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Relevant bibliographies by topics / Sulfonyl azide

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Academic literature on the topic 'Sulfonyl azide'

Author: Grafiati

Published: 3 June 2025

Last updated: 31 July 2025

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Journal articles on the topic "Sulfonyl azide"

1

Weidner, Karin, and Philippe Renaud. "Kinetic Study of the Radical Azidation with Sulfonyl Azides." Australian Journal of Chemistry 66, no. 3 (2013): 341. http://dx.doi.org/10.1071/ch12523.

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Rate constants for the reaction between a secondary alkyl radical and two different sulfonyl azides were determined using bimolecular competing radical reactions. The rates of azidation were determined by competition with hydrogen atom transfer from tris(trimethylsilyl)silane ((TMS)3SiH) of the 4-phenylcyclohexyl radical. 3-Pyridinesulfonyl azide and trifluoromethanesulfonyl azide were found to have rate constants for azidation of 2 × 105 M–1 s–1 and 7 × 105 M–1 s–1 at 80°C, respectively.

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Līpiņš, Dāgs Dāvis, Andris Jeminejs, Una Ušacka, Anatoly Mishnev, Māris Turks, and Irina Novosjolova. "Regioselective quinazoline C2 modifications through the azide–tetrazole tautomeric equilibrium." Beilstein Journal of Organic Chemistry 20 (March 28, 2024): 675–83. http://dx.doi.org/10.3762/bjoc.20.61.

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2-Chloro-4-sulfonylquinazolines undergo functional group swap when treated with an azide nucleophile: 1) the azide replaces the sulfonyl group at the C4 position; 2) the intrinsic azide–tetrazole tautomeric equilibrium directs the nucleofugal sulfinate from the first step to replace chloride at the C2 position. This transformation is effective with quinazolines bearing electron-rich substituents. Therefore, the title transformations are demonstrated on the 6,7-dimethoxyquinazoline core, which is present in pharmaceutically active substances. The methodology application is showcased by transfor

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3

Zhou, Bingwei, Yunkui Liu, Hongwei Jin, and Daohong Liu. "One-Pot Copper-Catalyzed Three-Component Reaction of Sulfonyl Azides, Alkynes, and Allylamines To Access 2,3-Dihydro-1H-imidazo[1,2-a]indoles." Synthesis 52, no. 09 (2020): 1417–24. http://dx.doi.org/10.1055/s-0037-1610739.

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A copper-catalyzed multicomponent reaction of sulfonyl azides, alkynes, and allylamines affording 2,3-dihydro-1H-imidazo-[1,2-a]indoles in moderate yields is reported. Four C–N bonds are constructed by way of azide-alkyne cycloaddition (CuAAC) and double Ullmann-type coupling reactions in a one-pot process.

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4

Van Hoof, Max, Santhini Pulikkal Veettil, and Wim Dehaen. "The Three-Component Synthesis of 4-Sulfonyl-1,2,3-triazoles via a Sequential Aerobic Copper-Catalyzed Sulfonylation and Dimroth Cyclization." Molecules 26, no. 3 (2021): 581. http://dx.doi.org/10.3390/molecules26030581.

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4-Sulfonyl-1,2,3-triazole scaffolds possess promising bioactivities and applications as anion binders. However, these structures remain relatively unexplored and efficient synthetic procedures for their synthesis remain desirable. A practical room-temperature, aerobic copper-catalyzed three-component reaction of aromatic ketones, sodium sulfinates, and azides is reported. This procedure allows for facile access to 4-sulfonyl-1,5-disubstituted-1,2,3-triazoles in yields ranging from 34 to 89%. The reaction proceeds via a sequential aerobic copper(II)chloride-catalyzed oxidative sulfonylation and

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5

Ottenbruch, Moritz, Fabian Mohr, and Stefan F. Kirsch. "Synthesis of Sulfonylisoureas via Sulfo-Click Reactions." Synthesis 52, no. 05 (2019): 695–702. http://dx.doi.org/10.1055/s-0039-1691505.

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The synthesis of sulfonylisoureas from thiocarbamates and sulfonyl azides via a new variant of the sulfo-click reaction is reported. Water was found to be the environmentally benign solvent of choice over various other solvents tested, and the use of any additives was not required to obtain complete conversion. The experimentally simple reaction tolerates a broad range of electron-donating and electron-withdrawing substituents attached on both the thiocarbamate and the sulfonyl azide, as shown with the synthesis of 27 sulfonylisoureas that were prepared in yields ranging from 34% to 78%.

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6

Fomich, Maksim. "Imidazole-1-sulfonyl Azide Hydrochloride." Synlett 25, no. 15 (2014): 2229–30. http://dx.doi.org/10.1055/s-0034-1378535.

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7

Moses, John, and Andrew Barrow. "Synthesis of Sulfonyl Azides via Lewis Base Activation of Sulfonyl Fluorides and Trimethylsilyl Azide." Synlett 27, no. 12 (2016): 1840–43. http://dx.doi.org/10.1055/s-0035-1561626.

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8

Yang, Dong, Jingqi Shi, Jiaming Chen, et al. "Visible-light enabled room-temperature dealkylative imidation of secondary and tertiary amines promoted by aerobic ruthenium catalysis." RSC Advances 11, no. 31 (2021): 18966–73. http://dx.doi.org/10.1039/d0ra10517a.

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9

Sun, Jiarui, Xiangsheng Cheng, John Kamanda Mansaray, Weihong Fei, Jieping Wan та Weijun Yao. "A copper-catalyzed three component reaction of aryl acetylene, sulfonyl azide and enaminone to form iminolactone via 6π electrocyclization". Chemical Communications 54, № 99 (2018): 13953–56. http://dx.doi.org/10.1039/c8cc06868b.

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We developed a copper-catalyzed three component reaction of aryl acetylene, enaminone and sulfonyl azide to construct iminolactone via copper-catalyzed alkyne–azide cycloaddition (CuAAC), Michael addition of metalated ketenimine followed by elimination and 6π electrocyclization.

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10

Zielińska, A. J., J. W. M. Noordermeer, A. G. Talma, R. Peters, and M. Van Duin. "CROSS-LINKING OF SATURATED ELASTOMERS WITH DI-AZIDES. PART II: MECHANISTIC STUDY." Rubber Chemistry and Technology 84, no. 2 (2011): 258–72. http://dx.doi.org/10.5254/1.3577546.

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Abstract In the first part, one di-sulfonyl azide: 1,3BDSA, and two di-azidoformates: GDAF and 4,4′DAF, were selected and extensively investigated as curing agents for EP(D)M rubbers. Although the mechanical properties of the vulcanizates vary significantly with the particular di-azide used, all of them act as effective curing agents compared to a peroxide/coagent curing system. To explain the differences in properties as well as to obtain a deeper understanding of the reaction mechanism, model compound experiments are performed with 4-methylheptane as substitute for the saturated ethylene–pro

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Dissertations / Theses on the topic "Sulfonyl azide"

1

Dobosh, Brian Joseph. "The Synthesis of Azides from Alcohols using Sulfonyl Azides." Youngstown State University / OhioLINK, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1219459733.

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Dobosh, Brian J. "The synthesis of azides from alcohols using sulfonyl azides /." Connect to resource online, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1219459733.

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3

Funakoshi, Yuuta. "Synthesis of Nitrogen-Containing Compounds from Terminal Alkynes and Sulfonyl Azides via N-Sulfonyl-1,2,3-triazoles." Kyoto University, 2017. http://hdl.handle.net/2433/227636.

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Stevens, Marc. "Multicomponent Reactions in 11C/12C Chemistry : – Targeting the Angiotensin II Subtype 2 Receptor." Doctoral thesis, Uppsala universitet, Institutionen för läkemedelskemi, 2016. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-295436.

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Section 1 of this thesis contains an introduction to method development in organic synthesis, multicomponent reactions, sulfonyl azides, tracer development in 11C chemistry and the biological target. Section 2 describes the use of sulfonyl azides in carbonylative chemistry. Paper I covers development of a diazotransfer protocol. In total, 30 arylsulfonyl azides were synthesised from primary sulfonamides (20–90% yield). 15N mechanistic studies were carried out and in Paper II, the products were converted into sulfonamides, sulfonylureas and sulfonyl carbamates (19–90% yield). For ureas and carb

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Book chapters on the topic "Sulfonyl azide"

1

Taber, Douglass. "The Carter Synthesis of (-)-Lycopodine." In Organic Synthesis. Oxford University Press, 2011. http://dx.doi.org/10.1093/oso/9780199764549.003.0099.

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Rich G. Carter of Oregon State University described (J. Am. Chem. Soc. 2008, 130, 9238) the first enantioselective synthesis of the Lycopodium alkaloid (-)-lyopodine 3. A key step in the assembly of 3 was the diastereoselective intramolecular Michael addition of the keto sulfone of 1 to the enone, leading to the cyclohexanone 2. The key cyclization substrate 1 bore a single secondary methyl group. While that could have been derived from a natural product, it was operationally easier to effect chiral auxiliary controlled conjugate addition to the crotonyl amide 4, leading, after methoxide excha

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2

Chemla, F., F. Ferreira, and A. Pérez-Luna. "From Sulfonyl Azides." In Heteroatom Analogues of Aldehydes and Ketones. Georg Thieme Verlag KG, 2012. http://dx.doi.org/10.1055/sos-sd-127-00201.

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Burton, J. W. "From Sulfonyl Azides." In Compounds of Groups 15 (As, Sb, Bi) and Silicon Compounds. Georg Thieme Verlag KG, 2002. http://dx.doi.org/10.1055/sos-sd-004-00109.

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Potter, Garrett T., Gordon C. Jayson, John M. Gardiner, Lorenzo Guazelli, and Gavin J. Miller. "Synthesis of 1,3,4,6-Tetra-O-acetyl-2-azido-2-deoxy-α,β-d-glucopyranose Using the Diazo-Transfer Reagent Imidazole-1-sulfonyl Azide Hydrogen Sulfate." In Carbohydrate Chemistry. CRC Press, 2017. http://dx.doi.org/10.1201/9781315120300-18.

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Drabowicz, J., P. Kiełbasiński, P. Łyżwa, A. Zając, and M. Mikołajczyk. "Reduction of Sulfonyl Azides." In Sulfur, Selenium, and Tellurium. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-039-00126.

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Tomé, A. C. "From Enaminones and Sulfonyl Azides." In Five-Membered Hetarenes with Three or More Heteroatoms. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-013-00640.

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Tomé, A. C. "Addition of Sulfonyl Azides to Alkynes." In Five-Membered Hetarenes with Three or More Heteroatoms. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-013-00670.

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8

Wolkenberg, S. E., and R. M. Garbaccio. "Electrophilic Amination of Chiral Enolates Using Sulfonyl Azides." In Three Carbon-Heteroatom Bonds: Acid Halides; Carboxylic Acids and Acid Salts. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-020-00372.

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9

Aitken, R. A., and K. M. Aitken. "Using Sulfones." In Nitro, Nitroso, Azo, Azoxy, and Diazonium Compounds, Azides, Triazenes, and Tetrazenes. Georg Thieme Verlag KG, 2010. http://dx.doi.org/10.1055/sos-sd-041-00301.

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10

Aitken, R. A., and K. M. Aitken. "Desulfonylation of Nitro Sulfones." In Nitro, Nitroso, Azo, Azoxy, and Diazonium Compounds, Azides, Triazenes, and Tetrazenes. Georg Thieme Verlag KG, 2010. http://dx.doi.org/10.1055/sos-sd-041-00268.

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