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Relevant bibliographies by topics / Substitution reactions. Nucleophilic reactions. Benzene

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Academic literature on the topic 'Substitution reactions. Nucleophilic reactions. Benzene'

Author: Grafiati

Published: 4 June 2021

Last updated: 1 February 2022

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Journal articles on the topic "Substitution reactions. Nucleophilic reactions. Benzene"

1

Mclure, FI, RK Norris, and K. Wilson. "Nucleophilic Substitution Reactions of Thienyl Neopentyl Substrates." Australian Journal of Chemistry 40, no. 1 (1987): 49. http://dx.doi.org/10.1071/ch9870049.

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The reaction of the chlorides (4)-(6), which are both neopentylic and thenylic , were studied. The chloride (4), unlike its analogue (13) in the benzene series, undergoes ready solvolysis with alcohols to give the corresponding ethers, e.g. (7)-(9). The chlorides (5) and (6) react more slowly than (4) but undergo methanolysis to give the methyl ethers (11) and (12) respectively. In the dipolar aprotic solvents, dimethyl sulfoxide and dimethylformamide, the reactions of the chlorides (4), (5) and (6) with the thiolate salt (16) appear to proceed by an SN1-like, an SN(AEAE) and an SRNl process r

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2

Emokpae, Thomas A., Patrick U. Uwakwe, and Jack Hirst. "The mechanisms of nucleophilic substitution reactions of aromatic ethers with amines in benzene." Journal of the Chemical Society, Perkin Transactions 2, no. 4 (1991): 509. http://dx.doi.org/10.1039/p29910000509.

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EMOKPAE, T. A., P. U. UWAKWE, and J. HIRST. "ChemInform Abstract: The Mechanisms of Nucleophilic Substitution Reactions of Aromatic Ethers with Amines in Benzene." ChemInform 22, no. 28 (2010): no. http://dx.doi.org/10.1002/chin.199128055.

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4

Jain, Ajay K., Vinod K. Gupta, and Anurag Kumar. "Aromatic nucleophilic substitution reactions of oxime ethers with aliphatic primary and secondary amines in benzene." Journal of the Chemical Society, Perkin Transactions 2, no. 1 (1990): 11. http://dx.doi.org/10.1039/p29900000011.

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Leznoff, Clifford C., and David M. Drew. "The use of bisphthalonitriles in the synthesis of side-strapped 1,11,15,25-tetrasubstituted phthalocyanines." Canadian Journal of Chemistry 74, no. 3 (1996): 307–18. http://dx.doi.org/10.1139/v96-035.

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Nucleophilic aromatic substitution reactions of 3-nitrophthalonitrile yield 3-hydroxyphthalonitrile and 3-neopentoxyphthalonitrile, the latter of which condensed to 1,8,15,22-tetraneopentoxyphthalocyanine as a mixture of isomers. Bisphthalonitriles such as 1,3-bis(2′,3′-dicyanophenoxy)-2,2-dipentylpropane, 1,3-bis(2′,3′-dicyanophenoxy)-2,2-diethylpropane, 1,3-bis(2′,3′-dicyanophenoxy)-2,2-dioctylpropane, and 1,3-bis(2′,3′-dicyanophenoxy)-2-methyl-2-trityloxymethylpropane all gave bis-crown-like 1,11,15,25-tetrasubstituted phthalocyanines as pure compounds when treated with lithium octoxide in

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6

Postigo, Al, and Roberto A. Rossi. "A Novel Type of Nucleophilic Substitution Reactions on Nonactivated Aromatic Compounds and Benzene Itself with Trimethylsiliconide Anions." Organic Letters 3, no. 8 (2001): 1197–200. http://dx.doi.org/10.1021/ol015666s.

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7

Beier, Petr, Tereza Pastýříková, and George Iakobson. "Preparation of SF5Aromatics by Vicarious Nucleophilic Substitution Reactions of Nitro(pentafluorosulfanyl)benzenes with Carbanions." Journal of Organic Chemistry 76, no. 11 (2011): 4781–86. http://dx.doi.org/10.1021/jo200618p.

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Zhao, Zhensheng, Islam Jameel, and Graham K. Murphy. "Vicinal Dichlorination of o-Vinylbiphenyls and the Synthesis of 9-(Arylmethyl)fluorenes via Tandem Friedel–Crafts Alkylations." Synthesis 51, no. 13 (2019): 2648–59. http://dx.doi.org/10.1055/s-0037-1611562.

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Reacting ortho-vinylbiphenyls with (dichloroiodo)benzene (PhICl2) gives vicinal dichlorides, rapidly, and in excellent yield at room temperature. Treating the vic-dichlorides with 50 mol% AlCl3 in the presence of arene nucleophiles results in sequential intramolecular and intermolecular Friedel–Crafts alkylations to generate 9-(arylmethyl)fluorene derivatives. The dichlorination and alkylation reactions are operationally simple and tolerant of a variety of functional groups and substitution patterns, and give the products in moderate to excellent yield.

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9

Sekiguchi, Shizen, Hiromi Ishikura, Yukitoshi Hirosawa, and Nobuyuki Ono. "Aromatic nucleophilic substitution reactions of 1-dialkylamino-substituted activated benzenes with various amines in dimethyl sulfoxide." Tetrahedron 46, no. 16 (1990): 5567–78. http://dx.doi.org/10.1016/s0040-4020(01)87755-3.

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Beier, Petr, Tereza Pastyrikova, and George Iakobson. "ChemInform Abstract: Preparation of SF5Aromatics by Vicarious Nucleophilic Substitution Reactions of Nitro(pentafluorosulfanyl)benzenes with Carbanions." ChemInform 42, no. 38 (2011): no. http://dx.doi.org/10.1002/chin.201138043.

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Dissertations / Theses on the topic "Substitution reactions. Nucleophilic reactions. Benzene"

1

HADDAD-FAHED, OMAIMA. "Catalyse micellaire de reactions de substitution nucleophile aromatique comportant des reactifs electriquement charges." Paris 6, 1987. http://www.theses.fr/1987PA066419.

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2

Martin, Peter Arnold. "Nucleophilic substitution reactions of some polyhalogenated compounds." Thesis, Durham University, 1987. http://etheses.dur.ac.uk/6876/.

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Rate measurements for the reactions of a series of polyfluoro - and polychloro - pyridines with aniline and ammonia in 60/40 dioxan/water at 25ºC has shown that chlorine, when ortho and para to the position of attack, is activating with respect to fluorine, but at the position meta to the point of attack, chlorine and fluorine are virtually equivalent in their effect on reaction rate. The trifluoromethyl and nitrile groups were found to be activating relative to fluorine when ortho and para to the position of substitution and the nitrile group was thus found to be ortho/para directing. The ort

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3

Drew, S. M. "Photochemical nucleophilic substitution reactions of quinones and related systems." Thesis, University of Leeds, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.374182.

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Van, der Westhuizen Carl Johan. "Nucleophilic substitution reactions of α-haloketones : a computational study". Diss., University of Pretoria, 2017. http://hdl.handle.net/2263/63346.

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This dissertation describes the computational modelling of reactions between α-haloketones and various nucleophiles. Nucleophilic substitution reactions of α-haloketones (also known as α- halocarbonyls in literature) are utilised in synthetic laboratories to obtain 1,2-disconnections; which are typically difficult to obtain otherwise. To gain insight into these reactions, DFT modelling was carried out in this project, with further understanding into these reactions being obtained using Quantum Fragment Along Reaction Pathway (QFARP) which is an extension of Interacting Quantum Atoms (IQA

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5

Jones, Craig Warren. "Nucleophilic aromatic substitution using supported copper(I) reagents." Thesis, University of York, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.236184.

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Iagrossi, Anna. "Stereochemical studies of reactions of phosphate and thiophosphate esters." Thesis, University of Leicester, 1988. http://hdl.handle.net/2381/33748.

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Nucleophilic substitution reactions involving phosphate monoesters have been investigated. Two general syntheses of O-alkyl or O-aryl [16O,18O] thiophosphate monoesters are reported. An independent and general method for the determination of the enantiomeric excess of isotopically chiral thiophosphate monoesters has been developed and the absolute configurations of the diastereoisomers of (2R)-O-(O-ethyl thiophosphoryl)-3, 4S-dimethyl-5S-phenyl-l,3,2-oxazaphos- pholidin-2-one have been assigned. The solvolysis of p-nitrophenyl [R-16O,18O] thiophosphate in ethanol gives rise to ethyl [16O, 18O]

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7

Balan, Gayatri. "Studies on the nucleophilic substitution reactions of a dimeric cyclopentadienone." Diss., Columbia, Mo. : University of Missouri-Columbia, 2007. http://hdl.handle.net/10355/6265.

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Thesis (M.S.)--University of Missouri-Columbia, 2007.<br>The entire dissertation/thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file (which also appears in the research.pdf); a non-technical general description, or public abstract, appears in the public.pdf file. Title from title screen of research.pdf file (viewed on January 11, 2008) Includes bibliographical references.

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8

James, Rachel Anne. "Nucleophilic substitution reactions of (alkoxymethylene) dimethylammonium chloride and cyclopropane methodology." Thesis, Imperial College London, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.342180.

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9

Williams, Kenneth Bruce. "The effect of methyl groups on nucleophilic substitution reactions of chlorocyclotriphosphazenes." Diss., Virginia Polytechnic Institute and State University, 1985. http://hdl.handle.net/10919/49962.

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The reactions of methyl-substituted chlorocyclotriphosphazenes with aryl Grignard reagents and with bifunctional amines, aminoalcohols, and alkoxides were investigated. The characterization data for the compounds formed in the reactions of monomethylpentachlorocyclotriphosphazene and the Grignard reagents were found to be informative with respect to the extent and nature of the interaction between the phosphazene ring and its exocyclic substituents. This interaction was found to be responsible for significant effects on the reactions of the phosphazene ring with nucleophiles. The reactions o

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10

Drury, Christopher John. "Nucleophilic substitution and cyclisation reactions of some polyfluoro-heteroaromatic and polyfluoroaromatic compounds." Thesis, Durham University, 1994. http://etheses.dur.ac.uk/5845/.

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This thesis describes the reactions of some highly fluorinated aromatic and heteroaromatic compounds, in particular derivatives of naphthalene, quinoline and isoquinoline. Chapter 1 provides a general introduction to the preparation, reactions and applications of fluorine containing organic materials. Chapter 2 describes the reactions of some quinoline- and isoquinoline- thiolates with dimethyl acetylenedicarboxylate in an attempt to form six membered heterocycles. Chapter 3 describes nucleophilic substitution reactions of heptafluoro- quinoline and -isoquinoline with sulphur and oxygen nucleo

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Books on the topic "Substitution reactions. Nucleophilic reactions. Benzene"

1

N, Charushin Valery, and Plas, H. C. van der., eds. Nucleophilic aromatic substitution of hydrogen. Academic Press, 1994.

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2

Mieczkowski, Józef Bogusław. Zastosowanie reakcji substytucji nukleofilowej do pełnych syntez wybranych alkaloidów i nowych układów heterocyklicznych. Wydawnictwa Uniwersytetu Warszawskiego, 1990.

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Burgers, Martijn Hendrik Willem. Zeolite-catalyzed nucleophilic aromatic substitution reactions =: Nucleofiele aromatische substitutie-reakties gekatalyseerd door metaalhoudende zeolieten. Delft University Press, 1995.

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Burgers, Martijn Hendrik Willem. Zeolite-catalyzed nucleophilic aromatic substitution reactions =: Nucleofiele aromatische substitutie-reakties gekatalyseerd door metaalhoudende zeolieten. Delft University Press, 1995.

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5

Nucleophilic aromatic displacement: The influence of the nitro group. VCH Publishers, 1991.

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6

Burgers, Martijn Hendrik Willem. Zeolit-Catalyzed Nucleophilic Aromatic Substitution Reactions. Delft Univ Pr, 1995.

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7

Terrier, Francois. Modern Nucleophilic Aromatic Substitution. Wiley & Sons, Incorporated, John, 2013.

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8

Modern Nucleophilic Aromatic Substitution. Wiley-VCH Verlag GmbH, 2013.

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9

Terrier, Francois. Modern Nucleophilic Aromatic Substitution. Wiley & Sons, Incorporated, John, 2013.

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10

Terrier, Francois. Modern Nucleophilic Aromatic Substitution. Wiley & Sons, Limited, John, 2013.

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Book chapters on the topic "Substitution reactions. Nucleophilic reactions. Benzene"

1

Ross, Sidney D. "Nucleophilic Aromatic Substitution Reactions." In Progress in Physical Organic Chemistry. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470171806.ch2.

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2

Ila, Hiriyakkanavar, Anand Acharya, and Saravanan Peruncheralathan. "Domino Reactions Initiated by Nucleophilic Substitution." In Domino Reactions. Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527671304.ch4.

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3

Carey, Francis A., and Richard J. Sundberg. "Functional Group Interconversion by Nucleophilic Substitution." In Part B: Reactions and Synthesis. Springer Berlin Heidelberg, 2001. http://dx.doi.org/10.1007/978-3-662-39510-3_3.

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4

Laan, Wouter, and Paul C. J. Kamer. "Palladium-catalysed Allylic Nucleophilic Substitution Reactions, Artificial Metalloenzymes." In Encyclopedia of Metalloproteins. Springer New York, 2013. http://dx.doi.org/10.1007/978-1-4614-1533-6_547.

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Dax, Karl, and Martin Albert. "Rearrangements in the Course of Nucleophilic Substitution Reactions." In Topics in Current Chemistry. Springer Berlin Heidelberg, 2001. http://dx.doi.org/10.1007/3-540-44422-x_9.

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6

Katritzky, Alan R. "The Non-Chain Radicaloid Mechanism of Some Nucleophilic Substitution Reactions." In Substituent Effects in Radical Chemistry. Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-4758-0_30.

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7

Yaylayan, V., J. R. Jocelyn Paré, R. Laing, and P. Sporns. "Intramolecular Nucleophilic Substitution Reactions of Tryptophan and Lysine Amadori Rearrangement Products." In The Maillard Reaction in Food Processing, Human Nutrition and Physiology. Birkhäuser Basel, 1990. http://dx.doi.org/10.1007/978-3-0348-9127-1_12.

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Atkins, Peter. "Missile Deployment: Nucleophilic Substitution." In Reactions. Oxford University Press, 2011. http://dx.doi.org/10.1093/oso/9780199695126.003.0020.

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The equivalent of a heat-seeking missile in chemistry is a ‘nucleophile’, a lover of nuclei. The ‘missile’ in this case is a special sort of molecule which sniffs out not heat but positive electric charge, the charge of a nucleus glinting through depleted regions of electron cloud in a target molecule. A candidate for such a missile is a negatively charged ion, which can be attracted to the partially exposed positive charge of a nucleus in the target. With nucleus-sniffing in mind, you can perhaps appreciate that if it is possible to blow away some of the electron cloud from the region of a particular C atom in the target molecule, then the nucleophile will home in on that atom and perhaps attach to it. By management of the electron clouds and adroit choice of the incoming missile, therefore, it is possible to build where and what we want. You shouldn’t lose sight of the fact that the ‘missile’ doesn’t just fly through the air and smash into a molecule: it jostles past the solvent molecules, which move aside or sometimes block it and turn it back. When thinking about the reactions in this section, think of the target atom in a molecule as glowing with positive charge and the incoming missile, the reagent, as having an abundance of negative charge spread over at least one of its atoms. The target and missile are drawn together through the solvent, and might snap together, in a manner I shall describe, once they are close to one another. A missile’s successful hunt for a target might then result in reaction and the formation of a new compound. How are the target prepared and the missile launched? One procedure is to go the whole electrical hog and prepare a molecule with a full positive charge on the C atom that has been chosen to be the foundation of the new construction, the proposed site of reaction. The whole hog can be achieved by snipping out an atom that initially is attached to the C atom.

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9

Edenborough, Michael. "Nucleophilic Substitution Reactions." In Organic Reaction Mechanisms. CRC Press, 2017. http://dx.doi.org/10.1201/9781315273181-11.

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Chanda, A., and V. V. Fokin. "Nucleophilic Substitution Reactions." In Water in Organic Synthesis. Georg Thieme Verlag KG, 2012. http://dx.doi.org/10.1055/sos-sd-206-00527.

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Conference papers on the topic "Substitution reactions. Nucleophilic reactions. Benzene"

1

Peixoto, Bárbara Pereira, José Walkimar de M. Carneiro, and Rodolfo Goetze Fiorot. "Substituição nucleofílica alifática: qual o mecanismo preferencial? Estudo computacional dos efeitos da estrutura do substrato e solvente." In VIII Simpósio de Estrutura Eletrônica e Dinâmica Molecular. Universidade de Brasília, 2020. http://dx.doi.org/10.21826/viiiseedmol2020122.

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Nucleophilic aliphatic substitution reactions constitute important steps in the synthesis of substances with biological activity and industrial appeal, beyond to participating in steps in biosynthetic routes of natural products. Unimolecular (SN1) and bimolecular (SN2) pathways can be understood as limiting cases of a mechanistic continuum. In between them, borderline mechanisms are proposed. The preference for one path over another depends on several factors, such as the structure of the substrate, the nucleophile and the solvent used. This plurality is still a topic of discussion and needs f

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