Academic literature on the topic 'Substituted anilines'

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Journal articles on the topic "Substituted anilines"

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Ohnishi, Atsushi, Tohru Shibata, Tatsuya Imase, Satoshi Shinkura, and Kanji Nagai. "Achiral Molecular Recognition of Substituted Aniline Position Isomers by Crown Ether Type Chiral Stationary Phase." Molecules 26, no. 2 (2021): 493. http://dx.doi.org/10.3390/molecules26020493.

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To understand the selectivity of the crown ether type chiral stationary phase (CSP), the retention selectivity for aniline and the positional isomers of substituted anilines were studied. In various substituted isomers, except nitroaniline, a remarkable decrease of retention due to steric hindrance was observed for the 2-substituted isomer. To determine the detailed molecular recognition mechanism, quantum chemical calculations were performed for the aggregates between the crown ether and the anilines. The results suggested that the 20-Crown-6, which includes a phenyl-substituted 1,1′-binaphth
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Gorokhov, Valery Yu, and Tatiana V. Makhova. "Para-(aza,thio)xanthenylated anilines in the pereaminination reaction." Butlerov Communications 60, no. 10 (2019): 32–35. http://dx.doi.org/10.37952/roi-jbc-01/19-60-10-32.

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It is known that the biochemical enzymatic reaction of the reversible transfer of an amino group from an amino-acid to a keto-acid is called a transamination reaction. However, the transamination reaction is applicable not only for biochemical enzymatic reactions, but is also often used in organic synthesis to produce aromatic azomethines. As objects of study in the transamination reaction, we selected substituted N-benzylidenanilines (imines, Schiff bases) and anilines, containing a biologically active heterocyclic fragment in the para-position of the aniline ring. We have shown the feasibili
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Verma, Anil K., Summon Koul, Tej K. Razdan, and Kamal K. Kapoor. "A new and efficient one-pot solid-supported synthesis of 1,2,4,6-tetraaryl-1,4-dihydropyridines." Canadian Journal of Chemistry 84, no. 8 (2006): 1064–73. http://dx.doi.org/10.1139/v06-128.

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1,2,4,6-Tetraaryl-1,4-dihydropyridines were obtained by the one-pot reaction of chalcones and substituted anilines on the surface of Bi(III)nitrate-Al2O3. The reaction seems to proceed via β-oxygenation of Bi(III) enolised chalcones followed by Michael addition and heteroannulation with simultaneous retro aldol disproportionation. The presence of the ring-activating groups at ortho and para positions in the aniline seems to be essential for the reaction.Key words: 1,2,4,6-tetraryl-1,4-dihydropyridines, chalcones, substituted anilines, Bi(III) nitrate-alumina catalyst.
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Shteinberg, Leon. "INFLUENCE OF SUBSTITUTES ON THE RATE OF THE REACTION OF ORTHOSUBSTITUTED BENZOIC ACIDS WTH ANILINE, CATALYZED BY POLYBUTOXYTITANATES." Ukrainian Chemistry Journal 87, no. 3 (2021): 18–40. http://dx.doi.org/10.33609/2708-129x.87.03.2021.18-40.

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The polybutoxytitanates catalysis of aniline acylation by orthosubstituted benzoic acids leads to the production of substituted benzanilides. Catalytic rate constants of the second order reaction (the first with respect to aniline and ortho-substituted benzoic acid; boiling ortho=xylene, 145°C) correlate well according to the Hammett and Bronsted equations with straight line segments with ρ=1.93 and α=0.66, in contrast to the reaction of aniline with meta- and parasubstituted benzoic acids and substituted anilines with benzoic acid. This dependence drops out 2=nitrobenzoic and 1=naphthoic acid
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Crampton, Michael R., Lynsey C. Rabbitt, and François Terrier. "Electrophilic aromatic substitution in substituted anilines; kinetics of the reaction with 4,6-dinitrobenzofuroxan." Canadian Journal of Chemistry 77, no. 5-6 (1999): 639–46. http://dx.doi.org/10.1139/v99-033.

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Kinetic results are reported for reaction of aniline and six of its N- and ring-substituted derivatives with 4,6-dinitrobenzofuroxan (DNBF) in water - dimethyl sulfoxide mixtures. In acidic solution σ-adducts, the result of electrophilic substitution in the anilines, are formed with bonding between a ring-carbon atom of the anilines and the 7-position of DNBF. Reaction normally occurs at the 4-position of the aniline unless this carries a substituent, when reaction occurs at the 2-position. A value of 2.0 for kH/kD, the kinetic isotope effect, indicates that in the reaction with aniline bond f
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Mishra, Neeraj Kumar, Miji Choi, Hyeim Jo, et al. "Direct C–H alkylation and indole formation of anilines with diazo compounds under rhodium catalysis." Chemical Communications 51, no. 97 (2015): 17229–32. http://dx.doi.org/10.1039/c5cc07767b.

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Shteynberg, Leon. "INFLUENCE OF SUBSTITUTES ON THE RATE OF THE REACTION OF META- АND PARASUBSTITUTED BENZOIC ACIDS WTH ANILINE, CATALYZED BY POLYBUTOXYTITANATES". Ukrainian Chemistry Journal 86, № 6 (2020): 108–31. http://dx.doi.org/10.33609/2708-129x.86.6.2020.108-131.

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The polybutoxytitanates catalysis of acylation of anilines by meta- and parasubstituted benzoic acid results in substituted benzanilides. The rate constants of this second-order reaction (the first in terms of aniline and substituted benzoic acid; boiling ortho-xylene, 145 °С) correlates well according to the Hammett equation with two straight lines for individual groups of substituents with ρ = 1.76 (electron donors) and 0.12 (electron acceptors). Oxybenzoic and phthalic acids, that do not react with aniline and inhibit the interaction of the latter with benzoic acid, fall out of this depende
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Lu, Hao, Kun Wang, Beibei Liu, et al. "Systematic oligoaniline-based derivatives: ACQ–AIE conversion with a tunable insertion effect and quantitative fluorescence “turn-on” detection of BSA." Materials Chemistry Frontiers 3, no. 2 (2019): 331–38. http://dx.doi.org/10.1039/c8qm00543e.

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Conversion from ACQ to AIE was achieved in aniline oligomer derivatives based on a novel “chain-insertion” pattern. The fully substituted anilines also showed a quantitative turn-on fluorescence response towards BSA.
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Shteynberg, Leon. "INFLUENCE OF SUBSTITUTES ON THE RATE OF REACTION OF SUBSTITUTED ANILINES WITH A BENZOIC ACID, CATALYZED BY POLYBUTOXYTITANATES." Ukrainian Chemistry Journal 86, no. 1 (2020): 36–59. http://dx.doi.org/10.33609/0041-6045.86.1.2020.36-59.

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The catalytic production of benzanilide by the interaction of benzoic acid with aniline is an important model process recently intensively developed in the field of the concept of «green chemistry», direct catalytic amidation, and its study is an urgent scientific and practical task. To solve this problem, the effect of substituents in the aniline core on the catalysis by polybut-oxytitanates on acylation of substituted anilines by benzoic acid was studied. The rate constants of this the second-order reaction (the first with respect to substituted aniline and benzoic acid; boiling ortho-xylene
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Asghar, Basim H. "Study of Kinetics, Equilibrium and the Influence of Steric Effects on Proton-Transfer in the Reactions of 2, 2, 4- and 2, 6- Substituted Anilines with 2-Phenoxy-3,5-dinitropyridine in DMSO." E-Journal of Chemistry 7, no. 1 (2010): 253–59. http://dx.doi.org/10.1155/2010/721387.

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Kinetic and equilibrium results for the reactions of 2-phenoxy-3,5-dinitropyridine (1), with a series of 2, 2, 4- and 2, 6- substituted anilines (2a-f), in the presence of DABCO in DMSO are reported. The reactions yield the 2-anilino derivatives (5), without the accumulation of intermediates. Kinetics studies are compatible with a two-step mechanism involving initial nucleophilic attack by amine at the ring carbon substituted by phenoxy group followed by either base-catalyzed or uncatalyzed conversion to the product. The base-catalyzed pathway is likely to involve rate-limiting proton-transfer
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Dissertations / Theses on the topic "Substituted anilines"

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Jbarah, Abdel Aziz. "Spectroelectrochemistry of Substituted Anilines." Doctoral thesis, Universitätsbibliothek Chemnitz, 2006. http://nbn-resolving.de/urn:nbn:de:swb:ch1-200601985.

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Die Elektrochemie und die Spektroelektrochemie von Nitroanilinen (ortho-, meta- und para- Isomere) und deren entsprechenden Diaminoverbindungen (ortho-, meta- und para-Phenylendiamin) wurden an zwei verschiedenen Elektroden (Platin und Gold) und in zwei Elektrolytlösungen (saure und neutrale Perchloratlösung) untersucht. Die erhaltenen Messergebnisse wurden als Referenz für die spektroelektrochemische Untersuchung von Polyvinylaminen mit o- oder p- Nitroanilinsubstituenten verwendet. Es wurden außerdem spektroelektrochemische Untersuchungen mit anderen Polyvinylaminen, die das Wurster Kationra
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Scarfe, Graeme Bryan. "The in vivo metabolism of substituted anilines and acetanilides in rat using hyphenated NMR spectroscopic techniques." Thesis, Birkbeck (University of London), 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.325321.

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Tirkes, Seha. "Synthesis, Characterization, And Polymerization Of Polyether Bridged Thiophene And Aniline Derivatives." Phd thesis, METU, 2008. http://etd.lib.metu.edu.tr/upload/3/12609399/index.pdf.

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New compounds consisting of 3-thienyl and aniline units linked by polyether bridges have been synthesized and their electrochemical polymerization was performed via constant potential electrolysis and cyclic voltammetry. In the case of 3-thienyl derivatives two compounds, 1,12-di-3-thienyl-2,5,8,11-tetraoxadodecane (MI) and 1,15-di-3-thienyl-2,5,8,11,14-pentaoxapentadecane (MII) were synthesized utilizing literature methods and their corresponding polymers, poly(I) and poly(II) were prepared in an electrolytic solution containing 0.1 M terabutylammonium hexafluorophosphate (TBAPF6) dissolved i
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Monzón, Díaz Gabriel Andrés [Verfasser], and Paul [Akademischer Betreuer] Knochel. "Zincation of heterocycles and aryl nonaflates : directed magnesiation of highly substituted anilines and amino-substituted heterocycles ; synthesis of heterobenzylic zinc compounds ; new generation of iminium salts / Gabriel Andrés Monzón Díaz. Betreuer: Paul Knochel." München : Universitätsbibliothek der Ludwig-Maximilians-Universität, 2012. http://d-nb.info/1025821947/34.

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Cheng, Ying. "Part I: the 't-amino effect' in the Vilsmeier formylation of p-substituted tertiary anilines : part II: study of the chemistry of aminochlorocarbenes derived from Vilsmeier reagents by the action of bases." Thesis, University of Sunderland, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.297371.

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Athersuch, Toby James. "Analytical and chemometric investigations of congeneric substituted aniline metabolism." Thesis, Imperial College London, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.438992.

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SHAH, KUNAL G. "SYNTHESIS AND CHARACTERIZATION OF POLYANILINE, SUBSTITUTED POLYNAILINES AND THEIR COMPOSITES COATS ON AL-2024." University of Cincinnati / OhioLINK, 2001. http://rave.ohiolink.edu/etdc/view?acc_num=ucin997206229.

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Ait, Lyazidi Saâdia. "Rôle de l'eau et de la liaison hydrogène dans la structure et spectroscopie des molécules TICT : Corrélation d'une étude conformationnelle avec l'absorption et la fluorescence double d'anilines para-substituées en solutions et en matrices polymériques." Bordeaux 1, 1986. http://www.theses.fr/1986BOR10583.

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Mise en evidence du role determinant des traces d'eau contenues en impurete dans les solvants sur la fluorescence double des n,n-dialkylanilines para-substituees (molecules titc). L'origine de cette anomalie est un complexe par liaison hydrogene
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Devault, Damien. "Approche spatio-temporelle de la contamination par les herbicides de pré-levée du biotope de la Garonne Moyenne." Toulouse, INPT, 2007. http://ethesis.inp-toulouse.fr/archive/00000578/.

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L'application au milieu naturel d'un protocole de dosage des herbicides dans le sédiment a permit de dresser une cartographie de la contamination des sédiments et des eaux de surface appariées par les produits phytosanitaires. Au travers de ce premier état de la contamination du biotope aquatique, l'étude identifiera et caractérisera les sites où la charge en pesticides est la plus élevée : dans un contexte urbain et dans les discontinuités majeures propices à l'accumulation du sédiment (barrages). Des investigations furent alors menées pour comparer l'activité biologique du sédiment à sa char
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Jadhav, Abhijit V. "Crosslinking of polyaniline with aryl azides and the photolysis of vinyl azides and azidopropanones." University of Cincinnati / OhioLINK, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1204666531.

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Books on the topic "Substituted anilines"

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Panigrahi, Muktikanta, and Arpan Kumar Nayak. Polyaniline based Composite for Gas Sensors. IOR PRESS, 2021. http://dx.doi.org/10.34256/ioriip212.

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In this research work, we have demonstrated the synthesis, spectroscopic characteristics, thermal behaviour and DC conductivity of a few nanostructured composites, substituted conducting polymers (ICPs) and composites of ICPs. The physical properties of aforementioned composites are significantly changed by the doping with HCl, H2SO4, HNO3, H3PO4, or acrylic acid. The charge transport properties of these polymeric materials have been studied in detail because of their potential application in gas sensors. In the current work, varieties of conducting polymer based materials such as PANI-ES/Cloi
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Book chapters on the topic "Substituted anilines"

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Rosenkilde, S., A. Holm, T. Geisler, and P. S. Ramanujam. "Nonlinear Optical Effects in Substituted Anilines." In Springer Series on Wave Phenomena. Springer Berlin Heidelberg, 1990. http://dx.doi.org/10.1007/978-3-642-84206-1_20.

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Jansen, Susan A., Lawrence T. Sein, James M. Varnum, Thanh Duong, and Yen Wei. "Assessment of Electronic Factors Necessary for Corrosion Inhibition: An Analysis of Substituted Aniline Oligomers." In ACS Symposium Series. American Chemical Society, 2003. http://dx.doi.org/10.1021/bk-2003-0843.ch005.

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Denny, William A., William R. Wilson, and Brian D. Palmer. "Quantitative Structure—Activity Relationships for the Cytotoxicity of Substituted Aniline Mustards in Tissue Culture." In ACS Symposium Series. American Chemical Society, 1989. http://dx.doi.org/10.1021/bk-1989-0413.ch020.

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Griesbeck, A. G., and E. Zimmermann. "Nitration of Substituted Anilines." In Quinones and Heteroatom Analogues. Georg Thieme Verlag KG, 2006. http://dx.doi.org/10.1055/sos-sd-028-00774.

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Wong, Y. S. "Alkenylation of -Alkyl-Substituted Anilines." In 1,3-Dienes. Georg Thieme Verlag KG, 2009. http://dx.doi.org/10.1055/sos-sd-046-00389.

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Wong, Y. S. "Hydroxylation of -Alkyl-Substituted Anilines (Synthesis of -Quinol Imines)." In 1,3-Dienes. Georg Thieme Verlag KG, 2009. http://dx.doi.org/10.1055/sos-sd-046-00390.

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Urleb, U., and S. Gobec. "Phenazine 5-Oxides by Oxidative Condensation of Anilines and Substituted Nitrobenzenes." In Six-Membered Hetarenes with Two Identical Heteroatoms. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-016-01133.

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Pfeiffer, W. D. "Synthesis by Ring Closure from 2-Seleno-Substituted Anilines and a Carboxylic Derivative." In Five-Membered Hetarenes with One Chalcogen and One Additional Heteroatom. Georg Thieme Verlag KG, 2002. http://dx.doi.org/10.1055/sos-sd-011-01303.

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Taber, Douglass F. "Substituted Benzenes: The Kirsch Synthesis of Cybrodol." In Organic Synthesis. Oxford University Press, 2013. http://dx.doi.org/10.1093/oso/9780199965724.003.0063.

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Stephen L. Buchwald of MIT established (J. Am. Chem. Soc. 2010, 132, 14076) a Pd-catalyzed protocol for conversion of an aryl triflate 1 to the halide 2. Jie Wu of Fudan University prepared (Tetrahedron Lett. 2010, 51, 6646) aromatic halides from the corresponding carboxylic acids. Yong-Chua Teo of Nanyang Technological University described (Tetrahedron Lett . 2010, 51, 3910) the Mn-mediated conversion of 3 to 5, suggesting a benzyne intermediate. Takanori Shibata of Waseda University effected (Synlett 2010, 2601) the direct Ru-mediated coupling of aryl halides with amines, and Paul Helquist o
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Panigrahi, Muktikanta, and Basudam Adhikari. "Acrylic Acid (AA) Based Polyaniline Composite for Liquified Petroleum Gas (LPG) Sensors." In Polyaniline based Composite for Gas Sensors. IOR PRESS, 2021. http://dx.doi.org/10.34256/ioriip2124.

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N-substituted PANI-ES was obtained from N-phenyl-β-alanine (N-substituted aniline). N-phenyl-β-alanine was synthesized chemically from methyl acrylate and aniline precursor. ESI-MS, H1NMR spectroscopy and FTIR spectroscopy are employed to characterise the N-phenyl-β-alanine for structure elucidation. The structure and properties of corresponding polymers were investigated by X-ray diffraction, FTIR, UV-Visible, H1NMR, FESEM, solubility, and DC conductivity. On the basis of experimental results of prepared N-substituted aniline monomer and its corresponding polymer is proposed. At room temperat
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Conference papers on the topic "Substituted anilines"

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Yan, Shuxin, and Lee H. Spangler. "Nitrogen inversion mode in substituted anilines." In OSA Annual Meeting. Optica Publishing Group, 1992. http://dx.doi.org/10.1364/oam.1992.tul9.

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Pattanayak, Soumya Sundar, Tushar Bachhar, and Swagatadeb Sahoo. "Dielectric Relaxation Phenomena of Aniline and Substituted Anilines with Acetonitrile Under 9.36 GHz Electric Field." In 2018 3rd International Conference for Convergence in Technology (I2CT). IEEE, 2018. http://dx.doi.org/10.1109/i2ct.2018.8529794.

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Bulavka, Vladimir. "Willgerodt-Kindler Reaction under Microwave Irradiation. II. Action of Substituted Anilines and Sulfur on Substituted Benzaldehydes." In The 8th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2004. http://dx.doi.org/10.3390/ecsoc-8-01991.

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Ito, A., K. Ota, K. Yoshizawa, K. Tanaka, and T. Yamabe. "Magnetic properties of n-dodecyl substituted poly(m-aniline)." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.834724.

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Reis, A. K. C. A., D. R. Paiva, M. M. Reginato, and S. I. Alves. "Nonlinear optical study of p-bromo-benzylidene aniline-substituted." In 8th Ibero American Optics Meeting/11th Latin American Meeting on Optics, Lasers, and Applications, edited by Manuel Filipe P. C. Martins Costa. SPIE, 2013. http://dx.doi.org/10.1117/12.2025988.

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Bobal, Pavel, Josef Jampilek, Jan Otevrel, and Josef Sujan. "Microwave-assisted synthesis of new substituted anilides of quinaldic acid." In The 15th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2011. http://dx.doi.org/10.3390/ecsoc-15-00681.

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Mir, M. Amin, M. Waqar Ashraf, and Kim Andrews. "Preparation, spectral analysis of a substituted phenyl acetanilide from aniline." In FOURTH INTERNATIONAL CONFERENCE ON ADVANCES IN PHYSICAL SCIENCES AND MATERIALS: ICAPSM 2023. AIP Publishing, 2024. http://dx.doi.org/10.1063/5.0216052.

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Wiggins, J., B. Morasch, O. Durán, and B. Barea-López. "Cure Path Dependency on Meta-Alkyl Substituted Aniline Based Polybenzoxazine Thermosets." In SAMPE 2022. NA SAMPE, 2022. http://dx.doi.org/10.33599/nasampe/s.22.0758.

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Bhat, Kamala, Tesfaye Gebre, Ashok K. Batra, et al. "Synthesis, characterization, and bulk crystal growth of nonlinear 3-substituted salicylidene aniline derivatives." In Optical Science and Technology, SPIE's 48th Annual Meeting, edited by Mark G. Kuzyk, Manfred Eich, and Robert A. Norwood. SPIE, 2003. http://dx.doi.org/10.1117/12.508589.

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Dolezal, Martin, Miroslav Miletin, Jiri Hartl, Katarina Kralova, and Jiri Kunes. "Synthesis of Some Anilides of Substituted Pyrazine-2-carboxylic Acids and Their Photosynthesis-inhibiting Activity." In The 4th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2000. http://dx.doi.org/10.3390/ecsoc-4-01921.

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