Academic literature on the topic 'Sulfonium ion'

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Journal articles on the topic "Sulfonium ion"

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Kooter, Ingeborg M., Nicole Moguilevsky, Alex Bollen, et al. "The Sulfonium Ion Linkage in Myeloperoxidase." Journal of Biological Chemistry 274, no. 38 (1999): 26794–802. http://dx.doi.org/10.1074/jbc.274.38.26794.

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Kumar, Ashwani, and Chullikkattil P. Pradeep. "Aromatic sulfonium polyoxomolybdates: tuning the photochromic properties through substitutions on the counter ion moiety." CrystEngComm 20, no. 19 (2018): 2733–40. http://dx.doi.org/10.1039/c8ce00345a.

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A series of aromatic sulfonium Keggin hybrids have been developed which exhibited excellent photochromic properties under UV irradiation. The photo-coloration speed of these hybrids could be fine-tuned by changing the substituents on the sulfonium counter ion moiety.
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Melnyk, Michael C., and Kenneth L. Busch. "POSITIVE ION LIQUID SECONDARY ION MASS SPECTRA OF AROMATIC SULFONIUM SALTS." Phosphorus, Sulfur, and Silicon and the Related Elements 122, no. 1 (1997): 287–98. http://dx.doi.org/10.1080/10426509708043517.

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Ardiansah, Bayu, Hiroki Tanimoto, Takenori Tomohiro, Tsumoru Morimoto, and Kiyomi Kakiuchi. "Sulfonium ion-promoted traceless Schmidt reaction of alkyl azides." Chemical Communications 57, no. 70 (2021): 8738–41. http://dx.doi.org/10.1039/d1cc02770k.

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Schmidt reaction by sulfonium ions is described. The bond scission reaction through 1,2-migration was achieved without any trace of the activators. The one-pot substitution reactions were also demonstrated.
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Lewis, Charles A., and Richard Wolfenden. "Sulfonium Ion Condensation: The Burden Borne by SAM Synthetase." Biochemistry 57, no. 26 (2018): 3549–51. http://dx.doi.org/10.1021/acs.biochem.8b00477.

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Mensink, Rens A., Hidde Elferink, Paul B. White, Nathalie Pers, Floris P. J. T. Rutjes, and Thomas J. Boltje. "A Study on Stereoselective Glycosylations via Sulfonium Ion Intermediates." European Journal of Organic Chemistry 2016, no. 27 (2016): 4656–67. http://dx.doi.org/10.1002/ejoc.201600898.

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Maji, Tanmoy, Sanjib Banerjee, Avijit Bose, and Tarun K. Mandal. "A stimuli-responsive methionine-based zwitterionic methacryloyl sulfonium sulfonate monomer and the corresponding antifouling polymer with tunable thermosensitivity." Polymer Chemistry 8, no. 20 (2017): 3164–76. http://dx.doi.org/10.1039/c7py00460e.

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This report describes a dual pH- and thermo-responsive methionine-based zwitterionic methacryloyl sulfonium sulfonate monomer and the corresponding zwitterionic antifouling polymer with ion-induced tunable thermosensitivity.
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Ghavami, Ahmad, Blair D. Johnston, Matthew D. Maddess, et al. "Synthesis of 1,4-anhydro-D-xylitol heteroanalogues of the naturally occurring glycosidase inhibitor salacinol and their evaluation as glycosidase inhibitors." Canadian Journal of Chemistry 80, no. 8 (2002): 937–42. http://dx.doi.org/10.1139/v02-078.

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The syntheses of two 1,4-anhydro-D-xylitol heteroanalogues (8 and 9) of the naturally occurring sulfonium ion, salacinol (3), containing a sulfur or nitrogen atom in the ring are described. Salacinol (3) is one of the active principles in the aqueous extracts of Salacia reticulata that are traditionally used in Sri Lanka and India for the treatment of Type 2 diabetes. The synthetic strategy relies on the nucleophilic attack of sulfur or nitrogen analogues of 1,4-anhydro-D-xylitol at the least-hindered carbon of 2,4-O-benzylidene-L-erythritol-1,3-cyclic sulfate. The sulfonium ion 8 inhibited ba
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Kramer, Jessica R., Nathan W. Schmidt, Kristine M. Mayle, Daniel T. Kamei, Gerard C. L. Wong, and Timothy J. Deming. "Reinventing Cell Penetrating Peptides Using Glycosylated Methionine Sulfonium Ion Sequences." ACS Central Science 1, no. 2 (2015): 83–88. http://dx.doi.org/10.1021/acscentsci.5b00054.

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Lequan, M., R. M. Lequan, P. Delhaes, and C. Hauw. "New Examples of Ternary Organic Conductors: Sulfonium Ion Radical Salts." Molecular Crystals and Liquid Crystals 120, no. 1 (1985): 353–56. http://dx.doi.org/10.1080/00268948508075818.

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Dissertations / Theses on the topic "Sulfonium ion"

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Son, Ea-Ji-Ru. "Studies on Resolution of Enantiomeric Dialkylaryl Sulfonium Ions with NMR Shift Reagents." TopSCHOLAR®, 1997. http://digitalcommons.wku.edu/theses/358.

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Praseodymium(III) NMR shift reagent, which is an upfield shift reagent, is focused on for assessment of enantiomeric excess and resolution of methyl sulfonium ions. A series of alkylmethylphenylsulfonium ions were analyzed, where alkyl is ethyl (I), butyl(H), octyl (III), and benzyl(IY). The praseodymium agent gives base-lined resolution of the ortho hydrogens resonance for I and IH. All spectra are strongly temperature-dependent. I is shifted more than ED, consistent with a steric effect. Assignments for I were made by gradually increasing the concentration of the shift reagent and by analyzi
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GHANIMI, AHMED. "Rupture cathodique de liaison carbone-heteroatome des ethers, des thioethers et des ions sulfonium." Rennes 1, 1995. http://www.theses.fr/1995REN10022.

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Ce travail decrit de nouvelles donnees concernant la coupure cathodique de liaisons carbone-oxygene et carbone-soufre, soit a l'electrode de travail, soit en solution quand le transfert d'electron a lieu en phase homogene. Ainsi, le comportement cathodique des hexaalkoxytriphenylenes a ete etudie. Il est montre que dans les conditions experimentales choisies, la reaction cathodique est limitee a une monocoupure bielectronique. Ceci a permis l'obtention de nouveaux triphenylenes dissymetriques. De cette facon, la methode cathodique permet d'acceder a des triphenylenes associant deux sites compl
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Widehammar, Hugo. "Molecular insight into ion interactions at charged interfaces exposing sulfonate headgroups." Thesis, KTH, Yt- och korrosionsvetenskap, 2021. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-289861.

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Hur elektrolytlösningar interagerar med laddade ytor är viktigt för många fenomen. I detta arbete undersöktes samspelet mellan flera joner med en negativt laddad yta som exponerade sulfonat funktionella grupper mot lösning. Särskild vikt lades på deprotoneringsbeteendet vid ytan. Samspelet mellan olika joner och sulfonatgruppen hade inte tidigare beaktats ur ett molekylärt perspektiv. Här användes ett Langmuir-monolager bestående av dokosan-1-sulfonsyra deponerat på olika elektrolytlösningar som modellsystem. För att studera molekylära interaktioner mellan ytan och elektrolyterna användes Vibr
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Li, Jing. "Synthesis of Donor-based Analogues as Inhibitors of Mycobacterial Glycosyltransferases." Phd thesis, 2009. http://hdl.handle.net/10048/869.

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Tuberculosis (TB) is the disease arising from infection by Mycobacterial tuberculosis and kills millions of people every year. Difficulties in the treatment of TB and the emergence of multiple-drug resistant and extreme-drug resistant M. tuberculosis strains have increased interest in finding new antimycobacterial agents. The cell wall of mycobacteria is essential for the survival of these bacteria and enzymes involved in its assembly are key targets for anti-mycobacterial chemotherapy. One of the largest components of the cell wall is the arabinogalactan, which is composed of arabinofurano
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Balaji, Pandur Venkatesan. "Studies on the Stereoselective Geminal and Vicinal Heterodifunctionalization of Alkenes." Thesis, 2016. http://hdl.handle.net/2005/3101.

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The thesis entitled “Studies on the Stereoselective Geminal and Vicinal Heterodifunctionalization of Alkenes” consists of three chapters. Chapter 1: Part A: Bromonium Ion Mediated Stereoselective Geminal Aminooxygenation of Vinylarenes In this part (part-A) of Chapter 1, the development and mechanistic studies of the first method for the non-Wacker intermolecular geminal aminooxygenation of vinylarenes (styrenes) has been presented (Scheme 1). Sheme 1 The role of the substituent on controlling the competitive vicinal and geminal addition pathways has been studied. It was found that the unsu
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Lien, Yi-Hsing, and 練易鑫. "Assessment of Chitosan Mixed Matrix and Sulfonic Chitosan Matrix as Copper Ion Adsorbents." Thesis, 2008. http://ndltd.ncl.edu.tw/handle/73618295629793857599.

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碩士<br>國立臺灣大學<br>化學工程學研究所<br>96<br>In this study, chitosan mixed matrices and sulfonic chitosan matrices were prepared for copper ion adsorption process. Ion exchange resins (Amberjet 1200H, Rohm & Haas) were incorporated into the stereo structure of chitosan matrices to fabricate chitosan mixed matrices. The porous structure of chitosan matrices could make the copper ion solution flowing though the matrices. The copper ions would be easily caught by the amino groups of chitosan matrices or sulfonic groups of ion exchange resins. The specific surface area of chitosan mixed matrices are 72.2
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Book chapters on the topic "Sulfonium ion"

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Shapiro, Stanley K., and Fritz Schlenk. "The Biochemistry of Sulfonium Compounds." In Advances in Enzymology - and Related Areas of Molecular Biology. John Wiley & Sons, Inc., 2006. http://dx.doi.org/10.1002/9780470122679.ch6.

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Ratti, Simona, and Mario Giordano. "Allocation of Sulfur to Sulfonium Compounds in Microalgae." In Sulfur Assimilation and Abiotic Stress in Plants. Springer Berlin Heidelberg, 2008. http://dx.doi.org/10.1007/978-3-540-76326-0_15.

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Csapó, J., I. Tóth-Pósfai, and Z. S. Csapó-Kiss. "Separation of D- and L-amino acids by ion exchange column chromatography in the form of 2-sulfonic acid alanyl dipeptides." In Amino Acids. Springer Netherlands, 1990. http://dx.doi.org/10.1007/978-94-011-2262-7_12.

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Winkelmann, Jochen. "Diffusion coefficient of 1-amino-2-naphthol-4-sulfonic acid in water." In Diffusion in Gases, Liquids and Electrolytes. Springer Berlin Heidelberg, 2018. http://dx.doi.org/10.1007/978-3-662-54089-3_886.

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Siems, Werner, Tilman Grune, Andreas Werner, Gerhard Gerber, Peter Buntrock, and Wolfram Schneider. "Influence of Oxypurinol on Colitis Induced in Rat Colon by Trinitrobenzene Sulfonic Acid Treatment." In Advances in Experimental Medicine and Biology. Springer US, 1991. http://dx.doi.org/10.1007/978-1-4899-2638-8_83.

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Sirsam, Rajkumar, and Ghayas Usmani. "Esterification of Ethanol and Maleic Acid in Packed Bed Reactor Catalyzed by Sulfonic Acid Functionalized Silica (SAFS)." In Recent Advances in Chemical Engineering. Springer Singapore, 2016. http://dx.doi.org/10.1007/978-981-10-1633-2_5.

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Bhikhabhai, Rama, Mattias Algotsson, Ulrika Carlsson, et al. "Amino Acid Sequencing of Sulfonic Acid-Labeled Tryptic Peptides Using Post-Source Decay and Quadratic Field MALDI-ToF Mass Spectrometry." In Methods in Proteome and Protein Analysis. Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/978-3-662-08722-0_19.

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Wang, Qian, Marlon Lutz, Matthew Reichert, Daniel P. Becker, and M. Paul Chiarelli. "Chapter 12. New Analytical Approaches for the Detection of Micropollutants in Natural Waters: Identification of 3,5-Dichloro-4-Hydroxybenzene Sulfonic Acid as an Unknown Persistent Pollutant." In Comprehensive Series in Photochemical & Photobiological Sciences. Royal Society of Chemistry, 2015. http://dx.doi.org/10.1039/9781782622154-00239.

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Tokitoh, N., and W. Ando. "Addition of a Sulfonium Ion to Alkynes." In Fully Unsaturated Small-Ring Heterocycles and Monocyclic Five-Membered Hetarenes with One Heteroatom. Georg Thieme Verlag KG, 2001. http://dx.doi.org/10.1055/sos-sd-009-00039.

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Fringuelli, F., and O. Piermatti. "Rearrangement of Sulfonium and Ammonium Ylides." In Water in Organic Synthesis. Georg Thieme Verlag KG, 2012. http://dx.doi.org/10.1055/sos-sd-206-00340.

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Conference papers on the topic "Sulfonium ion"

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Lu, Yi Heng, Shuang Chun Ma, Ying Chen, and Wen Quan Feng. "Perfluorinated sulfonic acid ion-exchange membrane doped silicotungstic acid thermal stability and conductivity." In 2015 International Conference on Advanced Engineering Materials and Technology. Atlantis Press, 2015. http://dx.doi.org/10.2991/icaemt-15.2015.139.

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Fuchiwaki, Masaki, Kazuhiro Tanaka, and Keiichi Kaneto. "Planate Conducting Polymer Actuator and Its Application." In ASME 2006 2nd Joint U.S.-European Fluids Engineering Summer Meeting Collocated With the 14th International Conference on Nuclear Engineering. ASMEDC, 2006. http://dx.doi.org/10.1115/fedsm2006-98486.

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We propose a planate conducting polymer actuator which can transform only its central part locally and a micro pump using its actuator as a drive source. We have developed a planate conducting polymer actuator based on polypyrrole and two types of acids, such as p-phenol sulfonic acid and dodecylbenzene sulfonic acid, by electrodeposition. Its structure was patterned bimorph structure with anion-driven, cation-driven and bimorph layers. The planate conducting polymer actuator could deform only its central part locally. And, we have proposed a micro pump using the planate conducting polymer act
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Yang, Ren, Steven Soper, and Wanjun Wang. "A New Negative-Tone, UV Lithography Photoresist for Fabrication of Ultra-High-Aspect-Ratio Microstructures." In ASME 2006 International Mechanical Engineering Congress and Exposition. ASMEDC, 2006. http://dx.doi.org/10.1115/imece2006-14713.

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We report a new type of negative-tone photoresist in this paper. The resist is based on the composite of EPON resins 154 165 (both from Hexion Specialty Chemicals, Inc., Columbus, OH 43215). These two epoxy resins were mixed in an optimal ratio and dissolved into the gamma-butyrolactone (GBL) solvent. The mixture was then photosensitized by adding a given amount of triaryl sulfonium salt to obtain the new negative tone photoresist that can be used in for ultra high aspect ratio microstructures with UV lithography. The preliminary study has found that microstructures with height of more than 10
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Li, Fenggang, Peng Yan, Caixia Ju, et al. "The Influence of Environment on the Hydrous Ferric Oxide Composite Resin Adsorption of -Naphthalene Sulfonic Acid." In International Conference on Advances in Energy, Environment and Chemical Engineering. Atlantis Press, 2015. http://dx.doi.org/10.2991/aeece-15.2015.165.

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Ionita, Mariana. "Molecular Modeling for Calculation of Mechanical Properties of Polyaniline-Carbon-Nanotubes." In ASME 2010 10th Biennial Conference on Engineering Systems Design and Analysis. ASMEDC, 2010. http://dx.doi.org/10.1115/esda2010-24833.

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Atomistic models of polyaniline (PANI)-single walled carbon nanotubes (CNTs) were built in order to assess the effect of quantity and quality of CNTs and temperature on the calculated mechanical properties of PANI. Three different types of CNTs were considered: single walled carbon nanotubes m-polyaminobenzene sulfonic acid functionalized (CNTs-PABS), single walled carbon nanotubes octadecylamine functionalized (CNTs-ODA) and single walled carbon nanotubes carboxylic acid functionalized (CNTs-CX). Atomistic models were built for PANI-functionalized CNTs with a range of CNTs content, contained
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Chen, Peng-Yu, Wei-Hui Chen, and Che-Wun Hong. "Nanofludic Analysis on Methanol Crossover of Direct Methanol Fuel Cells." In ASME 2008 First International Conference on Micro/Nanoscale Heat Transfer. ASMEDC, 2008. http://dx.doi.org/10.1115/mnht2008-52095.

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Direct methanol fuel cells (DMFCs) are considered as a competitive power source candidate for portable electronic devices. Nafion® has been widely used for the electrolyte of DMFCs because of its good proton conductivity and high chemical and mechanical stability. However, the major problem that must be solved before commercialization is the high methanol crossover through the membrane. There are a number of studies on experiments about the methanol crossover rate through the membrane but only few theoretical investigations have been presented [1–3]. In this paper, an atomistic model [4] is pr
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Shahinpoor, Mohsen. "Smart Thin Sheet Batteries Made With Ionic Polymer Metal Composites (IPMC’s)." In ASME 2004 International Mechanical Engineering Congress and Exposition. ASMEDC, 2004. http://dx.doi.org/10.1115/imece2004-60954.

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Presented is some experimental results and theoretical modeling pertaining to thin (30 microns) paper-like sheets of ionic polymer metal composites (IPMC’s) as paper batteries. These materials can generate electrical power by means of mechanical flexing, normal pressure and motion in general and they are smart because they are self-powered but rechargeable by moisture. Thin sheets or paper-like labels of IPMC’s can be bonded, glued or attached to any flexible or rigid substrate or can be laminated and can generate power by the motion of that substrate or any normal or oblique pressure exerted
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Berechet, Mariana Daniela, Demetra Simion, Maria Stanca, et al. "Antibacterial and antioxidant activities of lemon balm (Melissa officinalis L.) essential oil." In The 8th International Conference on Advanced Materials and Systems. INCDTP - Leather and Footwear Research Institute (ICPI), Bucharest, Romania, 2020. http://dx.doi.org/10.24264/icams-2020.ii.2.

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Lemon balm (Melissa officinalis L.) belongs to the Lamiaceae family. Essential oil extracted from the aerial parts of lemon balm has been investigated for the protection of fruits during storage, as insecticidal, as well as in medicine, due to its bioactive properties. In this paper, the composition and identification of components from Melissa officinalis L. essential oil were determined by gas chromatography coupled with mass spectrophotometry (GC/MS) analysis. Total phenol content (TPC) and the scavenging activity towards 2,2-diphenyl-1-picrylhydrazyl (DPPH·) and 2,2′-azino-bis (3-ethylbenz
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Artemev, Alexandr, Elena Veselova, Irina Nikitina, and Galina Viktorovna. "RECOVERY OF NEPHELINE FROM APATITE FLOTATION TAILINGS OF APATITE-NEPHELINE COMPLEX MINERAL COMPOSED ORES." In GEOLINKS Conference Proceedings. Saima Consult Ltd, 2021. http://dx.doi.org/10.32008/geolinks2021/b2/v3/19.

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"The recovery of all possible useful components from ores corresponds to modern approach to the mineral raw materials processing and provides a reduction in the amount of waste sent to tailings dumps. The increasing complexity of the mineral composition of the ore leads to the fact that the existing beneficiation methods and regimes do not provide the necessary quality of the obtained concentrates. This study shows the peculiarities of nepheline recovery from apatite flotation tailings of apatite-nepheline ores with low nepheline fraction. Two reagent regimes were tested for nepheline reverse
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Wysocki, Sławomir, Rafał Wiśniowski, and Magdalena Gaczoł. "New Drilling Muds for Drilling in Clay Rocks." In ASME 2017 36th International Conference on Ocean, Offshore and Arctic Engineering. American Society of Mechanical Engineers, 2017. http://dx.doi.org/10.1115/omae2017-61476.

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The paper describes studies on the development of the new formulas of water-based drilling mud for drilling in clays and shales. The research were undertaken as a part of the OPTIDRILTEC project. First stage of the project included studies related to selection of ionic inhibitors of hydration. The tests of inorganic agents with various concentrations influence on technological parameters of the developed drilling muds was undertaken. The disintegration and linear swelling tests under influence of developed muds with different ionic inhibitors were conducted on the rock samples. Miocene shale w
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Reports on the topic "Sulfonium ion"

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Wagener, Ken. Precision Morphology in Sulfonic, Phosphonic, Boronic, and Carboxylic Acid Polyolefins. Defense Technical Information Center, 2013. http://dx.doi.org/10.21236/ada606523.

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Litt, Morton. Poly(p-Phenylene Sulfonic Acids). PEMs with frozen-in free volume. Office of Scientific and Technical Information (OSTI), 2016. http://dx.doi.org/10.2172/1236792.

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