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Journal articles on the topic 'Steric effects'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 July 2025

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1

Adams, Kerry J., Jill Cowie, Steven G. D. Henderson, Gillian J. McCormick, and Alan J. Welch. "Steric effects in heteroboranes." Journal of Organometallic Chemistry 481, no. 2 (1994): C9—C11. http://dx.doi.org/10.1016/0022-328x(94)85038-0.

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2

Tenner, M. G., E. W. Kuipers, A. W. Kleyn, and S. Stolte. "Steric effects in molecular adsorption." Journal of Chemical Physics 89, no. 10 (1988): 6552–53. http://dx.doi.org/10.1063/1.455376.

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3

Tobisu, M., and N. Chatani. "Remote Control by Steric Effects." Science 343, no. 6173 (2014): 850–51. http://dx.doi.org/10.1126/science.1250335.

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4

Mainos, Constantin. "Steric effects in multiphoton excitation." Physical Review A 50, no. 4 (1994): 3216–33. http://dx.doi.org/10.1103/physreva.50.3216.

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5

Traylor, Teddy G., Douglas J. Taube, Karen A. Jongeward, and Douglas Magde. "Steric effects on geminate recombinations." Journal of the American Chemical Society 112, no. 19 (1990): 6875–80. http://dx.doi.org/10.1021/ja00175a022.

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6

Ziemkowska, Wanda, Sylwia Kwaśniewska, Rafał Wróblewski, and Romana Anulewicz-Ostrowska. "Steric effects in alkylalane dioldiates." Journal of Organometallic Chemistry 651, no. 1-2 (2002): 72–79. http://dx.doi.org/10.1016/s0022-328x(02)01256-1.

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7

Novak, Igor. "Substituent effects on steric strain." Chemical Physics Letters 380, no. 3-4 (2003): 258–62. http://dx.doi.org/10.1016/j.cplett.2003.08.109.

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8

Muszalska, Elżbieta, Waldemar Górski, and Zbigniew Galus. "Steric effects in electrode processes." Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 294, no. 1-2 (1990): 87–95. http://dx.doi.org/10.1016/0022-0728(90)87137-9.

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9

Ishiguro, Shin-ichi, Yasuhiro Umebayashi, Kenta Fujii, and Ryo Kanzaki. "Solvent conformation and ion solvation: From molecular to ionic liquids." Pure and Applied Chemistry 78, no. 8 (2006): 1595–609. http://dx.doi.org/10.1351/pac200678081595.

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Metal ions are solvated in solution, and, in a sterically congested organic solvent, those solvent molecules that are simultaneously bound to the metal ion will be subject to consequential steric interactions through space. The molecular structure of a solvent, particularly that of any functional groups in the vicinity of the coordinating atom to the metal ion, plays a key role in the solvation steric effect. Weak solvation steric effects lead to a distorted octahedral structure for six-coordinate transition-metal(II) ions, whereas strong steric effects lead to a decreased solvation number. In

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10

Wepster, B. M., and P. E. Verkade. "Steric effects on mesomerism. IV. Steric effects on mesomerism in derivatives of ortho-nitro-acetanilide." Recueil des Travaux Chimiques des Pays-Bas 68, no. 1 (2010): 88–110. http://dx.doi.org/10.1002/recl.19490680110.

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11

Wepster, B. M., and P. E. Verkade. "Steric effects on mesomerism. V.) steric effects on mesomerism in derivatives of para-nitro-acetanilide." Recueil des Travaux Chimiques des Pays-Bas 69, no. 11 (2010): 1393–406. http://dx.doi.org/10.1002/recl.19500691109.

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12

A., Abdul Jameel, and Krishna Pillay M. "Nature of ortho effect in the oxidation of ortho-substituted-benzaldehydes with pyridinium chlorochromate." Journal of Indian Chemical Society Vol. 76, Feb 1999 (1999): 101–3. https://doi.org/10.5281/zenodo.5852439.

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Department of Chemistry, Jamal Mohamed College, Tiruchirappalli-620 020, India Department of Chemistry, Bharathidasan University, Tiruchirappalli-620 024, India <em>Manuscript received 10 February 1998, revised 25 August 1998, accepted 9 September 1998</em> Rate constants for the oxidation reaction of ortlzo-substituted benzaldehydes with pyridinium chlorochromate are correlated with equations log <em>k</em><sub>2</sub>= ασ<sub>1</sub> + β σ<sub>k</sub> + <sup>\(\Psi\)</sup>  v +<em> h</em> log <em>k</em><sub>2</sub>= ασ<sub>1</sub> + β &s

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13

Regan, C. K. "Steric Effects and Solvent Effects in Ionic Reactions." Science 295, no. 5563 (2002): 2245–47. http://dx.doi.org/10.1126/science.1068849.

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14

Kim, Yongho, Christopher J. Cramer, and Donald G. Truhlar. "Steric Effects and Solvent Effects on SN2 Reactions." Journal of Physical Chemistry A 113, no. 32 (2009): 9109–14. http://dx.doi.org/10.1021/jp905429p.

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15

Ostrawsky, C., K. Blum, and G. Gillan. "Steric effects in electron-molecule scattering." Journal of Physics B: Atomic, Molecular and Optical Physics 28, no. 11 (1995): 2269–83. http://dx.doi.org/10.1088/0953-4075/28/11/023.

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16

Menger, F. M., and Kingsley H. Nelson. "The question of remote steric effects." Tetrahedron Letters 35, no. 9 (1994): 1347–48. http://dx.doi.org/10.1016/s0040-4039(00)76214-9.

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17

Crossley, Maxwell J., Leslie D. Field, Adrienne J. Forster, Margaret M. Harding, and Sever Sternhell. "Steric effects on atropisomerism in tetraarylporphyrins." Journal of the American Chemical Society 109, no. 2 (1987): 341–48. http://dx.doi.org/10.1021/ja00236a008.

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18

HENRY, CELIA. "Steric Effects Don't Explain Ethane Conformation." Chemical & Engineering News 79, no. 23 (2001): 10. http://dx.doi.org/10.1021/cen-v079n023.p010a.

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19

Lockhart, Thomas P. "Steric effects in neophyltin(IV) chemistry." Journal of Organometallic Chemistry 287, no. 2 (1985): 179–86. http://dx.doi.org/10.1016/0022-328x(85)87253-3.

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20

Cowie, Jill, Bruce D. Reid, Jude M. S. Watmough, and Alan J. Welch. "Steric effects in heteroboranes. Part 7." Journal of Organometallic Chemistry 481, no. 2 (1994): 283–93. http://dx.doi.org/10.1016/0022-328x(94)85037-2.

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21

Welch, Alan J. "ChemInform Abstract: Steric Effects in Metallacarboranes." ChemInform 31, no. 25 (2010): no. http://dx.doi.org/10.1002/chin.200025314.

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22

Baños, Ruben, José Arcos, Oscar Bautista, and Federico Méndez. "Steric and Slippage Effects on Mass Transport by Using an Oscillatory Electroosmotic Flow of Power-Law Fluids." Micromachines 12, no. 5 (2021): 539. http://dx.doi.org/10.3390/mi12050539.

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In this paper, the combined effect of the fluid rheology, finite-sized ions, and slippage toward augmenting a non-reacting solute’s mass transport due to an oscillatory electroosmotic flow (OEOF) is determined. Bikerman’s model is used to include the finite-sized ions (steric effects) in the original Poisson-Boltzmann (PB) equation. The volume fraction of ions quantifies the steric effects in the modified Poisson-Boltzmann (MPB) equation to predict the electrical potential and the ion concentration close to the charged microchannel walls. The hydrodynamics is affected by slippage, in which the

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23

Císařová, Ivana, Jaroslav Podlaha, Stanislav Böhm, and Otto Exner. "Steric Effects and Steric Inhibition of Resonance in Benzene Derivatives: 2,3-Dimethylbenzoic Acid." Collection of Czechoslovak Chemical Communications 65, no. 2 (2000): 216–26. http://dx.doi.org/10.1135/cccc20000216.

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Structure of 2,3-dimethylbenzoic acid was determined both by single-crystal X-ray diffraction and by ab initio calculation at an RHF/6-31+G** level. Comparing with a previous X-ray analysis of another crystal modification of the same compound, it was possible to estimate the effect of crystal forces on the conformation. The isolated molecule is not planar as deduced previously, mainly from IR spectra, but the carboxyl group is twisted out of the ring plane by a torsion angle ϕ = 12°. In the crystal, the molecule is more flat and ϕ is reduced to 7 and 1° in the two modifications, respectively.

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24

Howard, T. J. "Competition between steric and non-steric directive effects in catalytic hydrogenation: Preliminary communication." Recueil des Travaux Chimiques des Pays-Bas 83, no. 9 (2010): 992–94. http://dx.doi.org/10.1002/recl.19640830914.

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25

Ploom, Anu, Ants Tuulmets, and Jaak Järv. "Structure-reactivity relationships in organosilicon chemistry revisited." Open Chemistry 9, no. 5 (2011): 910–16. http://dx.doi.org/10.2478/s11532-011-0075-x.

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AbstractAvailable quantitative data of the reactivity of organosilicon compounds were subjected to correlation analysis. As an alternative to the carbon chemistry values, the scale of steric constants E S (Si) can be used for organosilicon compounds and the inductive effect is best expressed by two terms, involving the parameter of electronegativity of substituents. Alkyl substituents contribute to the reactivity exclusively through their steric effects, steric and polar effects in silicon compounds are additive and the resonance effect is insignificant. The correlation analysis can be employe

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26

Lee, Yong-Min, Mi Yoo, Heejung Yoon, Xiao-Xi Li, Wonwoo Nam, and Shunichi Fukuzumi. "Direct oxygen atom transfer versus electron transfer mechanisms in the phosphine oxidation by nonheme Mn(iv)-oxo complexes." Chemical Communications 53, no. 67 (2017): 9352–55. http://dx.doi.org/10.1039/c7cc04035k.

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Direct oxygen atom transfer from Mn(iv)-oxo to Ph<sub>3</sub>P occurs, exhibiting significant steric effects of the ortho-substitution of the phenyl group, whereas in the presence of HOTf, the mechanism is switched to electron transfer from Ph<sub>3</sub>P to Mn(iv)-oxo, exhibiting no steric effects.

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27

Bisi, F. "Steric Effects in Polar Nematic Liquid Crystals." Molecular Crystals and Liquid Crystals 541, no. 1 (2011): 132/[370]—141/[379]. http://dx.doi.org/10.1080/15421406.2011.570182.

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28

Konkoli, Zoran, Henrik Johannesson, and Benjamin P. Lee. "Fluctuation effects in steric reaction-diffusion systems." Physical Review E 59, no. 4 (1999): R3787—R3790. http://dx.doi.org/10.1103/physreve.59.r3787.

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29

Baumstark, A. L., and P. C. Vasquez. "Epoxidation by dimethyldioxirane. Electronic and steric effects." Journal of Organic Chemistry 53, no. 15 (1988): 3437–39. http://dx.doi.org/10.1021/jo00250a007.

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30

Uggerud, Einar. "Steric and electronic effects in SN2 reactions." Pure and Applied Chemistry 81, no. 4 (2009): 709–17. http://dx.doi.org/10.1351/pac-con-08-10-03.

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This article gives an overview of recently published literature on the factors that govern SN2 reactivity. By comparing reactivity in solution with that in the isolated gas phase, it has become possible to dissect the contribution of the solvent from that of the intrinsic molecular properties. This has proven to be an extremely important and fruitful step forward in obtaining key knowledge not available before. The gas-phase studies have made it clear that organic chemists need to revise radically their concepts and ideas about this crucial reaction type. This is particularly true with regard

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31

Hinchliffe, Paul S., J. Matthew Wood, Andrew M. Davis, Rupert P. Austin, R. Paul Beckett, and Michael I. Page. "Unusual steric effects in sulfonyl transfer reactions." Journal of the Chemical Society, Perkin Transactions 2, no. 9 (2001): 1503–5. http://dx.doi.org/10.1039/b104923m.

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32

Jean, Yves, Isabelle Demachy, Agustı́ Lledos, and Feliu Maseras. "Electronic against steric effects in distorted amides." Journal of Molecular Structure: THEOCHEM 632, no. 1-3 (2003): 131–44. http://dx.doi.org/10.1016/s0166-1280(03)00294-x.

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33

Larsen, John W., and Doyoung Lee. "Steric Effects on Diffusion into Bituminous Coals." Energy & Fuels 20, no. 1 (2006): 257–61. http://dx.doi.org/10.1021/ef0501851.

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34

Groaning, Michael D., and A. I. Meyers. "Remote steric effects in the Sakurai reaction." Tetrahedron Letters 40, no. 46 (1999): 8071–74. http://dx.doi.org/10.1016/s0040-4039(99)01703-7.

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35

Bordwell, F. G., Mark J. Bausch, Jin Pei Cheng, Thomas H. Cripe, Tsuei Yun Lynch, and Mark E. Mueller. "Steric inhibition of synergistic radical stabilizing effects." Journal of Organic Chemistry 55, no. 1 (1990): 58–63. http://dx.doi.org/10.1021/jo00288a012.

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36

Jenner, Gérard. "Steric effects in high pressure Knoevenagel reactions." Tetrahedron Letters 42, no. 2 (2001): 243–45. http://dx.doi.org/10.1016/s0040-4039(00)01930-4.

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37

Gould, Ian R., and Samir Farid. "Steric effects in photoinduced electron-transfer reactions." Journal of Physical Chemistry 97, no. 50 (1993): 13067–72. http://dx.doi.org/10.1021/j100152a006.

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38

Castelino, R. W., G. Hallas, and D. C. Taylor. "Steric and Electronic Effects in Basic Dyes." Journal of the Society of Dyers and Colourists 88, no. 1 (2008): 25–27. http://dx.doi.org/10.1111/j.1478-4408.1972.tb03036.x.

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39

Ferguson, Angus S., and Geoffrey Hallas. "Steric and Electronic Effects in Basic Dyes." Journal of the Society of Dyers and Colourists 89, no. 1 (2008): 22–24. http://dx.doi.org/10.1111/j.1478-4408.1973.tb03102.x.

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40

Gandhi, Sham S., Geoffrey Hallas, and Jeffrey Thomasson. "Steric and Electronic Effects in Basic Dyes." Journal of the Society of Dyers and Colourists 93, no. 12 (2008): 451–54. http://dx.doi.org/10.1111/j.1478-4408.1977.tb03318.x.

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41

Hwu, R. Jih-Ru, Shwu-Chen Tsay, and Buh-Luen Cheng. "ChemInform Abstract: Steric Effects of Silyl Groups." ChemInform 30, no. 16 (2010): no. http://dx.doi.org/10.1002/chin.199916347.

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42

Falklöf, Olle, and Bo Durbeej. "Steric Effects Govern the Photoactivation of Phytochromes." ChemPhysChem 17, no. 7 (2016): 954–57. http://dx.doi.org/10.1002/cphc.201501080.

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43

Desler, Ewa, Radwan Allnajar, and Radomir Jasiński. "Sterical index: a novel, simple tool for the interpretation of organic reaction mechanisms." Scientiae Radices 2, no. 1 (2023): 69–74. http://dx.doi.org/10.58332/scirad2023v2i1a06.

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A new, simple index for the quantitative description of steric effects was proposed based on the results of DFT calculations. This effect was connected with the disturbance of synchronicity within transition states of the model Diels-Alder reaction. The obtained results offer the possibility of predicting steric effects determined by alkyl groups for a wide range of bimolecular processes.

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44

Toma, Mateja, Gabrijel Zubčić, Jasmina Lapić, Senka Djaković, Davor Šakić, and Valerije Vrček. "Ferrocenoyl-adenines: substituent effects on regioselective acylation." Beilstein Journal of Organic Chemistry 18 (September 19, 2022): 1270–77. http://dx.doi.org/10.3762/bjoc.18.133.

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A series of N6-substituted adenine–ferrocene conjugates was prepared and the reaction mechanism underlying the synthesis was explored. The SN2-like reaction between ferrocenoyl chloride and adenine anions is a regioselective process in which the product ratio (N7/N9-ferrocenoyl isomers) is governed by the steric property of the substituent at the N6-position. Steric effects were evaluated by using Charton (empirical) and Sterimol (computational) parameters. The bulky substituents may shield the proximal N7 region of space, which prevents the approach of an electrophile towards the N7 atom. As

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45

Trofimenko, Swiatoslaw, Joseph C. Calabrese, Peter J. Domaille, and Jeffery S. Thompson. "Steric effects in polypyrazolylborate ligands. Poly(3-isopropylpyrazolyl)borates: ligands of intermediate steric requirements." Inorganic Chemistry 28, no. 6 (1989): 1091–101. http://dx.doi.org/10.1021/ic00305a019.

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46

Liu, Jinn-Liang, Dexuan Xie, and Bob Eisenberg. "Poisson-Fermi Formulation of Nonlocal Electrostatics in Electrolyte Solutions." Computational and Mathematical Biophysics 5, no. 1 (2017): 116–24. http://dx.doi.org/10.1515/mlbmb-2017-0007.

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Abstract We present a nonlocal electrostatic formulation of nonuniform ions and water molecules with interstitial voids that uses a Fermi-like distribution to account for steric and correlation efects in electrolyte solutions. The formulation is based on the volume exclusion of hard spheres leading to a steric potential and Maxwell’s displacement field with Yukawa-type interactions resulting in a nonlocal electric potential. The classical Poisson-Boltzmann model fails to describe steric and correlation effects important in a variety of chemical and biological systems, especially in high field

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47

Zheng, Jiaxuan, Beinan Jia, and Yongjun Jian. "Steric Effects on Space Electroosmotic Thrusters in Soft Nanochannels." Mathematics 9, no. 16 (2021): 1916. http://dx.doi.org/10.3390/math9161916.

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The influence of steric effects on the performances of space electroosmotic thrusters (EOTs) was numerically delineated in soft nanochannels for which its walls are covered with polyelectrolyte materials. The size effect of the ionic species, namely the steric effect, is neglected in many previous research studies, but it has vital influences on electrostatic potential and electroosmotic velocity, which is further introduced into the present study in order to understand and improve the exploration of nano electroosmotic thrusters with soft channels. The thruster’s thrust, specific impulse, tot

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48

Slot, Thierry K., Nathan Riley, N. Raveendran Shiju, J. Will Medlin, and Gadi Rothenberg. "An experimental approach for controlling confinement effects at catalyst interfaces." Chemical Science 11, no. 40 (2020): 11024–29. http://dx.doi.org/10.1039/d0sc04118a.

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49

Hoshyargar, Vahid, Seyed Nezameddin Ashrafizadeh, and Arman Sadeghi. "Drastic alteration of diffusioosmosis due to steric effects." Physical Chemistry Chemical Physics 17, no. 43 (2015): 29193–200. http://dx.doi.org/10.1039/c5cp05327g.

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50

KULANDAIVELU, KARUNAKARAN, GURUMURTHY RAJAGOPALA, and PITCHAIMUTHU ELANGO KUPPANNAGOUNDER. "Steric and Resonance Effects on the Kinetics of Oxidation of Organic Sulfides by Quinolinium Fluorochromate." Journal of Indian Chemical Society Vol. 75, May 1998 (1998): 297–99. https://doi.org/10.5281/zenodo.5927158.

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Department of Chemistry, Annamalai University, Annamalainagar-608 002 Department of Chemistry, Gandhigram Rural Institute, Gandhigram-624 302 <em>Manuscript received 25 March 1996, revised 20 August 1997, accepted 30 September 1997</em> Kinetics of oxidation of dialkyl, alkyl phenyl and benzal methyl phenyl sulfides to their sulfoxides by quinolinium fluorochromate (QFC) have been followed in aqueous acetic acid. The order of the reaction is found to be one each with respect to QFC, H<sub>3</sub>O<sup>+</sup> and the sulfide. Increase in the dielectric constant of the medium decreases the rate

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