaramillo. Taxonomy of Causes, Impacts and Policy Responses to the Food Price Crisis in the Andean Region. Inter-American Development Bank, 2009. http://dx.doi.org/10.18235/0010910.

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This paper analyzes the causes, effects and policy alternatives associated with the recent international food price crisis in the Andean region. Additionally, the document makes a first approach to the policy options utilized to confront the crisis, discussing the mix of policies and their potential effectiveness, using a qualitative methodology based in part on schemes proposed in Manzano and Stein (2008), and Malarín (2008). A final section underscores various messages common to the countries of the region. Specifically, the report concludes that this crisis offers a great opportunity for tr

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