Academic literature on the topic 'Substituted formamides'

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Journal articles on the topic "Substituted formamides"

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Schönewerk, Jens, and Horst Hartmann. "On the Formation and 1H NMR-spectroscopic Characterization of N,N-Diaryl-substituted Formamide Chlorides." Zeitschrift für Naturforschung B 67, no. 4 (2012): 277–84. http://dx.doi.org/10.1515/znb-2012-0401.

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The reaction of N,N-diaryl-substituted formamides with oxalyl chloride gives rise, instead to the formation of the expected salt-like formamide chlorides, to the formation of corresponding non-ionic N-dichloromethyl-substituted diarylamines.
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Nath, Dilip Chandra Deb, Christopher M. Fellows, Toshiaki Kobayashi, and Teruyuki Hayashi. "Hydroamidation of Alkenes with N-Substituted Formamides." Australian Journal of Chemistry 59, no. 3 (2006): 218. http://dx.doi.org/10.1071/ch06010.

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Hydroamidation of olefins with N-substituted formamides is performed with dodecacarbonyltriruthenium (Ru3(CO)12) at 180°C under N2 or CO atmosphere in toluene and in a series of ionic liquids. Yields of 99% with 94–97% exo selectivity are found in the addition of N-methylformamide to 2-norbornene under CO both in toluene and in the ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide [bmim][NTf2]. The presence of CO or a phosphine is necessary for significant reaction to occur, with CO more effective than triphenylphosphine in all ionic liquids investigated. Reasonable yi
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Gao, Lingfeng, Haoming Tang, and Zhiyong Wang. "Oxidative coupling of methylamine with an aminyl radical: direct amidation catalyzed by I2/TBHP with HCl." Chem. Commun. 50, no. 31 (2014): 4085–88. http://dx.doi.org/10.1039/c4cc00621f.

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Liu, Defu, Jincheng Mao, Guangwei Rong, Hong Yan, Yang Zheng, and Jie Chen. "Concise synthesis of semicarbazides and formylhydrazines via direct addition reaction between aromatic azoarenes and N-substituted formamides." RSC Advances 5, no. 25 (2015): 19301–5. http://dx.doi.org/10.1039/c4ra17015f.

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M., UMAR ALl, M. MESHRAM H., and G. PARANJPE M. "Raney Nickel Desulphuration of 1-Substituted- and 1,3-Disubstituted-thioureas." Journal of Indian Chemical Society Vol. 62, Sep 1985 (1985): 666–69. https://doi.org/10.5281/zenodo.6322632.

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Department of Chemistry, Nagpur University, Nagpur-140 010 Manuscript <em>received 16 May 1984, revised 13 May 1985, accepted 11 September 1985</em> Certain 1-aryl-1,3 diaryl- and 1-aryl-3-tetra-<em>O</em>-acetyl-<em>&beta;</em>-D-glucopyranosyl thio&shy;ureas have been successfully desulphurated into the related mono- and 1,3-di-substituted formamidines with the help of Raney nickel catalyst. A few of them have been con&shy;verted into the corresponding formamides also. Structure of the products have been established through usual chemical transformations, ir, nmr and mass spectral analysis.
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Tieppo, N., P. Redondo, F. Pauzat, O. Parisel, J. C. Guillemin, and Y. Ellinger. "Building formamide and N-substituted formamides from isocyanates on hydrogenated water ices." Astronomy & Astrophysics 695 (March 2025): A133. https://doi.org/10.1051/0004-6361/202450614.

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Context. Many complex organic molecules (COMs) observed in the interstellar medium (ISM) are probably not formed in the gas phase. A large consensus has developed that it could be related to the icy surfaces in this environment. Aims. We investigate the process of building N-substituted formamides in the ISM by successive additions of atomic hydrogen to isocyanates. The key point is to see whether the pre-adsorption of the atomic hydrogen on the ice surface is a driving vector as it is for the formation of CH3OH from CO. Methods. We use quantum numerical simulations, namely density functional
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Gupta, Shyam Sunder R., Akhil V. Nakhate, Kalidas B. Rasal, Gunjan P. Deshmukh, and Lakshmi Kantam Mannepalli. "Oxidative amidation of benzaldehydes and benzylamines withN-substituted formamides over a Co/Al hydrotalcite-derived catalyst." New Journal of Chemistry 41, no. 24 (2017): 15268–76. http://dx.doi.org/10.1039/c7nj03123h.

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Comins, Daniel L. "Synthesis of MAPA Reagents and 2-Alkyl(aryl)aminopyridines from 2-Bromopyridine Using the Goldberg Reaction." Molecules 27, no. 6 (2022): 1833. http://dx.doi.org/10.3390/molecules27061833.

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A short and economical synthesis of various 2-methylaminopyidine amides (MAPA) from 2-bromopyridine has been developed using the catalytic Goldberg reaction. The effective catalyst was formed in situ by the reaction of CuI and 1,10-phenanthroline in a 1/1 ratio with a final loading of 0.5–3 mol%. The process affords high yields and can accommodate multigram-scale reactions. A modification of this method provides a new preparation of 2-N-substituted aminopyridines from various secondary N-alkyl(aryl)formamides and 2-bromopyridine. The intermediate aminopyridine formamide is cleaved in situ thro
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Zhou, Zhou, Jin-Tao Yu, Yongnan Zhou, Yan Jiang, and Jiang Cheng. "Aqueous MCRs of quaternary ammoniums, N-substituted formamides and sodium disulfide towards aryl thioamides." Organic Chemistry Frontiers 4, no. 3 (2017): 413–16. http://dx.doi.org/10.1039/c6qo00670a.

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A three-component reaction of quaternary ammonium salts, N-substituted formamides and aqueous sodium disulfide was developed, leading to aryl/heteroaryl thioamides in moderate to good yields with good functional group compatibility.
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Vohra, Rahul, та David B. Maclean. "Enamines from formamides. Synthesis of 1,2,3,4-tetrahydro-1-substituted β-carbolines". Canadian Journal of Chemistry 72, № 7 (1994): 1660–67. http://dx.doi.org/10.1139/v94-209.

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Pyridines and benzopyridines substituted with trimethylsilylmethyl groups, α or γ to the nitrogen atom, have been found to react with formamides by way of a Peterson reaction to form enamines. Trimethylsilylmethylbenzene behaved similarly. The enamines prepared from Nb-formyl-Na,Nb-dimethyltryptamine cyclized readily to β-carbolines. The reaction of formamides with lithiated 4-methylpyridines as a route to enamines was examined but proved to be less general and proceeded in lower yield than the route by way of the Peterson reaction. The nuclear magnetic resonance and mass spectra of the enamin
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Dissertations / Theses on the topic "Substituted formamides"

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Yang, Li. "Syntheses, X-ray Diffraction Structures, and Kinetics on New Formamidinate-Substituted Triosmium Clusters." Thesis, University of North Texas, 2010. https://digital.library.unt.edu/ark:/67531/metadc33217/.

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The reaction between the formamidine ligand PriN=CHNHPri and the activated cluster Os3(CO)10(MeCN)2 has been studied. A rapid reaction is observed at room temperature, yielding the hydride clusters HOs3(CO)9[&#956;-OCNPriC(H)NPri] and HOs3(CO)10[&#956;-NPriC(H)NPri] as the principal products. The spectroscopic data and X-ray diffraction structures of those formamidinate-substituted clusters will be present. The thermal reactivity of the clusters has been investigated, with the face-capped cluster HOs3(CO)9[&#956;-NPriC(H)NPri] found as the sole observable product. The relationship between thes
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Ahmadzadeh, Samii Arianeh. "Le formamide, un substitut de l'eau dans les microémulsions : utilisation d'une réaction de Diels-Adler comme sonde chimiques." Toulouse 3, 1988. http://www.theses.fr/1988TOU30025.

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Ahmadzadeh, Samii Arianeh. "Le Formamide, un substitut de l'eau dans les microémulsions utilisation d'une réaction de Diels-Alder comme sonde chimique /." Grenoble 2 : ANRT, 1988. http://catalogue.bnf.fr/ark:/12148/cb376112200.

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Gube, Andrea. "Zielgerichtete Synthese von helikalen und zyklischen Harnstoffoligomeren über die Beeinflussung der Kettenkonformation." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2012. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-100144.

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In der vorliegenden Arbeit sollten sowohl neue Polyharnstoffe als auch makrozyklische Harnstoffe bzw. Amidine auf Basis von 2,6-Diaminopyridin im Hinblick auf eine potentielle Anwendung in der supramolekulare Chemie hergestellt und charakterisiert werden. Ab initio-Berechnungen zufolge, sollten die linearen Harnstoffoligomere aufgrund von nichtkovalenten Wechselwirkungen ab dem Tetramer eine helikale Struktur aufweisen. In dieser Arbeit sollten die Harnstoffoligomere über einen stufenweisen Aufbau mit 2,6-Diaminopyridin (2,6-DAPy) bzw. dem Dimermolekül als Ausgangsstoff synthetisiert werden.
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Barve, Balaji D., and 巴拉吉. "Transition Metal Catalyzed Direct C-H Functionalization of Formamides and Ethers for the Synthesis of Carbamates and Acetals from 2-Carbonyl Substituted Phenols." Thesis, 2014. http://ndltd.ncl.edu.tw/handle/8p2w29.

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博士<br>高雄醫學大學<br>醫藥暨應用化學研究所<br>102<br>The thesis entitled “Transition Metal Catalyzed Direct C-H Bond Functionalization Reactions of Formamides and Ethers for the Synthesis of Carbamates and Acetals from 2-Carbonyl-Substituted Phenols” is divided into four chapters. Chapter 1: Copper-Catalyzed Synthesis of Carbamates from β-Ketoesters and 2-Carbonyl Substituted Phenol by Direct C-H Bond Functionalization of Formamides In this chapter a brief summary was introduced on the recent advances in the synthesis of organic carbamates, transition metal catalyzed C–H bond functionalizat
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Chang, Chun-Hsi, and 張濬璽. "The study of selective synthesis and biological activity of pyrazolo[3,4-d]pyrimidine, N-(1H-pyrazol-5-yl)formamide, or N-(1H-pyrazol-5-yl)formamidine derivatives from N-1-Substituted-5-aminopyrazoles with new Vilsmeier-type reagents." Thesis, 2013. http://ndltd.ncl.edu.tw/handle/95634777776867134802.

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碩士<br>中國醫藥大學<br>藥物化學研究所碩士班<br>102<br>Various halomethyleniminium salts as novel Vilsmeier reagents were synthesized from the reaction of formamide or N-methylformamide with phosphoryl chloride. Treatment of N-1-substituted-aminopyrazoles including, N-1-(2-pyridinyl)-5-aminopyrazoles and N-1-(2-quinolinyl)-5-aminopyrazoles with these Vilsmeier reagents to obtain the corresponding pyrazolo[3,4-d]pyrimidine, N-(1H-pyrazol-5-yl)formamide, or N-(1H-pyrazol-5-yl)formamidine products. The experimentant results were different with our previous data which the formylated amidylpyazole and formamidine pr
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Book chapters on the topic "Substituted formamides"

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Rico, I., and A. Lattes. "Waterless Microemulsions — 3: Formamide, a Substitute of Water." In Surfactants in Solution. Springer US, 1986. http://dx.doi.org/10.1007/978-1-4613-1833-0_22.

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"N-Substituted formamide deformylase." In Class 3 Hydrolases. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-85705-1_38.

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Taber, Douglass F. "Substituted Benzenes: The Gu Synthesis of Rhazinal." In Organic Synthesis. Oxford University Press, 2015. http://dx.doi.org/10.1093/oso/9780190200794.003.0065.

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Sisir K. Mandal of Asian Paints R&amp;T Centre, Mumbai used (Tetrahedron Lett. 2013, 54, 530) a Ru catalyst to couple 2 with an electron-rich arene 1 to give 3. Jun-ichi Yoshida of Kyoto University (J. Am. Chem. Soc. 2013, 135, 5000) and John F. Hartwig of the University of California, Berkeley (J. Am. Chem. Soc. 2013, 135, 8480) also reported direct amination protocols. Tommaso Marcelli of the Politecnico di Milano and Michael J. Ingleson of the University of Manchester effected (J. Am. Chem. Soc. 2013, 135, 474) the electrophilic borylation of the aniline 4 to give 5. The regioselectivity of
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