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Journal articles on the topic 'Styrene derivatives'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Fujita, Morifumi, Koki Miura, and Takashi Sugimura. "Enantioselective dioxytosylation of styrenes using lactate-based chiral hypervalent iodine(III)." Beilstein Journal of Organic Chemistry 14 (March 20, 2018): 659–63. http://dx.doi.org/10.3762/bjoc.14.53.

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A series of optically active hypervalent iodine(III) reagents prepared from the corresponding (R)-2-(2-iodophenoxy)propanoate derivative was employed for the asymmetric dioxytosylation of styrene and its derivatives. The electrophilic addition of the hypervalent iodine(III) compound toward styrene proceeded with high enantioface selectivity to give 1-aryl-1,2-di(tosyloxy)ethane with an enantiomeric excess of 70–96% of the (S)-isomer.

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2

Madahi, Meysam, Dadkhoda Ghazanfari, and Sayed Ali Ahmadi. "Theoretical Study of the Chemical Properties and the Reaction Pathway of Decarbonylative Alkylative Esterification of Styrenes with Aliphatic Aldehydes." Journal of Chemistry 2022 (February 18, 2022): 1–11. http://dx.doi.org/10.1155/2022/4842630.

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Using inexpensive and available aliphatic aldehydes as an alkyl source is a useful and cost-effective way to extend the chain of benzyl esters; this decarbonylative alkylative esterification of styrene derivatives has been used for organic synthesis and medical chemistry. A cocatalyzed decarbonylative alkylative esterification of styrene derivatives with aliphatic aldehydes and iodobenzenediacetate to provide chain elongated benzoates was investigated by the density functional theory, and quantum theory of atoms in molecules analysis has been used. The chemical properties and the reaction path

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3

Duarte, Tiago A. G., Ana C. Estrada, Mário M. Q. Simões, et al. "Homogeneous catalytic oxidation of styrene and styrene derivatives with hydrogen peroxide in the presence of transition metal-substituted polyoxotungstates." Catalysis Science & Technology 5, no. 1 (2015): 351–63. http://dx.doi.org/10.1039/c4cy00702f.

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4

Spurcaciu, Bogdan, Lorena Iancu, Mircea Filipescu, et al. "Polymeric Nanofibers Manufactured by Electrospinning of Styrene-Ethylene-Butylene-Styrene (SEBS) Composites." Proceedings 29, no. 1 (2019): 84. http://dx.doi.org/10.3390/proceedings2019029084.

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The study aimed to synthesize nanofibers based on styrene-ethylene-butylene-styrene block-copolymers (SEBS) [1] and its composite derivatives, through the electrospinning (Figure 1) process [2]. [...]

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5

Iatsyshyn, Oksana, Michael Bratychak, Olena Shyshchak, Nataliya Mitina, and Olexander Zaichenko. "Copolymerization of Peroxy Derivatives of Dioxydiphenylpropane Diglycidyl Ether Monomethacrylate with Styrene." Chemistry & Chemical Technology 9, no. 3 (2015): 293–300. http://dx.doi.org/10.23939/chcht09.03.293.

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6

Mu, Xiaochun, and Yang Li. "Syndiospecific coordination (Co)polymerization of carbazole-substituted styrene derivatives using the scandium catalyst system." Polymer Chemistry 12, no. 43 (2021): 6291–99. http://dx.doi.org/10.1039/d1py00896j.

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Perfect syndiospecific polymerization of carbazole-substituted styrene derivatives was achieved using a rare-earth metal catalyst. Also copolymerization of FSt with styrene afforded copolymers with gradient sequence distributions and easily tunable incorporation rate.

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7

Wei, Xudong, Paul Johnson, and Richard J. K. Taylor. "Organolithium addition to styrene and styrene derivatives: scope and limitations." Journal of the Chemical Society, Perkin Transactions 1, no. 7 (2000): 1109–16. http://dx.doi.org/10.1039/a910195k.

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8

Mu, Xiaochun, Xuefei Leng, Chuanchuan Liu, Qiang Yao, and Yang Li. "Terpolymerization of Ethylene with Hexene and Styrene Derivatives by Half-Sandwich Scandium Catalyst." Polymers 16, no. 16 (2024): 2290. http://dx.doi.org/10.3390/polym16162290.

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The terpolymerization of ethylene with hexene and styrene derivatives was achieved with a rare earth metal catalyst (C5Me4SiMe3)Sc(CH2C6H4NMe2-o)2 to prepare functional polyethylene. The catalyst system exhibited high activity in the terpolymerization of ethylene with hexene and amine-substituted styrene, affording terpolymers a moderate molecular weight and a unimodal molecular weight distribution. In addition, the comonomer content of the terpolymers can be controlled by changing the feeding ratio of monomers. The aliphatic region of the 13C NMR spectra reveals that the structural units of t

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9

Abdallah, Dalia, Mohmad Asri Abd Ghani, Michael F. Cunningham, Peter M. Kazmaier, Barkev Keoshkerian, and Erwin Buncel. "Multi-armed, TEMPO-functionalized unimolecular initiators for starburst dendrimer synthesis via stable free radical polymerization. 1. Tri azo-functionalized unimer." Canadian Journal of Chemistry 82, no. 9 (2004): 1393–402. http://dx.doi.org/10.1139/v04-107.

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The synthesis of azobenzene-functionalized multi-armed unimolecular initiators or "unimers" that can be polymerized using styrene or styrenic derivatives via TEMPO (2,2,6,6-tetramethylpiperidenyl-1-oxyl) mediated stable free radical polymerization (SFRP) is described. The unimers are composed of an azobenzene-functionalized core and a TEMPO-modified unit. Homopolymers and copolymers of styrene and acetoxystyrene were synthesized using the mono-and trifunctionalized unimers as initiators under bulk conditions with average molecular weights and polydispersities reported. The studies lay the grou

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10

Potapov, Vladimir A., Roman S. Ishigeev, Lyudmila A. Belovezhets, Irina V. Shkurchenko, and Svetlana V. Amosova. "New Water-Soluble Condensed Heterocyclic Compounds with Antimicrobial Activity Based on Annulation Reactions of 8-Quinolinesulfenyl Halides with Natural Products and Alkenes." Applied Sciences 11, no. 18 (2021): 8532. http://dx.doi.org/10.3390/app11188532.

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The annulation reactions of 8-quinolinesulfenyl halides with natural products and alkenes affording new water-soluble [1,4]thiazino[2,3,4-ij]quinolin-4-ium derivatives in high or quantitative yields are developed in this study. The reactions with styrene derivatives and terminal alkenes including allyl arenes proceed in a regioselective manner but with the opposite regiochemistry. The reactions with terminal alkenes including allyl arenes occur in an anti-Markovnikov fashion (regarding addition of the 8-quinolinesulfenyl electrophile to the double bond) to give 2-organyl-2H,3H-[1,4]thiazino[2,

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11

Bogdanowicz-Szwed, Krystyna, та Aleksandra Pałasz. "Synthesis of 3,4-Dihydro-2H-pyrans by Hetero-Diels-Alder Reactions of Functionalized α,β-Unsaturated Carbonyl Compounds with Styrenes". Zeitschrift für Naturforschung B 56, № 4-5 (2001): 416–22. http://dx.doi.org/10.1515/znb-2001-4-515.

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Abstract Cycloadditions of 3-aryl-2-benzoyl-2-propenenitriles 1a,b to styrene (2a) and its methyl or methoxy-substituted derivatives 2b-d proceed regio- and diastereoselectively yielding cis and trans diastereoisomers of 2,4,6-triaryl-3,4-dihydro-2H-pyran-5-carbonitriles 3 and 4 in 59-72% yield. Cycloadducts cis-3 were the major products. Reaction of 5-(4-nitrobenzylidene)-1,3-dimethylbarbituric acid (5) with styrenes 2a-d afforded diastereoisomeric mixtures of 2H-pyrano[2,3-d]pyrimidine-2,4(3H)-diones cis-6 and trans-7 in 71 - 78% yield.

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12

Abbas, Ashraf A., Mohamed A. A. Elneairy та Yehia N. Mabkhot. "Versatile Starting Materials for Novel 1,ω-bis(pyridin-4-ylphenoxy)alkanes, and their Corresponding bis(thieno[2,3-b]pyridin-4-ylphenoxy) derivatives". Journal of Chemical Research 2001, № 4 (2001): 124–26. http://dx.doi.org/10.3184/030823401103169388.

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A synthesis is described, starting from p-hydroxybenzaldehyde, of some new bis(activated styrene) derivatives, and their conversion into novel bis(pyridin-4-yl) ethers and bis(thieno[2,3- b]pyridine) derivatives.

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13

Bandi, Vijayalakshmi, Veerababurao Kavala, Che-Hao Hsu та ін. "Synthesis of functionalized unsymmetrical 1,3-butadiene-3-yne derivatives from β-halo styrene derivatives and their application in the synthesis of trisubstituted pyridines". RSC Adv. 7, № 74 (2017): 46704–12. http://dx.doi.org/10.1039/c7ra07128k.

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An approach for the synthesis of functionalized unsymmetrical 1,3-butadiene-3-yne derivatives is reported starting from β-halo styrene and phenyl acetylene derivatives in the presence of PdCl<sub>2</sub> and CuI catalysts.

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14

Zhao, Zeng, Jinxin Wang, Zhiteng Du, Yuzhu Li, Qingyan Sun та Huizi Jin. "Kinetic Resolution of β-Alkyl Phenylethylamine Derivatives through Palladium-Catalyzed, Nosylamide-Directed C−H Olefination". Molecules 28, № 4 (2023): 1852. http://dx.doi.org/10.3390/molecules28041852.

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Palladium-catalyzed C-H activation reactions have attracted the attention of organic researchers due to their unique high selectivity, broad functional group tolerance, and high efficiency, and they are widely used in natural products and asymmetric synthesis. Here, we report an example of enantioselective C-H alkenylation between β-alkyl phenylethylamine compounds and styrenes with Boc-L-lle-OH as the ligand and nosylamide as the directing group. This reaction is applicable to styrene containing various electron-deficient and electron-donating substitutions and may be utilized for the synthes

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15

Yang, Hongling, Xun Zhang, Yi Yu, et al. "Manganese vacancy-confined single-atom Ag in cryptomelane nanorods for efficient Wacker oxidation of styrene derivatives." Chemical Science 12, no. 17 (2021): 6099–106. http://dx.doi.org/10.1039/d1sc00700a.

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16

Tsuchiya, Yuto, Ryota Onai, Daisuke Uraguchi та Takashi Ooi. "Redox-regulated divergence in photocatalytic addition of α-nitro alkyl radicals to styrenes". Chemical Communications 56, № 75 (2020): 11014–17. http://dx.doi.org/10.1039/d0cc04821f.

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17

Demonceau, Albert, François Simal, Corine A. Lemoine, Alfred F. Noels, Igor T. Chizhevsky, and Pavel V. Sorokin. "[OsH4(PPh3)3]: New Catalyst for the Selective Cyclopropanation of Activated Olefins." Collection of Czechoslovak Chemical Communications 61, no. 12 (1996): 1798–804. http://dx.doi.org/10.1135/cccc19961798.

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The title compound was found to be an efficient catalyst for the selective cyclopropanation of activated olefins by ethyl diazoacetate. The cyclopropane yields range from moderate to good (75 to 95%) for activated olefins such as styrene and styrene derivatives, but are rather low (20 to 30%) for non-activated olefins such as terminal and cyclic alkenes. In the intermolecular competition, styrene was 45 times more reactive than cyclooctene. In all cases, trans (exo) cyclopropane predominated over the cis (endo) isomer.

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18

Banasz, Radosław, and Monika Wałęsa-Chorab. "Photolithographic patterning of viologens containing styrene groups." RSC Advances 13, no. 24 (2023): 16206–10. http://dx.doi.org/10.1039/d3ra02287k.

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19

Dolgin, I. S., Petr P. Purygin, Y. P. Zarubin та A. V. Samorodov. "Synthesis, Study of Dielectric Properties, Thermogravimetric Analysis and Hemolytic Effect of Copolymers Based on Various Derivatives of Styrene and α-Methylstyrene". Materials Science Forum 1022 (лютий 2021): 203–11. http://dx.doi.org/10.4028/www.scientific.net/msf.1022.203.

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The paper describes the synthesis of three new copolymers based on styrene and α-methylstyrene derivatives by radical emulsion copolymerization in an aqueous medium in the presence of an ammonium persulfate initiator and potassium stearate emulsifier. In early study, it was found that copolymers based on methoxy derivatives of styrene have the advanced dielectric properties, as compared to polystyrene and a copolymer of styrene and α-methylstyrene. In addition, the latest scientific literature provides data on the biological activity of styrene copolymers. Thus, the synthesis and study of the

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20

Wu, Gwo-Wen, Ging-Ho Hsiue, and Jin-Sheng Yang. "Stress relaxation in poly(styrene-butadiene-styrene) and poly(styreneisoprene-styrene) triblock copolymers and their derivatives." Materials Chemistry and Physics 37, no. 2 (1994): 191–96. http://dx.doi.org/10.1016/0254-0584(94)90092-2.

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21

Barthelemy, Anne-Laure, Béatrice Tuccio, Emmanuel Magnier, and Guillaume Dagousset. "Intermolecular Trapping of Alkoxyl Radicals with Alkenes: A New Route to Ether Synthesis." Synlett 30, no. 13 (2019): 1489–95. http://dx.doi.org/10.1055/s-0037-1611785.

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Alkoxyl radicals are highly reactive species which rapidly react by hydrogen atom transfer (HAT) or β-fragmentation to afford a carbon-centered radical. We discuss herein how these RO· radicals can be efficiently trapped in an intermolecular manner by styrene derivatives when they are generated by photoredox catalysis from the corresponding N-alkoxypyridinium salts. This allows for the synthesis of valuable ethers with complete anti-Markovnikov regioselectivity.1 Introduction2 Anti-Markovnikov Alkoxylation of Alkenes: Background3 Addition of Alkoxyl Radicals to Styrenes4 Summary and Outlook

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22

Wei, Xudong, Paul Johnson, and Richard J. K. Taylor. "ChemInform Abstract: Organolithium Addition to Styrene and Styrene Derivatives: Scope and Limitations." ChemInform 31, no. 30 (2010): no. http://dx.doi.org/10.1002/chin.200030065.

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23

Zhang, Minghua, Minmin Fan, Shuhua Peng, et al. "Synthesis and properties of EPDM-based oil-absorptive gels with different types of EPDM and styrene derivatives." RSC Advances 11, no. 3 (2021): 1605–13. http://dx.doi.org/10.1039/d0ra08409c.

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24

Liu, Yu-Chang, Yan Liu, and Zhong-Liu Wu. "Synthesis of enantiopure glycidol derivatives via a one-pot two-step enzymatic cascade." Organic & Biomolecular Chemistry 13, no. 7 (2015): 2146–52. http://dx.doi.org/10.1039/c4ob02186j.

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25

Yang, Lincan, Heyu Shen, Li Han, et al. "Sequence regulation in living anionic terpolymerization of styrene and two categories of 1,1-diphenylethylene (DPE) derivatives." Polymer Chemistry 11, no. 32 (2020): 5163–72. http://dx.doi.org/10.1039/d0py00731e.

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In living anionic polymerization, gradient, block and random sequences of two categories of DPE derivatives were easily generated by implementing different feed strategies and screening the DPE derivative pairs with different reactivities.

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26

Wu, Liu-Hai, Kai Zhao, Zhi-Liang Shen, and Teck-Peng Loh. "Copper-catalyzed trifluoromethylation of styrene derivatives with CF3SO2Na." Organic Chemistry Frontiers 4, no. 9 (2017): 1872–75. http://dx.doi.org/10.1039/c7qo00416h.

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A radical-type copper(i)-catalyzed direct trifluoromethylation of styrene derivatives using CF<sub>3</sub>SO<sub>2</sub>Na as a trifluoromethylating source for accessing trifluoromethylated alkenes has been developed.

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27

Hui, Junfeng, Huimin Chu, Wenlei Zhang, et al. "Multicomponent metal–organic framework derivatives for optimizing the selective catalytic performance of styrene epoxidation reaction." Nanoscale 10, no. 18 (2018): 8772–78. http://dx.doi.org/10.1039/c8nr01336e.

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28

Puleo, Thomas R., Alivia J. Strong та Jeffrey S. Bandar. "Catalytic α-Selective Deuteration of Styrene Derivatives". Journal of the American Chemical Society 141, № 4 (2019): 1467–72. http://dx.doi.org/10.1021/jacs.8b12874.

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29

Seijas, Julio A., M. Pilar Vázquez-Tato, César Entenza, M. Montserrat Martínez, M. Gabriela Ònega та Susana Veiga. "Synthesis of β-phenylethylamines from styrene derivatives". Tetrahedron Letters 39, № 28 (1998): 5073–76. http://dx.doi.org/10.1016/s0040-4039(98)00907-1.

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30

Wang, Zhi-Min, та K. Barry Sharpless. "Asymmetric Dihydroxylation of α-Substituted Styrene Derivatives". Synlett 1993, № 08 (1993): 603–4. http://dx.doi.org/10.1055/s-1993-22547.

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31

Adamik, Réka, Tamás Földesi, and Zoltán Novák. "Photocatalytic Palladium-Catalyzed Fluoroalkylation of Styrene Derivatives." Organic Letters 22, no. 20 (2020): 8091–95. http://dx.doi.org/10.1021/acs.orglett.0c03043.

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32

Stadermann, Jan, Sven Fleischmann, Martin Messerschmidt, Hartmut Komber, and Brigitte Voit. "Multifunctional Block Copolymers Based on Styrene Derivatives." Macromolecular Symposia 275-276, no. 1 (2009): 35–42. http://dx.doi.org/10.1002/masy.200950104.

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33

Nakai, Yukako, Akira Takahashi, Raita Goseki, and Hideyuki Otsuka. "Facile modification and fixation of diaryl disulphide-containing dynamic covalent polyesters by iodine-catalysed insertion-like addition reactions of styrene derivatives to disulphide units." Polymer Chemistry 7, no. 28 (2016): 4661–66. http://dx.doi.org/10.1039/c6py00963h.

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34

Mamedli, S. B. "Copolymerization of butyl methacrylate with cyclopropyl styrene and its chlorinated derivatives." Plasticheskie massy 1, no. 1-2 (2023): 27–30. http://dx.doi.org/10.35164/0554-2901-2023-1-2-27-30.

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The radical copolymerization of butyl methacrylate with p-cyclopropyl styrene (I) and its monochlorine- (II), gemdichlorine-substituted derivatives (III) has been carried out and the basic regularities of formation of functionally substituted cyclopropyl styrene have been revealed. The composition and structure of the synthesized copolymers have been established. The copolymerization constants have been determined, the Alfrey–Price Q–e parameters and the microstructure of copolymers have been calculated. It has been established that the new copolymers are characterized by good optical indices

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35

An, Miao, Wanyi Liu, Xiaoying Zhou та ін. "Highly α-position regioselective ring-opening of epoxides catalyzed by halohydrin dehalogenase from Ilumatobacter coccineus: a biocatalytic approach to 2-azido-2-aryl-1-ols". RSC Advances 9, № 29 (2019): 16418–22. http://dx.doi.org/10.1039/c9ra03774h.

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36

Bai, Hongyuan, Zhi Zhang, Hongwei Ma, et al. "Investigation of the features in living anionic polymerization with styrene derivatives containing annular substituents." Polymer Chemistry 10, no. 9 (2019): 1140–49. http://dx.doi.org/10.1039/c8py01825a.

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37

Hu, Liwen, Guangfu Liao, Ting Guo, Haiyang Gao, Lei Ying, and Yong Cao. "Wide bandgap poly(meta-styrene) derivatives containing pendant carbazolyl groups as hosts for efficient solution-processed organic light emitting diodes." Polymer Chemistry 10, no. 32 (2019): 4449–58. http://dx.doi.org/10.1039/c9py00923j.

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38

Zheng, Yinan, Ying You, Qianqian Shen, Junjie Zhang, Le Liu, and Xin-Hua Duan. "Visible-light-induced anti-Markovnikov hydrosulfonation of styrene derivatives." Organic Chemistry Frontiers 7, no. 15 (2020): 2069–74. http://dx.doi.org/10.1039/d0qo00497a.

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A visible-light-induced anti-Morkovnikov hydrosulfonation reaction of styrene derivatives with sodium sulfinates has been developed, featuring mild reaction conditions, good functional-group tolerance, good yields and high regioselectivity.

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39

Bertrand, Olivier, Paul Wilson, James A. Burns, Gordon A. Bell, and David M. Haddleton. "Cu(0)-mediated living radical polymerisation in dimethyl lactamide (DML); an unusual green solvent with limited environmental impact." Polymer Chemistry 6, no. 48 (2015): 8319–24. http://dx.doi.org/10.1039/c5py01420d.

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40

Yao, Yao, Zhen Wang, and Bin Wang. "Tetra-n-butylammonium bromide (TBAB)-initiated carbonylation–peroxidation of styrene derivatives with aldehydes and hydroperoxides." Organic Chemistry Frontiers 5, no. 16 (2018): 2501–4. http://dx.doi.org/10.1039/c8qo00525g.

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41

Kobayashi, Kazuhiro, Kazuna Miyamoto, Osamu Morikawa, and Hisatoshi Konishi. "Synthesis of Benzazetine Derivatives by Intramolecular Iodoamination ofo-(Acylamino)styrene Derivatives." Bulletin of the Chemical Society of Japan 78, no. 5 (2005): 886–89. http://dx.doi.org/10.1246/bcsj.78.886.

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42

He, Liangyou, and C. Akira Horiuchi. "Cerium (IV) sulfate mediated oxidative addition of 1-phenylcycloalkenes and styrene derivatives in methanol: Synthesis of 1,2-dimethoxy compounds." Journal of Chemical Research 2000, no. 4 (2000): 172–73. http://dx.doi.org/10.3184/030823400103167039.

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43

Li, Wei-Yu, Qi-Qiang Wang, and Luo Yang. "Fe-Catalyzed radical-type difunctionalization of styrenes with aliphatic aldehydes and trimethylsilyl azide via a decarbonylative alkylation–azidation cascade." Organic & Biomolecular Chemistry 15, no. 47 (2017): 9987–91. http://dx.doi.org/10.1039/c7ob02598j.

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44

Yamamoto, Daisuke, Masayuki Soga, Hiromasa Ansai, and Kazuishi Makino. "Manganese-catalysed hydroperoxidation of carbon–carbon double bonds using molecular oxygen present in air and hydroxylamine under ambient conditions." Organic Chemistry Frontiers 3, no. 11 (2016): 1420–24. http://dx.doi.org/10.1039/c6qo00318d.

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A highly efficient manganese-catalysed hydroperoxidation of carbon–carbon double bonds of enynes as well as styrene derivatives using N-hydroxyphthalimide, N-hydroxybenzotriazole or N-hydroxysuccinimide was developed.

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45

Li, Yu-Xia, Qi-Qiang Wang, and Luo Yang. "Metal-free decarbonylative alkylation–aminoxidation of styrene derivatives with aliphatic aldehydes and N-hydroxyphthalimide." Organic & Biomolecular Chemistry 15, no. 6 (2017): 1338–42. http://dx.doi.org/10.1039/c7ob00030h.

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A convenient metal-free decarbonylative alkylation–aminoxidation of styrene derivatives with aliphatic aldehydes and N-hydroxyphthalimide (NHPI) to yield phthalimide protected alkoxyamines was developed for the first time.

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46

López, Luis, Enol López, and Giacomo Lonzi. "Synthesis of Functionalized Cyclopentene Derivatives through Gold-Catalyzed Reaction of Stabilized Vinyldiazo Compounds and Styrenes." Synthesis 28, no. 19 (2017): 4461–68. http://dx.doi.org/10.1055/s-0036-1590885.

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The reaction of alkenyldiazo compounds with styrene derivatives in the presence of [Au(IPr)(MeCN)][SbF6] provided cyclopentene derivatives resulting from a formal [3+2] cycloaddition reaction as major products. This reaction outcome stands in marked contrast to that previously observed for other olefinic derivatives. From a mechanistic point of view, this process would involve the initial generation of a highly electrophilic alkenylgold carbene intermediate, which would be subsequently involved in a stepwise carbocationic process.

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47

Ding, Jiawei, Changlei Yang, Liqiong Zhou, et al. "Free Radical Polymerization of Styrene and Maleimide Derivatives: Molecular Weight Control and Application as a Heat Resistance Agent." Molecules 30, no. 9 (2025): 1863. https://doi.org/10.3390/molecules30091863.

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Poly (styrene-maleic anhydride) copolymers, due to their unique structure, are extensively functionalized and modified for preparing heat stabilizers, compatibilizers, and other functional additives. Using 4-methylpent-1-ene-2,4-diyl diphenyl (α-MSD) as a chain transfer agent, a series of molecular-weight-controlled maleic anhydride-derived styrene copolymers, poly(N-p-fluorophenylmaleimide-alt-styrene) (PFS) and poly(N-p-carboxylphenylmaleimide-alt-styrene) (PCS), were synthesized via free radical copolymerization. The molecular weights of PFS and PCS were adjusted to explore their impact on

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48

Sauer, Daniel F., Malte Wittwer, Ulrich Markel, et al. "Chemogenetic engineering of nitrobindin toward an artificial epoxygenase." Catalysis Science & Technology 11, no. 13 (2021): 4491–99. http://dx.doi.org/10.1039/d1cy00609f.

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Chemogenetic engineering turned the heme protein nitrobindin into an artificial epoxygenase: MnPPIX was introduced and subsequent protein engineering increased the activity in the epoxidation of styrene derivatives by overall 7-fold.

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49

Zhang, Guoting, Lingling Zhang, Hong Yi, et al. "Visible-light induced oxidant-free oxidative cross-coupling for constructing allylic sulfones from olefins and sulfinic acids." Chemical Communications 52, no. 68 (2016): 10407–10. http://dx.doi.org/10.1039/c6cc04109d.

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Abstract:

An oxidant-free dehydrogenative sulfonylation of α-methyl-styrene derivatives was developed for the construction of allylic sulfones by using eosin Y as a photosensitizer in conjunction with a cobaloxime catalyst.

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50

Khamrai, Jagadish, Saikat Das, Aleksandr Savateev, Markus Antonietti, and Burkhard König. "Mizoroki–Heck type reactions and synthesis of 1,4-dicarbonyl compounds by heterogeneous organic semiconductor photocatalysis." Green Chemistry 23, no. 5 (2021): 2017–24. http://dx.doi.org/10.1039/d0gc03792c.

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Abstract:

We report the synthesis of 1,4-dicarbonyl compounds and substituted alkenes (Mizoroki–Heck type coupling) starting from secondary and tertiary alkyl halides and vinyl acetate or styrene derivatives using visible-light photocatalysis.

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