Academic literature on the topic 'Substituted aldehydes'

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Journal articles on the topic "Substituted aldehydes"

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Seebacher, Werner, Michael Hoffelner, Ferdinand Belaj, et al. "Formation of 5-Aminomethyl-2,3-dihydropyridine-4(1H)-ones from 4-Amino-tetrahydropyridinylidene Salts." Molecules 28, no. 19 (2023): 6869. http://dx.doi.org/10.3390/molecules28196869.

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Various 4-aminotetrahydropyridinylidene salts were treated with aldehydes in an alkaline medium. Their conversion to 5-substituted β-hydroxyketones in a one-step reaction succeeded only with an aliphatic aldehyde. Instead, aromatic aldehydes gave 5-substituted β-aminoketones or a single δ-diketone. The new compounds were characterized using spectroscopic methods and a single crystal structure analysis. Some of them showed anticancer and antibacterial properties.
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Mason, Katelynn M., Michael S. Meyers, Abbie M. Fox, and Sarah B. Luesse. "Application of heterocyclic aldehydes as components in Ugi–Smiles couplings." Beilstein Journal of Organic Chemistry 12 (September 15, 2016): 2032–37. http://dx.doi.org/10.3762/bjoc.12.191.

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Efficient one-pot Ugi–Smiles couplings are reported for the use of furyl-substituted aldehyde components. In the presence of these heterocyclic aldehydes, reactions tolerated variations in amine components and led to either isolated N-arylamide Ugi–Smiles adducts or N-arylepoxyisoindolines, products of tandem Ugi–Smiles Diels–Alder cyclizations, in moderate yields. A thienyl-substituted aldehyde was also a competent component for Ugi–Smiles adduct formation.
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Jockers, R., and R. D. Schmid. "Synthesis of Long-Chain Triazine Aldehydes - Substrates of Bacterial Luciferase and Photosynthetic Inhibitors." Zeitschrift für Naturforschung C 47, no. 7-8 (1992): 573–79. http://dx.doi.org/10.1515/znc-1992-7-814.

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S-triazines are photosynthetic inhibitors. They have been substituted with ω-aminoundecanoic acid. The coupling products have been transformed into triazine aldehydes. These compounds displace radioactive terbutryn and have inhibitory effects on photosynthesis in plants and bacteria. Triazine aldehydes were shown to be effective substrates for bacterial luciferase. A competitive assay between photosystem-II-herbicides and aldehyde-labeled triazines is discussed.
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Liepa, AJ, AJ Liepa, TC Morton та TC Morton. "Synthesis of 1-(α-Acyloxy-2-hydroxybenzyl)Azoles and Related Compounds by an Acyl Transfer Reaction". Australian Journal of Chemistry 42, № 11 (1989): 1961. http://dx.doi.org/10.1071/ch9891961.

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Novel azole adducts were produced by reaction of azoles and 2-acyloxyaryl aldehydes. The mechanism of the reaction involves attack by the azole at the carbonyl group and transfer of the acyl group to form an azole-substituted benzylic ester. 2-Acyloxyaryl ketones did not undergo an analogous reaction. An aminal was formed rather than an azole-substituted benzylic carbonate when a 2-aryl aldehyde carbonate was used as substrate.
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Larnaud, Florent, Charlène Calata, Anaïs Prunier, et al. "Convergent access to mono-fluoroalkene-based peptidomimetics." Organic & Biomolecular Chemistry 20, no. 6 (2022): 1205–18. http://dx.doi.org/10.1039/d1ob02441h.

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Expeditive racemic synthesis of monofluoroalkene peptide isosteres from aldehydes and substituted aromatic sulfones is reported. The olefination reaction is highly Z-selective from substituted aldehydes to afford transoid peptide mimic precursors.
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Pelttari, Eila, Eliisa Karhumäki, Jane Langshaw, and Hannu Elo. "Carbohydrazones of Substituted Salicylaldehydes as Potential Lead Compounds for the Development of Narrow-Spectrum Antimicrobials." Zeitschrift für Naturforschung C 62, no. 7-8 (2007): 483–86. http://dx.doi.org/10.1515/znc-2007-7-805.

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Certain substituted salicylaldehydes are known to have highly potent antimicrobial activity against bacteria and fungi, but the mechanism underlying this remarkable activity is not known, and almost nothing has been reported on the effects of further modification of the structures, such as the formation of hydrazone-type derivatives. We report now a study on the antimicrobial properties of the carbohydrazone derivatives of several substituted salicylaldehydes. The compounds studied were synthesized from ring-substituted salicylaldehydes and carbohydrazide in the mole ratio 2:1. They were teste
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Reddymasu, Sreenivasulu, Hatti Islavathu, Venkata Sri Ranganath Kalluri, and Ramesh Raju Rudraraju. "Asymmetric hydrogenation of N-heterocycles with sodium cyanoborohydride and S-(–)-binol." Journal of Indian Chemical Society 93, Oct 2016 (2016): 1217–20. https://doi.org/10.5281/zenodo.5639391.

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Department of Chemistry, Acharya Nagarjuna University, Nagarjuna Nagar-522 510, Andhra Pradesh, India <em>E-mail</em> : rrrau1@gmail.com Department of Chemistry, Guru Ghasidas Viswavidyalaya (Central University), Bilaspur-495 009, Chhattisgarh, India <em>Manuscript received online 12 February 2016, accepted 22 May 2016</em> Asymmetric hydrogenation of indole-3-aldehydes, indazole-3-aldehyde and aza indole-3-aldehydes with sodium cyanoborohydride and S-binol under glac. acetic acid over a period of 1&ndash;2 h gave enantiomeric excess of 3-substituted 2,3-dihydro alcohols in good yields. This i
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Sapnakumari, M., K. Divya, K. B. Aswin, and J. Dalin. "Antimicrobial and Antioxidant Study of Some Newly Synthesized Chalcones and Cyclohexenone Derivatives." Asian Journal of Chemistry 35, no. 1 (2022): 114–18. http://dx.doi.org/10.14233/ajchem.2023.24057.

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Chalcones and cyclohexenone derivatives obtained from various substituted aldehydes and substituted acetophenones are described. Chalcones were obtained by the Claisen-Schmidt condensation reaction of aldehydes with substituted acetophenones. Base catalyzed cyclocondensation of ethyl acetoacetate to chalcones under microwave irradiation leads to the formation of cyclohexenone derivatives. The prepared compounds are characterized by IR, 1H NMR and 13C NMR spectral methods. These are screened for their antimicrobial activity against Staphylococcus aureus, Escherichia coli, Aspergillus niger, Asp
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Gaweł, Marta, Justyna Piechocka, and Rafał Głowacki. "TIAZYNOWE I TIAZOLYDYNOWE POCHODNE AMINOKWASÓW SIARKOWYCH I WYBRANYCH ENDOGENNYCH ALDEHYDÓW." Wiadomości Chemiczne 78, no. 11 (2024): 1607–25. https://doi.org/10.53584/wiadchem.2024.11.9.

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Sulfur-containing amino acids, including cysteine (Cys) and homocysteine (Hcy), as well as aldehydes such as formaldehyde (FA), acetaldehyde (AA), pyridoxal 5`-phosphate (PLP), acrolein (ACR), malondialdehyde (MDA), croton aldehyde (CA) and 4-hydoxynonenal (4-HNE) widely occur in the human body. As indicated in the literature, abnormal (elevated) concentrations of these compounds in humans may result in or even be the cause of the occurrence/development of some civilization diseases. At the same time, the literature provides the evidence that Cys and Hcy are a highly reactive towards aldehydes
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Halder, Bipasa, Himadri S. Maity, and Ahindra Nag. "One Pot Synthesis of Biscoumarins and Pyranocoumarins by Coconut Juice as a Natural Catalyst." Current Organocatalysis 6, no. 1 (2019): 20–27. http://dx.doi.org/10.2174/2213337206666190219142408.

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Background: The conception of ‘Green chemistry’ is the much inventive chemistry which is potent and more environmentally benign. It is notable that many organic reactions take place in conventional organic solvents, known as volatile organic compounds. Being concerned about the environmental impact, we report a promoting medium, coconut juice (ACC) for one-pot synthesis of biscoumarins and pyranocoumarins which is safe, harmless, green and environmentally benign. Methods and Results: Substituted biscoumarins have been achieved by the reaction of biscoumarin and substituted aromatic aldehydes i
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Dissertations / Theses on the topic "Substituted aldehydes"

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Pinar, Ayse Nur. "Reaction Of Propargyl Aldehydes With Hydrazinium Salts: Synthesis Of Ferrocenyl And Phenyl Substituted Pyrazoles." Master's thesis, METU, 2008. http://etd.lib.metu.edu.tr/upload/3/12609769/index.pdf.

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Pyrazoles have been focus of a large number of investigations in the design and synthesis of novel biologically active agents that show remarkable medicinal activities. Although pyrazoles have been studied for over a century as an important class of heterocyclic compounds, they still continue to attract considerable attention due to the wide range of medicinal activities they possess. Recent studies have shown that combination of a ferrocenyl unit with structural features of pyrazoles can lead to products with enhanced or/and unexpected biological activity since several ferrocene derivatives h
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Walts, Alan Edmund. "I. Total Synthesis of (-)-ptilocaulin. II. Stereoselective reactions of allylboronic esters with substituted aldehydes." Thesis, Massachusetts Institute of Technology, 1985. http://hdl.handle.net/1721.1/15290.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 1985.<br>MICROFICHE COPY AVAILABLE IN ARCHIVES AND SCIENCE.<br>Vita.<br>Includes bibliographical references.<br>by Alan Edmund Walts.<br>Ph.D.
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Stanfield, Charles Freeman. "Synthesis of alpha-amino aldehydes as kallikrein inhibitors; synthetic methods for preparation of beta-substituted cysteine analogues." Diss., The University of Arizona, 1989. http://hdl.handle.net/10150/184738.

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The first half of this dissertation describes the synthesis and biological activities of a series of amino aldehydes; which were derivatives of the basic amino acids, arginine, lysine and ornithine. The synthesis of the amino aldehydes was complicated by the difficulty of producing an intermediate oxidation state (the aldehyde) in the presence of two other functional groups (the α-amino, and the side chain functionality). The amino aldehydes were of biological interest due to the fact that they were inhibitors of the proteolytic enzymes called kallikreins. The kallikreins are known to be invol
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Ramos, Ferronatto Gabriel. "Dynamic resolution of alpha-substituted dihydrocinnamic aldehydes. A new asymmetric synthesis of pharmaceutically important amine building blocks." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2013. http://amslaurea.unibo.it/6081/.

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Crystallization-induced diastereoisomer transformation (CIDT) was successfully employed in the enantioselective synthesis of 2-alkyl-3-aryl-propan-1-amines. These products are seen as potentially useful building blocks in the field of asymmetric organic chemistry, notably for pharmaceutically relevant compounds. The procedure was based on a recently reported protocol for deracemization of dihydrocinnamic aldehydes in which enantiomerically enriched 1-(amino(phenyl)methyl)naphthalen-2-ol (Betti base) is employed as a resolving agent. Additionally, fenpropimorph, a biologically active substance
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Pernik, Indrek. "Exploring small bite-angle PNP and PCP ligands for the rhodium-catalysed intermolecular hydroacylation of b-s-substituted aldehydes with alkenes and alkynes." Thesis, University of Oxford, 2014. http://ora.ox.ac.uk/objects/uuid:aaf41dc2-1147-44f4-b609-5bf7ada1b060.

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This thesis discusses the intermolecular hydroacylation reaction using cationic rhodium bis- phosphine complexes as catalysts. A series of small bite-angle rhodium bis-phosphine complexes have been prepared and characterised. The reactivity of these complexes has been investigated in order to gather information about the effect of subtle changes in the ligand design and they are compared to the previously reported catalysts. Chapter 2 presents the challenges involved in the synthesis of small bite-angle isopropyl and cyclohexyl PNP and PCP bis-phosphine ligand containing rhodium complexes. The
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Dharap, Y. V. "Facile synthesis of aziridines using copper hydrotalcite under microwave irradiation; synthesis of 3-substituted2(1h)-quinolinones catalyzed by hydrotalcite like anionic clays; rearrangement of α-pinene epoxide to campholenic aldehyde with modified beta zeolite catalyst and regioselective nitration of phenols with new phosphorus based ionic liquids". Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 2008. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/2633.

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CHEN, JUNG-HSUAN, and 陳蓉萱. "1. An Efficient and Convenient Synthesis of Fully-Substituted 1,2,3-Triazole 2.Organocatalytic Domino Michael /Hemiacetalization of beta-Tetralone and alpha,beta-Unsaturated Aldehydes 3. Total Synthesis of (±)-Viroallosecurinine." Thesis, 2011. http://ndltd.ncl.edu.tw/handle/89468652340197012528.

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博士<br>國立臺灣師範大學<br>化學系<br>100<br>There are three parts of research topics in this thesis. The first topic is an alternative and direct access to fully-substituted 1,2,3-triazoles. Treatment of diazo compound with 4-methoxyaniline derived aryl imines in the presence of DBU provided ethyl 1-(4-methoxyphenyl)-5-phenyl-1H-1,2,3-triazole-4-carboxylate in good to high yields. A reasonable mechanism is proposed that involves the addition of an imine nitrogen atom to the terminal nitrogen atom of the diazo compound, followed by aromatization to give the 1,2,3-triazole. The presence of the 4-carboxy gro
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Strotman, Neil Adham. "I. Stereochemistry of cyclopropane formation involving group (IV) organometallic complexes : II. Slower stoichiometric and faster catalytic reduction of aldehydes by the PPh₃ substituted hydroxycyclopentadienyl ruthenium hydride [2,5-Ph₂-3,4-Tol₂([eta]⁵-C₄COH)]Ru(CO)(PPh₃)H: a highly complex chemoselective catalyst for hydrogenation of aldehydes over ketones /." 2005. http://catalog.hathitrust.org/api/volumes/oclc/70792586.html.

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Chang, Feng-Shuo, and 張峰碩. "Synthesis of Chiral 3-Substituted BINOLate Ligands and BINOLate Derivatives and Application to Asymmetric Phenylation of Aldehyde." Thesis, 2009. http://ndltd.ncl.edu.tw/handle/60614635828327485044.

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碩士<br>國立中興大學<br>化學系所<br>97<br>In recent years, our laboratory have been reported the asymmetric aryl additions of different organoaluminum and highly reactive PhTi(OiPr)3 reagent to aldehydes or ketones catalyzed by the titanium catalyst of (S)-BINOL. A wide variety of substrates are examined to afford products, in, general, in excellent enantioselectivities of >90% ee. In addition, we have been reported the highly palladium-catalyzed cross-coupling reactions of ArTi(OiPr)3 with aryl bromides. The (S)-BINOL molecule was selected as the ligand since BINOL is a remarkable ligand applied to m
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Books on the topic "Substituted aldehydes"

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Calvert, Jack, Abdelwahid Mellouki, John Orlando, Michael Pilling, and Timothy Wallington. Mechanisms of Atmospheric Oxidation of the Oxygenates. Oxford University Press, 2011. http://dx.doi.org/10.1093/oso/9780199767076.001.0001.

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Prepared by an international team of eminent atmospheric scientists, Mechanisms of Atmospheric Oxidation of the Oxygenates is an authoritative source of information on the role of oxygenates in the chemistry of the atmosphere. The oxygenates, including the many different alcohols, ethers, aldehydes, ketones, acids, esters, and nitrogen-atom containing oxygenates, are of special interest today due to their increased use as alternative fuels and fuel additives. This book describes the physical properties of oxygenates, as well as the chemical and photochemical parameters that determine their rea
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Book chapters on the topic "Substituted aldehydes"

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JEDLIŃSKI, Z. J., M. BERO, J. KASPERCZYK, and M. KOWALCZUK. "Polymerization of Substituted Oxiranes, Epoxy Aldehydes, and Derived Oxacyclic Monomers." In ACS Symposium Series. American Chemical Society, 1985. http://dx.doi.org/10.1021/bk-1985-0286.ch016.

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HATADA, K., T. KITAYAMA, Y. OKAMOTO, et al. "Polymers of α-Substituted Benzyl Methacrylates and Aliphatic Aldehydes as New Types of Electron-Beam Resists." In ACS Symposium Series. American Chemical Society, 1985. http://dx.doi.org/10.1021/bk-1984-0266.ch020.

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Euston, Susan E., Graham H. Freeman, Kathryn E. Kitson, and Trevor M. Kitson. "Effect of Substituted Bromoacetanilides on Cytosolic Aldehyde Dehydrogenase." In Advances in Experimental Medicine and Biology. Springer US, 1996. http://dx.doi.org/10.1007/978-1-4615-5871-2_27.

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Göttlich, R. "Heteroatom-Substituted Allyl Anions." In Aldehydes. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-025-00262.

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Lindenschmidt, A. "3-Silicon-Substituted Aldehydes." In Aldehydes. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-025-00586.

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Lindenschmidt, A. "3-Tin-Substituted Aldehydes." In Aldehydes. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-025-00588.

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Lindenschmidt, A. "3-Boron-Substituted Aldehydes." In Aldehydes. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-025-00590.

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Lindenschmidt, A. "3-Halogen-Substituted Aldehydes." In Aldehydes. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-025-00592.

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Lindenschmidt, A. "3-Oxygen-Substituted Aldehydes." In Aldehydes. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-025-00594.

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Lindenschmidt, A. "3-Sulfur-Substituted Aldehydes." In Aldehydes. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-025-00606.

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Conference papers on the topic "Substituted aldehydes"

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Ito, Hiroshi, Klaas Schildknegt, and Eugene A. Mash. "Negative chemical amplification resist systems based on polyhydroxystyrenes and N-substituted imides or aldehydes." In Advances in Resist Technology and Processing VIII, edited by Hiroshi Ito. SPIE, 1991. http://dx.doi.org/10.1117/12.46389.

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Birca, Maria, Roman Rusnac, and Aurelian Gulea. "Iron(III) coordination compound with some n(4) -substituted thiosemicarbazones of salicyl aldehyde and cinnamic aldehyde derivatives." In Conferința științifică națională cu participare internațională "Integrare prin cercetare și inovare", dedicată Zilei Internaționale a Științei pentru Pace și Dezvoltare. Moldova State University, 2025. https://doi.org/10.59295/spd2024n.71.

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In this paper, the purpose of synthesis of Fe(III) coordination compounds with some N(4)-substituted thiosemicarbazones of salicyl aldehyde and cinnam aldehyde derivatives was pursued: which contain as a radical in the N(4) position: tert-butyl, cyclohexyl; allyl, methyl. The structure of thiosemicarbazones HnL1-5 was confirmed by FTIR spectroscopy and TLC analysis, melting point and NMR spectra. Based on the above-mentioned ligands, 5 coordination combinations were obtained, the research of which was carried out with the help of infrared spectroscopy. All synthesized compounds are being resea
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Rao, Vencherla V. R. Seshagiri, Maddali V. S. Murali Krishna, T. Kishen Kumar Reddy, D. Srikanth, and P. V. Krishna Murthy. "Experimental Investigations on DI Diesel Engine With Low Heat Rejection Combustion Chamber With Carbureted Ethanol and Crude Jatropha Oil." In ASME 2015 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2015. http://dx.doi.org/10.1115/imece2015-53259.

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It has been found that the vegetable oils and alcohols (ethanol and methanol) are promising substitute fuels for diesel fuel, because they are renewable in nature. However drawbacks associated with crude vegetable oil (high viscosity and low volatility) and ethanol (low cetane number and low energy content) which cause combustion problems in CI engines, call for engine with hot combustion chamber. Investigations were carried out on single–cylinder, four–stroke, water cooled, 3.68 kW direct injection diesel engine at a speed of 1500 rpm to evaluate the performance of a engine with medium grade
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