Academic literature on the topic 'Sulfones – Analyse'

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Journal articles on the topic "Sulfones – Analyse"

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Park, In-Woo, M. V. Ramana Reddy, E. Premkumar Reddy, and Jerome E. Groopman. "Evaluation of Novel Cell Cycle Inhibitors in Mantle Cell Lymphoma." Blood 108, no. 11 (2006): 4748. http://dx.doi.org/10.1182/blood.v108.11.4748.4748.

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Abstract Signature abnormalities in the cell cycle and apoptotic pathway have been identified in mantle cell lymphoma (MCL), affording the opportunity to develop targeted therapies. Here, we report on a novel class of kinase inhibitors, styryl sulfones, that differ from prior cell cycle inhibitors in that they are not related to purines or pyrimidines. We observed that two closely related compounds, ON013100 and ON01370, altered the growth and cell cycle status of MCL lines and potently inhibited the expression of several important molecules, including CDK4, p53, MDM2, cyclin D, and cyclin B.
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Mattern, Gregory C., Gilbert D. Parker, Debra L. Green, and Gregory L. Yeutter. "Determination of Phenol Sulfone, Phenol Sulfoxide, and Phenol Sulfonic Acid Metabolites of Fenamiphos in Soil by Liquid Chromatography." Journal of AOAC INTERNATIONAL 78, no. 5 (1995): 1286–93. http://dx.doi.org/10.1093/jaoac/78.5.1286.

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Abstract An analytical method has been developed to quantitate fenamiphos phenol sulfone, phenol sulfoxide, and phenol sulfonic acid in soil. Both control and analyte-fortified soil samples from Fresno, CA, were extracted with methanol–water (2 + 1) and partitioned with ethyl acetate. Fenamiphos phenol sulfone and phenol sulfoxide were determined by re-versed-phase liquid chromatography (LC) with UV detection at 240 nm after cleanup by silica solid-phase extraction. Fenamiphos phenol sulfonic acid was determined by reversed-phase ion-pairing LC with UV detection at 240 nm after cleanup by amin
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Aroney, MJ, RJW LeFevre, RK Pierens, HJ Stootman, and MGM Yong. "Dipole Moments, Kerr Constants and Solute Conformations of the Aryl Methyl Sulfones p-XC6H4S(02)CH3 (X = H, Cl, BR or NO2)." Australian Journal of Chemistry 40, no. 3 (1987): 619. http://dx.doi.org/10.1071/ch9870619.

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Measurements are reported of the infinite-dilution dipole moments and molar Kerr constants of dimethyl sulfone and of the four aryl methyl sulfones p-XC6H4S(02)CH3 (X = H, Cl, Br or NO2) dissolved in carbon tetrachloride or dioxan at 298 K and under light of 589 nm. The experimental data are analysed to obtain information on the solution-state conformations in relation to steric and electromeric effects operative between the aryl and methanesulfonyl groups.
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Dinnebier, Robert, Natalia Sofina, Lars Hildebrandt, and Martin Jansen. "Crystal structures of the trifluoromethyl sulfonates M(SO3CF3)2 (M = Mg, Ca, Ba, Zn, Cu) from synchrotron X-ray powder diffraction data." Acta Crystallographica Section B Structural Science 62, no. 3 (2006): 467–73. http://dx.doi.org/10.1107/s0108768106009517.

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The crystal structures of divalent metal salts of trifluoromethyl sulfonic acid (`trifluoromethyl sulfonates') M(SO3CF3)2 (M = Mg, Ca, Ba, Zn, Cu) were determined from high-resolution X-ray powder diffraction data. Magnesium, calcium and zinc trifluoromethyl sulfonate crystallize in the rhombohedral space group R\bar3. Barium trifluoromethyl sulfonate crystallizes in the monoclinic space group I2/a(C2/c) and copper trifluoromethyl sulfonate crystallizes in the triclinic group P\bar1. Within the crystal structures the trifluoromethyl sulfonate anions are arranged in double layers with the apola
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Schneider, Thomas H., Max Rieger, Kay Ansorg, et al. "Vinyl sulfone building blocks in covalently reversible reactions with thiols." New Journal of Chemistry 39, no. 7 (2015): 5841–53. http://dx.doi.org/10.1039/c5nj00368g.

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A combination of quantum-chemical calculations, Hirshfeld surface analyses and reactivity studies predicts how to turn vinyl sulfones into electrophiles that react covalently but reversibly with thiols.
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Thiehoff, C., M. C. Holland, C. Daniliuc, K. N. Houk, and R. Gilmour. "Can acyclic conformational control be achieved via a sulfur–fluorine gauche effect?" Chemical Science 6, no. 6 (2015): 3565–71. http://dx.doi.org/10.1039/c5sc00871a.

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Herein detailed conformational analyses of β-fluorosulfides, -sulfoxides and -sulfones are disclosed, thus extending the scope of the fluorine gauche effect to the 3<sup>rd</sup> Period (X = SR, SOR, SO<sub>2</sub>R; ϕ<sub>FCCS</sub> ≈ 60°).
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Zhang, Su Xia, Yi Hong Tang, Yan Lu, and Ya Ming Niu. "Synthesis, Characterization of Poly(Aryl Ether Sulfone)s Based on Naphthalene Isomers." Advanced Materials Research 490-495 (March 2012): 3698–702. http://dx.doi.org/10.4028/www.scientific.net/amr.490-495.3698.

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Six new poly(aryl ether sulfone)s were synthesized from 1,5-, 2,6- and 2,7- Bis-(4-fluorosulfonyl)naphthalene isomers with different diphenol. The structure of the poly(aryl ether sulfone)s were characterized by IR spectroscopy and elemental analysis, and the results were in good agreement with the expected structures. The glass transition temperatures were found to be in the range 219-236oC by DSC thermal analysis. The WAXD and thermogravimetric analyses revealed amorphous morphology and excellent thermal stability of the polymers.
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Al-Ghamdi, Youssef O., Khalid A. Alamry, Mahmoud A. Hussein, Hadi M. Marwani, and Abdullah M. Asiri. "Sulfone-modified chitosan as selective adsorbent for the extraction of toxic Hg(II) metal ions." Adsorption Science & Technology 37, no. 1-2 (2018): 139–59. http://dx.doi.org/10.1177/0263617418818957.

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In this study, a new category of sulfone-modified chitosan derivatives as surface-selective adsorbents for the extraction of toxic Hg(II) metal has been synthesized in good yield. Sulfone-modified chitosan/5–20 based on variable loading of the corresponding phenacyl bromide (5, 10, 15, and 20% with respect to the original weight of the pure chitosan) was synthesized. The β-ketosulfone derivative, namely 1–(4-bromophenyl)-2-(phenylsulfonyl)ethanone, was first prepared by treatment of the corresponding phenacyl bromide with a sufficient amount of sodium benzene sulfinate; its chemical structure
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Teixeira, Cátia, José R. B. Gomes, Thierry Couesnon, and Paula Gomes. "Molecular docking and 3D-quantitative structure activity relationship analyses of peptidyl vinyl sulfones: Plasmodium Falciparum cysteine proteases inhibitors." Journal of Computer-Aided Molecular Design 25, no. 8 (2011): 763–75. http://dx.doi.org/10.1007/s10822-011-9459-4.

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Cocchi, Marina, Dario Iarossi, M. Cristina Menziani, Pier G. De Benedetti, and Chiaro Frassineti. "Correlation and multivariate analyses of spectroscopic and dihydropteroate synthase inhibitory activity data in 4-aminoaryl (multisubstituted aryl) sulfones." Structural Chemistry 3, no. 2 (1992): 129–37. http://dx.doi.org/10.1007/bf00671811.

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Dissertations / Theses on the topic "Sulfones – Analyse"

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Gastaldi, Stéphane. "Les radicaux sulfonyle en synthèse organique : application à la synthèse de l'acide kai͏̈nique." Aix-Marseille 3, 1997. http://www.theses.fr/1997AIX30091.

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L'acide kainique est une pyrrolidine trisubstituee en position 2, 3 et 4, la stereochimie des substituants est trans au niveau des carbones 2 et 3, et cis au niveau des carbones 3 et 4. L'addition radicalaire de tsseph sur des 4-aza-1,6-dienes correctement fonctionnalises est une voie d'acces au squelette carbone de l'acide -kainique. Toutefois, l'elimination, via un selenoxyde, du groupe phenylselanyle n'est pas regioselective et ne permet pas l'acces au motif isopropenyle de l'acide kainique avec des rendements satisfaisants. Le rearrangement radicalaire des sulfones allyliques a permis en u
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Saaedan, Ahmed Mohamed. "Photoréactivité en phase hétérogène : dimérisation en phase solide en série benzothiophénique et oxydation photocatalytique de composés insaturés." Montpellier 2, 1992. http://www.theses.fr/1992MON20078.

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La photodimerisation, en phase solide, de sulfones de benzothiophenes (premiere partie) correspond a un processus topochimique controle par la structure des composes de depart (orientation des molecules dans la maille cristalline et distances entres les doubles liaisons impliquees dans la dimerisation). Les resultats sont justifies par analyse cristallographique des monomeres et des dimeres et confirmes, pour ces derniers, par des calculs de mecanique moleculaire. La deuxieme partie etudie l'oxydation photocatalytique, en presence d'un semi-conducteur irradie, d'alkyls benzenes et de different
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Badami, Anand Shreyans. "Morphological and Structure-Property Analyses of Poly(arylene ether sulfone)-Based Random and Multiblock Copolymers for Fuel Cells." Diss., Virginia Tech, 2007. http://hdl.handle.net/10919/29469.

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The commercialization of proton exchange membrane (PEM) fuel cells depends largely upon the development of PEMs whose properties are enhanced over current perfluorinated sulfonic acid PEMs. Understanding how a PEMâ s molecular weight and morphology affect its relevant performance properties is essential to this effort. Changes in molecular weight were found to have little effect on the phase separated morphologies, water uptake, and proton conductivities of random copolymers. Changes in block length, however, have a pronounced effect on multiblock copolymers, affecting surface and bulk mor
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Masuda, Marie. "Covalent modification of endogenous proteins for functional analyses and drug discovery based on N-sulfonyl pyridone chemistry." Kyoto University, 2018. http://hdl.handle.net/2433/235991.

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Westmeier, Johannes [Verfasser], and Paultheo von [Akademischer Betreuer] Zezschwitz. "Kupfer- und Rhodium-katalysierte asymmetrische Additionen an Cycloalkenone und analoge N-Sulfonyl-Imine / Johannes Westmeier. Betreuer: Paultheo von Zezschwitz." Marburg : Philipps-Universität Marburg, 2015. http://d-nb.info/1069375152/34.

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Raghavapuram, Shravanthi. "Tailoring the Degree of Branching in Hyperbranched Poly (arylene ether sulfone)s and Poly(arylene ether ketone)s prepared via an A2 + BB′B″ Approach." Wright State University / OhioLINK, 2009. http://rave.ohiolink.edu/etdc/view?acc_num=wright1261430736.

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De, Castro Emmanuelle. "Le frottement des toles galvanisées en emboutissage : étude par tof-sims de la réactivité de surface vis-à- vis de l'acide oléique et des sulfonates de calcium." Paris, ENMP, 2003. http://www.theses.fr/2003ENMP1137.

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Schory, David Henry. "Quantum Chemical Investigations of Nucleophilic Aromatic Substitution Reactions and Acid Dissociations of Aliphatic Carboxylic Acids." Wright State University / OhioLINK, 2009. http://rave.ohiolink.edu/etdc/view?acc_num=wright1253480264.

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Qian, Yu. "Analyser le gène PKC-2 chez Caernorhabditis elegans et crible les mutants contre sérotonine chez le C. elegans souche pkc-2 (ok328)." Phd thesis, Université Claude Bernard - Lyon I, 2009. http://tel.archives-ouvertes.fr/tel-00712129.

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La myopathie de Duchenne est une maladie génétique qui se caractérise principalement par une dégénérescence progressive des muscles squelettiques dont la cause est l'absence de dystrophine fonctionnelle dans les muscles. A ce jour, il n'existe toujours pas de traitement efficace contre ces maladies. Comme le plus grand gène connu chez l'Homme, la dystrophine code pour une protéine de 427kDa. La protéine connecte l'actine avec le DAPC (Dystrophin Associated Protein Complex) dans les muscles striés. Pour l'instant, il y a 3 hypothèses concernant le mécanisme du DMD. L'absence de la dystrophine p
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Perrin, Jean-Christophe. "Etude expérimentale multi-échelles de la dynamique de l'eau dans les membranes ionomères utilisées en pile à combustible." Phd thesis, Grenoble 1, 2006. http://tel.archives-ouvertes.fr/tel-00115418.

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Cette étude présente une démarche expérimentale originale permettant de sonder la dynamique de l'eau dans les membranes polymères échangeuses d'ions utilisées pour l'application pile à combustible. Grâce à l'utilisation de trois techniques complémentaires, la diffusion des molécules d'eau a été suivie à l'échelle moléculaire (diffusion quasi-élastique des neutrons ; 1 pico s < t < 1 nano s), à l'échelle macroscopique (RMN à gradient de champ pulsé ; 1 milli s < t < 1 s) et à l'échelle dite « intermédiaire » (relaxométrie RMN ; 1 nano s < t < 10 micro sec). Les expériences ont été menées en fon
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Book chapters on the topic "Sulfones – Analyse"

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De Benedetti, P. G. "Molecular modeling and quantitative structure-activity analysis of antibacterial sulfanilamides and sulfones." In Progress in Drug Research / Fortschritte der Arzneimittelforschung / Progrès des recherches pharmaceutiques. Birkhäuser Basel, 1991. http://dx.doi.org/10.1007/978-3-0348-7136-5_5.

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Bhikhabhai, Rama, Mattias Algotsson, Ulrika Carlsson, et al. "Amino Acid Sequencing of Sulfonic Acid-Labeled Tryptic Peptides Using Post-Source Decay and Quadratic Field MALDI-ToF Mass Spectrometry." In Methods in Proteome and Protein Analysis. Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/978-3-662-08722-0_19.

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Rivera-Rubero, Selimar, and Steven Baldelli. "Sum Frequency Generation Spectroscopy and Electrochemical Analysis of the 1-Butyl-3-methylimidazolium Bis{(trifluoromethyl)sulfonyl}amide Double Layer Structure on the Platinum Electrode." In ACS Symposium Series. American Chemical Society, 2009. http://dx.doi.org/10.1021/bk-2009-1030.ch020.

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"2,2′-Azinobis- (3-Ethylbenzothiazoline-6-Sulfonic Acid)." In Flow Injection Analysis of Food Additives. CRC Press, 2015. http://dx.doi.org/10.1201/b19644-45.

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"Effects of Doping and Post-Treatments on PANI Films." In Advances in Chemical and Materials Engineering. IGI Global, 2020. http://dx.doi.org/10.4018/978-1-5225-9896-1.ch005.

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It is well known that the sample preparation, experimental measurement, and technique have played a vital role in empirical research work. In this chapter, the detailed discussions on the doping and various post-treatments on the PANI thin films have been made. The in-depth studies on gold, silver, aluminum, lithium, HCl, and camphor sulfonic acid (CSA) doped PANI nanocomposites and thin films have been undertaken in this chapter, followed by discussing the effect of post-annealing treatment and ion reaction medium. The impact of different doping and post-treatment on the properties of PANI films viz. microstructural, optical-electrical, thermal, etc., have been analyzed herein. The structural and optoelectrical properties of PANI films and its nanocomposites have also been discussed in which metal-nanoparticles inserted PANI films achieve particular consideration due to its relatively thought-provoking non-linear optical properties.
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CHANG, J. Y., R. KNECHT, P. JENOE, and S. VEKEMANS. "AMINO ACID ANALYSIS AT THE FEMTOMOLE LEVEL USING THE DIMETHYLAMINOAZOBENZENE SULFONYL CHLORIDE PRECOLUMN DERIVATIZATION METHOD: Potential and limitation." In Techniques in Protein Chemistry. Elsevier, 1989. http://dx.doi.org/10.1016/b978-0-12-682001-0.50038-5.

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Conference papers on the topic "Sulfones – Analyse"

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Ionita, Mariana. "Molecular Modeling for Calculation of Mechanical Properties of Polyaniline-Carbon-Nanotubes." In ASME 2010 10th Biennial Conference on Engineering Systems Design and Analysis. ASMEDC, 2010. http://dx.doi.org/10.1115/esda2010-24833.

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Atomistic models of polyaniline (PANI)-single walled carbon nanotubes (CNTs) were built in order to assess the effect of quantity and quality of CNTs and temperature on the calculated mechanical properties of PANI. Three different types of CNTs were considered: single walled carbon nanotubes m-polyaminobenzene sulfonic acid functionalized (CNTs-PABS), single walled carbon nanotubes octadecylamine functionalized (CNTs-ODA) and single walled carbon nanotubes carboxylic acid functionalized (CNTs-CX). Atomistic models were built for PANI-functionalized CNTs with a range of CNTs content, contained
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Chen, Peng-Yu, Wei-Hui Chen, and Che-Wun Hong. "Nanofludic Analysis on Methanol Crossover of Direct Methanol Fuel Cells." In ASME 2008 First International Conference on Micro/Nanoscale Heat Transfer. ASMEDC, 2008. http://dx.doi.org/10.1115/mnht2008-52095.

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Direct methanol fuel cells (DMFCs) are considered as a competitive power source candidate for portable electronic devices. Nafion® has been widely used for the electrolyte of DMFCs because of its good proton conductivity and high chemical and mechanical stability. However, the major problem that must be solved before commercialization is the high methanol crossover through the membrane. There are a number of studies on experiments about the methanol crossover rate through the membrane but only few theoretical investigations have been presented [1–3]. In this paper, an atomistic model [4] is pr
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Pois, P. D., and W. G. M. Agterof. "Qualitative and Quantitative Analysis by High-Performance Liquid Chromatography of Synthetic Alkylaryl Sulfonates: Surfactants for Potential Application in Enhanced Oil Recovery." In SPE Oilfield and Geothermal Chemistry Symposium. Society of Petroleum Engineers, 1985. http://dx.doi.org/10.2118/13571-ms.

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Liu, Ya, Amy T. Kan, Chao Yan, Fei Wang, Lu Wang, and Mason B. Tomson. "An Assay Method for the Detection of all Scale Inhibitors at Extremely low Concentration." In SPE International Oilfield Scale Conference and Exhibition. SPE, 2014. http://dx.doi.org/10.2118/spe-169762-ms.

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Abstract Accurate detection of scale inhibitors has always been vitally important to monitor scale treatment during oil and gas production. However, there remains an ongoing challenge to analyze scale inhibitors at low concentrations, especially with polymeric scale inhibitors. This paper presents an assay method designed to detect all types of scale inhibitors, especially at low concentrations, and an expert program developed to guide the method. The program guides the preparation of a field brine barite solution at a fixed barite super-saturation. Scale inhibitor concentration is then measur
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Berechet, Mariana Daniela, Demetra Simion, Maria Stanca, et al. "Antibacterial and antioxidant activities of lemon balm (Melissa officinalis L.) essential oil." In The 8th International Conference on Advanced Materials and Systems. INCDTP - Leather and Footwear Research Institute (ICPI), Bucharest, Romania, 2020. http://dx.doi.org/10.24264/icams-2020.ii.2.

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Lemon balm (Melissa officinalis L.) belongs to the Lamiaceae family. Essential oil extracted from the aerial parts of lemon balm has been investigated for the protection of fruits during storage, as insecticidal, as well as in medicine, due to its bioactive properties. In this paper, the composition and identification of components from Melissa officinalis L. essential oil were determined by gas chromatography coupled with mass spectrophotometry (GC/MS) analysis. Total phenol content (TPC) and the scavenging activity towards 2,2-diphenyl-1-picrylhydrazyl (DPPH·) and 2,2′-azino-bis (3-ethylbenz
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Artemev, Alexandr, Elena Veselova, Irina Nikitina, and Galina Viktorovna. "RECOVERY OF NEPHELINE FROM APATITE FLOTATION TAILINGS OF APATITE-NEPHELINE COMPLEX MINERAL COMPOSED ORES." In GEOLINKS Conference Proceedings. Saima Consult Ltd, 2021. http://dx.doi.org/10.32008/geolinks2021/b2/v3/19.

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"The recovery of all possible useful components from ores corresponds to modern approach to the mineral raw materials processing and provides a reduction in the amount of waste sent to tailings dumps. The increasing complexity of the mineral composition of the ore leads to the fact that the existing beneficiation methods and regimes do not provide the necessary quality of the obtained concentrates. This study shows the peculiarities of nepheline recovery from apatite flotation tailings of apatite-nepheline ores with low nepheline fraction. Two reagent regimes were tested for nepheline reverse
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Bolotov, Vasiliy Alexandrovich, Serguei Fedorovich Tikhov, Konstantin Radikovich Valeev, Vladimir Timurovich Shamirzaev, and Valentin Nikolaevich Parmon. "SELECTIVE FORMATION OF LINEAR ALPHA-OLEFINS VIA MICROWAVE CATALYTIC CRACKING OF LIQUID STRAIGHT-CHAIN ALKANES." In Ampere 2019. Universitat Politècnica de València, 2019. http://dx.doi.org/10.4995/ampere2019.2019.9894.

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Linear even-carbon-number alpha-olefins (LAO) with four or more carbon atoms are important compounds of high demand in chemical industry as precursors of a wide range of value-added chemicals [1]. LAO are used as co-monomers for polyethylene production, for the production of alcohols (mainly in detergents and plasticizers) and for synthesis of polyalphaolefins (used in synthetic lubricants). Alpha-olefins (C4, C6, C8 and C10) are mainly used to produce poly(vinyl chloride) plasticizers, high-density and linear low-density polyethylene to impart the stress-crack resistance. C10–C14 alpha-olefin
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