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Relevant bibliographies by topics / Sulfenic acid

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Journal articles

Academic literature on the topic 'Sulfenic acid'

Author: Grafiati

Published: 4 June 2021

Last updated: 12 February 2022

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Journal articles on the topic "Sulfenic acid"

1

Yoshimura, Toshiaki, Eiichi Tsukurimichi, Satoru Yamazaki, Shinichi Soga, Choichiro Shimasaki, and Kiyoshi Hasegawa. "Synthesis of a stable sulfenic acid, trans-decalin-9-sulfenic acid." Journal of the Chemical Society, Chemical Communications, no. 18 (1992): 1337. http://dx.doi.org/10.1039/c39920001337.

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2

Gupta, Vinayak, and Kate S. Carroll. "Rational design of reversible and irreversible cysteine sulfenic acid-targeted linear C-nucleophiles." Chemical Communications 52, no. 16 (2016): 3414–17. http://dx.doi.org/10.1039/c6cc00228e.

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We report the design of linear C-nucleophiles that react with sulfenic acid in a covalent, reversible manner. We further establish that linear C-nucleophile moieties present in the rheumatoid arthritis drug, tofacitinib and natural product, curcumin also form covalent adducts with sulfenic acid.

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3

Tripolt, Robert, Ferdinand Belaj, and Edgar Nachbaur. "Eine unerwartet stabile Sulfensäure: 4,6-Dimethoxy-1,3,5-triazin-2-sulfensäure; Synthese, Eigenschaften, Molekül- und Kristallstruktur / Unexpectedly Stable Sulfenic Acid: 4,6-Dimethoxy-1,3,5-triazine-2-sulfenic Acid; Synthesis, Properties, Molecular and Crystal Structure." Zeitschrift für Naturforschung B 48, no. 9 (1993): 1212–22. http://dx.doi.org/10.1515/znb-1993-0909.

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4,6-Dimethoxy-1,3,5-triazine-2-sulfenic acid (1) was prepared by the reaction of 4,6-dimethoxy-1,3,5-triazine-2(1H)-thion (3) with 2-benzenesulfonyl-3-(p-nitrophenyl)-oxaziridine (2) in THF solution and isolated as a stable crystalline solid. The new compound was characterized by analytical and spectroscopic data (IR, 1H and 13C NMR, UV, MS) supported by MNDO-PM 3 calculations. UV spectrometry was used for exact determination of the ionization constant of 1(pKa = 5.86 ± 0.02 at 20°C). According to 13C NMR data and X-ray analysis the sulfenic acid 1 adopts the sulfenyl structure (R—SOH) in the

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4

Sano, Tsukasa, Ryosuke Masuda, Shohei Sase, and Kei Goto. "Isolable small-molecule cysteine sulfenic acid." Chemical Communications 57, no. 20 (2021): 2479–82. http://dx.doi.org/10.1039/d0cc08422k.

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A small-molecule cysteine sulfenic acid (Cys–SOH) with ‘shelf stability’ protected by a molecular cradle was synthesized by direct oxidation of a thiol with H<sub>2</sub>O<sub>2</sub>. Its crystal structure and biologically relevant reactivity were elucidated.

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5

Tureček, František, Libor Brabec, Tomáš Vondrák, Vladimír Hanuš, Josef Hájíček, and Zdeněk Havlas. "Sulfenic acids in the gas phase. Preparation, ionization energies and heats of formation of methane-, ethene-, and benzenesulfenic acid." Collection of Czechoslovak Chemical Communications 53, no. 9 (1988): 2140–58. http://dx.doi.org/10.1135/cccc19882140.

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Methane-, ethene-, and ethynesulfenic acids were generated in the gas phase by flash-vacuum pyrolysis of the corresponding tert-butyl sulfoxides at 400 °C and 10-4 Pa. Benzenesulfenic acid was prepared from phenyl 3-buten-1-yl sulfoxide at 350 °C and 10-4 Pa. The sulfenic acids were characterized by mass spectrometry Threshold ionization energies (IE) were measured as IE(CH3SOH) = 9·07 ± 0·03 eV, IE(CH2=CHSOH) = 8·70 ± 0·03 eV, IE(HCCSOH) = 8·86 ± 0·04 eV, and IE(C6H5SOH) = 8·45 + 0·03 eV. Radical cations [CH3SOH].+, [CH2=CHSOH].+, and [HCCSOH].+ were generated by electron-impact-induced loss

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6

Chipiso, Kudzanai, and Reuben H. Simoyi. "Kinetics and Mechanism of Oxidation of d-Penicillamine in Acidified Bromate and Aqueous Bromine." Australian Journal of Chemistry 69, no. 11 (2016): 1305. http://dx.doi.org/10.1071/ch16050.

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The oxidation of the biologically active compound d-penicillamine (Depen) by acidic bromate has been studied. The stoichiometry of the reaction is strictly 1 : 1, in which Depen is oxidized only as far as the sulfonic acid with no cleavage of the C–S bond to yield sulfate. Electrospray ionization spectroscopy shows that Depen is oxidized through addition of oxygen atoms on the sulfur centre to successively yield sulfenic and sulfinic acids before the product sulfonic acid. In conditions of excess Depen over the oxidant, sulfenic acid was not observed. Instead, nearly quantitative formation of

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7

Schwan, Adrian L., and Stefan C. Söderman. "Discoveries in Sulfenic Acid Anion Chemistry." Phosphorus, Sulfur, and Silicon and the Related Elements 188, no. 4 (2013): 275–86. http://dx.doi.org/10.1080/10426507.2012.729116.

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8

Carballal, S., B. Alvarez, L. Turell, H. Botti, B. A. Freeman, and R. Radi. "Sulfenic acid in human serum albumin." Amino Acids 32, no. 4 (2006): 543–51. http://dx.doi.org/10.1007/s00726-006-0430-y.

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9

Freeman, Fillmore. "Mechanism of the cysteine sulfenic acid O-sulfenylation of 1,3-cyclohexanedione." Chem. Commun. 50, no. 31 (2014): 4102–4. http://dx.doi.org/10.1039/c4cc00925h.

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10

Barattucci, Anna, Tania M. G. Salerno, Franz H. Kohnke, Teresa Papalia, Fausto Puntoriero, and Paola Bonaccorsi. "Curcumin-based sulfenic acid as a light switch for the binding of biothiols." New Journal of Chemistry 44, no. 45 (2020): 19508–14. http://dx.doi.org/10.1039/d0nj04834h.

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